• Journal of the Korea Institute of Building Construction
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• v.17 no.3
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• pp.279-285
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• 2017

In this study, the development of concrete preventing initial frost damage and durability about that were evaluated by using anti-aging agent and admixture(reduced slag). As a result of experiment, initial hydration heat was increased by $C_{12}A_7$ of reduced slag components but it was not effective to development of strength. Also fluidity decreased with increasing replacement of reduced slag. This suggested that fluidity was low by rapid setting due to absent of gypsum in reduced slag components. In case of CR2G specimen that added 4% gypsum, the flow ability was higher than plain. It is considered that concrete developed using reduced slag should use $SO_3$. Result of durability experiments, the durability decreased with increasing replacement amount of reduced slag.

• Advances in concrete construction
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• v.6 no.1
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• pp.69-85
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• 2018

In order to provide sufficient stability and resistance against bleeding and segregation during transportation and placing, mineral admixtures are often used in self-compacting concrete mixes (SCC). These fine materials also contribute to reducing the construction cost and the consumption of natural resources. Many studies have confirmed the benefits of these mineral admixtures on properties of SCC in standard curing conditions. However, there are few published reports regarding their effects at elevated curing temperatures. The main objective of this study is to investigate the effect of three different mineral admixtures namely limestone powder (LP), granulated blast furnace slag (GS) and natural pozzolana (PZ) on mechanical properties and porosity of SCC when exposed to different curing temperatures (20, 40, 60 and $80^{\circ}C$). The level of substitution of cement by mineral admixture was fixed at 15%. The results showed that increasing curing temperature causes an improvement in performance at an early age without penalizing its long-term properties. However the temperature of $40^{\circ}C$ is considered the optimal curing temperature to make economical and high performance SCC. On the other hand, GS is the most suitable mineral admixture for SCC under elevated curing temperature.

• Proceedings of the Korean Geotechical Society Conference
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• 2009.03a
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• pp.58-63
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• 2009

Biaxial compression test was conducted on a transversely isotropic synthetic jointed rock model for the understanding of the fracture behaviors of a sedimentary or metamorphic rocks with well developed bedding or foliation in uni-direction. The joint angles employed for the model are 30, 45, and 60 degrees to the horizontal, and the synthetic rock mass was made of early strength cement. From the biaxial compression test, initiation propagation of tensile cracks at norm to the joint angle was found. The propagated tensile cracks eventually developed rock blocks, which was dislodged from the rock mass. Furthermore, the propagation process of the tensile cracks varies with joint angle: lower joint angle model shows more stable and progressive tensile crack propagation. The experiment results were validated from the simulation by using discrete element method PFC 2D. From the simulation, as has been observed from the test, a rock mass with lower joint angle produces wider damage region and rock block by tensile cracks. In addition, a rock model with lower joint angle shows a progressive tensile cracks generation around the opening from the investigation of the interacted tensile cracks.

• Journal of the Korea Concrete Institute
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• v.15 no.3
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• pp.497-503
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• 2003

Supplementary cementitious materials (SCM) such as fly ash, ground granulated blast furnace slag and silica fume are now being extensively used in concrete to control expansion due to alkali-silica reactivity (ASR). However, the replacement level of a single SCM needed to deleterious ASR expansion and cracking may create other problem and concerns. For example, incorporating silica fume at levels greater than 10％ by mass of cement may lead to dispersion and workability concerns, while fly ash can lead to poor strength development at early age, The combination of silica fume and fly ash in ternary cementitious system may alleviate this and other concerns, and result in a number of synergistic effects. The aim of the study was to enable evaluation of more realistic suitability of a silica fume-fly ash combination system for ASR resistance based on an in-house modification of ASTM C 1260 test method. The modification can be more closely identified with actual field conditions. In this study three different strengths of NaOH test solution(1N, 0.5N, and 0.25N) were used to measure the expansion characteristics of mortar bar made with a reactive aggregate. The other variable included longer testing period of 28 days instead of a conventional 14 days.

• Journal of the Korean Ceramic Society
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• v.44 no.9
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• pp.517-523
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• 2007

For the preparation of tricalciumaluminate $(C_3A)$ clinker, in traditional clinkering method using oxides and carbonates as a raw material, uneconomical repetition of burning have been necessary to avoid the melting of clinker by eutectic reaction in the system $CaO-Al_2O_3$. In this study, special starting raw materials for the clinker burning were prepared from a mixture of oyster shell and aluminium hydroxide by heating to $1100^{\circ}C$ and hydrating at $30^{\circ}C$. The starting raw materials, hardened body with weak hydraulic strength, were mainly composed of $C_3AH_6$ formed by resolution-precipitation mechanism of the system $CaO-Al_2O_3-H_2O$. By heating them, relatively pure $C_3A$ clinker could be obtained by one-time burning at the fairly lower temperature than that of conventional method. The easier formation of $C_3A$ clinker seemed to be caused by higher compositional homogeneity and stoichiometry of the starting materials, high surface area and crystallographic instability of the thermally decomposed products, and the catalytic effect of decomposed moisture on the early-stage crystallization of calciumaluminates. The basic hydration behavior of the clinker was also confirmed.

• Journal of the Korea Concrete Institute
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• v.16 no.6 s.84
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• pp.805-811
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• 2004

In this paper, effects of mixture proportion and material condition on both fundamental properties, drying and autogenous shrinkage of high performance concrete are discussed. According to the results, for the effect of mixture proportion on the fundamental properties, decrease in W/B and unit water content results in reduction of fluidity, while air content has no variation. Compressive strength exhibits an decreasing tendency with an increase in W/B and unit water content do not remarkable affect the compressive strength. For the effect of materials on the fluidity, the fluidity of low heat portland cement(LPC) is smaller than that of ordinary portland cement(OPC). The use of Polycarbonic acid based superplasticizer(PS) has more favorable effect on enhancing fluidity than Naphtalene based superplasticlzer(NS) and Melamine based superplasticizer(MS). Air content of concrete using LPC is larger than that using OPC. The effects of superplasticizer type on the air content is larger in order of MS, PS and NS. The use of LPC exhibited lower strength development at early age than OPC, whereas after 91days, similar level of compressive strength is achieved regardless of cement type. Compressive strength of concrete is not affected by SP type. For the effect of mixture proportion and materials on drying and autogenous shrinkage, an increase in W/B results in reduction of drying shrinkage and an decrease in water content leads to reduce drying shrinkage. Autogenous shrinkage is not observed until 49 days with the concrete mixture with $35\%$ of W/B and $145 kg/m^3$ of water content. This is due to the combination effects of expansion admixture and shrinkage reducing admixture, which causes an offset of autogenous shrinkage. The use of LPC results in a reduction in autogenous shrinkage compared with OPC. SP type has little influence on the autogenous shrinkage. It is found from the results that mixture proportioning of high performance concrete incorporating fly ash, silica fume, expansion admixture and shrinkage reducing admixture is need to focus on the increase in W/B and the reduction in water content and the use of LPC and MS is also required to use to secure the stability against shrinkage properties.

• Journal of the Korea Concrete Institute
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• v.14 no.6
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• pp.942-948
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• 2002

When fresh concrete is exposed to low temperature, the concrete may suffer frost damage due to freezing at early ages and the strength development may be delayed. One of the solution methods to resolve these problems is to reduce freezing temperature of concrete by the use of chemical admixture called Accelerator for freeze protection. In this study we Investigate the effect on the strength development of cement mortar using accelerator for freeze protection with the variable curing condition. As the result of this study, the mortar using accelerator for freeze protection show continuously the strength development in curing condition of -5$^{\circ}C$. And the compressive strength under variable temperature condition was higher than constant temperature condition in same maturity.

• Journal of the Korean Ceramic Society
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• v.45 no.11
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• pp.734-738
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• 2008

Ettringite$(3CaO{\cdot}Al_2O_3{\cdot}3CaSO_4{\cdot}32H_2O)$, one of the hydrated phase of Portland cement is usually formed in the early stage of hydration by the reaction of tricalciumaluminate$(C_3A)$ and gypsum. The rapid and strong crystal growth of separated rod-shaped ettringite have been utilized for the preparation of special cements of rapid setting, high strength and non-shrinking properties. The ettringite also has been noticed as a promising materials for the immobilization of various waste ions because of its unique crystal structure which has abundant channels and exchangeable ionic compounds. In this study, the formation and growth behavior of the ettringite was investigated in the system $C_3A-CaSO_4-H_2O$ using $C_3A$ clinker and gypsum to obtain a microporous body for waste ion immobilization. Ettringite was revealed to form by the dissolution-precipitation mechanism and the bulk body was by the entangled growth of rod-shaped ettringite crystals. The hardened body was composed of nearly pure rod-shaped ettringite interlocked each other with adequate mechanical strength. The homogeneity of structure, pore size, specific surface area and porosity of the hardened body were influenced by reaction temperature, water/powder ratio and the curing time. The hardened body prepared with water/powder ratio of 1 at $24^{\circ}C$ for one day showed excellent morphological properties for the purposed materials.

• Journal of the Korea Concrete Institute
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• v.17 no.1 s.85
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• pp.95-104
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• 2005

The research conducted to study the potential practicability of recycled aggregate concrete by analyzing the characteristics of concretes made of recycled quality aggregates produced by wet and dry process has found the following results. The air content of recycled aggregate concrete increased with increase of the substitut on rate due to mortar included while producing recycled aggregates. However, the concretes with aggregate produced by dry process had relatively low rate of increase in air content. The slump showed generally decreasing trend as the substitution rate of recycled aggregate increased regardless of the wet or dry process. It was assumed that the mortar particles remained in recycled aggregate absorbed the surplus hydration in concrete and decreased fluidity The compressive strength generally decreased as the substitution rate of recycled aggregate increased, however there was an increasing trend as well due to decreasing effect of water-cement ratio when the substitution rate of recycled aggregate reached 25, 50% after mix. This phenomena also appeared in early age, which meant that recycled aggregate concrete should not be retarded in setting when applied in the field. The tensile strength also reached the maximum when wet or dry recycled aggregate replaced with 25%. To conclude, recycled aggregates for concrete produced by wet or dry process are expected to demonstrate essential characteristics of concrete without significant decline in physical or dynamic quality when the substitution rate is below 25% although there are variations subject to water-cement ratio. However, slight differences are expected due to types of recycled aggregate and physical quality.

• Journal of the Korea institute for structural maintenance and inspection
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• v.8 no.2
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• pp.185-194
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• 2004

In recent years, construction company makes inroads into the world construction market, and receives the order of extra-large concrete structure under marine environment in south-east asia specially. At this point of time, to enhance the quality of concrete, we research the High Strength Concrete (HSC) containing mineral admixtures. In this study, therefore, HSC with various combination of ordinary portland cement(OPC), blast-furnace slag(SG), silica fume(SF), and expansion admixture(SS) are cured 23 and $35^{\circ}C$ considering the site weather, and are cured in water for 3, 7 or 56 days respectively. Test results show that the HSC cured at $35^{\circ}C$ gains higher early-age strength but eventually gains lower later-age strength compare with the HSC cured at $23^{\circ}C$. Especially, HSC with combination of OPC+SG+SF+SS or OPC+SG+SF show very excellent resistance of chloride penetration. The permeability of HSC was therefore enhanced as because of containing the proper content of SG, SF, and SS and making dense micro-structure of HSC.