• Title/Summary/Keyword: double porosity

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Surface Roughness and Sintering Characteristics of Fe-8 wt%Ni Component Fabricated by PIM (Fe-8 wt%Ni 나노합금분말 사출성형체의 소결특성 및 표면조도)

  • Cha, Berm-Ha;Lee, Jai-Sung
    • Journal of Powder Materials
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    • v.16 no.5
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    • pp.342-350
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    • 2009
  • Development of nanoparticulate materials technology is essential to processing of highly functional nanoparticulate materials and components with small and complex shape. In this paper, the effect of particle size on surface roughness and shrinkage of sintered Fe-8 wt%Ni nanopowder components fabricated by PIM were investigated. The Fe-8 wt%Ni nanopowder was prepared by hydrogen reduction of ball-milled Fe$_2$O$_3$-NiO powder. Feedstock of nanopowder prepared with the wet-milled powder was injection molded into double gear shaped part at 120$^{\circ}C$. After sintering, the sintered part showed near full densified microstructure having apparently no porosity (98%T.D.). Surface roughness of sintered bulk using nanopowder was less than 815 nm and it was about seven times lower than 7 $\mu$m that is typically obtainable from a sintered part produced from PIM.

Algin-Impregnated Vascular Graft II. Preliminary Animal Study

  • Jin Ho Lee;Byu
    • Journal of Biomedical Engineering Research
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    • v.12 no.3
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    • pp.157-164
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    • 1991
  • Microvel $^{\textregistered}$ double velour graft impregnated with a biodegradable algin was studied as a new vatscular graft. It is impervious to blood but still retains high porosity. This graft does not require preclotting during implantation and has good tissue ingrowth and biological healing properties. Two vascular grafts impregnated with algin (6mm in diameter) were implanted in the aorta of mongrel dogs without preclotting. Two identical grafts were preclctted and served as controls. The grafts were harvested 2 and 4 months postoperatively, and the healing pattern was examined by a light microscope after hemRtoxylineosin staining. It was observed that endothelial cells were incompletely covered on both algin-impregnated and control grafts after 2 month Implantation, while they were fully covered on both grafts after 4 month. There were no significant differences in subendothelial granulation tissue organization and fibrinoid material absorption between the algin-impregnated and control grafts. The algin-impregnated graft did not show any harmful effect on the healing and thus can be a new promising graft which is not necessary preclotting during the implantation.

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MODELLING OF PYROLYSIS PROCESSES OF POLYACRYLONITRILE

  • Lipanov, A.M.;Kodolov, V.I.;Ovchinnikova, L.N.;Savinsky, S.S.;Khokhriakov, N.V.;Sarakula, V.L.
    • Proceedings of the Korea Institute of Fire Science and Engineering Conference
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    • 1997.11a
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    • pp.112-119
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    • 1997
  • The modelling of carbon substances obtaining, for instance, carbon fibers which have high fire resistance, has been realized on the example of the polyacrylonitrile pyrolysis modelling. The pyrolysis is considered as a double step process when the formation of a liquid phase and the oxidation of substance are excluded. Three main reactions are considered: a) with the evolution of ammonia; b) with the evolution of hydrogen cyanide; c) with the evolution of hydrogen. Reactions b) and c) are sequential, and a) and b) are parallel. The problem is formulated as one-dimensional. The equations of energy, masses or concentrations, porosity and thermal conductivity are proposed. The mathematical model of the carbonization process is designed using tile kinetic characteristics of the above reactions and the thermodynamic parameters of reagents and products in these reactions. The equations received are calculated by Runge-Cutta method and by Adams method of the fourth order accuracy.

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Micro-Structural and Electrochemical Properties of Activated Carbon Synthesized from Natural Bamboo (천연 대나무로부터 합성된 활성 탄소의 미세구조 및 전기화학적 특성)

  • YANG, DONG-CHEOL;KIM, SU-WON;CHOURASHIYA, M.G.;PARK, CHOONG-NYEON;PARK, CHAN-JIN
    • Transactions of the Korean hydrogen and new energy society
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    • v.30 no.5
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    • pp.418-427
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    • 2019
  • Activated carbon was synthesized from bamboo charcoal by KOH activation at various temperatures for electrochemical double layer capacitor applications. The micro-structural and surface properties of all the samples were characterized by X-ray diffraction, scanning electron microscopy and N2 adsorption/desorption isotherm method. The electrochemical properties of the activated bamboo charcoal were examined by cyclic voltammetry in the potential window of -1.0 to 0.2 V in 6 M KOH electrolyte at different scan rates. An electrode made from the sample activated with 7.5 M KOH and heat treated at $750^{\circ}C$ for 3 h gave a maximum capacitance of 553 F/g at 1 mV/s and 450 F/g at 10mV/s.

Analysis of Flow Characteristics of Multiple Filter System (다중 필터 시스템의 유동특성 해석)

  • In-Soo Son;Mi-Young Seo;Jun-Ho Kim;Jin-Soek Yu
    • Journal of the Korean Society of Industry Convergence
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    • v.26 no.4_2
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    • pp.615-621
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    • 2023
  • In this study, flow analysis of single, double, and triple filter systems of cylindrical structures was performed to analyze the flow characteristics of each filter. As a result of the flow analysis of the filter system, the number of filters and the pressure drop rate tend to be proportional to each other. It was found that the area passing through the inside of the filter had almost the same pressure. The maximum pressure drop rate of the triple filter system was about 14.9% for the forward-flow and about 12.4% for the reverse-flow. It was determined that the performance of the filter was stable within 20% of the allowable pressure drop rate of the filter system, which is the standard presented to the Korea Water Technology Certification Institute(KWTCI). In the future, a study on the decompression characteristics of the filter system according to the effect of the arrangement interval and filter density of the triple filter will be conducted.

Changes of Rice Yield and Soil Physicochemical Properties in Long-term Dry Seeded Rice-Barley Double Cropping (건답직파 벼-보리 장기간 이모작 재배시 벼 수량 및 토양 물리화학성 변화)

  • Shin, Sang-Ouk;Park, Sung-Tae;Hwang, Chung-Dong;Hwang, Dong-Yong;Kim, Sang-Yeol;Moon, Huhn-Pal
    • KOREAN JOURNAL OF CROP SCIENCE
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    • v.46 no.6
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    • pp.459-463
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    • 2001
  • Changes of rice yield and soil physicochemical properties of the dry-seeded rice-barley double cropping system were investigated for 10 years from 1990 to 1999. Generally, seedling stand was more unstable in the rice-barley cropping system regardless of barley straw addition or removal than in the rice single cultivation as indicated by higher standard deviation of seedling stand across year. Rice yield in rice-barley double cropping cultivation was increased due to barley straw application starting from the second year, recording 2 to 19% increase (average of 9% for 10 years) due to higher spikelet number. Protein content and Mg/K equivalent ratio were similiar among the barley straw applied field, rice single crop and barley straw removed plots. Also, amylose content was not significantly different among cropping patterns. Physicochemical properties of soil was improved by applying the barley straw; soil porosity was higher and content of organic matter and cation exchange capacity of Ca increased but those of Mg and K did not differ.

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Effect of Barley Straw Application on Soil Properties, Rice Yield and Plowable Stress with Plowing Methods and Irrigation Rates in Barley- Rice Double Cropping System (이모작 벼 재배시 경운방법 및 관개량에 따른 쌀 수량, 토양특성에 대한 보릿짚 시용효과)

  • Yang, Chang-Hyu;Kim, Byung-Soo;Park, Woo-Kyun;Lee, Deog-Bae;Yoo, Chul-Hyun;Kim, Jae-Duk;Jeong, Kwang-Yong
    • Korean Journal of Soil Science and Fertilizer
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    • v.40 no.3
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    • pp.201-207
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    • 2007
  • To reduce both the floatation of the seedling of rice and the failure in standing in the paddy field when the barley straw was applied to paddy field before planting the rice, we tested the effect of rice rooting with plowing methods and irrigation rates for 2 years from 2003 to 2004. This study was carried out in paddy field with Fluvio-Marine deposit in Jeonbug series and the operating accuracy and the change of soil physico-chemical properties depending on plowing methods and irrigation rates following the barley straw applying were examined. There was a less floatation of barley straw in the dry-rotaryI+water-rotaryI(DRI+WRI) plot than in the plowing+water-rotary(PL+WRI) plot. The ratio of miss-planted and floating seedling also decreased by 1.7%, 2.6% in the DRI+WRIplot compared with PL+WRI plot. The soil physical property was improved with the decreasing soil hardness, bulk density and increasing soil porosity after the application of barley straw, especially enhanced greatly in the increase of porosity, gaseous phase and with the decrease of soil hardness, bulk density of subsurface soil in DRI+WRI plot. And the change of soil chemical property were increased the content of total carbon$^{\circ}{\S}$nitrogen$^{\circ}{\S}$organic matter and available phosphate while decreased the content of exchangeable cations and available silicate after the application of barley straw. Also the content of organic matter, available phosphate and cation exchangeable capacity were increased, whereas caron/nitrogen ratio was decreased in DRI+WRI plot compared with PL+WRI plot. The number of panicles, spikelets per square meter were increased and 1,000 grains weight of hulled rice was gained more in DRI+WRI plot at irrigation rate of $500ton\;ha^{-1}$, in DRI+WRII plot at irrigation rate of $700ton\;ha^{-1}$. So the rice yields were increased by 7%, in DRI+WRI and 5% in DRI+WRII plot, respectively compared with PL+WRI plot. The result of this study indicated that the most appropriate plowing method with barley straw application on rice cultivation at double cropping in normal paddy field plain land was DRI+WRI.

Effects of Barley Straw Application on Soil Physico-Chemical Properties and Nutrient Uptake in Rice Paddy Field of Double Cropping (벼 2모작 논에서 보릿짚 시용이 토양이화학성 및 양분흡수에 미치는 영향)

  • Yoo, Chul-Hyun;Yang, Chang-Hyu;Kang, Seung-Weon;Han, Sang-Soo;Kim, Seong-Jo
    • Korean Journal of Soil Science and Fertilizer
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    • v.34 no.2
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    • pp.110-116
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    • 2001
  • This experiment was carried out to investigate the effects of amount of nitrogen application with the barley straw application on the changes in soil physical and chemical properties. nutrient uptake and percentage recovery of chemical fertilizer N in the rice plant from 1997 to 1998. The soil physical properties, such as bulk density, hardness, porosity and gaseous phase were improved by barley straw application. There was also improvement or increment in the soil chemical properties, such as pH, organic matter, T-C. T-N, available $SiO_2$, exchangeable K and cation exchange capacity, but decrease in available $P_2O_5$. The $Fe^{+{+}}$ content in soil after barley straw application was high from tillering stage to panicle forming stage, but becoming lowered toward the heading stage, while $Mn^{+{+}}$ content was increased. N uptake with barley straw application was increased in the N $126kg\;ha^{-1}$ plot, but decreased in the N $141kg\;ha^{-1}$ plot. The uptake of fertilized N was continued longer in barley straw application than none-application plot. Percentage recovery of chemical fertilizer N in rice straw was around 1% at tillering stage, but was highly increasing till maximum tillering stage, while the recovery was generally low in barley straw application. Meanwhile, fertilizer P uptake in barley straw application was high, but potassium uptake was low at all different levels of N application.

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Preparation and characterization of PVDF/alkali-treated-PVDF blend membranes

  • Liu, Q.F.;Li, F.Z.;Guo, Y.Q.;Dong, Y.L.;Liu, J.Y.;Shao, H.B.;Fu, Z.M.
    • Membrane and Water Treatment
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    • v.7 no.5
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    • pp.417-431
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    • 2016
  • Poly(vinylidene fluoride) (PVDF) powder was treated with aqueous sodium hydroxide to obtain partially defluorinated fluoropolymers with expected properties such as improving hydrophilicity and fouling resistance. Raman spectrum and FT-IR results confirmed the existence of conjugated carbon double bonds after alkaline treatment. As the concentration increased, the degree of defluorination increased. The morphology and structure of membranes were examined. The permeation performance was investigated. The results showed that membrane's hydrophilicity increased with increase of the percentage of alkaline treated PVDF powder. Moreover, in terms of the water contact angle, it decreased from $92^{\circ}$ to a minimum of $68^{\circ}$; while water up take increased from 128 to 138%. Fluxof pure water and the cleaning efficiency increased with the increase of alkaline treated PVDF powder. The fouling potential also decreased with the increase of the percentage of alkaline treated PVDF powder. The reason that makes blending PVDF show different characteristics because of partial defluorination, which led the formation of conjugated C = C bonds and the inclusion of oxygen functionalities. The polyene structure followed by hydroxide attack to yield hydroxyl and carbonyl groups. Therefore, the hydrophilicity of blending membrane was improved. The SEM and porosity measurements showed that no obvious variations of the pore dimensions and structures for blend membranes were observed. Mechanical tests suggest that the high content of the alkaline treated PVDF result in membranes with less tolerance of tensile stress and higher brittleness. TGA results exhibited that the blend of alkaline treated PVDF did not change membrane thermal stability.

Investigation for Utilization of Separator Bag Filter Cement (세퍼레이터 백필터 집진 미립자시멘트 (SBFC : Separator Bag Filter Cement)의 활용성 검토)

  • Kim, Kyoung-Min;Park, Sang-Joon;Yoo, Jea-Kang;Lee, Eui-Bae
    • Journal of the Korean Recycled Construction Resources Institute
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    • v.5 no.3
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    • pp.78-83
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    • 2010
  • This paper presents the feasibility of incorporating ultrafine particles collected in the separator bag filter (separator bag filter cement, SBFC) during the cement manufacturing process as an substitution material for cement. SBFC does not require additional processes needed in the existing processes to manufacture high early strength cement such as modifying mineral components and adjusting the firing temperature. Moreover, it can also solve the issue of efficiency decrease resulted from the increase of the grinding time applied in the existing process of manufacturing microcement. Therefore, this research has examined the characteristics of SBFC and fresh properties and mechanical properties after making paste and mortar using SBFC in order to use SBFC as a material to gain early strength of concrete. For results, analyzing the chemical composition and physical properties of SBFC, its blaine value was $6,953cm^3/g$, about double than that of OPC, but its chemical composition showed no significant difference. According to the result of the paste and mortar examination, the paste and mortar mixed with SBFC showed a lower flowability, earlier setting time, and higher compressive strength than that with OPC. The result of microstructure analysis of paste, the paste mixed with SBFC indicated about 9% lower internal porosity at an early age than that of OPC. The compressive strength and flexural strength of mortar were higher in the order of SBFC ratio of 100, 50 and 0% SBFC.

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