• Journal of Environmental Science International
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• v.12 no.3
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• pp.307-317
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• 2003

In this study, the material cycle model was applied to suggest alternative management of water quality for Jeju Harbor. The distribution of COD, DIN (dissolved inorganic nitrogen) and DIP (dissolved inorganic phosphorus) concentrations was reasonably reproduced by simulations on the model area of the Jeju Harbor using a material cycle model. The simulations of COD, DIN and DIP concentrations were performed under the conditions of 20∼100% pollution loadings reductions from pollution sources. In case of the 100% reduction of the input loads from Sanzi river, concentrations of COD, DM and DIP were reduced to 39%, 78% and 52%, respectively at Jeju harbor. In contrast, in case of the pollutant loadings reductions from sediment, the effect of DIN and DIP reduction relatively seemed to increase around the center of study area. The 95% reduction of the pollutant loadings from river and sediment is required to meet the COD and nutrients concentration of second grade of ocean water quality criteria.

• Journal of Korean Society on Water Environment
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• v.30 no.1
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• pp.25-30
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• 2014

This study is done to prove the premise that both alkalinity and hardness affect on the dissolved phosphorus concentration so that the growth of algae is also affected in water bodies like rivers and lakes. Statistical analysis of the water quality data of 13 reservoirs collected for the last decade shows the relations between alkalinity and chlorophyll-${\alpha}$ and between hardness and chlorophyll-${\alpha}$ are not linear but follow second order equation. This relation seems to be due to two antagonistic effects accompanying a simultaneous increase in alkalinity and hardness. The increase stimulates the growth of algae by supplying carbonates and $Ca^{2+}$ to algae and at same time it causes a decrease in soluble phosphorus which retards algae to grow. These opposing tendencies are confirmed by theoretical calculations with the MINTEQ model. There seems to be ranges of alkalinity and hardness that are in favor of algae growth; the ranges are less than 44 mg/L as $CaCO_3$ in alkalinity and also less than 63 mg/L as $CaCO_3$ in hardness. This finding will provide a solid base to develop an effective water quality management of water bodies.

• Archives of Pharmacal Research
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• v.26 no.5
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• pp.416-420
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• 2003

The analytical method of antispasmodic agent tiropramide {$(\pm)\alpha$-(benzoylamino)-4-[2-(diethylamino)ethoxy]-N,N-dipropylbenzenepropanamide hydrochloride} was developed by gas chromatography/nitrogen-phosphorus detector (GC/NPD) in human plasma. Two kinds of tiropramide tablets were orally administered to volunteers by Latin square crossover design, and blood was withdrawn as designed schedule. The plasma of 1 mL was loaded on Sep-pak $C_{18}$ cartridge and eluted with methanol after washing with 30% methanol. The residue dissolved in 100 $\mu$L of methanol after evaporation was analyzed by GC/NPD. Precision (CV%) of intra-day was located within 2.6% and accuracy was less than 9.7%. Inter-day precision was below 8.7% and accuracy was relatively good as less than 14%. Plasma samples obtained from human volunteers were analyzed for the determination of tiropramide concentration by using this method. The method was sensitive, rapid and suitable enough to be applied for pharmacokinetic and bioequivalence studies of tiropramide in human volunteers.

• Membrane and Water Treatment
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• v.15 no.3
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• pp.117-130
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• 2024

The possibility of using lime/mineral solvent solutions has been investigated to effectively remove T-P from wastewater. The lime solvent solution showed an initial T-P removal efficiency of about 90% compared to the less efficient mineral solvent solution removal. High pH and dissolved Ca2+ can form hydroxyapatite minerals (Ca5(PO4)3(OH) or Ca10(PO4)6(OH)2 and can also remove SS and COD from wastewater. Feldspar dissolution solution can be reused twice because the Ca limited sample content provided, but further research is needed to discover other influencing parameters that control the T-P removal efficiency in real wastewater. Because it plays an important role of alkalinity in T-P removal, the success rate is limited. In practical applications, it is obtained according to the pH value wastewater in the environment. The results obtained in this study can highlight new insights on the use of limestone/dissolved mineral solutions to control T-P in wastewater, instead of directly using commercial chemical agents that can produce large amounts of unreacted chemical sludge.

• Journal of Korean Society on Water Environment
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• v.33 no.6
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• pp.670-679
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• 2017

An experiment to study the effect of temperature, light, and dredging on release of nutrients downstream from Gongjicheon in the Uiam reservoir was carried out in the laboratory using sediments from different depths. At various water temperatures, dissolved total nitrogen was not released, but the average nutrient flux of dissolved total phosphorus was increased (0.034 at $15^{\circ}C$, 0.005 at $20^{\circ}C$, 0.154 at $25^{\circ}C$, $0.592mg/m^2/d$ at $30^{\circ}C$). Dissolved total phosphorous was released in controlled darkness. In contrast, in controlled light, the concentrations of dissolved total phosphorous and dissolved total nitrogen in the overlying water steadily decreased during the study period (70 d), because they were continuously consumed by the growth of photosynthetic algae. However, there was no significant relationship between water nutrient concentration, nutrient release, and the depth of the sediment. We concluded that the dredging of sediment would not affect the nutrient release rate of the sediment, because there were no significant differences in the nutrient concentrations released from the sediment. When the sediment was removed from the surface to 20 cm in depth, the nutrients were not transferred to the water body, implying that the sediment removal had little effect on secondary pollution.

• Journal of Ecology and Environment
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• v.38 no.3
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• pp.293-305
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• 2015

In order to understand the mechanisms of conversion between different algal dominance, an experiment was performed in a greenhouse from 22 June to 10 July 2011. The experiment included a treatment group subjected to three instances of nutrient enrichment and a control with no nutrient enrichment. The initial water was dominated by Ankistrodesmus of Chlorophyta. The average water temperature at 08:30 h and 14:00 h during the experiment was $31.6^{\circ}C$ and $34.6^{\circ}C$, respectively. The results showed that the total nitrogen (TN), total phosphorus (TP), dissolved total nitrogen (DTN), dissolved total phosphorus (DTP), and soluble reactive phosphorus (SRP) concentrations in the treatment were significantly higher than in the control (P < 0.05). However, the TN/TP and DTN/DTP in the control was higher than in the treatment (P < 0.05). The dominant algae in the control did not change during the experiment, while the dominant algae in the treatment switched to Planktothrix of Cyanophyta on day 9. The chlorophyll a (Chl-a), wet weight of all algae, wet weight of Cyanophyta, and percentage of Cyanophyta in the control were all significantly lower than in the treatment (P < 0.05). Amounts of zooplankton, especially rotifers, were present at the end of the experimental period. The density of rotifers between the control and treatment was not significantly different (P > 0.05), while the copepod density in the treatment was higher than in the control (P < 0.05). We conclude that green algae dominance quickly switches to cyanobacteria dominance after nutrient enrichment in a greenhouse with elevated temperature.

• Journal of Environmental Science International
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• v.17 no.6
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• pp.611-621
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• 2008

This study intends to provide the necessary basic data needed for predicting the water quality and examining changes in water quality on the basis of the hydrological changes: an outflow or the character of a flow by investigating the interaction of the parameters through the estimation of optimal parameters need for predicting the water quality of the dam basin and the sensitivity among those estimated parameters. Im-Ha Dam in the upstream area of the Nakdong River was selected for analysis, and the water quality survey data necessary for parameter estimation was based on the monthly water quality data (water temperature, BOD, T-N and T-P) between December 1, $2005{\sim}$November 31, 2006. K1C(the saturated growth rate of plant plankton), K1RC (endogenous respiratory quotient of plankton), KDC(deoxidized ratio), K71C(minealized ratio of dissolved organic phosphorus), K83C(mineralized ratio of dissolved organic nitrogen) have been considered as the factors of the water quality performed in this water quality simulation, that is, the most effective parameters on BOD, T-N and T-P. In the result of the analysis of the sensitivity, KDC(deoxidized ratio) was the most sensitively reacted parameter on BOD and it was K71C(mineralized ratio of dissolved organic phosphorus) and K83C(mineralized ratio of dissolved organic nitrogen) on T-N and T-P. It is considered that it will be possible to apply the most optimal parameter to an analysis of the water quality simulation at Im-Ha Ho basin in the goal year by examining the interaction of the parameters through the parameters sampling which are able to applicable to prediction of the water quality and the analysis of the its sensitivity, in the future, also the analysis on the basis of the hydrological conditions: an outflow or the character of a flow will be needed.

• Korean Journal of Environmental Biology
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• v.42 no.1
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• pp.127-134
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• 2024

The feathery branched green alga Bryopsis plumosa (Hudson) C. Agardh bloomed at Songji Beach, Haenam, Korea, in November 2022. A terrible stench was present on the beach, and the bottom was covered in a thick green mat of green algae. The alga was identified as B. plumosa, which is an opportunistic species currently distributed worldwide. Dissolved inorganic nitrogen (DIN) and dissolved inorganic phosphorus (DIP) were analyzed in the bloomed area and compared with those of other vicinities. The DIN and DIP concentrations were 1.067 and 0.461 mg L^-1, respectively, which were 6 to 19 times higher than the average concentrations on southwest coasts, including Haenam. The B. plumosa bloom at Songji Beach in November 2022 appears to have depended on DIN and DIP concentrations in seawater. In this study, we report on the mass occurrence of B. plumosa, which appeared for the first time in Korea. This occurrence was found to be closely related to the concentration of nutrients in seawater. Therefore, it is necessary to manage the concentration of nutrients on land flowing into coastal waters to control green algal blooms such as Bryopsis.

• Journal of Korean Society on Water Environment
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• v.33 no.4
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• pp.434-440
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• 2017

In order to understand the characteristics of phosphorus in the paddy field, this study analyzed $PO_4-P$ and T-P concentrations of irrigation water, flooding water, and runoff from 2008 to 2010. The variation of phosphorous form within hydrologic cycle around the rice paddy field was investigated using the ratio of $PO_4-P$ to TP. In addition, the correlation between pH, EC, and DO in flooding water was analyzed and the factors affecting phosphorus form in paddy field were investigated. The concentration of T-P in flooding water was high during the survey period, and the concentration of T-P in runoff was assumed to be decreased by dilution due to irrigation and rainfall. On the other hand, the ratio of $PO_4-P$ to T-P was lower in flooding water than those of irrigation water and runoff, which was interpreted to be due to the fact that the phosphorus fertilizer was applied in the paddy field but the adsorption was rapidly occurred to the paddy field by the soil. The similar proportions of $PO_4-P$ to T-P in flooding water and runoff suggest that the form of phosphorus outflowed from the paddy is influenced by the form of phosphorus in the flooding water of paddy field. In addition, DO concentration in flooding water showed negative correlation with the concentrations of $PO_4-P$ and T-P. The effort to survey frequent irrigation water quality data is required for the analysis of phosphorus behavior in the paddy water system since concentration of phosphorous and DO in irrigation water would influence rhe form of phosphorous in flooding water and subsequent runoff.

• Korean Journal of Ecology and Environment
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• v.35 no.3 s.99
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• pp.213-219
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• 2002

The CellCaSi, a porous silicate material, was tested for the removal of phosphorus (P as phosphate) in water. The effect of the CellCaSi was investigated on the basis of both particle size (under 1,2, and 4 mm) and added amount (0, 1, 2.5, 5, and 10 g/1) of the CellCaSi. The removal efficiency of phosphorus was highest with a particle size of under 1 mm and also increased with an increasing amount of the CellCaSi. The pH change showed little effect on the phosphorus removal of the CellCaSi. The calcium ion was eluted from the CellCaSi into the water, while the aluminium and iron were not. The eluted calcium ion was combined with dissolved phosphorus and then precipitated. The highest removal efficiency of phosphorus was obtained by the combined addition of the CellCaSi, calcium chloride, and ferric chloride. That is, the phosphorus concentrations of 0.10 and 1.0 mg/1 decreased to 0.03 and 0.47 mg/l by the addition of the CellCaSi (1 g/l), calcium ion (30 mg/l), and ferric ion (1 mg/l) at day 8 after treatment. The water qualities at the end of the experiment were as follows: pH was 8.1 and conductivity was 318 ${\mu}$S/cm (a registered maximum conductivity of 500${\mu}$S/cm for raw and potable wafers).