• Transactions of the Korean hydrogen and new energy society
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• v.25 no.5
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• pp.482-490
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• 2014

Gaseous sulfur compound such as $H_2S$ or COS in coal- or biomass-derived hot syngas can be purified by solid sorbents at high temperatures. In this study, we investigated the physical properties and reactivity of solid regenerable desulfurization sorbents with 37.2, 41.9, and 46.5wt% ZnO to look into the ZnO content effect. The sorbents were produced by spray-drying method to apply to a fluidized-bed process. Sulfidation and regeneration reaction were carried out using a thermogravimetric analyzer. Sorbent prepared with 46.5wt% ZnO had physical properties suitable for a fluidized-bed process applications such as spherical shape, sufficient mechanical strength and density, high porosity and surface area. It showed high sulfur sorption capacity of 10.4wt% (ZnO utilization of 57%) at reaction temperatures of 500 and $650^{\circ}C$ for sulfidation and regeneration, respectively. However, the sulfur sorption capacity and ZnO utilization were significantly reduced and dimple shape appeared when the ZnO content decreased to 37.2 and 41.9wt%. Sulfur sorption capacity and regenerability were improved as reaction temperature increased within the experimental temperatures used in this work. The reaction temperature zones of $1500{\sim}550^{\circ}C$ and $650{\sim}700^{\circ}C$ are recommended for sulfidation and regeneration, respectively, to lead best reaction performances of the ZnO-based spray-dried sorbents developed in this work.

• Applied Chemistry for Engineering
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• v.10 no.5
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• pp.748-753
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• 1999

In gelcasting process of the Si powder slurry mixed with acrylamide monomers, it was characterized the effects of chemical parameters such as monomers and additives(polymerization initiator, catalyst and dispersant), Si powder and humidity at drying on processing parameters such as viscosity and idle time as well as on shrinkage and mechanical strength of green bodies. Generally, idle time decreased as initiator and catalyst amounts were increased, but rather depended on initiator. Idle times of the slurries greatly decreased to less than 1/2 time of the premix solutions in which gelation was delayed at higher MBAM portion as a crosslinking monomer. And fluidity of the slurries became worse at greater than 0.6 wt % dispersant. The green bodies showed only less than 7% of linear shrinkage without crack and distortion when dried for longer than 300 hrs under 98% humidity. Typically, the dried bodies containing 40, 50 vol % of Si powder displayed 64 and 36 Mpa in average, respectively.

• Journal of the Korea Concrete Institute
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• v.18 no.2 s.92
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• pp.177-188
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• 2006

Conventional nonlinear finite element analysis requires complicated modeling and analytical technique. Furthermore, it is difficult to interpret the analytical results presented as the stress-strain relationship. In the present study, a design-oriented analytical method using the truss model was developed. A reinforced concrete member to be analyzed was idealized by longitudinal, transverse, and diagonal line elements. Basically, each element was modeled as a composite element of concrete and re-bars. Simplified cyclic models for the concrete and re-bar elements were developed. RC beams and walls with various reinforcement details were analyzed by the proposed method. The inelastic strength, energy dissipation capacity, deformability, and failure mode predicted by the proposed method were compared with those of existing experiments. The results showed that the proposed model accurately predicted the strength and energy dissipation capacities, and to predict deformability of the members, the compression-softening model used for the concrete strut element must be improved.

• Journal of Biosystems Engineering
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• v.35 no.1
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• pp.64-68
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• 2010

Cattle feedlot manure could be used effectively as the solid fuel for heating of agricultural facilities. Therefore, this study was carried out to investigate the thermal and physicochemical characteristics of solid fuel extruded with cattle feedlot manure. Calorific values of the solid fuel extruded with cattle feedlot manure, which was dried to the moisture contents of 0.0% (w.b) and 35.0% (w.b,) were 14,906 kJ/kg and 11,797 kJ/kg, respectively. Calorific value of extruded solid fuel was linearly decreased with the increase of moisture content. The first, second, and third reaction point during thermal pyrolysis of solid fuels extruded with cattle feedlot manure was investigated as $108.1^{\circ}C$, $312.2^{\circ}C$, and $459.4^{\circ}C$, respectively. The maximum reaction point was presented at the temperature of $312.2^{\circ}C$. Weight loss of extruded cattle feedlot manure during thermal pyrolysis until $600^{\circ}C$ was reached to about 60%. Volume decrease of initial extruded cattle feedlot manure was 61% during drying for the use as solid fuel. Maximum strength of extruded cattle feedlot manure, which was dried as the moisture content of 10% (w.b.) was 41,9150 N/$m^2$. Ignition gas analysis of extruded cattle feedlot manure presented that it has small amount of $NO_x$ and $SO_x$. It was shown that dried cattle feedlot manure had main components of C and O including small amount of Mg, Si, and Ca.

• Journal of the Korean Ceramic Society
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• v.30 no.7
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• pp.535-542
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• 1993

It was investigated in this study that a preparation method, activation energy, surface area, pore volume, pore size distribution and DTA analysis of the dry gel in process of producing monolithic porous gel in Li2O-Al2O3-TiO2-SiO2 system by the sol-gel technique using metal alkoxides. Activation energy for gellation according to the variation of water concentration and the kind of catalysts ranged from 10 to 20kcal/mole. Monolithic dry gels were prepared after drying at 9$0^{\circ}C$ when the amount of water for gellation was 4~8 times more than the stoichiometric amount, that was necessary for the full hydrolysis of the mixed metal alkoxide. The specific surface area, the pore volume, the average pore radius of the dried gel at 18$0^{\circ}C$ according to the various kinds of catalyst were about 348~734$m^2$/g, 0.35~0.70ml/g and 10~35$\AA$, respectively. It showed that the dry gels were porous body. As a result ofthe analysis of DTA, it was confirmed that the exothermaic peaks at 715$^{\circ}C$ and 77$0^{\circ}C$ was clue to the crystallization of dried gel.

• Smart Structures and Systems
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• v.20 no.2
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• pp.175-180
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• 2017

The load-carrying capacity and structural behavior of concrete-filled steel tube (CFST) structures is highly influenced by the grouting compactness in the steel tube. Due to the invisibility of the grout in the steel tube, monitoring of the grouting progress in such a structure is still a challenge. This paper develops an active sensing approach with combined piezoceramic-based smart aggregates (SA) and piezoceramic patches to monitor the grouting compactness of CFST bridge structure. A small-scale steel specimen was designed and fabricated to simulate CFST bridge structure in this research. Before casting, four SAs and two piezoceramic patches were installed in the pre-determined locations of the specimen. In the active sensing approach, selected SAs were utilized as actuators to generate designed stress waves, which were detected by other SAs or piezoceramic patch sensors. Since concrete functions as a wave conduit, the stress wave response can be only detected when the wave path between the actuator and the sensor is filled with concrete. For the sake of monitoring the grouting progress, the steel tube specimen was grouted in four stages, and each stage held three days for cement drying. Experimental results show that the received sensor signals in time domain clearly indicate the change of the signal amplitude before and after the wave path is filled with concrete. Further, a wavelet packet-based energy index matrix (WPEIM) was developed to compute signal energy of the received signals. The computed signal energies of the sensors shown in the WPEIM demonstrate the feasibility of the proposed method in the monitoring of the grouting progress.

• KOREAN JOURNAL OF PACKAGING SCIENCE & TECHNOLOGY
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• v.4 no.2
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• pp.24-32
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• 1998

This study examined the effects of recycling on chemical pulp fibers from multiple recycles. Firstly, water-pretreated alkaline photocopy paper was disintegrated by TAPPI standard disintegrator at room temperature. After dewatering, this pulp was dried in oven at $80^{\circ}C$ for 24hrs. A sequence of wetting, disintegrating and drying was one recycling cycle and this cyclic treatment was repeated from zero to five times. The recycled handsheet dropped to 90% of the original brightness after five cycles, and lost the most brightness in the first two cycles. However, it had a gain of 10% in opacity after five cycles. And, in this study, the method for determining residual ink(toner) content in recycled handsheets were estabilished by means of SEM-EDX and atomic absorptive photometer. The change of residual ink percentage on recycled paper showed the effect of recycling numbers on deinkability of waste paper. A slight decrease in deinkability was noted for the recycled handsheets, which may be due to the change of fiber surface free energy connected with fiber swelling.

• Korean Journal of Materials Research
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• v.12 no.12
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• pp.930-934
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• 2002

Nanosized $WO_3$ powders were synthesized by the sol-precipitation process using $WCl_{6}$ as the starting material, ethanol as a solvent and $NH_4$OH solution as a precipitant, followed by a washing-drying treatment and calcination. The effects on the powder crystallinity and microstructure of calcination temperature were investigated with XRD and FE-SEM. The $WO_3$ powders calcined at $500^{\circ}C$ and $700^{\circ}C$ showed good crystallinity and their mean particle size was 30nm and 70nm, respectively. These powders were used for the preparation of pastes which were printed as thick films on alumina substrates with comb-type Pt electrodes. The particle size strongly influenced the $NO_2$ gas sensing property of the thick films. A significant reduction in the $NO_2$ sensitivity was observed for the film prepared from larger particle size, having thus a larger grain size. For the film having a smaller grain size, on the other hand, the higher $NO_2$ sensitivity was observed and the sensitivity increased with $NO_2$ concentration.

• Korean Journal of Environmental Agriculture
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• v.36 no.1
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• pp.29-35
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• 2017

BACKGROUND: This study was carried out to assess a biochemical methane potential of giant miscanthus (Miscanthus sacchariflorus) which was a promising candidate energy crop due to a high biomass productivity, in order to utilize as a feedstock for the biogas production. METHODSANDRESULTS: Giant miscanthus was sampled the elapsing drying time of 6 months after harvesting. TS (Total Solid) and VS (Volatile Solid) contents were 94.7 and 90.8%. And CP (Crude Protein), EE (Ether Extracts), and CF (Crude Fiber) contents of giant miscanthus were 1.4, 0.46, and 46.12%, respectively. In the organic composition of giant miscanthus, the NDF (Neutral Detergent Fiber) representing cellulose, lignin, and hemicellulose contents showed 86.88%, and the ADF (Acid Detergent Fiber) representing cellulose and lignin contents was 62.91%. Elemental composition of giant miscanthus showed 47.75%, 6.44%, 41.00%, and 0.28% for C, H, O, and N, respectively, and then, theoretical methane potential was obtained to $0.502Nm^3kg^{-1}-VS_{added}$. Biochemical methane potential was assessed as the range of $0.154{\sim}0.241Nm^3kg^{-1}-VS_{added}$ resulting the lower organic biodegradability of 30.7~48.0%. CONCLUSION: Therefore the development of pretreatment technology of the giant miscanthus was needed for the improvement of anaerobic digestability.

• Proceedings of the Korean Institute of Resources Recycling Conference
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• 2003.10a
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• pp.134-138
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• 2003

The purpose of this paper is to recycle the fly ash to the valuable resources and settle environment problems which was caused by the fly ash produced from the thermal power plant. Making the fly ash-cement matrix reused fly ash in large quantities, we looked into minutely the physical properties - the elastic modulus, the compressive strength - to increase the usefulness as the building materials for the structure widely. In this paper, the variables are the water-binder(39, 42, 45%), the fine aggregate ratio(37, 41, 45%). Because the fracture energy is influenced by the strength, it is showed to decrease with the increase of W/B and S/a. Besides, we will be able to know that basic properties of the fly ash-cement matrix are similar to that of concrete. But, it is needed to carry out durability experiment on the drying shrinkage, creep, freezing and thawing test to use structural materials.