• 한국세라믹학회지
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• 제39권10호
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• pp.919-927
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• 2002

표면층과 내부간의 기공구조가 다른 다공질체를 제조하기 위해 입자크기가 다른 두 종류의 분체를 이용하여 다공질 성형체를 제조하였다. 두 층간의 소결 수축율을 동일하게 제어하기 위해 성형밀도 변화에 따른 소결밀도 변화를 예측할 수 있는 Ford＇s equation을 도입하여 소결 수축율을 동일한 조건을 구하였다. 제조된 다공질체는 미세구조와 통기도를 조사함으로서 기공의 이중 구조화 여부를 평가하였다. SEM 관찰결과 기공크기가 다른 두 층으로 구성되어 있는 것을 확인하였다. 각 층의 통기도는 출발 입자크기와 기공율이 클수록 증가하였으며, 이중 기공구조를 갖는 시편의 통기도는 기공크기가 작은 층의 특성에 의존하였다.

• 대한치과보철학회지
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• 제44권2호
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• pp.147-156
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• 2006

Statement of problem: The high melting temperature and chemical reactivity of titanium necessitates casting machines different from those used in conventional casting. Despite the new developments in Ti casting systems , inadequate mold filling and internal porosity are frequently observed casting defects. Therefore, the study on the fabrication technique including sprue design to solve these casting defects is still necessary. Purpose: The purpose of this study was to evaluate the effect of sprue design and cross sectional area of sprue on the internal porosity. Materials and methods: 30 simulated cast three units titanium crowns were prepared. 5 cast crowns for each with different sprue design(sinlge sprue, double sprue and plate sprue) of two cross sectional areas (small and large cross sectional areas) were fabricated. The sections of titanium castings were photographed in a microscope at ${\times}100$ magnification to record internal porosities. Results and Conclusion: Within the limits of this study, the following conclusions were drawn: 1. There was a significantly lower in internal porosity of titanium castings for large cross sectional area of sprue group than the small group (P<.05) 2. There was no significant difference in internal porosity among sprue designs in similar cross sectional area of sprue (P>.05).

• 대한치과보철학회지
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• 제40권4호
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• pp.352-364
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• 2002

There has been a great interest in the use of titanium for fixed and removable prostheses in recent because of its excellent biocompatibility. However the high melting temperature and chemical reactivity of titanium necessitates casting systems different from those used in conventional casting. The current titanium casting systems are based on an electric-arc design for melting the metal in an argon atmosphere and its exclusive investment. Despite the new developments in Ti casting systems, inadequate mold filling and internal porosity are frequently observed casting defects. Therefore, the study on the fabrication technique including sprue design to solve these casting defects is still necessary. In this study to evaluate the effect of sprue design on the castability of simulated cast titanium crowns, 10 cylindrical cast crowns for each group with four different sprue design(Single group. Double group, Runner bar group. Reservoir group) were fabricated. An impression of the entire casting margin was made and cut at $90^{\circ}$ intervals, and the sections were photographed in a microscope at $100{\times}$ magnification to record marginal discrepancy. The internal porosities of the cast crowns were disclosed by radiographs. Within the limits of this study. the following conclusions were drawn. 1. The overall mean marginal discrepancies for each group were as follows: Double group, $43.65{\mu}m$; Reservoir group, $50.27{\mu}m$; Single group, $54.17{\mu}m$; Runner bar group, $58.90{\mu}m$ (p<0.05). 2. The mean of marginal discrepancies for wax patterns was $10.65{\mu}m$. 3 The numbers of internal porosity showed the most in Runner bar group followed by Single group, Reservoir group, and Double group.

• Journal of Pharmaceutical Investigation
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• 제40권4호
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• pp.245-250
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• 2010

Porous poly(lactic-co-glycolic acid) microspheres (PLGA MS) have been utilized as an inhalation delivery system and a matrix scaffold system for tissue engineering. Here, gelatin (type A) is introduced as an extractable pH-responsive porogen, which is capable of controlling the porosity and pore size of PLGA microspheres. Porous PLGA microspheres were prepared by a water-in-oil-in-water ($w_1/o/w_2$) double emulsification/solvent evaporation method. The surface morphology of these microspheres was examined by varying pH (2.0~11.0) of water phases, using scanning electron microscopy (SEM). Also, their porosity and pore size were monitored by altering acidification time (1~5 h) using a phosphoric acid solution. Results showed that the pore-forming capability of gelatin was optimized at pH 5.0, and that the surface pore-formation was not significantly observed at pHs of < 4.0 or > 8.0. This was attributable to the balance between gel-formation by electrostatic repulsion and dissolution of gelatin. The appropriate time-selection between PLGA hardening and gelatin-washing out was considered as a second significant factor to control the porosity. Delaying the acidification time to ~5 h after emulsification was clearly effective to make pores in the microspheres. This finding suggests that the porosity and pore size of porous microspheres using gelatin can be significantly controlled depending on water phase pH and gelatin-removal time. The results obtained in this study would provide valuable pharmaceutical information to prepare porous PLGA MS, which is required to control the porosity.

• 한국진공학회:학술대회논문집
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• 한국진공학회 2011년도 제40회 동계학술대회 초록집
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• pp.467-467
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• 2011

Reflecting the growing importance of nanomaterials in science and technology, controlling the porosity combined with well-defined structural properties has been an ever-demanding pursuit in the related fields of frontier researches. A number of reports have focused on the synthesis of various nanoporous materials so far and, recently, the nanomaterials with multimodal porosity are getting an emerging importance due to their improved material properties compared with the mono porous materials. However, most of those materials are obtained in bulk phases while the spherical nanoparticles are one of the most practical platforms in a great number of applications. Here, we report on the synthesis of the core-shell silica nanoparticles with double mesoporous shells (DMSs). The DMS nsnoparticles are spherical and monodispersive and have two different mesoporous shells, i.e., the bimodal porosity. It is the first example of the core-shell silica nanoparticles with the different mesopores coexisting in the individual nanoparticles. Furthermore, the carbon and silica hollow capsules were also fabricated via a serial replication process.

• Geomechanics and Engineering
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• 제2권3호
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• pp.191-202
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• 2010

The porosity (including the specific surface area and pore volume-diameter distribution) of montmorillonitic soft rock (MSR) was studied experimentally with an electrochemical treatment, based on which the change in porosity was further analyzed from the perspective of its electrokinetic potential (${\zeta}$ potential) and the isoelectric point of the electric double layer on the surface of the soft rock particles. The variation between the ${\zeta}$ potential and porosity was summarized, and used to demonstrate that the properties of softening, degradation in water, swelling, and disintegration of MSR can be modified by electrochemical treatment. The following conclusions were drawn. The specific surface area and total pore volume decreased, whereas the average pore diameter increased after electrochemical modification. The reduction in the specific surface area indicates a reduction in the dispersibility and swelling-shrinking of the clay minerals. After modification, the ${\zeta}$ potential of the soft rock was positive in the anodic zone, there was no isoelectric point, and the rock had lost its properties of softening, degradation in water, swelling, and disintegration. The ${\zeta}$ potential increased in the intermediate and cathodic zones, the isoelectric point was reduced or unchanged, and the rock properties are reduced. When the ${\zeta}$ potential is increased, the specific surface area and the total pore volume were reduced according to the negative exponent law, and the average pore diameter increased according to the exponent law.

• 전자공학회논문지A
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• 제29A권11호
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• pp.78-83
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• 1992

The current-voltage characteristics at SrO${\cdot}6Fe_{2}O_{3}$ electronic ceramics interfaces have been studied using cyclic voltammetric methods. The symmetrical and stable cyclic voltammograms, which indicate the same anodic and cathodic process, are obtained on the whole experiments. The approximate saturation current is 50$\mu$A but the value depends on the experimental processes of the electrode specimens. The current-voltage characteristics of SrO${\cdot}6Fe_{2}O_{3}$ electronic ceramics in dilute aqueous electrolytes or double deionized water are determined by the water adsorption process and the interconnected porosity effect. On the other hand, the current-voltage characteristics in relatively concentrate aqueous electrolytes are determined by the ionic adsorption process and the related electrical double layers. The SrO${\cdot}6Fe_{2}O_{3}$ electronic ceramics can be directly used as an electrochemically stabled resistor, electrode or a humidity sensor.

• 한국해안해양공학회지
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• 제13권4호
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• pp.263-272
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• 2001

최근 우리나라에서는 slit형 케이슨을 적용한 방파제 건설이 시도되고 있다. slit 케이슨 방파제는 수심이 비교적 깊은 해역에 적절하며, 다수의 실험적.이론적 연구가 수행되었다. 본 연구에서는 불규칙파를 적용한 2차원 수리모형실험을 실시하여 종 slit형 케이슨 방파제의 반사특성을 검토하였다. 실험은 단일 유수실과 이중 유수실을 가지는 종 slit형 케이슨 방파제에 대해 유공율, 유수실의 폭 및 slit의 수 등을 달리한 여러 가지 실험안을 설정하여 수행하였다. 실험결과에 의하면, 파형경사가 작을수록 반사율은 크게 나타남을 알 수 있다. 그리고 규칙파를 적용한 기존 연구결과에 의하면 상대유수실 폭 (B/L)이 0.2-0.25 부근에서 최소 반사율을 보였으나, 불규칙파를 적용한 본 연구에서는 B/L$_{s}$ ,=0.13~0.15 범위에서 최소의 반사율을 보였다. 또한 동일한 유공율 조건에서 slit의 폭이 클수록 반사율이 낮게 나타났으며, 전체적으로 단일 유수실보다 이중 유수실의 경우가 소파효과가 우수하였다.

• 한국해안·해양공학회논문집
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• 제32권6호
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• pp.420-433
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• 2020

기존 케이슨방파제의 안정성을 높이기 위해 케이슨 전면 또는 후면에 추가로 신규 케이슨을 설치하여 보강하는 경우 박리에 의한 에너지 손실효과와 케이슨과 케이슨 사이의 공극률 변화에 따른 개별 원형케이슨에 작용하는 파력 및 파처오름 특성 평가는 중요하다. 본 연구에서는 고유함수전개법에 투과성판에서의 속도는 판 전후의 압력차에 선형적으로 비례한다는 Darcy의 법칙을 이용하여 원형케이슨들간의 공극률 계수 변화에 따른 2열 배치된 원형방파제에 작용하는 파랑 특성을 분석하였다. 수치해석의 신뢰성을 확보하기 위해 Sankarbabu et al.(2008)의 수치 해석결과와 비교를 수행하였으며, 다양한 변수에 따른 개별 이중 원형케이슨에 작용하는 파력 및 파처오름 특성을 나타내었다.

• Wind and Structures
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• 제35권1호
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• pp.67-81
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• 2022

While the aerodynamics of solid bluff bodies is reasonably well-understood and methodologies for their reliable numerical simulation are available, the aerodynamics of porous bluff bodies formed by assembling perforated plates has received less attention. The topic is nevertheless of great technical interest, due to their ubiquitous presence in applications (fences, windbreaks and double skin facades to name a few). This work follows previous investigations by the authors, aimed at verifying the consistency of numerical simulations based on the explicit modelling of the perforated plates geometry and their representation by means of pressure-jumps. In this work we further expand such investigations and, contextually, we provide insight into the flow arrangement and its sensitivity to important modelling and setup configurations. To this purpose, Unsteady Reynolds-Averaged Navier-Stokes (URANS) and Large-Eddy Simulations (LES) are performed for a 5:1 rectangular cylinder at null angle of attack. Then, using URANS, porosity and attack angle are simultaneously varied. To the authors' knowledge this is the first time in which LES are used to model a porous bluff body and compare results obtained using the explicit modelling approach to those obtained relying on pressure-jumps. Despite the flow organization often shows noticeable differences, good agreement is found between the two modelling strategies in terms of drag force.