• Title/Summary/Keyword: dispersion method

Search Result 1,631, Processing Time 0.033 seconds

Effect of Preparation Method for Pd/C Catalysts on Pd Characterization and their Catalytic Activity (Pd/C 촉매 제조 방법에 따른 Pd 금속의 특성 및 촉매 활성)

  • Kim, Ji Sun;Hong, Seong-Soo;Kim, Jong-Hwa;Lee, Man Sig
    • Applied Chemistry for Engineering
    • /
    • v.26 no.5
    • /
    • pp.575-580
    • /
    • 2015
  • Pd/C catalysts were prepared by various preparation methods such as ion exchange, impregnation and polyol method and also characterized by nitrogen adsorption-desorption isothermal, XRD, FE-TEM and CO-chemisorption. The activities of these catalysts were tested in the hydrogenation of cyclohexene to cyclohexane. Catalytic activities of Pd/C catalysts were found to be effected by the chosen preparation methods. Pd dispersions of each Pd/C catalysts prepared by ion exchange, impregnation and polyol method were 17.55, 13.82% and 1.35%, respectively, confirmed by CO-chemisorption analysis. These were also in good agreement with the FE-TEM results. The Pd/C catalyst prepared by ion exchange method exhibits good performance with the cyclohexene conversion rate of 71% for 15 min. These results indicate that Pd/C catalyst having higher dispersion and lower particle size is in favor of hydrogenation cyclohexene and also Pd dispersion increases with the increment of catalytic activity.

A Study for the Optimum Joint Set Orientations and Its Application to Slope Analysis (사면해석을 위한 최적의 절리군 대표방향성 도출 및 활용기법 연구)

  • Cho, Taechin
    • Tunnel and Underground Space
    • /
    • v.28 no.4
    • /
    • pp.343-357
    • /
    • 2018
  • Algorithm which can analyze the slope failure behavior utilizing the comprehensive information of the dense point of joint poles and the joint set orientations, both of which are obtained statistically, and the defect pattern of pole distribution has been developed. This method overcomes the potential incorrectness of the hemispheric projection method utilizing the joint set orientations only and also enhances the reliability of slope failure analysis. To this end a method capable of calculating the joint dispersion index directly from the joint pole distribution, instead of contour map, has been devised. The representative orientations for the slope failure analysis has been determined by considering the number and orientations of cone angle-dependent joint sets as well as the joint dispersion index. By engaging these representative orientations to the hemispheric projection analysis more reliable slope failure examination has been carried out. Sensitivity analysis for the potentially unstable slope of plane failure mode has been performed. Significance of joint strength index and the external seismic loading on the slope stability has been fully analyzed.

Comparison of Post-dispersion Compensation Methods for Optical 40 Wavelength Division Multiplexing Channels at 3000km Transmission (파장다중화 광신호의 3000km 전송을 위한 후치분산 보상 방법 비교)

  • Choi, Bo-Hun
    • Journal of the Korea Institute of Information and Communication Engineering
    • /
    • v.17 no.10
    • /
    • pp.2466-2472
    • /
    • 2013
  • Post-dispersion compensation methods for the 3000 km long-haul transmission distance using 10 Gbps 40 wavelength division multiplexing channels were analyzed and compared. First, each channel was compensated by an individual dispersion value, next each group of eight channels by an individual value, and lastly all forty channels by a single value. Considering the lower and highest performance channels and their values, the post-dispersion compensation method by each channel group showed the possibility to simplify the transmission system without sacrifice of signal performance.

Physical Properties Variation of Grout Materials Based on the Water to Cement Ratio and the Mixing Speed (물시멘트비 및 혼합속도에 따른 주입재의 물성변화 연구)

  • Chun, Byung-Sik;Kim, Jin-Chun;Jang, Bui-Woong;Lee, Jun-Woo
    • Journal of the Korean GEO-environmental Society
    • /
    • v.1 no.1
    • /
    • pp.87-96
    • /
    • 2000
  • Generally, OPC(ordinary portland cement) is used for grouting in Korea, and bentonite has usually been added to prevent the deposition of cement particles. The dispersion of CB(cement bentonite) grout is influenced by variable factors i.e. water to cement ratio, particle size of cement, kind of bentonite, adding volume, method of adding, viscosity of CB grout materials and curdling time. Among variable factors, the viscosity of CB grout materials is influenced by the dispersion, and dispersion is improved as the speed of grout mixer increase. In this paper, the specification of construction was derived by estimating physical characteristics of CB grout materials and confirming the sate of dispersion. The results show that the engineering characteristics of CB grout materials vary with the water to cement ratio and the mixing speed.

  • PDF

Joint Inversion Analysis Using the Dispersion Characteristics of Love Wave and Rayleigh Wave (II) - Verification and Application of Joint Inversion Analysis - (러브파와 레일리파의 분산특성을 이용한 동시역산해석(II) - 동시역산해석기법의 검증 및 적용 -)

  • Lee Il-Wha;Joh Sung-Ho
    • Journal of the Korean Geotechnical Society
    • /
    • v.21 no.4
    • /
    • pp.155-165
    • /
    • 2005
  • Love wave and Rayleigh wave are the major elastic waves belonging to the category of the surface wave. Those waves are used to determine the ground stiffness profile using their dispersion characteristics. The fact that Love wave is not contaminated by P-wave makes Love wave superior to Rayleigh wave and other body waves. Therefore, the information that Love wave carries is more distinct and clearer than that of others. Based on theoretical research, the joint inversion analysis that uses the dispersion information of both Love and Rayleigh wave was proposed. Numerical analysis, theoretical model test, and field test were performed to verify the joint inversion analysis. Results from 2D, 3D finite element analysis were compared with those from the transfer matrix method in the numerical analysis. On the other hand, the difference of results from each inversion analysis was investigated in the theoretical model analysis. Finally, practical applicability of the joint inversion analysis was verified by performing field test. As a result, it is confirmed that considering dispersion information of each wave simultaneously prevents excessive divergence and improves accuracy.

Analysis of the Influence of Mutual Relation of Optical Pulse Frequency Chirp and Kerr Effect on the Mid-Span Spectral Inversion Methods for the Long-Haul Optical Transmission (광 펄스 주파수 첩과 Kerr 효과의 상호 관계가 장거리 광 전송을 위한 MSSI 보상 기법에 미치는 영향 분석)

  • 이성렬;이윤현
    • The Journal of Korean Institute of Electromagnetic Engineering and Science
    • /
    • v.13 no.9
    • /
    • pp.898-906
    • /
    • 2002
  • In this paper, we investigated the improvement degree of transmission distance of the various initial frequency chirped optical pulse with 5 dBm initial power dependence on the various bit rate and fiber dispersion coefficient, when MSSI(Mid-Span Spectral Inversion) with the optimal pump power condition is adopted for the compensation method for optical pulse distortion. And we analyzed the influence of mutual relation of optical pulse frequency chirp and Kerr effect on the MSSI methods for the long-haul optical transmission through the computer simulation. We found that the compensation degree of distorted optical pulse varies as a consequence of the variation of combined phase modulation of self phase modulation(Kerr effect) and initial frequency chirp parameter dependence on the fiber dispersion coefficient. And we found that, if the transmission bit rate is increased k times, the dispersion coefficient value of dispersion shift fiber is decreased $2^k$ times so as to be almost the same performance of the transmission system with k times lower bit rate.

$SnO_2$ Dispersion of Sintered Body in $In_2O_3-SnO_2$ Binary System ($In_2O_3-SnO_2$ 이성분계 소결특성에 있어서 $SnO_2$ 분산성)

  • Chun, Tae-Jin;Park, Wan-Soo;Cho, Muyung-Jin;Kim, Jong-Su;Kim, Young-Soo
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
    • /
    • 2006.11a
    • /
    • pp.198-198
    • /
    • 2006
  • Tin doped $In_2O_3$ sputtering target is widely used to produce a various kinds of flat panel display because of high transmittance in visible region and high electrical conductivity. In2O3 and SnO2 powders were prepared by a homogeneous precipitation method using metal source, respectively, the calcining and sintering behavior of the indium-tin oxide(In2O3-SnO2) composite powders were studied. The tin oxide(SnO2) dispersion condition in ITO sputtering target was improved by increasing calcining temperature. And the tin oxide dispersion was also improved by reducing the tin oxide contents in the ITO target from 30 to 5wt%. SnO2 dispersion and densification of ITO target is very difficult to control due to sublimation of SnO2 at over 1150C.

  • PDF

IMAGING THE UPPER CRUST OF THE KOREAN PENINSULA BY SURFACE WAVE TOMOGRAPHY (표면파 토모그래피를 이용한 한반도 상부지각의 이미지)

  • Cho, Kwang-Hyun;Herrmann, Robert B.;Lee, Kie-Hwa
    • 한국지구물리탐사학회:학술대회논문집
    • /
    • 2006.06a
    • /
    • pp.41-50
    • /
    • 2006
  • The crustal structure of Korean Peninsula have been investigated by analyzing group velocity dispersion data of surface wave. Cross.correlation of seismic background motions (Campillo and Paul, 2003; Shapiro et al., 2005) has been applied to estimate the short.period Rayleigh. and Love.wave group velocity dispersion characteristics of the region. Standard processing procedures were applied to the cross.correlation, except that signal whitening was used in place of one.bit sampling equalize power in signals from different times. Multiple.filter analysis was used to extract the group velocities from the estimate Green's functions, which were then use to image the spatially varying dispersion at periods between 0.5 and 20 seconds. The tomographic inversion technique used inverted all periods simultaneously to provide a smooth dispersion curve as a function of period in addition to the usual smooth spatial image for a given period. The Gyeongsang Basin in the southeastern part of the peninsula is clearly resolved with lower group velocities.

  • PDF

Characteristics of Compensation for Distorted WDM Channel with Inter-channel Interference due to Four-Wave Mixing (4-광파 혼합에 의한 채널 간섭이 존재하는 왜곡된 WDM 채널의 보상 특성)

  • 이성렬;손성찬;방효창;김지웅;조경룡
    • Journal of the Korea Institute of Information and Communication Engineering
    • /
    • v.8 no.6
    • /
    • pp.1234-1242
    • /
    • 2004
  • In this paper, the characteristics of compensation for interferenced mid-channel signal by neighbor channels through four-wave mixing (FWM) process dominantly is investigated as a function of channel input power, fiber dispersion coefficient and transmission length in WDM system with equally spaced channels. The compensation method used in this research is mid-span spectral inversion(MSSI). The highly nonlinear dispersion shifted fiber (HNL-DSF) is used as a nonlinear medium of optical phase conjugator (OPC) in order to compensate wideband WDM signals. First, we confirmed that the effect of FWM on channel interference is gradually reduced as fiber dispersion coefficient becomes gradually smaller, independent of signal format. And, we confirmed that RZ is better than NRZ as a modulation format for transmitting high power channel with allowable reception quality. But realization of flexible WDM systems regardless of channel number variation is possible by using NRZ rather than RZ format.

Higher QT Dispersion in Patients with Social Anxiety Disorder (사회불안장애의 QT Dispersion 연구)

  • Kwon, Young-Do;Lim, Se-Won;Oh, Kang-Seob
    • Korean Journal of Biological Psychiatry
    • /
    • v.17 no.1
    • /
    • pp.44-48
    • /
    • 2010
  • Objectives : Social phobia is frequently accompanied with autonomic nerve system symptoms. QT dispersion(QTd) is the maximum inter-lead difference in QT interval, an indicator of the autonomic nerve system(ANS) disparity of the heart itself. The objective of this study is to investigate the ANS disparity, which is measured by QTd, is associated with pathophysiology of social phobia. Methods : This research have compared QT dispersion of 25 physically healthy social phobia outpatients(16 men, 9 women, the average age $35.5{\pm}12.9$) and age and sex matched control group of mentally and physically healthy 25 volunteers(16 men, 9 women, the average age $34.83{\pm}12.7$). QTd was measured by previously described method. Results : QTd and rate-corrected QTd were significantly higher on the patient group than the control group[QTd(patients vs. controls : $52.60{\pm}27.63ms$ vs. $27.53{\pm}14.29ms$, p<0.0001), QTd(patients vs. controls : $55.79{\pm}27.98ms$ vs. $29.10{\pm}14.24ms$, p<0.0001)]. Conclusion : Our study showed that the patients with social phobia have higher QTd than the normal controls. These results suggest that the ANS disparity, which is measured by QTd, is associated with pathophysiology of social phobia.