• Journal of Electrochemical Science and Technology
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• v.2 no.2
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• pp.103-109
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• 2011

Nanocrystalline $LiFePO_4$ powders were prepared at 660-$670^{\circ}C$ in an Ar atmosphere using two different synthetic routes, solid-state and sol-gel. Both materials showed well-developed XRD patterns without any impurity peaks. Particles composed in the range of 200-300 nm from the solid-state method, and 50-100 nm from the sol-gel method, were confirmed through scanning electron microscopy and dynamic light scattering. The $LiFePO_4$ obtained by the sol-gel method offered a high discharge capacity (153 mAh/g) and stable discharge behavior, even at elevated temperatures (50 and $60^{\circ}C$), whereas poor electrochemical performance was observed from the solid-state method. Rate capability studies for sol gel-derived $LiFePO_4$ ranged from 0.2 to 30 C, which revealed excellent retention over 70 cycles with a 99.9% capacity.

• Proceedings of the Microbiological Society of Korea Conference
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• 2000.10a
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• pp.119-127
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• 2000

The development and performance of a competitive indirect immunoassay for the quantitative measurement of polychlorinated biphenyl compounds in insulating oils is presented. Reagent preparation and the assay characterisation, optimisation and validation steps are described. The dynamic range of the assay for Aroclors 1254 and 1260 in methanol was $50-800 {\mu}g\;ml^{-1}$ with $50\%$ signal inhibition values of 217 and $ 212 {\mu}g\;ml^{-1}$ respectively. Impending legislation in the UK is likely to decree that oils containing $ >50 {\mu}g\;ml^{-1}$ PCB be considered contaminated. Assay sensitivity increased with the degree of PCB chlorination. The assay of structurally related compounds of environmental concern yielded cross-reactivity values of under $0.6\%$. The immunoassay proved reliable for the analysis of transformer oils containing $>70{\mu}g\;ml^{-1}$ PCB, but over-estimated PCB levels in oils containing $<20{\mu}g\;ml^{-1}$ of the analyte with the oils requiring pre-treatment using either solid-phase extraction techniques or washing with KOH-ethanol/sulphuric acid to remove matrix interferents. The analytical performance of the assay was compared against a commercially available semi-quantitative immunoassay kit for PCBs in soil and water.

• Journal of Ocean Engineering and Technology
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• v.28 no.3
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• pp.185-192
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• 2014

The riser systems for floating offshore structures are known to experience tri-modal dynamic responses. These are owing to the combined loadings from the low-frequency response due to riser tension behavior, middle-range frequency response coming from winds and waves, and high-frequency response due to vortex induced-vibration. In this study, fatigue damage models were applied to predict the fatigue damages in a well-separated tri-modal spectrum, and the resultant fatigue damages of each model were compared with the most reasonable fatigue damage calculated by the inverse Fourier transform of the spectrum, rain-flow counting method, and Palmgren-Miner rule as a reference. The results show that the fatigue damage models developed for a wide-band spectrum are applicable to the tri-modal spectrum, and both the Benasciutti-Tovo and JB models could most accurately predict the fatigue damages of the tri-modal spectrum responses.

• Architectural research
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• v.17 no.3
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• pp.109-115
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• 2015

The dynamic pricing of electricity, where the electricity rate increases in a time zone with a high demand for electricity is typically applied to a building whose power reception capacity is greater than a certain size. This includes the time of use(TOU) electricity pricing in Korea which can induce the effect of reducing the power demand of a building. Meanwhile, a VRF (Variable Refrigerant Flow) system that uses electricity is regarded as one of the typical heating and cooling systems along with central air conditioning (central HVAC) for its easy operation and application to the building. Thus, to reduce power energy and operating costs of a building in which the TOU and VRF systems are applied simultaneously, we suggested a control for changing the indoor temperature setting within the thermal comfort range or limiting the rotational speed of an inverter compressor. In this study, to describe the features of the above-mentioned control and verify its effects, we evaluated the results obtained from the analysis of its operation data. Through the actual measurements in winter operations for 73 days since mid- December 2014, we confirmed a reduction of 10.9% in power energy consumption and 12.2% in operating costs by the new control. Also, a reduction of 13.3% in power energy consumption was identified through a regression analysis.

• Journal of the Society of Naval Architects of Korea
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• v.53 no.2
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• pp.85-91
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• 2016

The most important factor in the structural design of ships and offshore structures operating in arctic region is ice load, which results from ice-structure interaction during the ice collision process. The mechanical properties of ice related to strength and failure, however, show very complicated aspect varying with temperature, volume fraction of brine, grain size, strain rate and etc. So it is nearly impossible to establish a perfect material model of ice satisfying all the mechanical characteristics completely. Therefore, in general, ice collision analysis was carried out by relatively simple material models considering only specific aspects of mechanical characteristics of ice and it would be the most significant cause of inevitable errors in the analysis. Especially, it is well-known that the most distinctive mechanical property of ice is high dependency on strain rate. Ice shows brittle attribute in higher strain rate while it becomes ductile in lower strain rate range. In this study, the simulation method of ice collision to ship hull using the nonlinear dynamic FE analysis was dealt with. To consider the strain rate effects of ice during ice-structural interaction, strain rate dependent constitutive model in which yield stress and hardening behaviors vary with strain rate was adopted. To reduce the huge amount of computing time, the modeling range of ice and ship structure were restricted to the confined region of interest. Under the various scenario of ice-ship hull collision, the structural behavior of hull panels and failure modes of ice were examined by nonlinear FE analysis technique.

• Journal of the Korean Society of Visualization
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• v.18 no.2
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• pp.59-65
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• 2020

Vertical axis wind energy systems including 3 and 4 blades are numerically investigated in a two-dimensional (2D) computational domain. The power coefficient (C_p) is adopted to measure the efficiency of the system and the effect of the rotating velocity on the power coefficient is analyzed for the two different systems. The rotating velocity varies from 30 rad/s to 90 rad/s, which corresponds to the tip speed ratio (T.S.R) of 0.5 to 1.5. The torque exerted on the blades is mainly determined by the aerodynamic force in the x-direction and maximized when the blade is positioned at around θ = 186°. The efficiency of the 4-blade system is higher than that of the 3-blade system within the tip speed ratio range between 0.5 and 0.67, besides where the 3-blade system shows a better performance. For the 3-blade system, the maximum efficiency is reached to 0.082 at the tip speed ratio of 1.083. The maximum efficiency of the 4-blade system is 0.071 at T.S.R. = 0.92. The velocity fields in the x-direction, pressure fields, and the vorticity magnitude are analyzed in detail for the optimal cases of the 3- and 4-blades systems, respectively.

• Journal of Sensor Science and Technology
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• v.16 no.1
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• pp.17-23
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• 2007

This paper presents a miniaturized turn-counting sensor (TCS) where the geomagnetism and high-rpm rotation of ammunition are used to detect the turn number of ammunition for applications to small-caliber turn-counting fuzes. The TCS, composed of cores and a coil, has a robust structure with no moving part for increasing the shock survivability in the gunfire environments of ${\sim}30,000$ g's. The TCS is designed on the basis of the simulation results of an electromagnetic analysis tool, $Maxwell^{(R)}$3D. In experimental study, the static TCS test using a solenoid-coil apparatus and the dynamic TCS test (firing test) have been made. The presented TCS has shown that the induction voltage of $6.5{\;}mV_{P-P}$ is generated at the magnetic flux density of 0.05 mT and the rotational velocity of 30,000 rpm. From the measured signal, the TCS has shown the SNR of 44.0 dB, the nonlinearity of 0.59 % and the frequency-normalized sensitivity of $0.26{\pm}0.01{\;}V/T{\cdot}Hz$ in the temperature range of $-30{\sim}+43^{\circ}C$. Firing test has shown that the TCS can be used as a turn-counting sensor for small-caliber ammunition, verifying the shock survivability of TCS in high-g environments.

• Korean Journal of Materials Research
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• v.29 no.7
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• pp.443-450
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• 2019

Thermal management is a critical issue for the development of high-performance electronic devices. In this paper, thermal conductivity values of mild steel and stainless steel(STS) are measured by light flash analysis(LFA) and dynamic thermal interface material(DynTIM) Tester. The shapes of samples for thermal property measurement are disc type with a diameter of 12.6 mm. For samples with different thickness, the thermal diffusivity and thermal conductivity are measured by LFA. For identical samples, the thermal resistance($R_{th}$) and thermal conductivity are measured using a DynTIM Tester. The thermal conductivity of samples with different thicknesses, measured by LFA, show similar values in a range of 5 %. However, the thermal conductivity of samples measured by DynTIM Tester show widely scattered values according to the application of thermal grease. When we use the thermal grease to remove air gaps, the thermal conductivity of samples measured by DynTIM Tester is larger than that measured by LFA. But, when we did not use thermal grease, the thermal conductivity of samples measured by DynTIM Tester is smaller than that measured by LFA. For the DynTIM Tester results, we also find that the slope of the graph of thermal resistance vs. thickness is affected by the usage of thermal grease. From this, we are able to conclude that the wide scattering of thermal conductivity for samples measured with the DynTIM Tester is caused by the change of slope in the graph of thermal resistance-thickness.

• Korean Chemical Engineering Research
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• v.47 no.2
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• pp.169-173
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• 2009

Effects of variations sulfur/accelerator ratio on cross-linking and thermal degradation behavior of NR/CR rubber compounds were studied using both dynamic DSC and non-isothermal TGA. DSC thermograms of the given samples were obtained with several different heating rates, and after cross-liked in DSC, TGA thermograms with the same samples also obtained. Kissinger analysis was applied to assess the activation energies for the cross-linking and thermal decomposition processes. Results showed that the formation and thermal decomposition reaction of the samples occurred in the overall temperature range of $120{\sim}180^{\circ}C$ and $350{\sim}450^{\circ}C$, respectively, exhibiting that data could be well-fittable by Kissinger method. Furthermore, formation activation energy by DSC was estimated as $83.0{\pm}5.0kJ/mol$, which was much smaller than that of degradation by TGA, $147.0{\pm}2.0kJ/mol$. From these results, it was considered that, although variations of sulfur/accelerator ratio in the present experiments affected little on the formation mechanism and/or thermal degradation, they could play roles as the catalysts which lower the activation energy of formation. Because of stabilization after formation reaction, however, they have no more effects on the lowering the activation energy, showing higher values when decomposition, caused by main-chain scissions.

• Transactions of the Korean Society of Automotive Engineers
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• v.20 no.6
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• pp.73-82
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• 2012

The main and side reactions of the three selective catalytic reduction (SCR) reactions with ammonia over a vanadium-based catalyst have been investigated using synthetic gas mixtures in the temperature range of $170{\sim}590^{\circ}C$. The three SCR reactions are standard SCR with pure NO, fast SCR with an equimolar mixture of NO and $NO_2$, and $NO_2$ SCR with pure $NO_2$. Vanadium based catalyst has no significant activity in NO oxidation to $NO_2$, while it has high activity for $NO_2$ decomposition at high temperatures. The selective catalytic oxidation of ammonia and the formation of nitrous oxide compete with the SCR reactions at the high temperatures. Water strongly inhibits the selective catalytic oxidation of ammonia and the formation of nitrous oxide, thus increasing the selectivity of the SCR reactions. However, the presence of water inhibits the SCR activity, most pronounced at low temperatures. In this study, the experimental results are analyzed by means of a dynamic one-dimensional isothermal heterogeneous plug-flow reactor (PFR) model according to the Eley-Rideal mechanism.