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Colour Change of Black-dyed PET Fabrics by Sputter Coloration and Their Physical Properties (Sputter 착색에 의한 Black-dyed PET 직물의 색상 및 물성변화)

  • Koo, Kang;Won, Eun-Hee;Park, Young-Mi
    • Textile Coloration and Finishing
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    • v.18 no.4
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    • pp.11-19
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    • 2006
  • Black-dyed PET fabrics were sputtered with stainless steel through DC-magnetron type device to investigate the possibility of coloration effect, and then considered the morphological structure and physical characteristics such as water permeation ability and washing fastness. Change in color was estimated on the basis of CIELAB color system. The color coordination of metal plated PET was shifted to yellow-red from red-blue. Colour difference$({\Delta}E^*)$ was increased by sputtering conditions with increasing ion current and treatment time. Especially, $Lightness(L^*)$ value of PET was remarkably increased by sputtering, whereas $Chroma(C^*)$ increased gradually. From SEM analysis, rough and uneven craters were found and thickened on the fiber surfaces with longer sputtering time. And washing fastness was a little poor and absorption ability slightly decreased. There were little changes of breaking load and breaking extension. It was evident that observed uneven craters in the plated thin layer resulted in the colour change of PET fabrics by sputtering treatments.

Effect of Disperse Dyeing on UV-curable Flame-retardant Finish of PET Fabrics (분산염료 염색공정이 PET직물의 UV경화형 방염가공에 미치는 영향)

  • Jeong, Yong-Kyun;Jang, Jin-Ho
    • Textile Coloration and Finishing
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    • v.20 no.2
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    • pp.66-74
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    • 2008
  • Effect of disperse dyeing on flame retardant finishing of PET fabrics via UV curing using three UV curable phosphorous-containing methacrylates and ammonium polyphosphate(APP) was investigated. The dye fixation and flame retardancy of PET fabrics did not change significantly with excellent durability to five laundering cycles irrespective of the dyeing and finishing sequence. However, the flame retardancy of Pekoflam-treated fabrics was lower than that of the UV treated and decreased substantially when heat treatment was carried out before the dyeing. The dyeability of the flame-retardant PET fabrics was not affected in the case of UV curing of the methacrylates alone. However, UV finishing after the dyeing caused significant decrease in K/S and ${\Delta}E$ due to changed refraction and inherent color of surface coating of the UV curable monomers and APP. Whereas the heat treatment with Pekoflam decreased both color fastness to laundering and sublimation, surprisingly the UV finish of PET fabrics before and after the dyeing increased the color fastness probably resulting from the presence of photopolymerized surface layer on the fabrics.

Effect of Washing and Subsequent Heat Treatment on Water Repellency of Silk Fabric Treated with Fluorocarbon Resins

  • Park, Hyei-Ran;Lee, Mun-Cheul
    • Textile Coloration and Finishing
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    • v.24 no.3
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    • pp.173-179
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    • 2012
  • Silk fabric treated with fluorocarbon resins (Asahi Guard AG-7005 and AG-E061) were washed and subsequently heat treated varying the washing cycles and the temperature. After the processing, the water and oil repellencies, and contact angle to water were evaluated. The water and oil repellencies decreased by the washing and recovered by following heat treatment. Also ESCA measurement was carried out to investigate the surface chemical composition of the treated fiber. The $F_1s$ intensity of the treated fabric decreased by the washing and recovered by the subsequent heat treatment. On the other hand, the $O_1s$ intensity increased by the washing and decreased by following heat treatment. From the results, it is clear that change of the water and oil repellencies of the silk fabric treated with fluorocarbon resin occurred by the washing and subsequent heat treatment. Considering a change of the water repellency of the silk fabric treated with fluorocarbon resin, it seems likely that the fluoroalkyl group of the fluorocarbon resin rotates from surface to inside of the fiber by the washing to adapt to the hydrophilic circumstance, and the orientation of the fluoroalkyl groups of the resin disturbed by the washing recovers the orientation to the fiber surface after the subsequent heat treatment.

A Study on the Alkali Hydrolysis of PET fabric with Ultrasonic Application(I) - Decomposition Rate Constant and Activation Energy - (초음파를 적용한 PET 직물의 알칼리 가수분해에 관한 연구(I) - 분해속도상수와 활성화 에너지-)

  • 서말용;조호현;김삼수;전재우;이승구
    • Textile Coloration and Finishing
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    • v.14 no.4
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    • pp.214-222
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    • 2002
  • In order to give a silk-like touch to PET fabrics, the PET fabrics were treated with NaOH alkaline solution in various conditions. In alkaline treatment, the liquor flow type pilot weight reduction apparatus with magnetostrictive ultrasonic transducer was used for the study. The weight loss of PET fabrics hydrolyzed in 4% and 6% NaOH solution, at $95^\circ{C}$ and $99^\circ{C}$ for 60min. with ultrasonic application showed 3.7~4.6% higher than that of treated fabric without ultrasonic application. From the difference of specific weight loss, the treatment condition of the maximum of hydrolyzation effect appeared at $95^\circ{C}$ in $4^\circ{C}$ and at $90^\circ{C}$ in 6% NaOH solution, respectively. During the alkali hydrolysis of PET fabrics, the decomposition rate constant(k) increased exponentially with the treatment temperature and were not related with ultrasonic cavitation. The activation energy$(E_a)$ in decomposition of PET fabrics were 21.06kcal/mol with ultrasonic application and 21.10kcal/mol without ultrasonic application. The ultrasonic application gave a little higher value of the activation entropy$(\Delta{S}^\neq)$ and a little lower value of Gibbs free energy$(\Delta{S}^\neq)$ compared with not used ultrasonic apparatus.

Surface Modification of Cellulose Acetate using $UV/O_3$ Irradiation

  • Lee, Hae-Sung;Jeong, Yong-Kyun;Jang, Jin-Ho
    • Textile Coloration and Finishing
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    • v.18 no.5 s.90
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    • pp.35-41
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    • 2006
  • Upon $UV/O_3$ irradiation cellulose acetate (CA) films showed modified surface properties such as increased hydrophilicity and surface roughness as well as increased dyeability to cationic dyes. UV treatment induced photoscission of acetyl groups in the main chain of CA resulting in decreased degree of substitution from 2.2 to 1.3. The slight decreases in reflectance and transmittance were caused by remarkably increased nano-scale surface roughness of the CA surface as much as 20-fold, which can destructively interfere with visible lights of wavelength lower thu 500nm. Water contact angle decreased from $54^{\circ}\;to\;14^{\circ}$ with increasing UV energy. Surface energy also increased slightly. The surface energy change was attributed to significant contribution of polar component rather than nonpolar component indicating surface photooxidation of CA film. The increased dyeability to cationic dyes in terms of both K/S and %E may be due to photochemically introduced anionic and dipolar dyeing sites on the film surfaces.

Dyeing(Yarn) and Electrical properties of Textile sensor using multi-core type conductive fibers(Cotton/Nylon/Copper) (Cotton/Nylon/Copper 복합 전도직물센서 소재의 선염 및 전기적 특성)

  • Choi, Woo-Hyuk;Kim, Mi-Kyung;Ahn, B.J.;Kim, E.C.;Lee, B.H.
    • Proceedings of the Korean Society of Dyers and Finishers Conference
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    • 2011.03a
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    • pp.107-107
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    • 2011
  • 최근 IT(Information Technology)가 결합된 스마트 섬유의 수요가 꾸준히 증가하고 있다. 생활수준 향상에 따른 유저들의 청결, 쾌적에 대한 높은 관심속에서 생활 및 의료용 섬유에도 다양한 기능성이 요구되어지고 있다. 초경량, 흡한속건, 투습방수 등 레저 스포츠, 아웃도어 활동에 필요한 고기능성 소재는 제품의 고부가가치를 더하는 가치 상승 요인이긴 하지만 그 기술과 적용성이 이미 포화 상태에 도달했다고 볼 수 있다. 이에 국내 외 섬유 업체들은 스마트 섬유 열풍을 큰 기회로 삼아 헬스케어 기능, 엔터테인먼트 기능 등의 최첨단 기술과 결합되어진 특화된 섬유시장을 통해 더 높은 부가가치를 창출하고 새로운 섬유시장의 도약을 노리고 있다. 이에 본 연구에서는 위치추적이나 동선, 생체적 리듬 등을 파악할 수 있는 스마트 섬유용 전도성 섬유센서의 초기특성(전기적, 물리적 물성)을 유지함과 동시에 심미적인 효과와 새로운 기능성을 부여하기 위하여 전도성 센서소재의 최적 선염공정을 조사하고 외부적인 환경변화를 염두에 두어 그 물성 변화를 측정하였다.

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Expressive Characteristics of Floral Images in Contemporary Fashion (현대패션에 나타난 꽃 이미지의 표현특성)

  • Kim, Sun-Young
    • Journal of the Korean Society of Costume
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    • v.60 no.8
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    • pp.1-14
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    • 2010
  • This study is a discussion of the expressive characteristics of contemporary fashion design with floral images. It aims to help understand the overall trends of contemporary fashion design and textile motif design and expand the potential expression fields of originative design to natural objects such as flowers. Methodologically the study analyzed 976 pieces of data gathered from Haute Couture and Pr$\hat{e}$t-$\grave{a}$-Porter collections of 2005S/S-2009F/W, according to their types of expression. The study results show a share of 42.7% for plane type expressions by printing or weaving and a share of 51.5% for relief type expressions, compared with 5.7% for solid type expressions. However, those expressions represented elegant femininity with emphasis on formative beauty and were applied to fashion accessories or hair adornments. The expressive characteristics found from the analysis were represented by natural images, feminine elegance, and decorative aesthetics of handicrafts. Flowers in the contemporary fashion purify the internal emotions of humankind stand for personality and beauty in many different ways of expression and serve as a means of expressing more artistic values breaking out of stereotype.

An expert system approach for process planning of worsted spun yarns (전문가 시스템을 이용한 소모사의 공정계획)

  • 권영일;송서일
    • Proceedings of the Korean Operations and Management Science Society Conference
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    • 1994.04a
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    • pp.653-659
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    • 1994
  • Human experts have the various own knowledges to be applied in specialized domains. The fact that knowledge itself becomes more critical in the context of textile knowledge with rapid development of new fibers, automated equipments, processes and applications. Diversity of worsted spun yarns, lack of human expertise, and inconsistency among manually generated process plans in consequency of adjustment machine parameters owing to change up raw materials frequently increase the necessity of developing computer aided process planning(CAPP) systems for spinning process. Expert systems offer one of techniques to develop CAPP systems which would behave in a knowledgeable manner. Expert systems are the problem-solving computer program that can reach a level of performance comparable to that of a human expert in some specialized problem domain. This paper is described as job justification module. The job justification module performs to consult with users on which worsted spun yarn manufacturing process planning under the various factors, e.g., raw materials, machine parameters and required yarn counts. Also, the developed module informs the various knowledges relevant process planning. The job justification module offers the control parameters at each process and includes the various standard process plans as database. These knowledges are generated by facts and rules within rule bases.

Performance of fouled NF membrane as used for textile dyeing wastewater

  • Abdel-Fatah, Mona A.;Khater, E.M.H.;Hafez, A.I.;Shaaban, A.F.
    • Membrane and Water Treatment
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    • v.11 no.2
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    • pp.111-121
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    • 2020
  • The fouling of Nanofiltration membrane (NF) was examined using wastewater containing reactive black dye RB5 of 1500 Pt/Co color concentrations with 16890 mg/l TDS collected from El-alamia Company for Dying and Weaving in Egypt. The NF-unit was operated at constant pressure of 10 bars, temperature of 25℃, and flowrate of 420 L/min. SEM, EDX, and FTIR were used for fouling characterization. Using the ROIFA-4 program, the total inorganic fouling load was 1.07 mM/kg present as 49.3% Carbonates, 10.1% Sulfates, 37.2% Silicates, 37.2% Phosphates, and 0.93% Iron oxides. The permeate flux, recovery, salt rejection and mass transfer coefficients of the dye molecules were reduced significantly after fouling. The results clearly demonstrate that the fouling had detrimental effect on membrane performance in dye removal, as indicated by a sharp decrease in permeate flux and dye recovery 68%. The dye mass transfer coefficient was dropped dramatically by 34%, and the salt permeability increased by 14%. In this study, all the properties of the membrane used and the fouling that caused its poor condition are identified. Another study was conducted to regeneration fouled membrane again by chemical methods in another article (Abdel-Fatah et al. 2017).

A Study on the Biodiesel Production Technology using Lard Oil (동물성 유지를 이용한 Biodiesel 생산기술에 관한 연구)

  • Shin, Soo-Beom;Min, Byung-Wook;Yang, Seung-Hun;Park, Min-Seok;Kim, Hae-Sung;Paek, Doo-Hyeon
    • Journal of the Korean Applied Science and Technology
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    • v.23 no.1
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    • pp.19-25
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    • 2006
  • Flesh wasters from tannery create major environmental problems. Despite their considerable fat content, these waster do not find important usage. Their disposal is also troublesome and costly. We have investigated the possible use of this fat as the production of biodiesel(fatty acid methyl esters) by transesterification using with fossil fuels. The fat released the waste by boiling water under the optimal condition (i.e., temperature, $120^{\circ}C;$ decompression, 200mbar) and used to dry without refining for the production of fatty acid methyl esters. Under the optimal condition, the experimental value of biodiesel yield was about 96%. The result of the chemical and GC analysis showed fatty acid composition and characteristics of biodiesel. Evaluation of the product indicated that it was suitable for use as a biodiesel fuel. In result of this experiment oil extract from fleshing process can be transformed into an environmentally affination fuel, to provide economical and ecological profits.