• Elastomers and Composites
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• v.34 no.2
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• pp.156-176
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• 1999

Rubber chemicals such as accelerators, antidegradants, vulcanizing agents, processing agents and retarders are very important to the production and protection of tires and rubber goods. The use of accelerators and antidegradants are evaluated in various tire components. This paper will focus on how to vulcanize tires economically and maintain the physical properties of each tire component without severe degradation due to oxygen, heat and ozone. Also, new non-nitrosoamine accelerators and non-staining antiozonants will be discussed. Lastly, the future requirements of antidegradants and accelerators in the tire industry will be reviewed. Tires have been vulcanized with Sulfenamides as primary accelerators and either Guamdine's or Thiurams as secondary accelerators to achieve proper properties at service conditions. However, interior components such as the carcass can be vulcanized with Thiazoles as a primary accelerator to cure faster than the external components. Using the combination of Sulfenamide with secondary accelerators in a tire tread compound and the combination of a Thiazole and Guanidine in a carcass compound will be presented with performance data. Uniroyal Chemical and another Rubber Chemical Manufacturer have developed, "Tetrabenzyl Thiuram Disulfide," (TBzTD) as a non-Nitrosoamine accelerator, which could replace Nitrosoamine generating Thiurams. This new accelerator has been evaluated in a tread compound as a secondary accelerator. Also, Flexsys has developed N-t-butyl-2-benzothiazole Sulfenamide (TBSI) as a non-Nitrosoamine accelerator which could replace 2-(Morpholinothio) -benzothiazole (MBS), a scorch delayed Sulfendamide accelerator. TBSI has been evaluated in a Natural Rubber (NR) belt skim compound vs. MBS. An optimum low rolling resistant cure system has been developed in a NR tread with Dithiomorpholine (DTDM). Also, future requirements for developing accelerators will be discussed such as the replacement of DTDM and other stable crosslink systems. Antidegradants are divided into two different types for use in tire compounds. Internal tire compounds such as apex, carcass, liner, wire breaker, cushion, base tread and bead compounds are protected by antioxidants against degradation from oxygen and heat due to mechanical shear. The external components such as sidewall, chafer and cap tread com-pounds are protected from ozone by antiozonants and waxes. Various kinds of staining and non-staining antioxidants have been evaluated in a tire carcass compound. Also, various para-phenylene diamine antiozonants have been evaluated in a tire sidewall compound to achieve the improved lifetime of the tire. New non-staining antiozonants such as 2, 4, 6-tris-(N-1, 4-dimethylpentyl-p-phenylene diamine) 1, 3, 5 Trizine (D-37) and un-saturated Acetal (AFS) will be discussed in the tire sidewall to achieve better appearance. The future requirements of antidegradants will be presented to improve tire performance such as durability, better appearance and longer lasting tires.

• Journal of the Korea Institute of Building Construction
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• v.15 no.3
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• pp.265-271
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• 2015

This study is intended to produce a PC (Precast Concrete) member without a steam curing process in developing the high early strength concrete satisfying the condition of 10MPa in compressive strength at the age of 6 hours, and is intended to ensure economic feasibility by increasing the turnover rate of concrete form. Hence, high early strength cement with high $C_3S$ content and the hardening accelerator of powder type accelerating the hydration of $C_3S$ was used. And the properties of concrete were evaluated according to the hardening accelerator mixing ratio (0, 1.2, 1.6, 2.0). No big difference was found from the tests of both slump and air content. When 1.6 % or higher amounts of the hardening accelerator were mixed, the compressive strength of 10MPa was achieved at the age of 6 hours. From the test results of autogenous (drying) shrinkage and plastic shrinkage, it can be seen that there was a difference according to hydration reaction rate due to the addition of the hardening accelerator. However, it was shown that no problem arose with crack and durability. And it was shown that resistance to freezing-thawing, carbonation, and penetration were excellent.

• Journal of the Korea Concrete Institute
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• v.17 no.4 s.88
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• pp.595-602
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• 2005

The purpose of this study is to utilize recycled concrete aggregates as permeable pavement materials. This study evaluates mechanical properties and durability of porous concrete depending on mixing rates of recycled aggregates and polyme. As a result, void ratio and permeability coefficient of porous concrete for pavement increased a little as mixing rate of recycled aggregates increased. Void ratio and permeability coefficient increased a lot as mixing rate of polymer increased. As polymer was mixed $20\%$, national regulation of permeable concrete for pavement($8\%$ and 0.01cm/sec) was met. Compressive strength and flexural strength decreased as mixing rate of recycled aggregates increased but they increased a lot as mixing rate of polymer increased. Even when recycled aggregates were mixed $75\%\;with\;10\%$ polymer mixed, national regulation of pavement concrete(18MPa and 4.5MPa) was met. In addition, regarding sliding resistance, BPN increased as mixing rate of recycled aggregates increased. But BPN decreased as polymer was mixed. Compared to crushed stone aggregates, abrasion resistance and freeze-thaw resistance decreased as mixing rate of recycled aggregates Increased. When polymer was mixed, abrasion resistance and freeze-thaw resistance improved remarkably. Compared to non-mixture, $10\%$ mixture of polymer improved abrasion resistance and freeze-thaw resistance about $8.6\%$ and 3.8times respectively.

• Journal of the Korean Recycled Construction Resources Institute
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• v.3 no.2
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• pp.132-139
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• 2015

In this study, the different unit cement content by the ratio of water absorption and water-cement ratio are applied to examine the properties of the concrete used the aggregate recycled by the crushing treatment. According to the experimental results, in the mix of low strength and high water-cement ratio, both of the compressive strength is almost equal in the concrete using the recycled aggregate by the crushing treatment and the concrete using broken stones. It means that the recycled aggregate has the low effect of the amount of bonded mortar. But, in the mix of high strength and low water-cement ratio, the concrete using the recycled aggregate by the crushing treatment has 40% less of the compressive strength than that using broken stones by the effect of the amount of bonded mortar. On the other hand, after 8 weeks, the dry shrinkage of the recycled aggregate with 7% of the ratio of water absorption doubles that of the broken stones with 1% ($-350{\times}10^{-6}$), in other words $-700{\times}10^{-6}$. Thus, the dry shrinkage should be prior to any other conditions in recycling waste concrete for the aggregate for concrete. When the recycled aggregate with 3% of the ratio of water absorption is used, the compressive strength of the rich mix concrete ($450kg/m^3$ of the unit cement content) is equivalent to that of the concrete using broken stones, while in using the recycled aggregate with 7% of the ratio of water absorption, the rich mix concrete has 7% lower compressive strength than the concrete using broken stones. But, the compressive strength of the ordinary mix concrete ($350kg/m^3$ of the unit cement content) is far lower than that using broken stones.

• Journal of the Korean Wood Science and Technology
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• v.35 no.1
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• pp.51-63
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• 2007

The biodeterioration behaviors of wooden parts in the Janggeongpanjeon built in 15 century were investigated according to the types of wood species, positions and parts of wooden column, and environmental conditions. It was found that a high differences of deterioration in the progressing levels of wood decay, according to the types of wood species, positions and parts of wooden column, and environmental conditions. The decay levels were high in the contacted areas with stone foundation which are about up to 8~40 cm above it, although it was shown the many of wooden parts of the round columns are still good condition. In the case of decay type, it was shown the brown-rot in many of the columns at outside of building which made of hardwoods. The decay in position of the columns was most serious in the directions of east-north, west-north and north. It was also indicated that the durability of Zelkova serrata was higher than other wood species of the round columns, while it was in inferior anti-insects.

• Journal of the Korean Wood Science and Technology
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• v.45 no.2
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• pp.213-222
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• 2017

Heat treatment of wood is an attractive alternative environmentally-friendly treatment to add value of less valuable woods by improving color, dimensional stability, and natural durability. To improve the color properties of Korean white pine (Pinus koraiensis) and royal paulownia (Pauwlonia tomentosa), we treated the woods at $160^{\circ}C$, $180^{\circ}C$, $200^{\circ}C$, and $220^{\circ}C$ for 2 hours. Color change after heat treatment was evaluated using the CIE-Lab color system and survey was conducted to determine the consumer preferences towards color of heat-treated wood. Lightness ($L^*$) decreased with increasing temperature and the higher degree of change was obtained in royal paulownia. The red/green chromaticity ($a^*$) in both wood decreased after heat treatment at $160^{\circ}C$, and constantly increased after heat treatment at $180^{\circ}C$ to $220^{\circ}C$. Yellow/blue chromaticity ($b^*$) in Korean white pine tended to increase after heat treatment at $160^{\circ}C$, then decreased gradually afterwards. In royal paulownia, $b^*$ values linearly increased with increasing temperature. Overall color change (${\Delta}E^*$) increased with increasing temperature with higher degree obtained in royal paulownia. Samples with the clamps in both wood species showed lower degree of the change in $L^*$, $a^*$, b and ${\Delta}E^*$. The results of the consumer preferences test showed that the darker colors of heat-treated woods were more preferred by consumers compared to the lighter colors of untreated woods. Consequently, heat treatment could enhance the color properties of Korean white pine and royal paulownia woods for value added products.

• Food Science and Preservation
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• v.14 no.2
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• pp.154-159
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• 2007

In efforts to use pine needle extract as a substitute for sugar, fermented pine needle extract syrup was added to the wheat flour nea in the manufacture of white bread The extract was added to levels of 8.3%, 11% and 18% of total weight based on the Brix degree of the dough The cohesion of each dough was checked, and the physical properties and storage stabilities of the baked breads were analyzed during storage at mom temperature. Analysis of the cohesion of each dough by farinogram showed that dough with pine needle extract was better than dough with sugar, in terms of both stability and durability of mixing. The pH of dough with syrup was steady during storage at pH 5.4 5.8, which is favorable for yeast activity. The dough with syrup also showed low firmness and good extensibility, both of which would favorably affect gas retention on fermentation. Increases in syrup addition resulted in higher product volumes. Bread with syrup was slow to increase in hardness during storage, suggesting that higher syrup concentrations inhibited development of staleness. The addition of syrup also inhibited the growth of aerobic bacteria and mold on the bread surface. The addition of syn did not cause any negative effect. The use of pine none extract syrup may thus contribute to improvements the physical properties, the storage stability, and the hygienic quality of bread.

• Journal of the Korea Academia-Industrial cooperation Society
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• v.19 no.11
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• pp.319-325
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• 2018

The use of 3D printing (Additive Manufacturing) technology has expanded from initial model production to the mass production of parts in the industrial field based on the continuous research and development of materials and process technology. As a representative polymer material for 3D printing, the polyamide-based material, which is one of the high-strength engineering plastics, is used mainly for manufacturing parts for automobiles because of its light weight and durability. In this study, the specimens were fabricated using Selective Laser Sintering, which has excellent mechanical properties, and the flexural characteristics were analyzed according to the temperature of the two types of polyamide 12 and glass bead reinforced PA12 materials. The test specimens were prepared in the directions of $0^{\circ}$, $45^{\circ}$, and $90^{\circ}$ based on the work platform, and then subjected to a flexural test in three test temperature environments of $-25^{\circ}C$, $25^{\circ}C$, and $60^{\circ}C$. As a result, PA12 had the maximum flexural strength in the direction of $90^{\circ}$ at $-25^{\circ}C$ and $0^{\circ}$ at $25^{\circ}C$ and $60^{\circ}C$. The glass bead-reinforced PA12 exhibited maximum flexural strength values at all test temperatures in the $0^{\circ}$ fabrication direction. The tendency of the flexural strength changes of the two materials was different due to the influence of the plane direction of the lamination layer depending on the type of stress generated in the bending test.

• Journal of the Korea Academia-Industrial cooperation Society
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• v.20 no.1
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• pp.200-207
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• 2019

Cement is one of the most commonly used materials in the construction and civil engineering industry. However, emissions of carbon dioxide generated during the production of cement have been linked to climate change and environment pollutants. In order to replace cement, many studies have been actively performed research to utilizing Blast Furnace Slag(BFS), which is a byproduct of the steel industry. This study aims to investigate the physiochemical properties of the BFS powder based grout to determine whether it can be used as an environment-friendly grout material. As a fine powder, BSF can be used instead of cement grout due to its potential hydraulic property. BSF has also been known for its ability to strengthen materials long-term and to densify the internal structure of concrete. In order to investigate the physicochemical properties of the BFS powder based grout as a grout material, in this study assessment tests were performed through a gel-time measurement, uniaxial compressive strength, and chemical resistance tests, and heavy-metal leaching test. Characteristics and advantages of the slag were studied by comparing slag and cement in various methods.

• Journal of the Korea institute for structural maintenance and inspection
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• v.23 no.2
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• pp.28-36
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• 2019

The adhered mortars in recycled aggregate may lower the performance of the concrete, such as by reducing in strength and durability, and cracking. In the present study, the effects of nylon fiber (NF) on the mechanical and durable properties of 100% ordinary portland cement (OPC) and 50% ground granulated blast furnace slag (GGBFS) concretes incorporating recycled coarse aggregate (RA) were experimentally investigated. Concrete was produced by adding 0 and $0.6kg/m^3$ of NF and then cured in water for the predetermined period. Measurements of compressive and split tensile strength, water permeable pore and total charge passed through concrete were carried out, and the corresponding test results were compared with those of concrete incorporating crushed coarse aggregate (CA). In addition, the microstructures of 28-day concretes were observed by using SEM technique. Test results revealed that the RA concrete showed lower performance than CA concrete because of the adhered mortars in RA. However, it was obvious that the addition of NF in RA concrete was much effective in enhancing the performance of the concretes due to the bridge effect from NF. In particular, the application of NF2 (19 mm) exhibited a somewhat beneficial effect compared with concrete incorporating NF1 with respect to mechanical properties, especially for RA concrete.