• Title/Summary/Keyword: dye fastness

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A Study on the Substitution of Cr-containing Metal Complex Dyestuff with Reactive Dyestuff (반응성염료를 통한 Cr 함유 금속착염염료의 대체를 위한 연구)

  • Park, Young-Hwan;Kim, Moon-Jung;Lee, Hea-Jung;Lim, Jae-Ho;Ryu, Tae-Soo
    • Clean Technology
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    • v.15 no.2
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    • pp.91-101
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    • 2009
  • The metal complex dyes that are mainly used for good color fastness in dyeing amide fibers with highly concentrated colors usually contain toxic chromium. The remaining dye in th dyebath containing $Cr^{6+}$ causes not only environmental problems but also serious damages to human health. In this study, we applied reactive dyestuff for dyeing wool and nylon in order to substitute heavy metal dyestuff. The dyeing properties of reactive dyestuff in fibers as well as their absorption rates and fastness according to color concentration were investigated. By analyzing the quantity of heavy metals and toxic amine of reactive dyestuff, we investigated their harmfulness trends quantitatively. By comparing the reactive dyes with traditional metal complex dyes, we tried to find out the possibility of the reactive dye being a clean dyes in the future.

Developing Black Color by Natural Dyeing for Contemporary Fashion: Dyeing of Silk Fabrics (현대패션 활용을 위한 천연염색에 의한 검정색 구현(1): 견직물을 중심으로)

  • Yeo, Youngmi;Shin, Younsook
    • Textile Coloration and Finishing
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    • v.29 no.4
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    • pp.276-283
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    • 2017
  • The aim of this study is to develop an effective dyeing process for black color on the silk fabrics, using natural Indigo, Madder, Amur cork tree, Alder, Logwood, and Gallnut. All natural dye materials were water-extracted, concentrated, and freeze-dried. Seven different processes were carried out and the color differences(${\Delta}E$) of black color with each process from the chemical black dyed fabric were compared. The light, washing, and rubbing fastness were evaluated. The black dyeing of the silk fabrics was well carried and excellent black color was obtained in every methods. The profound black color could be obtained by the subtractive mixture of the three primary colors of red, yellow, and blue in the order of indigo(blue) - amur cork tree(yellow) - madder or lac(red). Black color was efficiently obtained by iron mordant when logwood or alder fruit was used. The color difference(${\Delta}E$) from the black color with chemical dyestuff was the lowest in the indigo - amur cork tree - lac - iron method. Light fastness and washing fastness were excellent in all dyeing processes, showing grade 5. The fastness to rubbing was excellent as shown grade 5 in the dry samples of logwood - iron process and alder fruit - iron process.

A Study on Natural Dyeing with Walnut Hull Extracts (호도 외피를 이용한 천연염색에 관한 연구(I))

  • Song, Kyung-Hun;Baik, Chun-Eui
    • Korean Journal of Human Ecology
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    • v.11 no.4
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    • pp.391-400
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    • 2002
  • This study was intended to research the dyeing with natural walnut hull extracts over cotton, flax, rayon, wool, nylon and silk. We studied the dyeing conditions and mordant effect, and observed dyeability. The result are as follows: 1. In the dyeability with natural walnut hull extracts, protein and polyamide fiber has more dye uptake rather than cellulose fiber. 2. The optimum condition in the dyeing with natural walnut hull extracts was at $90^{\circ}C$, 12%(o.w.b) concentration in 90 mins. 3. In the case of the dyeability by repeated dyeing number, the dyeability of good dyeability fiber is improved in the first or second dyeing, but that of bad dyebality fiber is improved when it is dyed more repeatedly. 4. In the dyeablity treated with mordants, Al, Sn, and Mg don't have any differences, but Cu and Fe have some difference. The color of Fe mordant is green and the color of Cu mordant is blue. 5. In the case of the color fastness with mordant treatment, nylon is better than silk and wool in color fastness to washing but silk is better than nylon and wool in color fastness to light.

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Dyeing Properties of Blanket Fabric of Dyeable Polypropylene

  • Kim, Hyun-Jin;Lee, Jin-Ah;Chang, Young-Min;Park, Jong-Ho;Kim, Sung-Dong
    • Textile Coloration and Finishing
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    • v.19 no.2
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    • pp.36-43
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    • 2007
  • Dyeing and fastness properties of a dyeable PP fiber were examined with four different types of disperse dyes. It was found that the dyed PP fiber could be cleared by soaping without using sodium hydrosulphite, and that the heat setting above $140^{\circ}C$ resulted in the melting of the PP fiber. The rates of dyeing and the extents of exhaustion of three primary E type dyes were different with each other, the apparent color strength did not increase with increasing dye concentration, and color fastness to washing was not satisfactory. In the cases of both high wash fastness and high light fastness dyes, the rates of dyeing were slow and the extents of exhaustion were very low. On the other hand, the dyeing rates of three primary S type dyes were similar and the build-up properties were good with good color fastnesses. It might be concluded that the best disperse dyes for the dyeable PP fiber were S type dyes.

Natural Dyeing of Sheep Leather with Amur Cork Tree (황백을 이용한 양피에의 천연염색)

  • Kim, Sangyool
    • Journal of Fashion Business
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    • v.20 no.5
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    • pp.76-86
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    • 2016
  • In this research, the dyeing properies of Amur cork tree on sheep leathers were evaluated. The proper dyeing conditions were identified with K/S values depending on the colorant concentration, dyeing time, dyeing temperature and dye bath pH. For the proper conditions, the changes of color for different mordants(Al, Cu and Fe) were observed as $L^*a^*b^*$ coordinates and H V/C values. The color fastnesses were also examined, and the antimicrobial properties were examined. The results were as follows: For the sheep leather, the optimized dyeing conditions were 300% o.w.f., 40 min., $40^{\circ}C$, and pH 5. The leather color was yellow in the dyeing and mordanting. Although the $L^*a^*b^*$ changed with the mordants and mordanting methods, the overall hue was yellow. The colorfastness to light was reduced compared to original(untreated) sheep leather. The rubbing fastness was generallry satisfactory as 4-5 rating. The dry-cleaning fastness(stain) of leathers were generally at the 4-5 level, but dry-cleaning fastness(fade) was a little reduced compared to original sheep leather. The dyed and pre-mordanted and dyed sheep leather showed excellent antimicrobial properties.

Dyeing and Antibacterial Properties of N-Containing Fibers Dyed with Henna (질소성분 함유 섬유에 대한 헤나 염색성 및 항균성에 관한 연구)

  • Oh, Kyung-Wha;Park, Jeong-Eun;Park, Myung-Ja
    • Journal of the Korean Society of Clothing and Textiles
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    • v.29 no.11
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    • pp.1520-1526
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    • 2005
  • Henna is a natural colorant and has been used to dye hair, skin and leather since civilization began. It has reddish brown to orange shade. The major color components of Henna are Lawsone(2-hydroxy-1,4-naphthaquinone) and Luteolin (3',4',5,7-tetrahydroxy-flavone). In this study, various fibers containing the nitrogen component, especially used fur underwear, were dyed with Henna under various dyeing conditions, then dyeing characteristics, color fastness, and anti-bacterial properties were evaluated. from the results, Henna has good affinity to the chlorinated wool>wool>Pu/nylon>nylon>soybean>silk in decreasing order. The color fastness of the wool fabric dyed with Henna to washing, dry-cleaning, and perspiration showed 4-5 grade. The color fastness to light was 3rd grade. These results are relatively good comparing with other natural dyes. Moreover dyed fabric with Henna showed excellent antibacterial activity.

Dyeing of Silk Fabrics Using Charcoals (숯을 이용한 견직물의 염색)

  • Jo, Won-Joo;Lee, Jeong-Sook
    • Journal of the Korean Society of Clothing and Textiles
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    • v.29 no.2
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    • pp.279-285
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    • 2005
  • In order to activate the characteristics of charcoals in fiber systems, this study was carried out to experiment with the particle size from two micrometers to ten micrometers of charcoal powders on silk fabrics. The results obtained were as follows; The silk fabrics were dyed with gray color by charcoals effectively. The K/S value, that is indicative of the dye affinity, became higher as the increase of dyeing temperature, dyeing time, and dyeing concentration. Te dyeing effects were the highest with 50%(o.w.f.) of charcoals at $100^{\circ}C$ for 120 minutes in this experiments, It was observed the surfaces of silk fibers were mainly adcorbed with charcoal powders of the particle size from two micrometers to four micrometers by scanning electron microscope. Dyed silk fabrics showed comparatively low fastness to the fade of launding, the stain of the treatment of perspirations, and the strain of water fastness test, but good fastness to the stran of laundering, te drycleaning, the fade of treatment of perspirations, and the fade of water fastness test. In connection with the functional properties of dyed fabrics, the deodorizations were drastically improved, and the far-infrared emissions improved highly, and also the antibacterials were comparatively good.

Dyeing with Natural Dye (II) ―Dyeing of Silk with Sappan Wood― (천연염료에 의한 염색(II) ―소목에 의한 견염색―)

  • Nam, Sung Woo;Chung, In Mo;Kim, In Hoi
    • Textile Coloration and Finishing
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    • v.7 no.4
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    • pp.87-96
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    • 1995
  • Colorant concentrates are prepared by use of concentration method of colorants extracted from Sappan wood using met hanol. Dyeabilities and fastness properties of silk fabrics dyed with concentrate of Sappan wood are investigated.The results obtained are as follows; 1. The storage stability of colorant concentrate is poor as concentration is excess. 2. Because the colors of dyeings are different with mordants, aluminium acetate, copper acetate, chromium alum and tin chloride are used in order to obtain reddish color. 3. The optimum dyeing temperature and dyeing time are 6$0^{\circ}C$ and 60 min, respectively. 4. Dry cleaning fastness is very good, and light fastness and washing fastness are low. 5. The dyeing method is simple owing to usehess of colorant concentrate prepared without extraction of colorant every time.

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The Study on Natural Dyeing with Artemisia (쑥을 이용한 천연염색에 관한 연구)

  • Im, Myeong-Eun;Yu, Hye-Ja;Lee, Hye-Ja
    • Journal of the Korean Society of Clothing and Textiles
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    • v.21 no.5
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    • pp.911-921
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    • 1997
  • Recently the interest in natural dyeing has been increased because of the color clarity, natural grace and reactionism in fashion. Indigo dyeing, safflower dyeing and Gal-ott in Cheju-Do become generally known, so the study about the natural dyeing is continued with national intrust and support. In this study, 1 used artemisia for various dyeing tests because we can get it easily. 1 tested the dyeability in wool as well as cotton and silk with wormwood in natural dyeing material. I also dyed nylon with the same material for the comparison of the molecular structure. The mercerization and the chitosan treatment were done in cotton to improve the low dyeability in the natural dyeing. The result of this study are as follows; We have to dye repeatedly to get deep color in natural dyeing, and mordant treatment brought good result in color difference and dyeing fastness. 1. Compared with silk, wool and nylon, the dyeability of cotton was the worse. The color difference of cotton was 18.81 without mordants , and 24.05 with mordant. The dyeability of cotton was much increased by mordants such as potassiumdichromate, copper sulfate, iron sulfate and salt water. The color of cotton was turned into yellow-green in potassium dichromate and yellow-green with deep green in copper sulfate. The mercerization and the chitosan treatment of cotton made the improvement in color, dyeability, laundering fastness, abrasion fastness. 2. The color difference of silk was 3 times as high as cotton. It showed the similar degree with the chitosan treated-cotton. That is to say, silk had good dyeability because it contains amino group and carboxyl group. The dyebility of silk was increased by a mordant such as iron sulfate, potassium dichromate and salt water, Drycleaning fastness showed 5 grade, abrasion-fastness was high over 4~5 grade and sunlight fastness showed 1 grade in all case. 3. The color difference of wool was the best among four fabrics because of 18 kinds of amino acids. It is considered that the sulfate of wool has the polarity and help metal- mordants get the better dyeability such as potassium dichromate, iron sulfate, copper sulfate, and aluminum chloride. The color was reddish-green in potassium dichromate, yellow.greenin iron sulfate and copper sulfate, and yellow in the rest mordants. Drycleaning fastness of wool showed over 4~5 grade, abrasion fastness 5 grade. Sunlight-fastness 1 grade. 4. The dyeability of nylon was almost same because of the similar molecular structure with silk. The clarity of color was poor. The color was yellow-green in copper sulfate and yellow in the rest mordants. Laundering fastness and abrasion-fastness of nylon was good. Sunlight- fastness represented 1 grade.

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