• Title/Summary/Keyword: e-matrix

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A study on the Initial Nanopore Formation in the Calix Arene Based Porogen Templated Porous Thin Film (칼릭스아렌 포로젠을 이용한 다공성 박막의 초기 나노기공 형성과정에 관한 연구)

  • Kim, Do-Hun;Yim, Jin-Heong
    • Korean Chemical Engineering Research
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    • v.49 no.5
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    • pp.669-675
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    • 2011
  • Fourier Transform Infrared Spectroscopy and in-situ Position Annihilation Lifetime Spectroscopy(PALS) analysis of hybrid film, which consist of silsesquioxane(SSQ) and 4-tert-butyl calix[4]arene-O,O',O",O'"-tetraacetic acid tetraethyl ester(CA[4]) have been investigated in order to understand initial formation of nanopore in the next generation porous low-k dielectrics(k < 2.0). SSQ/CA[4] can provide effective homogeneous thin film having porous structure. The porogen decomposition behavior were completely different in the two kinds of SSQ/CA[4] based hybrid film (i.e. SSQ/CA[4] 10 and SSQ/CA[4] 20%). Relatively small pores(1.5 nm) come from dispersion of uni-molecular CA[4] in the SSQ matrix have been generated at $300^{\circ}C$, while mesopores(2.5~3.0 nm) induced from self assembled CA[4] have been generated at $250^{\circ}C$. It might be due to highly interconnected structure of SSQ/CA[4] 20% hybrid thin film resulting in facile evacuating of decomposed fragment of CA[4] molecule.

Electrodeposition onto the Surface of Carbon Fiber and its Application to Composites(I) - Electrodeposition of MVEMA and EMA (탄소섬유 표면에의 고분자 전착과 복합재료 물성(I) - MVEMA와 EMA의 전착 -)

  • Kim, Minyoung;Kim, Jihong;Kim, Wonho;Kim, Booung;Hwang, Byungsun;Choi, Youngsun
    • Applied Chemistry for Engineering
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    • v.9 no.6
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    • pp.894-900
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    • 1998
  • An interphase between carbon fiber and epoxy matrix was introduced to increase impact strength of carbon fiber reinforced composites (CFRC) without sacrificing the interlaminar shear strength. Flexible polymers, I. e., MVEMA (poly(methyl vinyl ether-co-maleic anhydride)) and EMA(poly(ethylene-co-maleic anhydride)), which have reactive functional groups were considered as interphase materials. Weight hain of MVEMA and EMA onto the surface of carbon fibers was evaluated by changing the parameters of electrodeposition process. Electrodeposition mechanism of polymers which have anhydride functional group was identified by IR spectroscopy, that is, the generation of $RCOO^-$ functional group by the attack of hydroxide anion in the basic solution was observed. The weight gain was increased by increasing concentration of polymers, current density, and electrodeposition time. However the excess generation of oxygen gas decreased the weight gain by removing the deposited polymers. Washing in the running water easily removed the deposited polymers which are on the fiber surface without bonding, as a results, only 0.5 wt% of deposited polymers are remained.

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Fracture Network Analysis of Groundwater Folw in the Vicinity of a Large Cavern (분리열극개념을 이용한 지하공동주변의 지하수유동해석)

  • 강병무
    • The Journal of Engineering Geology
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    • v.3 no.2
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    • pp.125-148
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    • 1993
  • Groundwater flow in fractured rock masses is controlled by combined effects of fracture networks, state of geostafic stresses and crossflow between fractures and rock matrix. Furthermore the scaie dependent, anisotropic properties of hydraulic parameters results mainly from irregular paftems of fracture system, which can not be evaluated properly with the methods available at present. The basic assumpfion of discrete fracture network model is that groundwater flows only along discrete fractures and the flow paths in rock mass are determined by geometric paftems of interconnected fractures. The characteristics of fracture distribution in space and fracture hydraulic parameters are represented as the probability density functions by stochastic simulation. The discrete fracture network modelling was aftempted to characterize the groundwater flow in the vicinity of existing large cavems located in Wonjeong-ri, Poseung-myon, Pyeungtaek-kun. The fracture data of $1\textrm{km}^2$ area were analysed. The result indicates that the fracture sets evaluated from an equal area projection can be grouped into 6 sets and the fracture sizes are distributed in longnormal. The conductive fracture density of set 1 shows the highest density of 0.37. The groundwater inflow into a carvem was calculated as 29ton/day with the fracture transmissivity of $10^{-8}\textrm{m}^2/s$. When the fracture transmissivity increases in an order, the inflow amount estimated increases dramatically as much as fold, i.e 651 ton/day. One of the great advantages of this model is a forward modelling which can provide a thinking tool for site characterization and allow to handle the quantitative data as well as qualitative data.

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Proteome analysis of human stomach tissue: Separation of soluble Proteins by two-dimensional Polyacrylamide gel electrophoresis and identification by mass spectrometry

  • Ha, Geun-Hyoung;Lee, Seung-Uook;Kang, Deok-Gyeong;Ha, Na-Young;Kim, Soon-Hee;Kim, Ji-Na;Bae, Jong-Min;Kim, Jae-Won;Lee, Chang-Won
    • Proceedings of the Korean Society of Life Science Conference
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    • 2002.12a
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    • pp.20-47
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    • 2002
  • Two-dimensional gel electrophoresis (2-DE) maps for human stomach tissue proteins have been prepared by displaying the protein components of the tissue by 2-DE and identifying them using mass spectrometry. This will enable us to present an overview of the proteins expressed In human stomach tissues and lays the basis for subsequent comparative proteome analysis studies with gastric diseases such as gastric cancer. In this study, 2-DE maps of soluble fraction proteins were prepared on two gel images with partially overlapping pH ranges of 4-7 and 6-9. On the gels covering pH 4-7 and pH 6-9, about 900 and 600 protein spots were detected on silver staining, respectively. For protein identification, proteins spots on micropreparative gels stained by colloidal Coomassie Brilliant Blue G-250 were excised, digested in-gel with trypsln, and analyzed by peptide mass fingerprinting with delayed extraction-matrix assisted laser dosorption/ionization-mass spectrometry (DE-MALDI-MS). In all, 243 protein spots (168 spots in acidic map and 75 spots in basic map) corresponding to 136 different proteins were identified. Besides these principal maps, maps of lower resolution, i.e. overview maps (displayed on pH 3-10 gels) for total homogenate and soluble fraction, are also presented with some identifications mapped on them. Based on the 2-DE maps presented in this study, a 2-DE database for human stomach tissue proteome has been constructed and available at http://proteome.gsnu.ac.kr/DB/2DPAGE/Stomach/. The 2-DE maps and the database resulting from this study will serve important resources for subsequent proteomic studies for analyzing the normal protein variability in healthy tissues and specific protein variations in diseased tissues.

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Analysis of Land Cover Characteristics with Object-Based Classification Method - Focusing on the DMZ in Inje-gun, Gangwon-do - (객체기반 분류기법을 이용한 토지피복 특성분석 - 강원도 인제군의 DMZ지역 일원을 대상으로 -)

  • Na, Hyun-Sup;Lee, Jung-Soo
    • Journal of the Korean Association of Geographic Information Studies
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    • v.17 no.2
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    • pp.121-135
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    • 2014
  • Object-based classification methods provide a valid alternative to traditional pixel-based methods. This study reports the results of an object-based classification to examine land cover in the demilitarized zones(DMZs) of Inje-gun. We used land cover classes(7 classes for main category and 13 classes for sub-category) selected from the criteria by Korea Ministry of Environment. The average and standard deviation of the spectrum values, and homogeneity of GLCM were chosen to map land cover types in an hierarchical approach using the nearest neighborhood method. We then identified the distributional characteristics of land cover by considering 3 topographic characteristics (altitude, slope gradient, distance from the Southern Limited Line(SLL)) within the DMZs. The results showed that scale 72, shape 0.2, color 0.8, compactness 0.5 and smoothness 0.5 were the optimum weight values while scale, shape and color were most influenced parameters in image segmentation. The forests (92%) were main land cover type in the DMZs; the grassland(5%), the urban area (2%) and the forests (broadleaf forest: 44%, mixed forest: 42%, coniferous forest: 6%) also occupied mostly in land cover classes for sub-category. The results also showed that facilities and roads had higher density within 2 km from the SLL, while paddy, field and bare land were distributed largely outside 6 km from the SLL. In addition, there was apparent distinction in land cover by topographic characteristics. The forest had higher density at above altitude 600m and above slope gradient $30^{\circ}$ while agriculture, bare land and grass land were distributed mainly at below altitude 600m and below slope gradient $30^{\circ}$.

Expression of osteoclastogenesis related factors in dental implant patients (치과 임플란트에서 골개조 관련인자의 발현에 관한 연구)

  • Ryu, Seong-Hee;Kim, Bang-Sin;Jung, Seung-Gon;Han, Man-Seung;Kook, Min-Suk;Ohk, Seung-Ho;Oh, Hee-Kyun;Park, Hong-Ju
    • Journal of the Korean Association of Oral and Maxillofacial Surgeons
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    • v.36 no.5
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    • pp.386-391
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    • 2010
  • Introduction: Bone resorption is a unique function of osteoclasts. Osteoclasts are a specialized macrophage polykaryon whose differentiation is regulated principally by macrophage colony-stimulating factors, receptor activator of nuclear factor ${\kappa}B$ ligand (RANK) ligand, osteoprotegerin (OPG), and interleukins (IL). Reflecting the integrin-mediated signals, osteoclasts develop a specialized cytoskeleton that allows it to establish an isolated micro-environment between itself and the bone, wherein matrix degradation occurs by a process involving proton transport. The levels of IL-1, IL-6, OPG, and prostaglandin $E_2$ ($PGE_2$) expression were evaluated to study the correlations between dental implant teeth and the adjacent teeth. Materials and Methods: The exudate of the gingival crevice acquired from dental implants, adjacent teeth, opposite teeth and contralateral teeth of 24 patients. Results: 1. The levels of IL-1, IL-6, OPG and $PGE_2$ expression in dental implant teeth were higher than those of the contralateral teeth. 2. IL-1 revealed a higher expression level in the adjacent teeth than in dental implant teeth. 3. The dental implant teeth and adjacent teeth did not show a remarkable difference in the level of IL-1 expression. 4. All the other cytokines were strongly expressed in the dental implant compared to the adjacent teeth. Conclusion: These results suggest that there might be close correlation between dental implant teeth and adjacent teeth in terms of the expressions of cytokines that affect the development and regulation of osteoclasts.

An Ultrastructural Study on the Parotid Acinar Cells of X-irradiated Rats (X-선 조사를 받은 흰쥐 귀밑샘 샘포의 미세구조)

  • Yang, Nam-Gil;Park, In-Kyu;Ahn, E-Tay;Ko, Jeong-Sik;Park, Kyung-Ho;Kim, Jin-Gook
    • Applied Microscopy
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    • v.24 no.1
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    • pp.28-40
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    • 1994
  • Xerostomia and xerophthalmia are delicate or serous side effects, occuring when the radiotherapy is administered to the head and neck cancer patient. It is known that the cause of the above side effect is radiosensitivity of serous cells. In this study, the ultrastructural features of the parotid glands of the X-irradiated rats were observed. Sprague-Dawley rats weighing 200-250g each were anesthetized with sodium thiopental, and placed on the Mitsubishi linear accelerator. Only the head and neck areas of animals were exposured at the distance of 80cm, within the area of $30X30cm$, in the depth of 1cm, with the speed of 200R/min. Total doses applied were 3,000R or 6,000R depending on the experimental groups. Animals were sacrificed on the 6th hour, 2nd day and 6th day after the irradiation. Parotid glands were fixed in the 2.5% glutaraldehyde-1.5% paraformaldehyde solution, and followed by refixation in the 1% osmium tetroxide solution. Dehydrated blocks were embedded in araldite mixture, and ultrathin sections were cut. Sections were contrasted with the solution of uranyl acetate and lead citrate, and observed with JEM 100 CX-II electron microscope. The results were as follows: 1. Normal parotid acinar cells are two types; the light and the dark acinar cells. The light acinar cell contains dense secretory granules, whereas dark acinar cells contains granules of medium density with some darker spots within them, or other cells contain granules of medium density with darker rims. 2. Six hours after the irradiation, many acinar cells were degenerated showing variable stages of cytolytic bodies, light bodies, or dense degenerations. Within the acinar cell, Golgi apparatus and granular endoplasmic reticula were most severely altered elements. Granules showed more contrasting densities and irregularities. 3. Two days after the irradiation, some cytolytic bodies, and focal lucent degeneration of cytoplasm, and fine granular alteration of cytoplasmic matrix were pronounced. But other elements including secretory granules are rather looked unlatered. 4. Six days after the irradiation, most severe alterations were seen. Many intracellular canaliculi (or secretion figures), quanta of cytoplasm containing secretion antecedants, severely irregular luminal border, and again contrasting density of secretory granules showing tigroid spots or dense rims were noted. And myoepithelial degenerations were observed not uncommonly. 5. Irregular densities of secretory granules were interpreted as abnormal components of protein or carbohydrate portion are synthesized or abnormally metabolized under severe X-irradiation. 6. Myoepithelial degeneration and related alteration of nerve endings, etc., were suggested as the other causes of xerostomia following X-irradiation. 7. It is requested that radiation doses should be arranged, considering in mind not only the sensitivity of acinar cells but also the myoepithelial and neural functions.

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A Study of Secondary Mathematics Materials at a Gifted Education Center in Science Attached to a University Using Network Text Analysis (네트워크 텍스트 분석을 활용한 대학부설 과학영재교육원의 중등수학 강의교재 분석)

  • Kim, Sungyeun;Lee, Seonyoung;Shin, Jongho;Choi, Won
    • Communications of Mathematical Education
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    • v.29 no.3
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    • pp.465-489
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    • 2015
  • The purpose of this study is to suggest implications for the development and revision of future teaching materials for mathematically gifted students by using network text analysis of secondary mathematics materials. Subjects of the analysis were learning goals of 110 teaching materials in a gifted education center in science attached to a university from 2002 to 2014. In analysing the frequency of the texts that appeared in the learning goals, key words were selected. A co-occurrence matrix of the key words was established, and a basic information of network, centrality, centralization, component, and k-core were deducted. For the analysis, KrKwic, KrTitle, and NetMiner4.0 programs were used, respectively. The results of this study were as follows. First, there was a pivot of the network formed with core hubs including 'diversity', 'understanding' 'concept' 'method', 'application', 'connection' 'problem solving', 'basic', 'real life', and 'thinking ability' in the whole network from 2002 to 2014. In addition, knowledge aspects were well reflected in teaching materials based on the centralization analysis. Second, network text analysis based on the three periods of the Mater Plan for the promotion of gifted education was conducted. As a result, a network was built up with 'understanding', and there were strong ties among 'question', 'answer', and 'problem solving' regardless of the periods. On the contrary, the centrality analysis showed that 'communication', 'discovery', and 'proof' only appeared in the first, second, and third period of Master Plan, respectively. Therefore, the results of this study suggest that affective aspects and activities with high cognitive process should be accompanied, and learning goals' mannerism and ahistoricism be prevented in developing and revising teaching materials.

Assessment of Genetic Diversity and Relationships Between Korean Cattle and Other Cattle Breeds by Microsatellite loci (Microsatellite loci 분석에 의한 한우와 타 품종간의 유전적 유연관계)

  • Yoon, D.H.;Park, E.W.;Lee, S.H.;Lee, H.K.;Oh, S.J.;Cheong, I.C.;Hong, K.C.
    • Journal of Animal Science and Technology
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    • v.47 no.3
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    • pp.341-354
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    • 2005
  • For the genetic assessment of the cattle breeds including Hanwoo, eleven microsatellite markers on ten bovine autosomes were genetically characterized for 618 individuals of nineteen cattle breeds; North Eastern Asian breeds (Korean cattle, Korean Black cattle, Japanese Black cattle, Japanese Brown cattle, Yanbian cattle), Chinese yellow cattle (Luxi cattle, Nanyang cattle), European Bas taurus (Angus, Hereford, Charolais, Holstein, Limousin), African Bas taurus (N'Dama, Baoule), African Bas indicus (Kavirondo Zebu, White Fulani), Asian Bas indicus (Sahiwal, Nelore) and one Bali cattle, Bas banteng as an outbreed-reference population. Allele frequencies derived from the genotyping data were used in estimating heterozygosities, gene diversities and genetic distances. The microsatellite loci were highly polymorphic, with a total of 162 different alleles observed across all loci. Variability in allele numbers and frequencies was observed among the breeds. The average expected heterozygosity of North Eastern Asian breeds was higher than those of European and African taurines, but lower than those of Asian and African indicines. Genetic distances were estimated using Nei's DA genetic distance and the resultant DA matrix was used in the construction of the phylogenetic trees. The genetic distances between North Eastern Asian cattle breeds and Bas indicus were similar with those between European Bas taurus and Bas indicus, and African Bas taurus and Bas indicus, respectively. The clusters were clearly classified into North Eastern Asian, European and African taurines groups as well as different cluster with Chinese mainland breeds, firstly out-grouping with Bas indicus. These results suggest that Korean cattle, Hanwoo, had not been originated from a crossbred between Bas primigenius in Europe and Bas indicus in India and North Eastern Asian Bas taurus may be have separate domestication from European and African Bas taurus.

A Study on Pre-school Teachers' Perception of 7 Guidelines of Safety Education: Using IPA Methodology (유아교사가 인식하는 유치원 안전교육 표준안에 대한 연구 : IPA기법을 중심으로)

  • Kang, Min-Jung;Han, Sun-Ah
    • The Journal of the Korea Contents Association
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    • v.17 no.6
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    • pp.661-671
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    • 2017
  • The purpose of this study is to compare and analyze the difference between the importance perceived by pre-school teachers and their actual performance in regards to the 7 Guidelines of Safety Education set out by the Ministry of Education, and through the analysis, to identify the items that need priority support and those that need long-term improvement efforts for exemplary safety education for young children. For this, mean average and standard deviation were calculated and paired sample t-test conducted, and IPA(Importance-Performance Analysis) matrix method was performed to analyze the priority and long-term support items and improvement needs. The study results show differences in all areas and all items in the 7 Guidelines of Safety Education by the MoE in the pre-school teachers' perceived importance and actual performance. Areas and items that are identified to be in need of priority support for exemplary safety education in pre-schools; 2 items under 'Violence and Personal Safety' area and I item under 'Substance and Internet Addictions' area. Areas and items that are identified to be in need of long-term improvement efforts are; 6 items under 'First Aid and Emergency Treatment' area, 1 item under 'Violence and Personal Safety' area, 3 items under 'Workplace Safety Culture' area, 3 items under 'Substance and Internet Addictions' area and 1 item under 'Disaster and Safety' area.