• Title/Summary/Keyword: dissolving

Search Result 429, Processing Time 0.022 seconds

ESTIMATION FOR DEWATERABILITY ON INTERACTION BETWEEN CATIONIC FLOCCULANTS AND IONIC MATERIALS IN DISSOLVING WATER

  • Bae, Young-Han;Lee, Sung-Sik
    • Environmental Engineering Research
    • /
    • v.11 no.5
    • /
    • pp.266-276
    • /
    • 2006
  • Commonly, the flocculant is dissolved in process or recycle water in industrial plant which has many ionic materials. Therefore, the polymer degradation in aqueous solution by chemical, mechanical or bacteriological may occur, sometimes rapidly. Even if the same flocculant is dissolved, the flocculation characteristics and the properties of dissolving polymer varied with the kind of dissolving water. In this study, we try to estimate the interaction between flocculants and ionic materials in dissolving water using self inversing emulsion polymer; polyacrylamide-co-trimethyl ammonium ethyl acrylate chloride flocculants which have varying molecular weights and structures at a several conditions. The polymeric flocculant is dissolved in artificial dissolving water with Potassium Chloride (PC), Calcium Chloride anhydrous (CC), Potassium Hydroxide (PH), Sodium Chloride (SC), Sodium Bromate (SB) and Iron (II) Sulfate Heptahydrate (IS) as ionic sources. Experimental results indicate that the cationic and anionic ions in dissolving water induce the hydrolysis, degradation of cationic functional group and uncoiling of polymeric flocculants, therefore, the flocculation efficiency decreased by undesired polymer. According that result, it is important to estimate not only its structures and physical properties but also the qualities of dissolving water to optimize the efficiency.

Conversion of Woody Biomass for Utilization(III) - The Preparation of Dissolving Pulp by Oxygen·Alkali Method from Exploded Wood - (목질계 Biomass의 변환 이용(III) - 폭쇄처리재의 산소·알칼리법에 의한 용해용 펄프의 제조 -)

  • Lim, Bu-Kug;Yang, Jae-Kyung;Lee, Jong-Yoon
    • Journal of the Korean Wood Science and Technology
    • /
    • v.25 no.4
    • /
    • pp.68-74
    • /
    • 1997
  • This research was studied dissolving pulp for rayon production, which is not KP, SP methods but steam explosion and oxygen alkali treatment. The variation of characterization in wood cellulose after steam explosion and oxygen alkali treatment this follows. In the oxygen alkali treatment of exploded pine wood, yield of dissolving pulp was lower than steam-exploded oak wood, and we have obtained dissolving pulp that high purity cellulose, but degree of polymerization was inclined to decrease less than 200. In the case of steam-exploded oak wood, degree of polymerization was higher than steam-exploded pine wood but purity of cellulose was lower than its.

  • PDF

Development of Multipurpose Seed Paper from Waste Paper ( I ) - Focused on functional chemicals behavior - (폐지를 이용한 기능성 육묘지의 제조(제1보) -기능성 약제의 거동-)

  • Park Soung Bae;Eom Tae Jin
    • Journal of Korea Technical Association of The Pulp and Paper Industry
    • /
    • v.36 no.4 s.107
    • /
    • pp.41-48
    • /
    • 2004
  • To make a basepaper for multipurposed seed paper, old news print (ONP) and mixed office waste paper (MOW), modified and unmodified with a commercial cellulase, were investigated. Each handsheet was applied with different chemicals such as insecticides, germicides and herbicides. The interactions behaviors of chemicals used with base papers were evaluated by means of the contents of chemicals impregnation and dissolving behaviors in water and soil. The ONP and MOW treated with the cellulase had higher impregnation and dissolving capacities in both water and soil than untreated ONP and MOW. However, the modified ONP showed lower impregnation and dissolving capacities compared to the modified MOW. The content of impregnation of chemicals would be affected with the degree of microfibrils produced by the modification treatment. Otherwise, dissolving capacities of chemicals depend on the affinity of the residual lignin in the paper.

Conversion of Woody Biomass for Utilization(II) - Preparation of Dissolving Pulp by Solvolysis from Woody Biomass - (목질계 Biomass의 변환 이용(II) - 목질계 바이오매스로부터 solvolysis법에 의한 용해용 펄프의 제조 -)

  • Yang, Jae-Kyung;Lim, Bu-Kug;Chang, Jun-Pok;Lee, Jong-Yoon
    • Journal of the Korean Wood Science and Technology
    • /
    • v.25 no.4
    • /
    • pp.45-50
    • /
    • 1997
  • This research was studied for dissolving pulp preparation as the raw material of viscose rayon from woody biomass by solvolysis pretreatment. In the change of pulp characteristic after solvolysis pretreatment, the following results were obtained. In the case of solvolysis pretreatment, we have obtained pulp that high purity cellulose, and degree of polymerization was inclined to decrease less than 440 on the phosphoric acid as catalyst. Comparing phosphoric acid and formic acid as catalyst in the solvolysis pretreatment, using on formic acid catalyst is superior to phosphoric acid catalyst for making dissolving pulp.

  • PDF

Conversion of Woody Biomass for Utilization( I )-The Preparation of Dissolving Pulp from Mechanical Pulp- (목질계 Biomass의 변환이용(제1보)-기계펄프로부터 용해용펄프의 제조-)

  • 양재경;임부국;이종윤
    • Journal of Korea Technical Association of The Pulp and Paper Industry
    • /
    • v.29 no.3
    • /
    • pp.51-59
    • /
    • 1997
  • Dissolving pulp is a low yield(30∼35%) bleached chemical pulp that has a high cellulose content (95% or higher) suitable for use in cellulose derivatives such as rayon, cellulose acetate. This research was studied for dissolving pulp preparation as the raw material of viscose rayon from commertial pulps. (TMP, CP, DIP) In the change of pulp(cellulose) characteristics after sodium hypochlorite and solvolysis treatment. the following results were obtained In the case of sodium hypochlorite pretreatment, we have obtained pulp that high purity cellulose, but degree of polymerization was inclined to decrease less than 170∼240. Comparing sodium hypochlorite pretreatment and solvolysis pretreatment, solvolysis pretreatment is superior to sodium hypochlorite process for making dissolving pulp. We think that the low degree of polymerization of cellulose because of increasing degradation of cellulose during delignification treatment.

  • PDF

Fabrication and Characterization of Dissolving Microneedles Containing Lecithin for Transdermal Drug Delivery (레시틴이 함유된 경피 약물전달용 용해성 마이크로니들의 제작과 특성)

  • Choi, Won-Ho;Kim, Bumsang
    • Korean Chemical Engineering Research
    • /
    • v.59 no.3
    • /
    • pp.429-434
    • /
    • 2021
  • The feasibility of lecithin as a material for dissolving microneedles to improve skin permeability of drugs and the effect of the composition of lecithin on the mechanical strength, solubility, and skin permeability of rhodamine B (RhB) of the dissolving microneedles were investigated. Dissolving microneedles with needles of uniform shape and size were fabricated with the mold made using the laser-writing technique, simpler and more efficient method compared to the photolithography method, the conventional method to fabricate the microneedle mold. The composition of lecithin in the microneedle affected the mechanical strength and solubility of the needle thus, the mechanical strength of the needle increased as the composition of lecithin in the needle increased, resulting in improving the skin permeability of RhB contained in the microneedles. When comparing the microneedles containing same composition of amylopectin (AP), the skin permeability of RhB of the microneedles containing lecithin was higher. These results indicate that lecithin can be used as a material for dissolving microneedles and the skin permeability of the microneedle could be controlled by changing the composition of lecithin.

Characteristics and Hair Growth Efficacy of Water Dissolving Micro-needles Containing Minoxidil Regarding Length of Micro-needles (미녹시딜을 내포한 용융형 고분자 마이크로 니들의 길이에 따른 특성 및 발모 효능 관찰)

  • Han, Mee-Ree;Kim, Eun-Young;Jung, Yong-Hyun;Kim, Myoung-Seok;Park, Jung-Hwan
    • Polymer(Korea)
    • /
    • v.37 no.3
    • /
    • pp.393-398
    • /
    • 2013
  • Two types of polymeric micro-needles with 250 and $750{\mu}m$ lengths were prepared by a micromolding process. The geometry of dissolving micro-needles with minoxidil was investigated and the mechanical property of polymer micro-needles was also evaluated. Water dissolving micro-needles containing minoxidil were successfully inserted into skin and delivered minoxidil to the skin layer after 30 min of insertion. The observed hair growth was less when the minoxidil treatment was not applied or used without the micro-needles than that the minoxidil was applied by micro-needles. Histologically, these hair follicles became bigger, and the hair papillae were totally encircled by the hair bulbs. In this feasibility test, we show the successful delivery of minoxidil, and effective treatment of hair loss can be possible by using dissolving micro-needles with minoxidil.

The Preparation of CarboxymethylCellulose from Recycled Fiber(I) -The Reactivity in Carboxymethylation of Recycled Fiber- (재생(再生)펄프를 이용(利用)한 카르복시메틸세룰로오스의 제조(製造)(I) -재생(再生)펄프의 Carboxymethylation반응성(反應性)을 중심(中心)으로-)

  • Choi, Jeong-Heon;Jo, Byoung-Muk;Oh, Jung-Soo
    • Journal of the Korean Wood Science and Technology
    • /
    • v.21 no.1
    • /
    • pp.59-64
    • /
    • 1993
  • The purpose of this study is to investigate the preparation of the carboxymethylcellulose from recycled fiber, especially on the reactivity of carboxymethylation. Using a deinked pulp and a dissolving pulp. Green's method is adapted to the carboxymethylation. We conformed that the carboxymethyl group is led for recycled fiber by FT-IR analysis. The recycled fiber is more reactive than the dissolving pulp because the recycled fiber had been defiberated and pretreated with alkali. It suggests that deinking process is in accordance with pretreatment of CMC process. Therefore, it may be possible to prepare CMC from the recylced fiber economically.

  • PDF

Development of Fast Dissolving Tablet Containing Herb Extract by Freeze-Drying Technique

  • Kim, Jae-Il;Choi, Hoo-Kyun
    • Journal of Pharmaceutical Investigation
    • /
    • v.40 no.3
    • /
    • pp.161-166
    • /
    • 2010
  • A fast dissolving tablet was developed using the freeze-drying technique. Hyeonggaeyeongyotang was selected as a model oriental medicine. Formulation and processing parameters were studied to obtain freeze-dried tablet with high drug loading, good palatability, and fast disintegration time. $Kollidon^{(R)}$ CLM served as both matrix former and taste masking agent. Ethanol used as co-solvent, decreased the disintegration time of tablet. Aspartame was employed to impart better taste. Drying condition was found to have a major effect in the morphology of the tablets. Freeze-drying process was optimized to decrease the processing time and improve the appearance of the tablets.

The Tree Growth and Breakdown Characteristics of Unsaturated Polyester Dissolving the Electronegative Gases (부성기체를 용해시킨 불포화 폴리에스터의 Tree 성장과 절연파괴 특성)

  • 이보호;전춘생
    • The Transactions of the Korean Institute of Electrical Engineers
    • /
    • v.41 no.2
    • /
    • pp.178-184
    • /
    • 1992
  • This study treats the improvement of the dielectric strength of polymer by eliminating the air in it and dissolving electronegative gases. As experimental material, unsaturated polyester resin was used and the specimen was made by dissolving NS12T. SFS16T abd CCIS12TFS12T gases which have strong electron affinity. And also the electrical properties (tree growth and breakdown characteristics) of them were tested and discussed. The results are as follows. When the specimen dissolved with electronegative gas compared with one with air` 1) The tree breakdown voltage of the former is higher than that of the latter. 2) The tree growth of the former is slower than that of the latter. 3) The temperature dependence of the former is smaller than that of the latter. 4) The breakdown voltage of the specimen dissolved with electronegative gas is much higher than that dissolved with air.