• Title/Summary/Keyword: dyeing wastewater

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Performance of fouled NF membrane as used for textile dyeing wastewater

  • Abdel-Fatah, Mona A.;Khater, E.M.H.;Hafez, A.I.;Shaaban, A.F.
    • Membrane and Water Treatment
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    • v.11 no.2
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    • pp.111-121
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    • 2020
  • The fouling of Nanofiltration membrane (NF) was examined using wastewater containing reactive black dye RB5 of 1500 Pt/Co color concentrations with 16890 mg/l TDS collected from El-alamia Company for Dying and Weaving in Egypt. The NF-unit was operated at constant pressure of 10 bars, temperature of 25℃, and flowrate of 420 L/min. SEM, EDX, and FTIR were used for fouling characterization. Using the ROIFA-4 program, the total inorganic fouling load was 1.07 mM/kg present as 49.3% Carbonates, 10.1% Sulfates, 37.2% Silicates, 37.2% Phosphates, and 0.93% Iron oxides. The permeate flux, recovery, salt rejection and mass transfer coefficients of the dye molecules were reduced significantly after fouling. The results clearly demonstrate that the fouling had detrimental effect on membrane performance in dye removal, as indicated by a sharp decrease in permeate flux and dye recovery 68%. The dye mass transfer coefficient was dropped dramatically by 34%, and the salt permeability increased by 14%. In this study, all the properties of the membrane used and the fouling that caused its poor condition are identified. Another study was conducted to regeneration fouled membrane again by chemical methods in another article (Abdel-Fatah et al. 2017).

A comparative study of dyeing wastewater treatment capability for Aerobic Packed/Fluidized-Bed and Moving Media Complete Mixing Activated Sludge system (염색폐수 처리성능에 대한 호기성 고정 및 유동층 생물막공법과 회전매체를 가진 완전혼합 활성슬러지 공법의 비교연구)

  • 김홍태;김규창
    • Journal of Environmental Science International
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    • v.8 no.4
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    • pp.525-532
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    • 1999
  • This study was conducted to evaluate capability of dyeing wastewater treatment for 3 type reactors. These reactors were Packed Bed Reactor(PBR), Fluidized Bed reactor(FBR) and Moving Media Complete Mixing Activated Sludge reactor(MMCMAS). Experiments of PBR and FBR were performed by various packing ratios and organic loading rates, experiments of MMCMAS were performed by various organic loading rates. In order to obtain ${SBOD}_5$ removal efficiencies of more than 90%, the F/Mv ratios of PBR, FBR, MMCMAS were 0.11 kgBOD/kgMLVSS$\cdot$d, 0.12 kgBOD/kgMLVSS$\cdot$d, and 0.37 kgBOD/kgMLSS$\cdot$d, respectively. So MMCMAS system which has more active microorganisms showed better capability of organic removal and also stronger dynamic and shock loadings than those of PBR and FBR. In PBR and FBR, the media packing ratio of 20% showed better performance of organic matters removal effciencies than 10% and 30%, but sludge production rate at media packing ratio of 30% was relatively lower than that of 10% and 20%. When more than 90% organic matters removal efficiency was obtained, the ratios of attached biomass to total biomass at PBR, FBR, MMCMAS were 89~99%, 87~98%, and 54~80%, respectively. The ratio of attached biomass to total biomass was low in MMCMAS. This was formation of thin biofilm due to shear force between rotaing disc and water. The average sludge production rates(kgVSS/kgBODrem.) of PBR, FBR and MMCMAS were 0.20, 0.29 and 0.54, respectively.

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Microbe Isolation and Optimization for the Decolorization of Reactive Dye (반응성 염료의 색도 제거를 위한 균주 분리 및 최적화)

  • 신종철;최광근;전현희;김상용;이진원
    • KSBB Journal
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    • v.19 no.3
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    • pp.200-205
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    • 2004
  • For decolorization of various reactive dyes, 13 species of microbes were isolated from dyeing wastewater collected from Banweol industrial complex, Korea. Two strains among them showed good ability for removing celerity during the decolorization test with 5 different reactive dyes. And the optimal growth conditions were pH 7, 35$^{\circ}C$, yeast extract as nitrogen source, glucose as carbon source, and facultative anaerobic condition. As results, when Reactive Red 180 was used, 89 and 87% of decolorization efficiency were able to be obtained by using Bacillus anthracis and Bacillus cereus, respectively. Especially, Bacillus cereus showed good ability for decolorization of Reactive Blue 21, and the ratio was 76% Finally, it was considered that these two strains isolated in this study will be showed high decolorization ability to treat dyeing wastewater.

Treatment of dyeing wastewater using Moving Bed Bioractor (부유메디아 생물막 공정을 이용한 염색폐수처리)

  • Shin, Dong-Hoon;Lee, Sang-Hun;Ryu, Seung-Han;Park, Jun-Hyung;Jo, Seog-Jin
    • Proceedings of the Korean Society of Dyers and Finishers Conference
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    • 2011.03a
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    • pp.110-110
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    • 2011
  • 염색공업 폐수는 그 성분이 일반적으로 매우 복잡하며, 작업공정의 가동 사항에 따라 수질 변동이 큰것이 특징으로, 각 공정에서 배출되는 염료, 보조화학물질, PVA(Polyvinyl alchol), 전분, wax 등이 포함되어 있으며 pH가 높고, 색도로 인해 하천에 방류될 경우 확산성이 높아 미생물에 의한 자정작용을 방해하여 하천의 수중생태계를 파괴할 우려가 있다. 이러한 염색산업에서 발생하는 폐수는 일반적으로 응집침전, 부상분리법 등의 전처리한 후 활성오니공정으로 처리하는 방법이 널리 이용되고 있으나, 이들 처리공정으로는 폐수 속에 포함되어 있는 다양한화학적 구조의 색소성분 및 유해물질을 완벽하게 제거하는 것이 어려운 실정이다. 유기물 함량이 높은 염색폐수를 처리하기 위해 제안된 기술로는 산소활성슬러지법, 유동상 및 고정상 생물막법, 포괄고정화법 등이 있다. 이러한 기술들중 기존의 처리공정을 증축없이도 처리효율을 높일 수 있는 방법으로 담체를 이용한 부유메디아 생물막공정(Moving-Bed BioReactor, MBBR)이 있다. 이공정은 미생물이 부착, 성장할 수 있는 공극율과 비표면적이 큰 담체를 이용하므로 반응조내의 부유 미생물 뿐만 아니라 담체에 고농도로 부착된 부착 미생물에 의해서도 유기물을 제거하기 때문에 다른 공정들에 비해 처리효율이 뛰어나고 기존의 활성슬러지 공정에 비해 갑작스러운 부하변동 및 유독성 폐수유입에 대해서도 안정적으로 운전이 가능한 장점이 있다. 본연구에서는 부유메디아 생물반응기(Moving-Bed BioReactor, MBBR)을 이용하여 염색폐수내 $COD_{Mn}$, 색도 및 난분해성 물질인 PVA 저감에 대한 Lab-scale test 수행하였다. 실험에 사용된 염색폐수의 수질은 평균 pH 13, $COD_{Mn}$ 900 mg/L, SS 135 mg/L, 색도 1,134 [C.U.], PVA 593 mg/L였으며, 2L의 반응기를 사용하여 회분식 실험을 수행였다. 본 실험에서는 호기성 미생물에 의한 염색폐수의 생분해가 유지되는데 필요한 최적의 용존산소 농도와 이에 필요한 공기 폭기량을 결정하기 위하여 i) DO uptake rate측정과 ii) 담체의 충진율, iii) COD/N ratio, iv) Air 유량, v) 담체내 흡착제의 종류, vi) $Ca^{2+}$ 첨가가 염색폐수의 생분해에 미치는 영향을 살펴보았다. 운전시간을 7일로 하여 COD, 색도, PVA 등을 측정한 결과 담체를 첨가한 경우가 담체를 첨가하지 않은 경우 보다 제거효율이 뛰어났다. 특히 충진율 30%(C/N 3)의 경우에서 COD, 색도, PVA의 제거율이 각각 평균 65%, 70%, 60%로 가장 높은 제거효율을 나타내었다.

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Photocatalytic Membrane for Contaminants Degradation: A Review (오염물질 분해를 위한 광촉매 분리막: 총설)

  • Kahkahni, Rabea;Patel, Rajkumar;Kim, Jong Hak
    • Membrane Journal
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    • v.32 no.1
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    • pp.33-42
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    • 2022
  • Growing industrialization leads to severe water pollution. Organic effluents from pharmaceuticals and textile industries released in wastewater adversely affect the environment and human health. Presence of antibiotics used for antibacterial treatment in wastewater leads to the growth of drug resistance bacteria, which is very harmful for human being. Various small organic molecules are used for the preparation of organic dye molecules in the textile industries. These molecules hardly degrade, which is present in the wastewater effluents from printing and dyeing industries. In order to address these problems, photoactive catalyst is embedded in the membrane and wastewater are passed through it. Through this process, organic molecules are photodegraded and at the same time, the degraded compounds are separated by the membrane. Titanium dioxide (TiO2) is a semiconductor which behave as excellent photocatalyst. Photocatalytic ability is enhanced by the making its composite with other transition metal oxide and incorporated into polymeric membrane. In this review, the degradation of dye and drug molecules by photocatalytic membrane are discussed.

Recycling Technology of Sewage Sludge by Carbonization

  • Park, Sang-U;Jang, Cheol-Hyeon;Kim, Nak-Ju
    • Journal of Environmental Science International
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    • v.13 no.2
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    • pp.161-165
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    • 2004
  • This study has been conducted to develop a new recycling technology of sewage sludge using a carbonization process. The carbonizing yield, the calorific value and EC(electric conductivity) of carbonized sewage sludge had a tendency to be decreased with increase of the carbonizing temperature and time, but pH and the C/N were increased with increase the carbonizing temperature and time. The whole pore volume of carbonized sludge processed in the carbonizing furnace was /g, which was smaller than that in the electric furnace. But, the rates of mesopore and macropore were found to account for 100% therein. Rate of color and organic materials removal for dyeing wastewater were determined 70~97%, 78~83% on cotton yarn, 88~96%, 69~80% on wool wastewater and 77~89%, 77~87% on towel compared with powder activated carbon. Effect of carbonized sludge on chrysanthemum growth was investigated. Plant height and number of leaves was better mixture of carbonized sludge than comparison.

Isolation and Culture Characteristics of Strains for Color Removal of Disperse Dyes (분산성 염료의 색도제거를 위한 균주의 분리 및 성장 특성)

  • 조무환;허만우;한명호;강건우
    • Textile Coloration and Finishing
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    • v.12 no.1
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    • pp.25-31
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    • 2000
  • In order to decolorize disperse dyes by using biological treatment process, a strain which has potential ability to degrade disperse dyes was isolated from natural system. To increase the removal efficiency of decolorization in the aqueous solutions, the optimal condition of decolorization by this strain was investigated, and continuous plant test was also developed. The optimal culture conditions of temperature and pH were found to be 4$0^{\circ}C$ and 8.5~9, respectively. When yeast extract was mixed with polypeptone at the mixing ratio of 1:1 as a nitrogen source, decolorization efficiency was highest(93%) among the nitrogen sources. The strain to be screened was excellent to adjust to pH, and it seems to be have ability to control pH needed to growth. The optimal culture conditions in concentration of $MgSO_4\cdot{7H}_2O$ and $KH_2PO_4$ were 0.1%(w/v) and 0.2%(w/v). The result of continuous plant process using wastewater was as following : $COD_{Mn}$ removal efficiency was over than 50%, and this strain was very excellent in decolorization-efficiency for the wastewater of Taegu dyeing complex.

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Emission Characteristics of Odor Compounds from a Dyeing Wastewater Treatment Plant in an Industrial Complex Area in Daegu City (대구시 산업단지 염색폐수처리장의 악취발생 특성)

  • Lee, Chan-Hyung;Jeon, Hyun-Sook;Kwon, Byoung-Youne;Kim, Eun-Deok;Jang, Yun-Jae;Lee, Myeong-Sug;Keum, Jong-Lok;Song, Hee-Bong
    • Journal of Environmental Health Sciences
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    • v.43 no.4
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    • pp.314-323
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    • 2017
  • Objectives: This study evaluated the odor emission characteristics from a wastewater treatment plant in an industrial complex area in Daegu City. Methods: Odor samples were collected from March 2016 to December 2016 and were analyzed for specified offensive odor substances. The odor quotient and the odor contribution was calculated. Results: Ammonia, hydrogen sulfide, acetaldehyde, and toluene were detected in all samples for monitoring specified odor compounds. The result of contribution analysis is that hydrogen sulfide had the highest contribution in all processes, followed by acetaldehyde. Conclusion: The major components of odor can be determined by evaluating the degree of contribution to the odor intensity and the concentration of the individual odor component. To increase the effectiveness of odor reduction, rather than addressing high-concentration odor compounds, policies focused on materials with a high odor contribution are necessary.

Evaluation of effective process for oxidation and coagulation by ferrous ion and hydrogen peroxide

  • Moon, H.J.;Kim, Y.M.;Lee, S.H.
    • Proceedings of the Korean Environmental Sciences Society Conference
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    • 2003.11b
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    • pp.319-321
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    • 2003
  • This research was carried out to evaluate the removal efficiencies of CODcr and colour for the dyeing wastewater by ferrous solution in Fenton process. The results showed that COD was mainly removed by Fenton coagulation, where the ferric ions are formed in the initial step of Fenton reaction. On the other hand colour was removed by Fenton oxidation rather than Fenton coagulation. The removal mechanism of CODcr and colour was mainly coagulation by ferrous ion, ferric ion and Fenton oxidation. The removal efficiencies were dependent on the ferric ion amount at the beginning of the reaction. However the final removal efficiency of COD and colour was in the order of Fenton oxidation, ferric ion coagulation and ferrous ion coagulation. The reason of the highest removal efficiency by Fenton oxidation can be explained by the chain reactions with ferrous solution, ferric ion and hydrogen peroxide.

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염색폐수에 함유된 PVA 분해 미생물 선별 및 특성 연구

  • Choe, Gwang-Geun;Mun, Sun-Sik;Sin, Jong-Cheol;Lee, Sang-Hun;Kim, Sang-Yong;Lee, Jin-Won
    • 한국생물공학회:학술대회논문집
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    • 2002.04a
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    • pp.371-374
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    • 2002
  • Fifty microbes were isolated from dyeing wastewater. PVA degrading ability was tested by culturing individual strains or two different strains. When single strain was used, the PVA degrading efficiency was 60% at maximum. In the case of combination of two different strains, efficiency was increased up to 96%. And 80% of PVA was degraded within 3 days, which showed the fastest removal rate compared to previously reported data.

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