• Journal of Magnetics
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• v.1 no.2
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• pp.55-56
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• 1996

The effective magnetic moment of Cr$_2$O$_3$is determined by assuming that a proportional relation holds between its moment and the effective magnetic moment of hematite determined by the previous derived relaxation expression and the moments of Fe3+ ion and Cr3+ ion. The result obtained from the relation is found to be given by 0.10 in Bohr magneton which is in good agreement with the value obtained by use of the expression.

• Journal of the Korean Magnetics Society
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• v.4 no.3
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• pp.282-284
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• 1994

A theoretical expression for determining the effective magnetic moment of hematite(${\alpha}-Fe_{2}O_{3}$) particle of the parasitic ferromagnetism by the proton relaxation in water is derived. In deriving the expression it is found that the mathematical procedures are exactly the same as those applied for aqueous solutions containing free paramagnetic ions, except that the distance between the proton spin of water molecule and the corresponding electronic spin of the particle must be considered to be a radius vector rather than a relative distance. And it is also found that the average effective magnetic moment of the particle calculated by the expression is in good agreement with the experimental value determined by Hirai.

• Journal of the Korean Institute of Electrical and Electronic Material Engineers
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• v.23 no.6
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• pp.444-448
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• 2010

Based on first-principles calculations, we study the magnetic properties of Co, Ni, Fe, V, and Mn impurities in ZnO. The stabilities of the ferromagnetic state and the magnetic moment of each impurity largely depend on the amount of doped electron or hole. For lightly doped n-type ZnO, it is found that the doping of Ni ions is the most effective for inducing ferromagnetism, while Fe ions show the most stable ferromagnetic couplings for heavily doped n-type samples. The characteristics of the magnetic interactions of Co ions are similar with those of Fe ions, but Co ions require much larger amount of doped electron than Fe ions to show the ferromagnetic couplings. The ferromagnetic coupling between Mn and V ions is unstable in n-type conditions.

• Journal of Magnetics
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• v.21 no.1
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• pp.20-24
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• 2016

Magnetic properties of bio-magnetic molecule ferritin have been investigated. Two ferritin samples were synthesized under different magnetic fields, 0 and 9.4 T, respectively. This work is focused on the influence of magnetic field on biomineralization process. While magnetization vs. temperature (M-T) data of both samples measured at 1000 Oe are almost identical except for low temperature region (T < 6 K), magnetization vs. field (M-H) data show noticeable difference. From an analysis of M-H data by using a modified Langevin function, we could extract the saturation magnetization $m_0$(T), the effective magnetic moment ${\mu}_{eff}$(T) and the linear susceptibility x(T). The difference between the samples is most prominent in the x(T), whereby the x(T) of the sample prepared at 9.4 T is 1.7 times bigger than that of the other. In addition, from hysteresis and relaxation measurements, we found the sample prepared at 9.4 T showed strikingly smaller coercivity and slower relaxation.

• Proceedings of the Polymer Society of Korea Conference
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• 2006.10a
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• pp.23-24
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• 2006

Magnetic and magneto-optical properties of regioregular (>99%) poly(3-dodecylthiopenes are investigated. Faraday rotation of spin-coated films show extremely large Verdet constants, falling strongly with decreasing regioregularity. EPR spectroscopy at room temperature shows the presence of about 1 spin/190 monomers, indicative of delocalisation beyond a single polymer chain. SQUID measurements on the polymer give an effective magnetic moment of about 48900 mB, corrsponding to a S-value of 25.000. The Weiss-constant is 1.33 K indicating ferromagnetic coupling. Our experimental results show that organic polymer magnets can be prepared. Large MO effects allow the use of these materials in all-organic MO-sensors and devices.

• Bulletin of the Korean Chemical Society
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• v.16 no.7
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• pp.600-603
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• 1995

A series of samples in the Sm1-xSrxCoO3-y(x=0.00, 0.25, 0.50, 0.75 and 1.00) system has been prepared at 1200 ℃ under ambient atmosphere. The X-ray diffraction patterns of the samples with x=0.00 and 0.25 are indexed with orthorhombic symmetry like GdFeO3 and x=0.50 appears to be perfectly cubic. In the tetragonal system (x=0.75), the structure is similar to that of SrCoO2.80. The composition of x=1.00, SrCoO2.52, shows the brownmillerite-type structure. The reduced lattice volume is increased with x value in this system. The chemical analysis shows the τ value (the amount of the Co4+ ions in the system) is maximized at the composition of x=0.50. Nonstoichiometric chemical formulas are determined by the x, τ and y values. The electrical conductivity has been measured in the temperature range of 78 to 1000 K. The activation energy is minimum for those of x=0.25 and x=0.50 with metallic behavior. First-order semiconductor-to-metal transition of SmCoO3 is not observed. Instead, a broad, high-order semiconductor-to-metal transition is observed. In general, the effective magnetic moment is increased with increasing τ values at low temperature. At high temperature, the magnetic moment is maximum for that of x=0.00. The 3d-electrons are collective and give ferromagnetism in x=0.50.

• Korean Journal of Materials Research
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• v.4 no.6
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• pp.704-709
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• 1994

The $(LaS)_xCrS_2(x \approx 1.20$) of the incommensurate misfit layer was systhesized from reactant mixture of$La_S_3$,Cr and S at 1273K. Powder X-ray diffration of $(LaS)_xCrS_2(x \approx 1.20$) was indexed as a complex structure consisted with a monoclinic LaS-sublattice, a triclinic $CrS_{2}$-sublattice and their superlattice. The temperature dependence of sublattice dimension was investigated by the X-ray diffraction analysis at low temperature. The magnetic susceptibility of $(LaS)_xCrS_2(x \approx 1.20$) was measured between 77K and room temperature using a Faraday balance method. $(LaS)_xCrS_2(x \approx 1.20$) was paramagnetic on a $\sigma$-H plot at room temperature. The observed effective magnetic moment( p dr) was in fair agreement with the value calculated by spin-only contribution for $Cr^{3+}$ and spin and orbital contribution for $La^{3+}$.

• Journal of the Korean Ceramic Society
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• v.22 no.3
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• pp.25-28
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• 1985

The new compound $(Ba_{0.5}La_{0.5}) (Mg_0.5}Mo_{0.5})O_3$ is synthesized under the $H_2$-atmosphere and reveals to have a cation ordering between Mg and Mo in cubic lattic of ordered perovskite (a0=8.009(2)$\AA$) and obeys Curie-Weiss law below the room temperature with the effective magnetic moment of 1.60(5) Bohr Magneton.

• Journal of the Korean Magnetics Society
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• v.5 no.5
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• pp.753-757
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• 1995

Systematic studies on the crystal structure and magnetic properties of light rare earth element(RE) compounds with Pb, $REPb_{2}$, have been carried out. Their crystal structure has been identified to be a $MoSi_{2}$-type. The values of the effective magnetic moment for $CePb_{2},\;PrPb_{2}\;and\;NdPb_{2}$ are respectively very close to the theoretical values of $RE^{3+}$. These three compounds are antiferromagnetic and exhibit a metamagnetic transition. The magnitude of the Neel temperature is proportional to two-thirds of the de Gennes factor. The magnetic entropy change for $NdPb_{2}$ is contrast to the value for $CePb_{2}$ heavy-fermion compound, comparable to the theoretical value. The magnetic contribution to the temperature dependence of resistivity for $PrPb_{2}$ is given by a form of -lnT in a wide temperature range, implying the Kondo system in analogy with $Cepb_{2}$.

• Journal of the Korean Magnetics Society
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• v.16 no.5
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• pp.261-263
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• 2006

In order to investigate the magnetic properties of Eu ions in the single crystal $MnF_2$, the temperature dependent magnetic susceptibilities of the antiferromagnetic $MnF_2$ and the single crystal $MnF_2$(1.5% $EuF_3$) with the rutile structures were measured in the temperature range from 4K to 300K. The detailed analysis of the measured susceptibilities showed that the magnetic susceptibility by the doping of the small amount $EuF_3$ in the antiferromagnetic single crystal $MnF_2$ follows the antiferromagnetic Curie-Weiss law with the negative paramagnetic Curie temperature similarly as in $MnF_2$. It was also found that Eu ion has +3 valence. This solves the long standing discrepancy on this problem.