• Carbon letters
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• v.20
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• pp.10-18
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• 2016

Nanoporous carbon structures were synthesized by pyrolysis of grass as carbon precursor. The synthesized carbon has high surface area and pore volume. The carbon products were acid functionalized and characterized by Fourier transform infrared spectroscopy, X-ray diffraction, Brunauer–Emmett–Teller, transmission electron microscopy, and Energy Dispersive X-ray microanalysis. Acid functionalized nanoporous carbon was explored for use in removal of toxic Cr(VI) ions from aqueous media. An adsorption study was done as a function of initial concentration, pH, contact time, temperature, and interfering ions. The experimental equilibrium data fits well to Langmuir isotherm model with maximum monolayer adsorption capacity of 35.335 mg/g. The results indicated that removal obeys a pseudo-second-order kinetic model, and that equilibrium was reached in 10 min. A desorption study was done using NaOH. The results of the present study imply that acid functionalized nanoporous carbon synthesized from grass is an efficient, renewable, cost-effective adsorbent material for removal of hexavalent chromium due to its faster removal rate and reusability.

• Journal of Ocean Engineering and Technology
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• v.20 no.6 s.73
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• pp.35-40
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• 2006

In recent years, there's been strong demand for seawalls that havea gentle slope and permeability that serveswater affinity and disaster prevention from wave attack. The aim of this study is to examine wave transformation, including wave run-up that propagates on the coastal structures. A numerical model based on the weak nonlinear dispersive Boussinesq equation, together with the unsteady nonlinear Darcy law for fluid motion in permeable layer, is developed. The applicability of this numerical model is examined through Deguchi and Moriwaki's hydraulic model test on the permeable slopes. From this study, it is found that the proposed numerical model can predict wave transformation and run-up on the gentle slope with a permeable layer, but can't show accurate results for slopes steeper than about 1:10.

• Proceedings of the Korea Water Resources Association Conference
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• 2002.05b
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• pp.1027-1033
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• 2002

The solute transport in a two-dimensional heterogeneous porous medium is numerically studied by using a random walk particle tracking (RWPT) method. Lognormally isotropic hydraulic conductivity fields are generated by using the turning band methods with mean zero and four different values of standard deviation. The numerical transport experiments are carried out to investigate the large time and spatial effects of the variable pore velocity field on solute plumes. The behavior of the solute plume through numerical simulations is presented in terms of longitudinal and transverse spatial moments: displacement of center-of-mass, plume spread variance and skewness coefficient. It was observed that the dispersive behavior of the solute plume is strongly affected by the degree of heterogeneity in the flow domain.

• Bulletin of the Korean Chemical Society
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• v.8 no.3
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• pp.158-161
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• 1987

A Series of hydrophilic-hydrophobic copolymeric surfaces of 2-hydroxyethyl methacrylate (HEMA) and various alkyl methacrylate (RMA) have been prepared by in-situ solution copolymerization using a redox radical initiator. Contact angles of various probing fluids on the polymeric surfaces were determined in air (hydrophobic environment) and under water (hydrophilic environment). From contact angle data, the dispersive interaction contribution (${\gamma}^d_s$) and the polar contribution (${\gamma}^p_s$) to the total surface free energy (${\gamma}^d_s$) and interfacial energetic quantities (e.g., water-polymer, liquid-polymer interface, etc.) were estimated by surface and interface physicochemical theory. From the comparison of surface energetic components between hydrophobic and hydrophilic media, it is found that surface and interface energetic components of polymeric surface as a representative low-energy surface are highly dependent on environmental fluids. Also, from the correlation between interfacial energetic results and surface energetic criterion of biocompatibility, we found that HEMA/BMA, HEMA/HMA copolymer systems are in the region of biocompatibility.

• Asian Pacific Journal of Cancer Prevention
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• v.15 no.16
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• pp.6773-6779
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• 2014

Background: Nanotechnology opens new applications in many fields including medicine. Among all metallic nanoparticles, silver nanoparticles (silver NPS) have proved to be the most effective against a large variety of organisms including toxic cyanobacteria. Materials and Methods: Silver NPs were biosynthesized in vivo with different alga species namely, Spirulina piatensis, Chlorella vulgaris and Scenedesmus oh/iquus following two scenarios. First: by suspending a thoroughly washed algae biomass in 1 mM aqueous $AgN0_3$ solution. Second: by culturing them individually in culture media containing the same concentration of $AgN0_3$. Silver NPs were characterized using UV-Vis spectroscopy, transmission electron microscopy (TEM), energy dispersive analysis (EDX) and Fourier transform infra-red (FfIR) spectroscopy. The biosynthesized silver NPs were tested for cytotoxic activity against a cancer promoter cyanobacteruim Microcystis aeruginosa, considering effects on cell viability and chlorophyll content. Results: The surface plasmon band indicated the biosynthesis of silver NPs at ~400 nm. Transmission electron microscopy (TEM) revealed that the silver NPs had a mean average size below 100 nm. Energy-dispersive analysis X-ray (EDX) spectra confirmed the presence of silver element. FfIR spectral analyses suggested that proteins and or polysaccharides may be responsible for the biosynthesis of silver NPs and (-COO-) of carboxylate ions is responsible for stabilizing them. The toxic potentialities ofthe biosynthesized silver NPs against the cancer promoter cyanobacterium, Microcystis aeruginosa showed high reduction in viable cells count and the total chlorophyll content. Conclusions: The potential activity of the biosynthesized silver NPs from the studied algae species against Microcystis aernginosa cells is expected to be mainly mediated by the release of silver ions (Ag+) from the particle surface and bioactive compounds as indicated by FfIR analysis.

• Journal of Korea Water Resources Association
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• v.54 no.11
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• pp.863-873
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• 2021

The mechanical dispersion which dominates solute transport in porous media is caused by the difference in flow velocity within pores. Longitudinal dispersion coefficient and longitudinal dispersivity that are hydro-dispersive parameters of advection-dispersion equation can only be obtained by experiment. Hydraulic mean radius that represents the amount and intensity of flowing water within pores can be obtained by the formula using the factors for physical properties. A slug injection test was conducted and a power type empirical formula for obtaining a longitudinal dispersivity using a hydraulic mean radius in rockfill porous media was derived. It is possible to obtain the longitudinal dispersivity depending on transport distance because it contains a formula for a scale constant, and expected to be applicable to waterways filled with homogeneous gravel and small flow rate.

• Journal of the Korea Academia-Industrial cooperation Society
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• v.21 no.10
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• pp.30-39
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• 2020

Single-phase barium ferrite powder was synthesized using the sol-gel method. At this time, an attempt was made to find the optimal experimental conditions for the production of single-phase barium ferrite by varying the Fe to Ba molar ratio (Fe/Ba) and the heat treatment temperature. In addition, cobalt-substituted barium ferrite particles were prepared using cobalt, which has an excellent effect on coercivity control for the production of ferrite fine particles having a coercivity of 2.5 to 5.5 kOe for use in high-density magnetic recording media. The changes in the magnetic properties of these were investigated. X-ray diffraction (XRD), thermogravimetric-differential thermal analysis (TG-DTA), and field emission scanning electron microscopy (FE-SEM) were used to observe the synthesis of single-phase, and Fourier transform infrared spectroscopy (FT-IR) and energy dispersive X-ray spectrometry (EDS) were used to analyze the chemical structure and composition. The coercivity of the cobalt-substituted barium ferrite powder was measured by vibrating sample magnetometry (VSM). As a result, single-phase Barium ferrites were synthesized when the Fe/Ba molar ratio was 10, and the heat treatment temperature was 900 ℃. The coercivity decreased with increasing the amount of Co added. Barium ferrite, having a coercivity of 2.5 to 5.5 kOe for use in high-density magnetic recording media, was synthesized when the Co to Fe(Co/Fe) molar ratio was less than 0.16.

• Journal of the Korean Institute of Telematics and Electronics D
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• v.36D no.7
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• pp.1-8
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• 1999

A complete electromagnetic simulation for a ground-penetrating radar(GPR) is implemented by employing 3-dimensional dispersive finite-difference time-domain(FDTD) method. The presented simulation model includes the cavity-backed bow-tie antennas, which are terminated by resistors. And an equivalent cirvuit consisting of the input impedance of the antenna and the characteristic impedance of the feed line is used to calculate the response in the receiving antenna. Actual emasurements of a GPR system including our manufactured bow-tie antenna pair are performed just above dry sand contained in a PVC tank. It is confirmed that the FDTD simulation results agree well with the actual measurement data.

• Journal of Power System Engineering
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• v.17 no.2
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• pp.56-62
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• 2013

A technique is presented that uses a circular waveguide for the measurement of the bulk shear (S-wave) velocities of unconsolidated, saturated media, with particular application to near surface soils. The technique requires the measurement of the attenuation characteristics of the fundamental torsional mode that propagate along an embedded pipe, from which the acoustic properties of the surrounding medium are inferred. From the dispersion curve analysis, the feasibility of using fundamental torsional mode which is non-dispersive and have constant attenuation over all frequency range is discussed. The principles behind the technique are discussed and the results of an experimental laboratory validation are presented. The experimental data are best fitted for the different depths of wetted sand and the shear velocities are evaluated as a function of depths. Also the characteristics of the reflected signal from the defects are examined and the reflection coefficients are calculated for identifying the relation between defect sizes and the magnitude of the reflected signal.

• Journal of electromagnetic engineering and science
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• v.17 no.4
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• pp.191-196
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• 2017

Microwave wireless power transmission (MWPT) is a promising technique for low and medium power applications such as wireless charging for sensor network or for biomedical chips in case with long ranges or in dispersive media such. A key factor of the MWPT technique is its efficiency, which includes the wireless power transmission efficiency and the radio frequency (RF) to direct current (DC) voltage efficiency of RF-DC converter (which transforms RF energy to DC supply voltage). The main problem in designing an RF-DC converter is the nonlinear characteristic of Schottky diodes; this characteristic causes low efficiency, higher harmonics frequency and a change in the input impedance value when the RF input power changes. In this paper, rather than using harmonic termination techniques of class E or class F power amplifiers, which are usually used to improve the efficiency of RF-DC converters, we propose a new method called "optimal input impedance" to enhance the performance of our design. The results of simulations and measurements are presented in this paper along with a discussion of our design concerning its practical applications.