• Title/Summary/Keyword: dissolved organics

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Reduction of Suspended Solids in First Flush from a Building Rooftop using Various Media (여과재를 활용한 건물옥상유출 초기빗물의 부유물질 저감)

  • Kim, Seongbeom;Lee, Wontae
    • Journal of Korean Society of Environmental Engineers
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    • v.39 no.4
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    • pp.214-219
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    • 2017
  • We analyzed the water quality of first flush and rainfall runoff from a building rooftop, and investigated the removal of suspended solids (SS) in first flush using various media to develop a first flush filtration system. Particle size distribution exhibited most of particles in first flush from the rooftop ranged from 10 to 30 ${\mu}m$. SS concentrations maxed in 10~20 min and decreased afterwards. Dissolved organics and inorganic materials in runoff also showed highest levels in first flush (10 min). Filtration tests using anthracite (AC), polyurethane (PU), polypropylene (PP) showed about 50% of SS removal during the first 10 min operation, but the removal rates dramatically decreased after 20 min of filtration. Based upon the results from rinse and run cycle tests, only AC could achieve nice cycles without distinct decease of SS removal. SS removal rates increased with higher depth of media bed and lower flowrate. The system achieved over 50% of SS removal with a media depth of 30 cm and flowrate < 12 L/min.

Treatment Characteristics and Application of DAF Process for Effective Solid Separation in BNR Municipal Wastewater Treatment System (BNR 하수처리시스템에서 효과적 고형물 분리를 위한 DAF 공정의 적용과 처리특성)

  • Kwak, Dong-Heui;Rhu, Dae-Hwan
    • Journal of Korean Society of Water and Wastewater
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    • v.24 no.3
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    • pp.267-276
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    • 2010
  • Many plants have been improved to adapt the target of the biological treatment processes changed from organics to nutrients since the water quality criteria of effluent was reinforced and included T-N and T-P for the municipal wastewater treatment plant. To meet the criteria of T-N and T-P, the conventional biological reactor such as aeration tank in activated sludge system is changed to the BNR (biological nutrient removal) processes, which are typically divided into three units as anaerobic, anoxic and oxic tank. Therefore, the solid separation process should be redesigned to fit the BNR processes in case of the application of the DAF (dissolved air flotation) process as an alternatives because the solid-liquid separation characteristics of microbial flocs produced in the BNR processes are also different from that of activated sludge system as well. The results of this study revealed that the microbial floc of the anaerobic tank was the hardest to be separated among the three steps of the unit tanks for the BNR processes. On the contrary, the oxic tank was best for the removal efficiency of nutrients as well as suspended solid. In addition, the removal efficiency of nutrients was much improved under the chemical coagulation treatment though coagulation was not indispensable with a respect to the solid separation. On the other hand, in spited that the separation time for the microbial floc from the BNR processes were similar to the typical particles like clay flocs, over $2.32{\times}10^3$ ppm of air volume concentration was required to keep back the break-up of the bubble-floc agglomerates.

Temporal Variation of Water Quality of the Western Chinhae Bay in Summer (진해만 서부해역의 하계 수질의 시간변동 특성)

  • Cho Hyeon-Seo;Lee Dae-In;Yoon Yang-Ho;Lee Moon-Ok;Kim Dong-Myung
    • Journal of the Korean Society for Marine Environment & Energy
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    • v.7 no.1
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    • pp.13-21
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    • 2004
  • Temporal changes of Chl-α, physical and chemical factors were investigated by diurnal observation at 2-hour interval at three fixed stations in the western Chinhae Bay from 12 Aug. to 13 Aug. 1999. Difference of dissolved oxygen between surface and bottom layer was maximum when the thermocline were strong. Organic distribution such as COD was affected by the growth of phytoplankton. Limitting factor was nitrogen, that is, inorganic nitrogen plays a significant role on regulating the algal growth. Surface distribution of dissolved inorganic nitrogen was very low compared to bottom layer by uptake of organisms. Maximum value of Chl-α at station C2 and C11 were observed from subsurface layer, ranges of which exceeded possibility concentration of red tide outbreak, 10 mg/㎥. On the other hand, that of C15 exist at surface layer. In this area, DIN and DIP concentrations increased by input sources such as rainfall and benthic flux before the bloom of phytoplankton. Accumulation of phytoplankton occurred at subsurface layer by the rapid uptake of DIN, especially nitrate ion, when strong thermocline existed as approach to the afternoon, which led to the increase of organics in water column and oxygen deficiency water mass at bottom layer until late at evening. Since then, DIN increases gradually as water temperature decrease to minimum. The quantitative understanding of nitrogen of fluxed to and from the various sources is necessary for environmental management.

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Application of Newly PAC Selection Method Based on Economic Efficiency (경제성을 고려한 새로운 PAC 선정방법의 적용)

  • Kim, Young-Il;Bae, Byung-Uk
    • Journal of Korean Society of Environmental Engineers
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    • v.28 no.11
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    • pp.1141-1147
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    • 2006
  • In order to applicate a newly method for powdered activated carbon(PAC) selection based on economic efficiency, PAC adsorption tests were performed for removal of MIB and dissolved organic carbon(DOC) in drinking water supplies. The removal rate of MIB increased when the PAC dose increased. The Coal-based PACs were superior for adsorption of MIB compared to wood-based PACs. PAC adsorption of DOC and $UV_{254}$ were a little different for different PACs and types of raw water, but both were lower than adsorption of MIB. Among the tested PACs, the one called P-1000 was most effective for removal of MIB, DOC and $UV_{254}$. Most of the organics in the tested samples were proven by excitation emission matrix(EEM) results to be fulvic-like materials. Especially, fulvic-like materials, humic-like materials, and soluble microbial byproduct(SMP)-like materials decreased after contact with PAC. P-1000 which had the lowest MIB cost index(MCI) was selected as the optimum PAC for the target water. PAC efficiency and treatability, particle size and distribution, and the cost associated with PAC dosing for MIB removal according to DOC concentration should all be considered before making the final selection of the best PAC for the target water.

The Effects of Environmental Conditions on the Reduction Rate of TNT by $Fe^0$ (환경요인이 $Fe^0$에 의한 TNT의 환원 반응속도에 미치는 영향)

  • 배범한
    • Journal of Korea Soil Environment Society
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    • v.5 no.2
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    • pp.87-97
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    • 2000
  • The effects of environmental conditions, initial dissolved oxygen concentrations, pH, and the presence of electron carrier vitamin $B_{12}$, on the reduction rate of Tn by $Fe^0$ was quantitatively analyzed using a batch reactor In all experiments, TNT reduction was best described with a first order reaction and the reduction rate decreased with the increase in the initial DO concentration. However, the specific reaction rate did not decrease linearly with the increase in the initial DO concentration. In the presence of HEPES buffer 0.2 and 2.0 mM(pH 5.7$\pm$0.2), the specific reaction rate increased more than 5.8 times, which showed reduction rate is rather significantly influenced by the pH of the solution. To test the possibility of reaction rate enhancement, well-known electron carrier(or mediator) , vitamin $B_{12}$, has augmented besides $Fe^0$. In the presence of 8.0 $mu\textrm{g}$/L of vitamin $B_{12}$, the specific reaction rate increased as much as 14.6 times. The results indicate that the addition of trace amount of vitamin $B_{12}$ can be a promising rate controlling option for the removal of organics using a $Fe^0$ filled permeable reactive barrier.

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Comparison of Pollutant Removal Efficiency in Road Sediment with Media Using Filter Separator (필터 분리기를 이용한 여재별 도로퇴적물의 오염물질 제거효율 비교)

  • Bang, Ki-Woong;Lee, Jun-Ho;Choi, Chang-Su;Lee, Sang-Ill
    • Journal of Korean Society of Environmental Engineers
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    • v.29 no.3
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    • pp.332-340
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    • 2007
  • Storm runoff from road contains significant loads of particulate and dissolved solids, organic constituents and metal elements. Micro particle is important when considering pollution mitigation because pollutant metal and organics have similar behavior with particles. The objective of this research is to evaluate the hydrodynamic filter separator performance for road storm runoff treatment. A various types of media such as perlite, granular activated carbon, zeolite were used for column test packing media and filter separator, and to determine the removal efficiency with various surface loading rate. As the results of column test, the highest SS removal efficiency was using mixed media(granular activated carbon, zeolite and perlite), and granular activated carbon mixed with zeolite has higher heavy metal removal efficiency than perlite. In laboratory scale hydrodynamic filter separator study, the operation ranges of surface loading rates were from 192 to 1,469 $m^3/m^2/day$. The estimated overall removal efficiencies of hydrodynamic filter separator for typical storm runoff were SS 48.1%, BOD 31.9%, COD 32.6%, TN 15.5%, and TP 17.3%, respectively. For the case of heavy metals, overall removal efficiencies were Fe 26.0%, Cu 19.4%, Cr 25.7, Zn 16.6%, and Pb 15.0%, respectively. The most appropriate medium for hydrodynamic filter separator was perlite mixed with granular activated carbon to treatment of road storm runoff.

Comparison of Performances of Forward Osmosis and Membrane Distillation Processes for Shale Gas Plant Water Treatment (셰일가스 플랜트 용수 처리를 위한 정삼투(FO)와 막증발(MD) 공정의 성능 비교)

  • Koo, Jaewuk;Lee, Sangho;Shin, Yonghyun;Yun, Taekgeun
    • Transactions of the Korean Society of Mechanical Engineers B
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    • v.39 no.3
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    • pp.279-284
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    • 2015
  • As non-conventional oil resources such as shale gas have been widely developed, proper treatment of flowback and produced water is becoming important. However, application of conventional water treatment techniques is limited due to high concentration of pollutants such as oil and grease, organics, harmful chemicals, and inorganic ions. In this study, we examined the feasibility of using forward osmosis (FO) and air gap membrane distillation (AGMD) as novel treatment options for shale gas wastewater. Laboratory-scale FO and MD devices were fabricated and used for the experiments. Results showed that FO could be used to treat the synthetic wastewater. Using 5 M NaCl as the draw solution, the flux was approximately $6L/m^2-hr$ during the treatment of low range wastewater (TDS: 66,000 mg/L). Nevertheless, AGMD was more effective to treat high range wastewater (Total Dissolved Solid: 260,000 mg/L) than FO.

Characteristics of Leachate with Passed Time in Expired Landfill (사용종료매립지에서 시간경과에 따른 침출수의 특성)

  • Kim, Eun-Ho;Kim, Hyeong-Seok;Sung, Nak-Chang;Heo, Jong-Soo
    • Korean Journal of Environmental Agriculture
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    • v.16 no.2
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    • pp.136-141
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    • 1997
  • In this study, we can be obtained the following conclusions about the characteristics of leachate with passed time in the expired landfill. Compared with the expired landfilling H. and S., pH shows a tendency to increase in E., because $NH_3$ is created by anaerobic degradation and dissolved in leachate. The initial BOD and COD of E. and S. are high in similar concentration but H. is low, Since the organics of waste in H. are lower than in E. and S. during landfilling. SS of E. in concentration is increased and very altered, because food of combustible in E. is higher than it in H. and S.. According to passed time, T-N is high in concentration but T-P shows a similar tendency. Heavy metals of leachate is lower than threshold concentrations. If leachate is treated biologically, microbes are not inibitory.

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Removal Characteristics of Boron and Humic Acid by Pre-blending Seawater and Brackish Water Using UF-SWRO Hybrid Process in Pilot-scale Plant for Desalination (UF-SWRO 혼합공정을 이용한 해수담수화 파일럿 플랜트에서의 해수와 기수의 블렌딩을 통한 보론 및 휴믹산 제거 특성)

  • Kim, Won-Kyu;Shin, Sung-Hoon;Lee, Haksu;Woo, Dal-Sik
    • Journal of Korean Society of Environmental Engineers
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    • v.38 no.1
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    • pp.34-41
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    • 2016
  • Using UF-SWRO hybrid process, pre-blending tests of seawater and brackish water were performed to investigate the effects on removal of boron and humic acid (HA). Feedwater pre-blending was set based on TDS concentration from 15,000 mg/L to 27,000 mg/L and analyzed for boron removal characteristics. Also organics rejection at same TDS concentration range was investigated by injecting HA. Boron concentration appeared to be high as TDS concentration was high ranging from 76.60% to 83.27%, but boron concentration in final produced water was increased up to 0.69 mg/L from 0.48 mg/L. In cases of HA tests at 10 mg/L, 22,500 mg/L TDS appeared to be higher removal rate of 17.59% than a very poor result of 8.43% in 27,000 mg/L. But high HA removal rate of 57.14% was obtained in produced water with 22,500 mg/L TDS containing 10 mg/L of HA and 27,000 mg/L TDS yielded lower boron removal rate of 54.49%. Meanwhile it was found that a relatively high flux and recovery rate were obtained following process when feedwater was injected with HA. It is considered that most of fouling substances were eliminated by binding between HA and $Ca^{2+}$. Thus, when desalination using UF-SWRO with respect to boron and HA, TDS concentration is determined to be advantageous as lower.

Application of Lime Stone, Sand, and Zeolite as Reactive Capping Materials for Marine Sediments Contaminated with Organic Matters and Nutrients (유기물 및 영양염류로 오염된 해양퇴적물 정화를 위한 석회석, 모래, 제올라이트의 반응성 피복 소재로서 적용성 평가)

  • Kang, Ku;Park, Seong-Jik
    • Journal of Korean Society of Environmental Engineers
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    • v.39 no.8
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    • pp.470-477
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    • 2017
  • In this study, the applicability of calcite, sand, and zeolite for the remediation of sediments contaminated with organics and nutrients were investigated. Sediments and seawater for water tank experiments were sampled from Pyeongtaek harbor, and 1 cm or 3 cm of calcite, sand, and zeolite were capped on the sampled sediments. pH, electric conductivity (EC), dissolved oxygen (DO), chemical oxygen demand (COD), total nitrogen (TN), and total phosphorus (TP) were monitored for 63 days. The sampled sediments were highly contaminated with organic matter and total nitrogen. DO in uncapped condition was exhausted within 10 days but DO in capping condition except 3 cm of zeolite capping was prolonged above 2 mg/L. Capping efficiency for interrupting COD release from sediments was in the following order: zeolite 1 cm > calcite 1 cm > calcite 3 cm > sand 3 cm ${\cong}$ zeolite 3 cm ${\cong}$ sand 1 cm. Zeolite was found to be effective for interrupting nitrogen release. T-P was not observed in both uncapped and capped sediment, i.e., all experimental conditions. It can be concluded that zeolite can be effectively used for the remediation of sediments highly contaminated with organic matter and nitrogen.