• Title/Summary/Keyword: dolomite

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Talc Mineralization in the Middle Ogcheon Metamorphic Belt (II) : Poongjeon Talc Deposit (중부옥천변성대의 활석광화작용에 관한 연구 (II) : 풍전활석광상을 중심으로)

  • Park, Hee-In;Lee, In Sung;Hur, Soon Do;Shin, Dong Bok
    • Economic and Environmental Geology
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    • v.30 no.6
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    • pp.543-551
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    • 1997
  • Poongjeon talc deposits is emplaced in dolomite and dolomitic limestone of the Cambro-Ordovician Samtaesan Formation. Ore in Poongjeon is low grade talc and the deposit has been known as the contact metasomatic or hydrothermal replacement type related to the intrusion of late Cretaceous granite in this area. X-ray diffraction, electron microprobe analysis, fluid inclusion and stable isotope analysis were utilized to examine the mineralogy of the ore and the origin of the ore fluid. The ore from Poongjeon mine mainly consists of talc and tremolite with minor amount of illite, vermiculite, smectite, and chlorite-vermiculite mixed layer. Occurrence of ore body indicates that the talc-tremolite ore was formed through the replacement by the $SiO_2$-rich hydrothermal fluid along the bedding and dike boundaries, or contact of amphibolite and basic dike with carbonate rocks. The temperature and pressure of the ore forming fluids at the time of the talc mineralization were estimated as $350^{\circ}C$ and 400 bar, respectively, based on the heating and freezing data of the fluid inclusions in quartz from talc-tremolite veins. During the talc-tremolite formation, fluids were divided into $CO_2$-enriched fluid and $CO_2$-poor fluid from $CO_2$ immiscibility (or effervescence). Oxygen isotope values (${\delta}^{18}O$) of the talc-tremolite fall within a range between 12.2 and 12.9‰. Hydrogen isotope values(${\delta}D$) of the ore range from -60 to -85‰ and $H_2O$ contents range from 2.0 to 3.4 wt.%. ${\delta}^{18}O$ and ${\delta}D$ values of talc ore indicate that the hydrothermal fluid involved in talc-tremolite formation was of igneous origin. Oxygen and hydrogen isotopic exchange between talc ore and the surface water was negligible after talc-tremolite ore formation.

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The Mineralogy and Geochemistry of the Uppermost Sediments of the Lake Hovsgol, North Mongolia : It's Implication to the Paleoenvironmental Changes

  • Tumurhuu, D.;Narantsetseg, Ts.;Ouynchimeg, Ts.
    • The Korean Journal of Quaternary Research
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    • v.18 no.2 s.23
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    • pp.3-3
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    • 2004
  • One short core with length of 146cm(HB-107, at coordinates of $N51^{\circ}$11'37.5";$E100^{\circ}$24'45.6", from 229m water depth was subject of the present study. The sub-samples of the core were analyzed for the water contents (WC%), biogenic silica, identification of the main phases, grain size distribution, geochemistry and some physical properties of sediment(Wet density and Magnetic susceptibility) with aims of recording palaeo-environmental changes in Northem Mongolia. The evaluation of the geochemical and mineralogical proxies on palaeo-climated and palaeo-environmental changes are based on comparison to the behvior of biogenic silica through core, as later one had been showed itself, as good indicator of the climate and environmental fluctuation. Age model of the investigating core based on previously C 14 dated core HB105 taken from the central part of the Hobsgol Lake and the result had been published elsewhere. The core consists of two litological varieties : upper diatomaceous silt, lower clay. According to the age model the upper diatomaceous silt formed during the Holocene, lower caly-during the late Pleistocene glacial period. The geochemistry and phase identification analysis on the core samples are resulted in determining main minerals that form the bottom sediments and their geochemistry. The main include quartz, felspar, muscovite, clinochlore, amphibole and carbonate phase(dolomite and calcite). Through the core not only occur the relative quantitative changes of the main phases, but also happen that the carbonate phase completely disappear in diatomaceous silt. This is believed to be related to the lake water salinity changes, which occurred during the trassition period from Pleistocene glacial-to the Holocene interglacial. These abrupt changes of the mineralogy have been clearly traced in geochemistry of sediments, specially in calcium concentration, which is high in lower clay and low in upper diatomaceous silt. That means, geochemistry and mineralogy of the bottom sediments can be used as proxy data on palaeo-climate and palaeo-environmental changes.

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Low-Temperature Sintering and Dielectric Properties of BaSn(BO3)2 Ceramics (BaSn(BO3)2세라믹스의 저온소결 및 유전특성)

  • Nam, Myung-Hwa;Kim, Hyo-Tae;Hwang, June-Cheol;Nam, Joong-Hee;Yeo, Dong-Hoon;Kim, Jong-Hee;Nahm, Sahn
    • Journal of the Korean Ceramic Society
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    • v.43 no.2 s.285
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    • pp.92-97
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    • 2006
  • Dolomite type $BaSn(BO_3)_2$ ceramics with rhombohedral crystal structure has been synthesized via solid state reaction route. Dielectric properties were measured for the samples sintered at $1050\~1200^{\circ}C$ for 2 h in air. Dielectric constant, loss tangent, and temperature coefficient were increased with sintering temperature due to the evolution of $BaSnO_3$, secondary, phase. Optimum dielectric properties were obtained at the $BaSn(BO_3)_2$ ceramics sintered at $1100^{\circ}C.\;CuO/Bi_2O_3$ was added to $BaSn(BO_3)_2$ ceramics to lower the sintering temperature for LTCC application, then Co and Fe-based coloring agents were added for colorizing the LTCC tape. Typical dielectric properties of $BaSn(BO_3)_2$ ceramics with $5 wt\%\;CuO/Bi_2O_3\;and\;3wt\%$ Co-coloring agent that sintered at $900^{\circ}C$ were $\varepsilon_r=9.89,\;tan{\delta}=0.92\times10^{-3},\;and\;TCC=112ppm/^{\circ}C$. Thus obtained LTCC tape was co-fired with Ag paste for compatibility test and revealed no sign of Ag reaction with the ceramics.

A Study on the Development of Equation from Calculation about Emissions of Greenhouse Gases in Glass Manufacturing Industries (유리 제조 산업분야의 온실가스 배출량 산정식 개발에 관한 연구(I))

  • Chung, Jin-Do;Ko, Byong-Su;Kim, Jang-Woo;Chae, Soo-Joh;Koo, Kyung-Wan;Hwang, Seung-Min
    • Journal of Environmental Science International
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    • v.18 no.5
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    • pp.509-515
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    • 2009
  • The aim of this study is investigated greenhouse gas emissions of glass industry, and when calculates greenhouse gas emission, using formula(Tier 3) advising in IPCC(Intergovernmental Panel on Climate Change) and using self designed formula(Tier 3+) authors of this study. Studied to propose calculation formula that can compare these two calculation results and apply to domestic. Formula of Tier 3 calculated to theoretical composition of carbonate material, And Formula of Tier 3+ calculated on the basis of chemical substance formation table that get from glass manufacture company(The S company). As a result, Dolomite, Soda ash, Limestone, Industrial Barium carbonate is calculated value of Tier 3+ lower than value of Tier 3, And Industrial Potassium carbonate, Industrial Strontium carbonate was calculated value of Tier 3 lower than value of Tier 3. This study finding, formula of Tier 3+ has higher confidence than formula of Tier 3 when consider revision about purity of injection raw material. And hereafter, When calculate greenhouse gas emissions about nonmetallic mineral industry, use of Tier 3+ is considered that should be encouraged.

A Study on the Recycling of Molten Ladle Slag Residue into LF Process (Ladle내 잔류(殘留) 용융(熔融)슬래그의 LF 공정(工程)으로 재활용(再活用)에 관한 연구(硏究))

  • Kim, Young-Hwan;Yoo, Jung-Min;Kim, Dong-Sik;Lim, Jong-Hoon;Yang, Sung-Ho
    • Resources Recycling
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    • v.22 no.1
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    • pp.36-41
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    • 2013
  • LF slag is formed by EAF carryover slag and slag former(such as lime, dolomite) put into the ladle during the tapping molten metal. After LF process, continuous casting is started when molten steel is sent from ladle to tundish through bottom nozzle of ladle. Conventionally, remained molten slag and steel in ladle are poured into a slag port and they are transferred to a slag yard and then recycled. In this study, we investigated about recycling of molten LF slag residue(including Fe residue to reuse) which is made in steelmaking process. As a result, lime usage was decreased about 2.2~3.2 kg/steel-ton and also molten steel yield rate was increased about 0.3 ~ 0.5 percent point.

Consideration for the Highest Temperature Point Movement of the Dongrae Thermal Water in the Pusan Area. (Poster)

  • Kim Tong-Kwon;Lee Jin-Soo;Lee Seung-Gu;Song Yoon-Ho;Kim Tack-Hyun
    • Proceedings of the Korean Society of Soil and Groundwater Environment Conference
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    • 2005.10a
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    • pp.158-159
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    • 2005
  • This study showed that the highest temperature point of the Dongrae thermal spring in Pusan was moved to the north direction of the Dongrae fault as times goes by. The Br concentration(1.5mg/L) in Dongrae thermal waters indicated the influence of 2% seawater mixing. If the simple mixing without hydrochemical reaction occurs between seawater and thermal water, the concentration of Mg will be about 20mg/L. But the low concentration(0.1 mg/L) of Mg, contrary to high concentration(10 mg/L) of surrounding groundwater not affected by thermal water, suggested the thermal water, seawater and rock interactions. The calculation of saturation index(SI) by using the geochemical code of EQ3NR showed that the Mg in thermal groundwater, which was introduced by seawater, was removed by the precipitation of Antigorite (SI: log Q/K =71.753, $Mg_{48}Si_{24}O_{85}(OH)_{62}$) and Tremolite (SI: 8.463, $Ca_2Mg_5Si_8O_{22}(OH)_2$), Talc (SI: 6.409, $Mg_3Si_4O_{10}(OH)_2$), Dolomite (SI: 2.014, $CaMg(CO_3)_2$), Chrysotile (SI: 3.698, $Mg_3Si_2O_5(OH)_4$) in the crack of fault zone. The highest temperature point in the study area will move to north direction and stop in the Jangjun area without the input of seawater.

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Characteristics of Hydraulic Lime using Low-grade Dolomitic Limestone

  • Moon, Ki-Yeon;Choi, Moon-Kwan;Cho, Jin-Sang;Cho, Kye-Hong;Ahn, Ji-Whan
    • Journal of the Korean Ceramic Society
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    • v.53 no.2
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    • pp.206-214
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    • 2016
  • This study aims to produce dolomitic hydraulic lime (D-NHL) using domestic low grade dolomitic limestone and to determine the effect of adding blast furnace slag (BFS) and gypsum as part of an investigation of the hydration properties of D-NHL to increase the mechanical properties. The main mineral phases of D-NHL as a hydraulic lime binder were $Ca(OH)_2$, $Mg(OH)_2$, $C_2S$, $C_3S$, and MgO residues. $Ca(OH)_2$ transformed into $CaCO_3$ in D-NHL paste over the period of 28 days, but the carbonation of $Mg(OH)_2$ and the hydration of $C_2S$ did not occur until hydration, after 28 days. Through an investigation of the hydration properties of D-NHL pastes mixed with BFS and gypsum, Al-based compounds such as calcium aluminate hydrates ($C_4AH_{13}$) and ettringite were observed at early hydration time. The compressive strength was improved due to the increased quantities of these hydration products. These results show that good performance results from the application of dolomitic hydraulic lime and that a high value product can be made from domestic waste materials.

Effect of Soil Conditioners for Contaminated Soil of Abandoned Zinc Mine Area on Growth of Chrysanthemum zawadskii and Caryopteris incana(Tunb) Miq (아연폐광지역 오염토양에 대한 토양개량제 처리가 구절초와 층꽃나무의 생육에 미치는 영향)

  • Park, Eun-A;Choi, Young;Lee, Sang-Gak;Chiang, Mae-Hee
    • Journal of Bio-Environment Control
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    • v.12 no.4
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    • pp.245-251
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    • 2003
  • This study was cnducted ton investigate the effect of soil conditioner such as dolomite, slkudge and organic manure on changes of soil chemical properties of abandoned zinc mine area. Growth responses of Chrysanthemum azwadskii and Caryopteris incana (Tunb) Miq affected by the appication were also determined. In thejsoil of abandoned zinz mine area, total heavy metal contents espectially Cd, Cu, Pb and Zn were high and organic matter contents was low. Application of sludge for phytoremediation resulted in higher soil organic content that other treatments tested. Heavy metal concentrations after application of soil conditioners were not different among treatments. The growth of C. zawadskii and C. incana (Tunb) Miq were significantly higher in sludge treatment than those in other treatments The cholrophyll content, chlorophyll flouorescence, protein content, photosynthetic rate and transpiration were high in sludge treatment. The heavy metal contents of C. zawadskii were the lowest in sludge treatment while those of C. incana (Tunb) Miq was the highest in sludge treatment.

Stratigraphy and Tectonics of Okcheon System in the Area between Chungju and Munkyeong (충주문경간(忠州聞慶間)의 옥천계(沃川系)의 층서(層序)와 구조(構造))

  • Kim, Oku Joon
    • Economic and Environmental Geology
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    • v.1 no.1
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    • pp.35-46
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    • 1968
  • Some of geologists in Korea recently postlated that Okchon system previously known to be precambrian age was the metamorphosed sediments of post-Chosen (Ordovician and pre-Kyeongsang (late Jurassic to Cretaceous) periods, or even definitely of Triassic period simply on the basis of the fact that Okcheon system overlies the Great Limestone series of Chosen system of Camber-ordovician age, and of other few assumptions of minor importance. As a result of such correlation, thick series of metasediments and Okcheon system of unknown age were established in this particular region and vaguely correlated to Paleozoic and Mesozoic sediments. Recent study done by the author reveled that: 1) only the upper Okcheon bed of S. Nakamura was true Okcheon system, and the middle and lower Okcheon beds were excluded, because they were correlated to Cambrian and Permian sediments resfectively, 2) Sangnaeri, Seochangri, and rengam formations of unknown age, and Baekhwasan, Jobong, and Ihwaryeong formations of Okcheon system of also unknown age were the metamorphosed Yangdeok system of Cambrian age, all of these formations were differentiated by the previous workers and were equivalent to the middle Okcheon system of S. Nakamure, and. 3) These metamorphosed Yangdeok system overlaid apparently the Great Limestone series in forms of overthrust and klippe which were produced by the orogeny took place during post-Daedong and pre-Kyeongsang period (probably middle to the Jurassic). The Sobaeksan Range, folded mountain Chains was also formed by this orogeny. Thus, Okcheon system newly defined by the author is precambrain age and consists in ascending order of Kemyenogsan, Hyangsan dolomite, and Daehangsan quartzite formation which were previously classified into metasediments of unknown age, and Munjuri, and Hwangkanri, formations which were differentiated into Okcheon system unknown age by the previous workers, but are of reversed sequence. Myeongori and Bukrori formations of Okcheon System are regard by the author as part of Hwangkanri formation. Few other assumption of minor important taken by the previous workers as their positive evidences are carefully explained that they were misinterpreted.

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Suggesting Optimum Mix Proportion of Hardener for Soil-pavement Concrete Incorporating Natural Organic Lime and Magnesia-lime (천연유기석회 및 고토석회를 조합한 흙 포장 콘크리트용 경화재의 최적배합안 도출)

  • Han, Min-Cheol;Han, Jun-Hui
    • Journal of the Korea Institute of Building Construction
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    • v.20 no.2
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    • pp.113-121
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    • 2020
  • Lots of soil-pavement concrete placed showed a number of problems such as decreasing strength, and durability. In this research, to provide a solution of the problem reported the wasting materials of natural organic lime and magnesia lime were used as a hardener to achieve sufficient performance of soil-pavement concrete. Namely, as a stimulus of blast furnace slag, the natural organic lime and magnesia lime were tested within the mix proportion of 0 to 10 % for each lime to make a new hardener. As a result, in the case of mortar with 1 to 3 % of cement to fine aggregate, 30 % replaced blast furnace slag showed the more favorable results with 5 to 5 % of mix proportion for natural organic lime and magnesia lime.