• Korean Journal of Air-Conditioning and Refrigeration Engineering
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• v.19 no.1
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• pp.51-59
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• 2007

The waste bunker usually consists of waste entrance zone and waste pit. In this paper, the distributions of air flow, $NH_3$ concentration and $H_2S$ concentration in a waste bunker were investigated to prevent an odor generated in a waste pit from dispersing to the waste entrance zone by numerical method. Four cases were considered such that 1) the waste incinerators is operated, 2) the waste incinerators is stopped, 3) the waste incinerator is operated and the direction of a supply diffuser is $45^{\circ}$ upward, 4) the waste incinerator is stopped and the direction of a supply diffuser is $45^{\circ}$ upward. In case of 1), the fresh air from the waste entrance zone is exhausted smoothly to the main exhaust grill of the waste pit. It means that an odor dispersion to the waste entrance zone will not occur. However in case of 2), the induction of fresh air is so small and the supply air with an odor in waste pit can flow to the waste entrance zone. Therefore, an odor will be dispersed to the waste entrance zone. This paper shows the solution that the supply diffuser with the direction of $45^{\circ}$ upward is chosen. As a result in case of 3) and 4), an odor dispersion to the waste entrance zone does not occurred and on odor is exhausted smoothly to the auxiliary exhaust grill.

• Journal of Integrative Natural Science
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• v.11 no.1
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• pp.30-38
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• 2018

CALPUFF is one of the recommended air pollution models by EPA with AERMOD. It has been used to simulate the ambient concentration of critical air pollutants as well as non-critical pollutants such as persistent organic matters and the organic materials causing odor. In this model, the air pollutants go through dispersion, transportation, chemical reaction, and deposition process. These mechanisms are significantly influenced by meteorological condition. This study produces the meteorological field in three different methods for the simulation of $SO_2$ using CALPUFF: 1) CALMET model by using both ground-level and aerological observation, 2) CALMET model by using MM5 results with NCEP/NCAR reanalyzed data, 3) CALMET model by using MM5 results in which FDDA is applied with NCEP/NCAR reanalyzed data as well as the meteorological data of Korea Meteorological Administration. As a result of CALPUFF model, the resolved concentration of $SO_2$ showed different behaviors in three cases. For the first case, the fluctuation of SO2 concentration was frequently observed while the fluctuation is reduced in the second and third cases. In addition, the maximum concentration of $SO_2$ in the first case was about 2~3 times higher than the second case, and about 4~6 times higher than the third case. These results can be caused by the accuracy of the resolved meteorological field. It is inferred that the meteorological field of the first case could be less accurate than other two cases. These results show that the use of correct meteorological data can improve the result of dispersion model. Moreover, the contribution of various sources such as point, line, and area sources on the ambient concentration of air pollutant can be roughly estimated from the sensitivity analysis.

• Resources Recycling
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• v.7 no.4
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• pp.35-42
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• 1998

Surface mount technology is the biggest theme in the area of deιIronic component. To miniatunze an electronic component, s such as ferrite chip inductor, the cer뼈lic wet process for green-sheet lamination and/or screen printing method through a s solvent medium system is widely used. The preparation and characterization of NiCuZn Ferrite (NCZF) shurry and the green s sheet using the water mixed binder system has been studied. The 21 vol% of NCZF slurry was prepared by a ball milling. The p polyacrylic vinyl copolymer (Mw; 60,000) was used as a binder. Th$\xi$ mixture of distilled water, isopropyl alcohol (IPA) and 2l butoxy ethanol was used as a dispersion medium. The water content of medium varied from about 40% to 80%. As the results. Thc disp$\xi$rston stability of the NCZF slurry was attributed to the free polymer rather than the electrostatic force of the particle. T The viscosity of the NCZF slurry was greatly depended on the ratio of water content in the medium.

• Applied Chemistry for Engineering
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• v.3 no.3
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• pp.430-439
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• 1992

To improve the adhesion of interface and dispersion of glass beads in the composite, HDPE filled with glass brads, we encapsulated the g1ass beads with polymer by phase separation method using complex coacervation in organic solvent. EMAA and EAA were used as the polymeric wall materials. The microencapsulation efficiency and morphology were observed by thermogravimetric analysis and SEM, respectively. And also we investigated the physical and dynamic mechanical properties of the composite as the function of the beads contents and microencapsulation efficiency. Compared with the composite containing non-treated glass beads, the decrease in tensile strengthe of the composites containing the encapsulated glass beads become markedly small, and about 30~40% Increase in tensile modulus was observed. From the results of the dynamic mechanical analysis, it was found that the adhesion of interface and dispersion could be improved upon encapsulation.

• Applied Chemistry for Engineering
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• v.23 no.2
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• pp.190-194
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• 2012

10 wt% Mn supported on various commercial $TiO_2$ catalysts were prepared by wet-impregnation method for the low temperature selective catalytic reduction (SCR) of NO with $NH_3$. A combination of various physico-chemical techniques such as BET, XRD, XPS and TPR were used to characterize these catalysts. MnOx surface densities on MnOx/$TiO_2$ catalyst were related to surface area. As MnOx surface density lowered with high dispersion, the SCR activity for low temperature was increased and the reduction temperature ($MnO_2$ ${\rightarrow}$ $Mn_2O_3$) of surface MnOx was lower. For a high SCR, MnOx could be supported on a high surface area of $TiO_2$ and should be existed a high dispersion of non-crystalline species.

• Applied Chemistry for Engineering
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• v.31 no.2
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• pp.200-207
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• 2020

In this study, the effect of calcination temperature on the production of RuTi catalyst in NH₃-SCO (selective catalytic oxidation) was investigated. The RuTi catalyst was prepared using the wet impregnation method, and calcined at 400~600 ℃ for 4 h in air condition. The catalysts were named RuTi x00 where x00 means the calcination temperature. According to XRD (X-Ray diffraction), TEM (transmission electron microscope), H₂-TPR (H₂-temperature programmed reduction) analyses, RuTi x00 catalysts displayed that the dispersion of active metal decreased via increasing the calcination temperature. The catalysts with low dispersion showed a decrease in the surface adsorption oxygen species (O_β) and NH₃ adsorption amount via XPS, and NH₃-TPD analyses. Therefore, the RuTi 400 catalyst was well dispersed in the active metal on TiO₂ surface, and also, the NH₃ removal efficiency was excellent.

• Journal of Environmental Impact Assessment
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• v.31 no.5
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• pp.271-285
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• 2022

The AERMET, the AERMOD meteorological preprocessing program, mainly used for environmental impact assessment and Integrated Environmental Permit System (IEPS) in Korea, has not considered the land covers characterasitics, and used only the past meteorological data format CD-144. In this study, two results of AERMET application considering CD-144 format and ISHD format, being used internationally, were compared. Also, the atmospheric dispersion characteristics were analyzed with consideration of land cover. In the case of considered the CD-144 format, the actual wind speed was not taken into account in the weak wind (0.6~0.9m/s) and other wind speed due to the unit conversion problem. The predicted concentration considering land cover data was up to 387% larger depending on the topographic and emission conditions than without consideration of land cover. In conclusion, when using meteorological preprocessing program in AERMOD modelling, AERMET, with ISHD format, land cover characterasitics in the area should be considered.

• Korean Chemical Engineering Research
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• v.59 no.3
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• pp.359-365
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• 2021

We investigated experimentally the ignition characteristic of dust and the hazard evaluating for electrostatic discharge. The ignition energy experiments were performed on sample dusts such as PE(HD), PE(LD), PMMA using the MIKE-3 apparatus. The formation of flame during the ignition of PE(HD) dust clouds occurred after the delay time of about 8 ms, and the flame kernels were not observed in center of ignition occurrence area. The voltage increased with increasing the number of dust dispersions and the increase rate of measured voltage with dust concentration was the highest in the order of PMMA, PE(LD) and PE(HD). For the effect of dispersion condition on the voltage in PE(HD) dust, the results were obtained that the voltage increased as the number of dispersions increased and as the concentration increased under the same dispersion number. The safety voltages to prevent fire and explosions by electrostatic ignition were estimated that PE(HD), PE(LD)-1, PE(LD)-2, and PMMA were 2.58, 44.72, 25.82, and 8.16 kV, respectively. We proposed the method for estimating the minimum ignition energy by using the measured voltage data for efficient investigation of electrostatic ignition hazard.

• Journal of the Korean Institute of Gas
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• v.26 no.2
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• pp.39-48
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• 2022

The domestic gas detector installation standards applied to gas detectors, which are one of the facilities that can prevent accidents such as fire, explosion, and leakage that can cause serious industrial accidents, do not take into account the behavioral characteristics of hazardous chemicals in the atmosphere. It can be seen that the technical basis is insufficient because the standard is applied. Therefore, in this study, the size of the leak hole for each facility mainly used in chemical plants and the diffusion distance according to the concentration of interest of hazardous chemicals were analyzed, and based on this, the optimal installation distance for gas detectors for each material was suggested. Using the method presented in this study, more economical and effective gas detector installation can be expected, and furthermore, it can be expected to help prevent serious industrial accidents.

• Journal of ILASS-Korea
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• v.29 no.2
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• pp.83-90
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• 2024

Understanding the fundamental characteristics of supersonic hydrogen jets is important for the optimization of combustion in hydrogen engines. Previous studies have used helium as a surrogate gas to characterize the hydrogen jet characteristics due to potential explosion risks of hydrogen. It was based on the similarity of hydrogen and helium jet structures in supersonic conditions that has been confirmed using hole-type injectors and large-cone-angle pintle-type injectors. However, the validity of using helium as a surrogate gas has not been examined for recent small-cone-angle pintle-type injectors applied to direct-injection hydrogen engines, which form a supersonic hollow cone near the nozzle and experience the jet collapse downstream. Differences in the physical properties of hydrogen and helium could alter the jet development characteristics that need to be investigated and understood. This study compares supersonic jet structures of hydrogen and helium injected by a small-cone-angle (50°) pintle-type hydrogen injector and discusses their differences and related mechanisms. Jet penetration length and dispersion angle are measured using the Schlieren imaging method under engine-like injection conditions. As a result, the penetration length of hydrogen and helium jets showed a slight difference of less than 5%, and the dispersion angle showed a maximum of 10% difference according to the injection condition.