• Title/Summary/Keyword: dispersion phenomenon

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The Preparation for Sintered Body of $CeO_2$ Based Complex Oxide in Low Temperature Solid Oxide Fuel Cells Using Colloidal Surface Chemistry (콜로이드 계면화학을 이용한 저온형 고체전해질용 $CeO_2$계 복합 산화물의 소결체 제조)

  • 황용신;최성철
    • Journal of the Korean Ceramic Society
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    • v.37 no.7
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    • pp.705-712
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    • 2000
  • In this study, the dispersion stability of CeO2 based complex oxide was studied, and density, porosity, and microstructure of green body were investigated using colloid surface chemistry to manufacture the Gd2O3 doped CeO2 solid electrolyte in an aqueous system. To prepare the stable slurry for slip casting, the dispersion stability was examined as a function of pH using ESA(electrokinetic sonic anplitude) analysis. The dynamic mobility of particles was enhanced with anionic and cationic dispersant were added the amount of 0.5wt% respectively, but pH value in slurries didn't move to below 6.0 because of the influence of dopants. This phenomenon also appeared in the CeO2-Y2O3 and CeO2-Sm2O3 systems, so it could be inferred that rare earth dopants such as Gd2O3, Sm2O3 and Y2O3 not only have the similar motion with changing pH in an aqueous system but also can be dissolved in the range of pH 6.0∼6.5. In CeO2-Gd2O3 system, when the anionic dispersant was added the amount of 0.5wt% and pH value in slurries was fixed at 9.5, the green body density was 4.07g/㎤, and the relative density of sintered body was 95.2%. It could be inferred from XRD analysis that Gd3+ substituted into Ce4+ site because there was no free Gd2O3 peak.

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Bird Strike Analysis of Radome Using Smoothed Particle Hydrodynamics Technique (입자완화 유체동역학 기법을 이용한 레이돔 조류충돌해석)

  • Yun, Gangsik;Kim, Youngjin;Kim, Moon-soo;Kim, Jihyeon;Kim, Taehyeong;Yoon, Siyoung;Park, Sungkyun;Seo, Won-gu;Oh, Dongho
    • Journal of the Korea Institute of Military Science and Technology
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    • v.20 no.6
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    • pp.743-751
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    • 2017
  • To evaluate the structural integrity of the helicopter radome, we performed bird strike analysis using SPH (Smoothed Particle Hydrodynamics) technique. Since the SPH method is a meshfree method, there is no phenomenon such as mesh tangling and it is suitable to predict the dispersion behavior of debris and debris cloud generated by high-speed impact. In order to observe the scattering direction of fractured bolts, the analysis were performed under the condition that the fracture occurs at the proof load. As a result of bird strike analysis, there is no secondary damage as well as the damage due to, the dispersion behavior of the bird model, and the scattering of the fractured bolts and radome. From the additional analysis that were performed to determine the actual bolt fracture, only plastic deformation is predicted since the maximum stress of the bolt does not exceed the ultimate stress.

A Study on Change of Sea Water Quality due to the Development Plan of Ilgwang Harbour (일광항의 항만개발에 따른 수질변화에 관한 연구)

  • 이중우;국승기
    • Journal of Korean Port Research
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    • v.12 no.2
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    • pp.303-312
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    • 1998
  • It is necessary to quantitatively asses the influence of tidal currents to analysis the coastal current patterns before or after constructing offshore structures like as breakwaters. This assesment can be made through the use of simulation models designed to reproduce the water movements of the area. And it is very important to predict a phenomenon of pollutant dispersion in the area. In this study, in order to predict the changes of sea water quality for the port development plan, Ilgwang harbour, located at the east coast of Pusan, the numerical computations were carried out. The flow patterns were investigated before and after the development of the harbour bay and coastal area connected on it. The computational models are an extension of earlier work on the flow which used the ADI Method (Alternating Direction Implicit Method) in appling to Osaka Bay by KANEKO et al. The transport of pollutant constituents depends upon the currental characteristics of the water-transporting medium. In the currental flow model, water velocities and water levels are computed throughout the regions of it. These value are then used in the mass-balance equation to obtain the pollutant-constituent transport. As a result of this research, the present water quality of Ilgwang harbour and the coastal areas connected on it was proved out some good condition. The changes of sea water quality due to the port development plan of the Ilgwang habour bay and the coastal area were not large compared with the present condition, but it will be likely able to get worse by increasing the semi-enclosed areas in the harbour bay. In order to improve the water quality of the area after development, the method to activate tidal exchange in the area can be needed, as a mitigation technique.

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Electric Conduction Mechanisms Study within Zr Doped Mn3O4 Hausmannite Thin Films through an Oxidation Process in Air

  • Said, L. Ben;Boughalmi, R.;Inoubli, A.;Amlouk, M.
    • Applied Microscopy
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    • v.47 no.3
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    • pp.131-147
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    • 2017
  • In this work further optical and electrical investigations of pure and Zr doped $Mn_3O_4$ (from 0 up to 20 at.%) thin films as a function of frequency. First, the refractive index, the extinction coefficient and the dielectric constants in terms of Zr content are reached from transmittance and reflectance data. The dispersion of the refractive index is discussed by means of Cauchy model and Wemple and DiDomenico single oscillator models. By exploiting these results, it was possible to estimate the plasma pulse ${\omega}_p$, the relaxation time ${\tau}$ and the dielectric constant ${\varepsilon}_{\infty}$. Second, we have performed original ac and dc conductivity studies inspired from Jonscher model and Arrhenius law. These studies helped establishing significant correlation between temperature, activation energy and Zr content. From the spectroscopy impedance analysis, we investigated the frequency relaxation phenomenon and hopping mechanisms of such thin films. Moreover, a special emphasis has been putted on the effect of the oxidation in air of hausmannite thin films to form $Mn_2O_3$ ones at $350^{\circ}C$. This intrigue phenomenon which occurred at such temperature is discussed along with this electrical study. Finally, all results have been discussed in terms of the thermal activation energies which were determined with two methods for both undoped and Zr doped $Mn_3O_4$ thin films in two temperature ranges.

Application of Geomorphological Features for Establishing the Preliminary Landslide Hazard (초기 산사태 위험도 구축을 위한 지형요소의 활용)

  • Cha, A Reum;Kim, Tai Hoon;Gang, Seok Koo
    • Journal of Korean Society for Geospatial Information Science
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    • v.23 no.3
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    • pp.23-29
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    • 2015
  • Due to the characteristics of landslide disasters including debris flow, the rapid speed to downward and difficulty to respond or evacuate from them, it is imperative to identify their potential hazards and prepare the reduction plans. However, the current landslide hazards generated by a variety of methods has been raised its accuracy because of the complexity of input data and their analyses, and the simplification of the landslide model. The main objective of this study is, therefore, to evaluate the preliminary landslide hazard based on the identification of geomorphological features. Especially, two methodologies based on the statistics of the directional data, Vector dispersion and Planarity analyses, are used to find some relationships between geomorphological characteristics and the landslide hazard. Results show that both methods well discriminate geomorphological features between stable and unstable domains in the landslide areas. Geomorphological features are closely related to the landslide hazard and it is imperative to maximize their characteristics by adapting multiple models rather than individual model only. In conclusions, the mechanism of landslide is not determined solely by a simple cause but the complex natural phenomenon caused by the interactions of the numerous factors and it is of primary importance to require additional researches for the outbreaking mechanism that are based on various methodologies.

Study on Thermal Stability Characteristics of Surge Arrester for High Power (전력용 피뢰기의 열안정화 특성)

  • Han, Se-Won;Cho, Han-Goo
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2004.07b
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    • pp.1142-1145
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    • 2004
  • ZnO surge arresters continuously endure the operating voltages during the operation course, and in the mean time, which need to withstand occasionally transient voltages of lightning and switching overvoltages. Under these voltages, the ZnO varistors inside arresters would have aging phenomena, one important result of aging phenomena is the increasing of resistive currents of varistors, which leads to the increasing of power losses of varistors. And the operating voltage is continuously applied on the ZnO varistors, there is a degradation phenomenon existing in ZnO varistors. When the degradation reaches a certain degree, then the arrester must stop operation. The degradation is related to the applied voltage ratio, the applied voltage ratio is high, the degradation is quickly. When the power loss is higher than the thermal dispersion ability of house of arrester, then the arrester will thermally breakdown. In this study the thermal stability characteristics of surge arresters for high power wil be discussed on the view point of watt losses and thermal breakdown.

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Surface Plasmon Resonances of Metal Colloidal Particles Synthesized by a Photo-Chemical Process (광화학적 방법을 이용한 금속입자의 합성과 광학적 특성 연구)

  • Ko, Min-Jin;Plawsky, Joel
    • Journal of the Korean Chemical Society
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    • v.43 no.1
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    • pp.1-7
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    • 1999
  • Metal colloidal particles have been prepared by a photo-chemical process in an aqueous solution containing semiconductor nanocrystallites. Metal colloidal particles produced in CdS and AgBr exhibit different absorption spectra. Au particles produced in solution with CdS show typical Au plasmon resonance absorption spectra. On the other hand Ag particles in solution with AgBr shows surface plasmon resonance absorption spectra which are red-shifted, as compared to that of a dispersion of homogeneous Ag colloidal particles in the same host. The extent of red-shift depends on the UV illumination time. This phenomenon is interpreted within the context of effective medium theory for small volume fractions. From the theory, a metal coated particle predicts Ag plasmon resonance, red shifted with respect to 400 nm that would be associated with a silver particle in solution. The absorption peak position is very sensitive to the coating thickness.

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Atmospheric Environment Prediction to Consider SST and Vegetation Effect in Coastal Urban Region (해수면온도와 식생효과를 고려한 연안도시지역의 대기환경예측)

  • Ji, Hyo-Eun;Lee, Hwa-Woon;Won, Gyeong-Mee
    • Journal of Environmental Science International
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    • v.18 no.4
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    • pp.375-388
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    • 2009
  • Numerical simulation is essential to indicate the flow of the atmosphere in the region with a complicated topography which consists of many mountains in the inland while it is neighboring the seashore. Such complicated topography produces land and sea breeze as the mesoscale phenomenon of meteorology which results from the effect of the sea and inland. In the mesoscale simulation examines, the change of the temperature in relation to the one of the sea surface for the boundary condition and, in the inland, the interaction between the atmosphere and land surface reflecting the characteristic of the land surface. This research developed and simulated PNULSM to reflect both the SST and vegetation effect as a bottom boundary for detailed meteorological numerical simulation in coastal urban area. The result from four experiments performed according to this protocol revealed the change of temperature field and wind field depending on each effect. Therefore, the lower level of establishment of bottom boundary suitable for the characteristic of the region is necessary to figure out the atmospheric flow more precisely, and if the characteristic of the surface is improved to more realistic conditions, it will facilitate the simulation of regional environment.

A Study on Permittivity of Multi-walled Carbon nanotube/Epoxy Composites (다중벽 탄소나노튜브/에폭시 복합재료의 유전율에 관한 연구)

  • 이상의;박기연;김천곤;한재흥
    • Composites Research
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    • v.17 no.3
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    • pp.38-44
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    • 2004
  • The electromagnetic interference (EMI) shielding is very essential for commercial and military purposes. We fabricated multi-walled carbon nanotube (MWNT)/epoxy composites and studied the electromagnetic characteristics of the composites before we study the characteristics of MWNT-added glass fiber-reinforced composites. After setting up the fabrication process, we measured the permittivity of MWNT/epoxy composites with process variables and MWNT concentrations in X-band (8.2GHz~12.4GHz). We also observed re-aggregation phenomenon of MWNTs and investigated its effect on the permittivity. The permittivity of the composites was influenced by the degree of dispersion of MWNTs and increased almost linearly as MWNT concentration increases.

Pullout Performance of Reinforcing Fiber Embedded in Nano Materials Cement Mortar with Nano Clay Contents (나노클레이 첨가량에 따른 나노재료 시멘트 모르타르에 정착된 보강섬유의 인발성능)

  • Oh, Ri-On;Park, Chan Gi
    • Journal of The Korean Society of Agricultural Engineers
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    • v.55 no.3
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    • pp.113-121
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    • 2013
  • Recently, it has been studied for the application of nano-materials in the concrete. Applied a small amount of nano-materials can achieve the goal of high strength, high performance and high durability. The small addition of nano clay improves strength, thermal stability, and durability of concrete because of the excellent dispersion. The present study has investigated the effectiveness, when varying with the contents of nano clay, influencing the pull-out behavior of macro synthetic fibers in nano materials cement mortar. Pullout tests conducted in accordance with the Japan Concrete Institute (JCI) SF-8 standard for fiber-reinforced concrete test methods were used to evaluate the pullout performance of the different nano clay. Nano clay was added to the 0, 1, 2, 3, 4 and 5 % of cement weight. The experimental results demonstrated that the addition of nano clay led to improve the pull-out properties as of the load-displacement curve in the precracked and debonded zone. Also, the compressive strength, flexural strength and pullout performance and of Mix No. 1 and No. 2 increased up to the point when nano clay used increased by 2 and 3 % contents, respectively, but decreased when the exceeded 3 and 4 %, respectively. It was proved by verifying increase of the scratching phenomenon in macro synthetic fiber surface through the microstructure analysis on the surface of macro synthetic fiber.