• Textile Coloration and Finishing
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• v.31 no.1
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• pp.25-32
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• 2019

The influence of the contact amount of carbon dioxide per unit mass of dyestuff(${\alpha}$) on dyeing uniformity in supercritical fluid dyeing is analyzed in this study. The experiments using a 5L class Pilot Scale dyeing machine is carried out for this study purpose. For a fixed temperature and pressure, the amount of sample and the dyeing leveling time were considered as process variables. The results show that the increase in the amount of the sample causes a higher color difference than the reference sample, and it also increases the amount of residual dye. On the other hand, the color difference tended to decrease with the increase in dyeing time. Based on these results, the correlation between ${\alpha}$ value and dyeing uniformity in supercritical fluid dyeing is obtained.

• Proceedings of the Korean Institute of Building Construction Conference
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• 2013.11a
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• pp.190-191
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• 2013

In this research, the fundamental experiment for colour concrete(by using pigment) has been invested. Fundamental properties and dyeability for the colour mortar as the changing replacement ratio of pigment has been tested. For the conclusion, with the increasing ratio of pigment, the flow and compressive strength for the mortar has been decreased, For the dyeability, there's little difference when replacement ratio of dyestuff changed when the colour is red and yellow, but large difference when the blue pigment was used. Consider about the workability and strength of the mortar, the optimum pigment's replacement ratio is fixed as 2.5%.

• The Research Journal of the Costume Culture
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• v.24 no.5
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• pp.577-587
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• 2016

Natural dye extracted from Salicornia bigelovii was applied to silk fabrics by dip dyeing process. The dyeing properties and the functionalities of the silk fabrics were determined. Factors affecting the dyeing properties such as dyestuff concentration, temperature, time and pH were studied. The colorimetric parameters $L^*$, $a^*$, $b^*$, and H, V/C values were measured to select the optimal mordanting conditions. The color-fastnesses of the dyed and mordanted fabrics were estimated for practical use; in addition, the antibacterial property, ultraviolet protection properties were evaluated. The dyeabilities of silk increased depending on the increasing dye concentration, dyeing time, and dyeing temperature. And optimum dyeing results were achieved when dyeing with 300% (o.w.f.) of dye concentration at $90^{\circ}C$ for 100 minutes and at pH 3. The dyed silk fabrics without mordants produced yellow (Y) color and showed yellow (Y) or green yellow (GY) colors depending on the mordants type. The light fastness of dyed and Al mordanted silk fabrics were found to be excellent, and the drycleaning and rubbing fastness were good. The dyed silk fabrics showed no antibacterial property, but Al and Cu mordanted silk fabrics showed 99.9% reduction rate. The ultraviolet protection properties of the dyed silk fabric was improved. And the ultraviolet protection properties of mordanted samples showed very good ultraviolet protection properties.

• Fibers and Polymers
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• v.6 no.3
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• pp.224-228
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• 2005

This paper focuses on the application of a novel mathematical limit approach derived for K/S values in reactive dyeing of cotton fabrics. The relation obtained from Kubelka-Munk equation is used because the Kubelka-Munk equation is the basic relationship among fabric reflectance, fabric dye content and dyestuff characteristics. The limit approach derived in a former paper is applied to the laboratory dyeings and the dyeing behavior of some reactive dyes on cotton knitted fabric has been obtained. The results of the laboratory experiments are discussed using the new mathematical approach. When the actual K/S values obtained from the dyeings and the calculated K/S values derived by the limit approach are considered independently, it is observed that the limit relation is val id for low dye concentration applications. When the K/S values are calculated taking the K/S value of the initial dyeing concentration $(0.1\;\%\;owf)$ as the starting concentration by applying the result of the derived limit approach, the calculated K/S values fit with the ones obtained in actual dyeings. It is concluded that the novel approach presented in the paper can be used in calculating the K/S values when the initial dyeings at low dye concentrations are carefully carried out.

• Textile Coloration and Finishing
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• v.29 no.4
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• pp.276-283
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• 2017

The aim of this study is to develop an effective dyeing process for black color on the silk fabrics, using natural Indigo, Madder, Amur cork tree, Alder, Logwood, and Gallnut. All natural dye materials were water-extracted, concentrated, and freeze-dried. Seven different processes were carried out and the color differences(${\Delta}E$) of black color with each process from the chemical black dyed fabric were compared. The light, washing, and rubbing fastness were evaluated. The black dyeing of the silk fabrics was well carried and excellent black color was obtained in every methods. The profound black color could be obtained by the subtractive mixture of the three primary colors of red, yellow, and blue in the order of indigo(blue) - amur cork tree(yellow) - madder or lac(red). Black color was efficiently obtained by iron mordant when logwood or alder fruit was used. The color difference(${\Delta}E$) from the black color with chemical dyestuff was the lowest in the indigo - amur cork tree - lac - iron method. Light fastness and washing fastness were excellent in all dyeing processes, showing grade 5. The fastness to rubbing was excellent as shown grade 5 in the dry samples of logwood - iron process and alder fruit - iron process.

• Journal of Fashion Business
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• v.13 no.1
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• pp.115-124
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• 2009

Chitosan and CA/BTCA were employed in order to induce crosslinking in the fiber for the improvement of wrinkle recovery of the cotton fabrics and the endowment of anti-microbial functions to the fabric. The treated fabrics were dyed by using reactive dyestuff and their dyeing behaviors were investigated. As a result, the fabric treated with chitosan only exhibited more dye-uptake amount than the untreated fabric, and the treated and untreated fabrics together showed excellent light-fastness and wash-fastness. In the cases that CA or BTCA was added to the chitosan, the CA-treated showed better dye-uptake and dyeing properties as light-fastness than the BTCA-treated. In conclusion, it is possible to maintain the dye-uptake level at reduced treatment cost when the CA is employed as a substitute cross-linking agent for BTCA.

• Fashion & Textile Research Journal
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• v.8 no.4
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• pp.465-470
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• 2006

Walnut hull is a by-product from the Walnut tree, used as natural dyestuff from ancient times. This study was done to examine the effects of extractive conditions on the properties of walnut hull extracts for making efficient use of the walnut hull as a natural colorant. Aqueous extracts of walnut hull were prepared at various extractive concentration, temperature and time. Then they were characterized using UV-Vis. Spectrophotometer, FT-IR Spectrometer, Prep Liquid Chromatography, and Energy dispersive X-ray spectrometer. The aqueous extracts have two absorbency peaks of UV-Vis. Spectrum, shoulder type peak in the range of 270-280 nm and broad type band around 420 nm. Intensity of absorbency is increased with increase of extraction concentration and time. However, Boiling temperature extraction method showed the most efficiency of all. Intensity of absorbency is also affected by extraction pH. The Prep LC examined two kinds of isolated colorant with different molecular weight. FT-IR spectra of hull extracts showed an absorption band around $3400cm^{-1}$, the peaks at $1700-1600cm^{-1}$, which are characteristic of aromatic compounds with unsaturated ketone and benzene ring. It showed that the extraction contained some mineral ions, such as K, Ca, Si, Mg.

• Fashion & Textile Research Journal
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• v.11 no.4
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• pp.672-677
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• 2009

To reduce the dependence of wool dyeing on the temperature several solvents with different properties and structures were added to the dye bath of C. I. Acid Yellow 42. Nearly the same total solubility parameters(${\delta}_t$) of solvents as those of wool fiber and hydrophobic part of the dyestuff were needed to increase disaggregation of dye molecules, loosening the wool fiber and wickabilty of dyeing solution; besides, the large surface tension(${\gamma}$) value of the solvents and the well balanced values of the three-component Hansen solubility parameters such as dispersion(${\delta}_d$), polar(${\delta}_p$), and hydrogen(${\delta}_h$) bonding parameters were required. Among the added solvents dimethyl phthalate(DMP) and acetophenone(AP) were satisfied with these conditions and worked the most successfully in the low temperature wool dyeing. Their effectiveness proven by the dyeing rate and the activation energy ($E_a$) of the dyeing was in the order of DMP > AP > DBE > CH > M >NONE. In conclusion the total solubility parameters(${\delta}_t$), the three-component Hansen parameters and the surface tension(${\gamma}$) of DMP and AP could be the guidelines to select suitable solvents for low temperature wool dyeing.

• Journal of Fashion Business
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• v.9 no.1
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• pp.57-66
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• 2005

In natural dyeing, a number of supplementary methods have been practiced since deep shades of the dyed fabrics are not developed satisfactorily. The methods include using the mordants effectively or subjecting the fabrics to reiterated dyeing processes. In this study, we obtained deep shades in the dyeing of fabrics using Rhusjara ica as the dyestuff and applied chitosan to the fabric specimens in order to diversify the colors. Silk fibers and PET(polyethylene terephthalate) fibers were pretreated using chitosan, and subsequently dyed using different types of mordants. As the mordanting agents, Al, Sn, and Fe were employed. Various shades have been resulted in since the interactions of the mordants are different toward the silk fibers and PET fibers. In this study, we investigated the effect of the chitosan treatment along with the change of the mordanting agents on the color change for the silk and PET fibers.

• Journal of Fashion Business
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• v.11 no.5
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• pp.79-89
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• 2007

The effect of chitosan treatment on the dyeing and dye fastness, and mechanical properties of hair was investigated in this study when the carotinoid dyestuffs extracted from African Marigold(Tagetes erecta L.) were applied to the hair. The sequences of the chitosan treatment were changed in dyeing and mordanting procedures, i.e., pre-treatment, mid-treatment, and post-treatment. While the effect of chitosan application on the color shade change was not significant, the pre-treatment of the chitosan increased the dye uptake. Discoloration and fading was observed in the lightfastness test when chitosan was mid-treated. Alkali perspiration and acid perspiration fastness test results showed that chitosan post-treatment gave lower tendency. Washing fastness results showed that chitosan post-treatment and mid-treatment gave lower values, which indicates that chitosan deters the direct formation of insoluble complex among fiber-dyestuff-mordant. In the mechanical characteristics results, however, initial modulus and breaking strength increased significantly in the post-treatment and pre-treatment of chitosan.