• Title/Summary/Keyword: double layer

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Oxidation-treated of Oxidized Carbons and its Electrochemical Performances for Electric Double Layer Capacitor (산화처리 탄소의 전기화학적 거동 및 이를 이용한 EDLC 특성)

  • Yang, Sun-Hye;Kim, Ick-Jun;Jeon, Min-Je;Moon, Seong-In;Kim, Hyun-Soo;An, Kye-Hyeok;Lee, Yun-Pyo;Lee, Young-Hee
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2007.06a
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    • pp.481-481
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    • 2007
  • This work describes the effect of the number of roll pressing and the composition of carbon black on the electric and mechanical properties of carbon-PTFE electrode, in which composition is MSP 20 : carbon black: PTFE = 95-x : x : 5 wt.%. It was found that the best electric and mechanical properties were obtained in sheet electrode roll-pressed for about 15 times and in sheet electrode, in which composition is MSP 20 : carbon black: PTFE = 80 : 15 : 5 wt.%. These behaviors could be explained by the network structure of PTFE fibrils and conducting paths linked with carbon blacks, respectively. On the other hand, cell capacitor using the sheet electrode with 15 wt.% of carbon black attached on aluminum current collector with the electric conductive adhesive, in composition is carbon black : CMC = 70 : 30 wt.%, has exhibited the best rate capability in the current range of $0.5mA/cm^2$ $100mA/cm^2$ and the lowest equivalent series resistance.

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Plugging and Re-opening Phenomena of the 5Cr-1Mo Steel Leak Hole by Water Leakage in Sodium Atmosphere (소듐 분위기에서 물누출에 의한 5Cr-1Mo Ferrite강 구멍의 막힘과 재개방 현상)

  • Jeong, Kyung-Chai;Kim, Tae-Joon;Choi, Jong-Hyeun;Park, Jin-Ho;Hwang, Sung-Tai
    • Applied Chemistry for Engineering
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    • v.9 no.5
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    • pp.674-679
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    • 1998
  • Small water leak experiment was carried out in liquid sodium atmosphere using a specimen of ferrite steel, which will be expected to be a material of the heat transfer tube of liquid metal fast breeder reactor. Self-plugging phenomena of leak path could be explained by the products of reaction and corrosion by sodium-water reaction. Also, re-opening mechanism of self-plugged path could be explained by the thermal transient and vibration of heat transfer tube. As a result, perfect re-opening time of self-plugged leak path was observed to be 129 minutes after water leak initiation. Re-opening shape of a specimen was appeared with double layer of circular type, and re-opening size of this specimen surface was about 2 mm diameter on sodium side.

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TiN Surface-Alloying of Ti-6Al-4V Alloy by CO2 Laser (CO2 레이저에 의한 Ti-6Al-4V 합금(合金)의 TiN 표면합금화(表面合金化))

  • Park, S.D.;Lee, O.Y.;Song, K.H.
    • Journal of the Korean Society for Heat Treatment
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    • v.8 no.1
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    • pp.32-43
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    • 1995
  • Ti-6Al-4V alloy are widely used in chemical and aircraft industries for their good corrosion resistance and high strength to weight ratio. Surface alloying of Ti alloy by $CO_2$ laser is able to produce few hundred micrometers thick TiN surface-alloyed layer with high hardness on the substrate very simplely by injecting reaction gas($N_2$) into a laser-generated melt pool and adjust the hardness to the specific requirements of the individual application by changing of laser processing parameters. This research has been investigated the effect of such parameters on TiN surface-alloying of Ti-6Al-4V alloy by $CO_2$ laser. The maximum hardness of TiN surface-alloyed zone waw obtained by injecting 100% $N_2$ gas and it was decreased as the amount of $N_2$ gas in Ar and $N_2$ gas mixture was decreased. As scanning speed was increased, the hardness and depth of TiN surface-alloyed zone was decreased at constant laser power. The surface hardness after double scanning laser treatment is higher than that of single scanning. At constant laser power, the surface roughness is increased after the surface alloying if laser scanning speed is decreased.

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A Reliable Data Capture in Multi-Reader RFID Environments (다중 태그 인식 기반의 신뢰성 있는 데이터 수집 환경)

  • Lee, Young-Ran
    • Journal of the Korea Academia-Industrial cooperation Society
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    • v.12 no.9
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    • pp.4133-4137
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    • 2011
  • Reliable Multi-Reader RFID identification is one of issues in Multi-Reader RFID realization program in recent. And the Multi-Reader RFID reader has difficulty to obtain reliable data in data capture layer. The reason is that unreliable readings such as a false positive reading and a false negative reading and missed readings can happen by reader collision problems, noise, or the mobility of tagged objects. We introduce performance metrics to solve these reader problems. We propose three solutions the Minimum Overlapped Read Zone (MORZ) with Received Signal Strength Indicator (RSSI), the Spatial-Temporal Division Access (STDA) method, and double bigger size of tags attached on the object. To show the improvement of the proposed methods, we calculate tag's successful read rates in a smart office, which consists of Multi-Reader RFID systems.

Heating and Cooling Energy Demand Analysis of Standard Rural House Models (농어촌 주택 표준모델의 냉난방에너지요구량 분석)

  • Lee, Chan-Kyu;Kim, Woo-Tae
    • Journal of the Korea Academia-Industrial cooperation Society
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    • v.13 no.8
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    • pp.3307-3314
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    • 2012
  • The annual energy demand of the standard rural house models was analyzed using the DesignBuilder. Indoor temperature set-point, U-value of outer wall, type of window, and degree of ventilation were selected as simulation parameters. In all the simulation cases, heating energy demand was higher than cooling energy demand regardless of the building size. When the lower U-value of the outer wall was applied to account for the thicker insulation layer, heating energy demand was decreased while cooling energy demand was increased. However, it is better to reduce the area of outer wall which is directly exposed to outdoor air because reducing the U-value of the outer wall is not effective in decreasing heating energy demand. Among the four different window types, the double skin window is most favorable because heating energy demand is the lowest. For a fixed infiltration rate, higher ventilation rate resulted in an increased heating energy demand and had minor impact on cooling energy demand. As long as the indoor air quality is acceptable, lower ventilation rate is favorable to reduce the annual energy demand.

Study of Corrosion of Brass Coated Steel Cords in the Acetonitrile Solution of Sulfenamide Derivatives by Tafel Plot and AC Impedance Measurements

  • Young Chun Ko;Byung Ho Park;Hae Jin Kim;Q Won Choi;Jongbaik Ree;Keun Ho Chung
    • Bulletin of the Korean Chemical Society
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    • v.15 no.2
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    • pp.122-126
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    • 1994
  • Corrosion of brass coated steel cords in the acetonitrile solution of sulfenamide derivatives, N-Cyclohexylbenzothiazole-2-sulfenamide (CBTS), N,N'-Dicyclohexylbenzothiazole-2-sulfenamide (DCBS), N-tert-Butylbenzothiazole-2-sulfenamide (TBBS), N-tert-Amylbenzothiazole-2-sulfenamide (TABS), and N-Oxydiethylbenzothiazole-2-sulfenamide (OBTS) was investigated by potentiostatic anodic and cathodic polarization (Tafel plot), DC polarization resistance, and AC impedance measurements. The corrosion current densities and rates are 1.236 ${\mu}A /cm^2$ and 0.655 MPY for CBTS; 1.881 ${\mu}A/cm^2$ and 0.988 MPY for DCBS; 2.367 ${\mu}A/cm^2$ and 1.257 MPY for TBBS; 3.398 ${\mu}A /cm^2$ and 1.809 MPY for TABS, respectively. OBTS among derivatives under study shows the lowest corrosion density (0.546 ${\mu}A /cm^2$) and the slowest corrosion rate (0.288 MPY). Also, the charge transfer resistances and the double layer capacitances are 275.21 $k{\Omega}{\cdot}cm^2$ and 7.0 ${\mu}F{cdot}cm^{-2}$ for CBTS; 14.24 ${\mu}F{\cdot}cm^2$ and 26 ${\mu}F{\cdot}cm^{-2}$ for DCBS; 54.15 $k{\Omega}{\cdot}cm^2$ and 26 ${\mu}F{\cdot}cm^{-2}$ for TBBS; 0.96$k{\Omega}{\cdot}cm^2$ and 83 ${\mu}F{\cdot}cm^{-2}$ for TABS, respectively. The weaker the electron donating inductive effect of derivatives is and the smaller the effect of steric hindrance is, the more the corrosion of brass coated steel cords in the acetonitrile solution of sulfenamide derivatives is prevented. The above results agree with that observed in the field of tire industry.

Determination of the Hybrid Energy Storage Capacity for Wind Farm Output Compensation (풍력발전단지 출력보상용 하이브리드 에너지저장장치의 용량산정)

  • Kim, Seong Hyun;Jin, Kyung-Min;Oh, Sung-Bo;Kim, Eel-Hwan
    • Journal of the Korean Solar Energy Society
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    • v.33 no.4
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    • pp.23-30
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    • 2013
  • This paper presents the determination method of the hybrid energy storage capacity for compensating the output of wind power when disconnecting from the grid. In the wind power output compensation, a lot of charging and discharging time with lithium-ion battery will be deteriorated the life time. And also, this fluctuation will cause some problems of the power quality and power system stability. To solve these kind of problems, many researchers in the world have been studied with BESS(Battery Energy Storage System) in the wind farm. But, BESS has the limitation of its output during very short term period, this means that it is difficult to compensate the very short term output of wind farm. Using the EDLC (Electric Double Layer Capacitor), it is possible to solve the problem. Installing the battery system in the wind farm, it will be possible to decrease the total capacity of BESS consisting of HESS (Hybrid Energy Storage System). This paper shows simulation results when not only BESS is connected to wind farm but also to HESS. To verify the proposed system, results of computer simulation using PSCAD/EMTDC program with actual output data of wind farms of Jeju Island will be presented.

Induced Polarization Surveys of Contaminants and Introduction to Case Studies (오염원에 대한 유도분극탐사 반응 및 사례 소개)

  • Kim, Bitnarae;Caesary, Desy;Yu, Huieun;Cho, AHyun;Song, Seo Young;Cho, Sung Oh;Joung, Inseok;Nam, Myung Jin
    • Journal of Soil and Groundwater Environment
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    • v.25 no.2_spc
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    • pp.86-100
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    • 2020
  • Analyzing and monitoring environmental contaminants based on geophysical exploration techniques have become important and it is now widely applied to delineate spatial distribution geophysical characteristics in wide area. Among the techniques, induced polarization (IP) method, which measures polarization effects on electrical potential distribution, has drawn much attention as an effective tool for environmental monitoring since IP is sensitive to changes in biochemical reactions. However, various reactions stemming from the presence of multiple contaminants have greatly enhanced heterogeneity of polluted sites to result in highly variable electrical characteristics of the site. Those contaminants influence chemical and physical state of soil and groundwater to alter electrical double layer, which in turn influences polarization of the media. Since biochemical reactions between microbes and contaminants result in various IP effects, IP laboratory experiments were conducted to investigate IP responses of the contaminated soil samples under various conditions. Field IP surveys can delineate the spatial distribution of contamination, while providing additional information about electrical properties of a target medium, together with DC resistivity. Reviewing IP effects of contaminants as well as IP surveys can serve as a good starting point for the application of IP survey in site assessment for environmental remediation.

Analysis of Commercial Recycling Technology and Research Trend for Waste Cu Scrap in Korea (국내 구리 함유 폐자원의 재활용 상용화 기술 및 연구동향 분석)

  • Kang, Leeseung;An, HyeLan;Kang, Hong-Yoon;Lee, Chan Gi
    • Resources Recycling
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    • v.28 no.1
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    • pp.3-14
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    • 2019
  • Copper is used in many electronic components and construction parts due to its excellent electrical conductivity and heat transfer characteristics, and also used for pre-plating for double layer coating such as nickel, so that copper is an essential material in modern industry. Despite the expected increase of usage and importance on wiring, sensors and data equipment in the next generation industries, it is hard for securing stable copper supply and resource management resulting from the copper prices are fluctuating owing to the economic crisis in Europe, the low economic growth trend in China, and President Trump's commitment to public industrial facilities investment in U.S.. Since most of the domestic copper consumption is used by electrolytic copper cathode, we studied not only copper recycling technology which is being commercialized but also current research trend under the research stage. This study aims to examine the characteristics of each process and the areas where future recycling technology development is required.

Effect of Organic Solvent Extractives on Korean Softwoods Classification Using Near-infrared Spectroscopy

  • Yeon, Seungheon;Park, Se-Yeong;Kim, Jong-Hwa;Kim, Jong-Chan;Yang, Sang-Yun;Yeo, Hwanmyeong;Kwon, Ohkyung;Choi, In-Gyu
    • Journal of the Korean Wood Science and Technology
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    • v.47 no.4
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    • pp.509-518
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    • 2019
  • This study analyzed the effect of organic solvent extractives on the classification of wood species via near-infrared spectroscopy (NIR). In our previous research, five species of Korean softwood were classified into three groups (i.e., Cryptomeria japonica (cedar)/Chamaecyparis obtuse (cypress), Pinus densiflora (red pine)/Pinus koraiensis (Korean pine), and Larix kaempferi (Larch)) using an NIR-based principal component analysis method. Similar tendencies of extractive distribution were observed among the three groups in that study. Therefore, in this study, we qualitatively analyzed extractives extracted by an organic solvent and analyzed the NIR spectra in terms of the extractives' chemical structure and band assignment to determine their effect in more detail. Cedar/cypress showed a similar NIR spectra patterns by removing the extractives at 1695, 1724, and 2291 nm. D-pinitol, which was detected in cedar, contributed to that wavelength. Red pine/Korean pine showed spectra changes at 1616, 1695, 1681, 1705, 1724, 1731, 1765, 1780, and 2300 nm. Diterpenoids and fatty acid, which have a carboxylic group and an aliphatic double bond, contributed to that wavelength. Larch showed a catechin peak in gas chromatography and mass spectroscopy analysis, but it exhibited very small NIR spectra changes. The aromatic bond in larch seemed to have low sensitivity because of the 1st overtone of the O-H bond of the sawdust cellulose. The three groups sorted via NIR spectroscopy in the previous research showed quite different compositions of extractives, in accordance with the NIR band assignment. Thus, organic solvent extractives are expected to affect the classification of wood species using NIR spectroscopy.