• Title/Summary/Keyword: dispersion method

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Properties of Dye Sensitized Solar Cells with Porous TiO2 Layers Using Polymethyl-Methacrylate Nano Beads

  • Choi, Minkyoung;Noh, Yunyoung;Kim, Kwangbae;Song, Ohsung
    • Korean Journal of Materials Research
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    • v.26 no.4
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    • pp.194-199
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    • 2016
  • We prepared polymethyl methacrylate (PMMA) beads with a particle size of 80 nm to improve the energy conversion efficiency (ECE) by increasing the effective surface area and the dye absorption ability of the working electrodes (WEs) in a dye sensitized solar cell (DSSC). We prepared the $TiO_2$ layer with PMMA beads of 0.0~1.0 wt%; then, finally, a DSSC with $0.45cm^2$ active area was obtained. Optical microscopy, transmission electron microscopy, field emission scanning electron microscopy, and atomic force microscopy were used to characterize the microstructure of the $TiO_2$ layer with PMMA. UV-VIS-NIR was used to determine the optical absorbance of the WEs with PMMA. A solar simulator and a potentiostat were used to determine the photovoltaic properties of the PMMA-added DSSC. Analysis of the microstructure showed that pores of 200 nm were formed by the decomposition of PMMA. Also, root mean square values linearly increased as more PMMA was added. The absorbance in the visible light regime was found to increase as the degree of PMMA dispersion increased. The ECE increased from 4.91% to 5.35% when the amount of PMMA beads added was increased from 0.0 to 0.4 wt%. However, the ECE decreased when more than 0.6 wt% of PMMA was added. Thus, adding a proper amount of PMMA to the $TiO_2$ layer was determined to be an effective method for improving the ECE of a DSSC.

Design of Turbulent In-situ Mixing Mixer and Fabrication of Cu-TiB2 Nanocomposities (난류 용탕 In-situ 합성 믹서의 설계 및 Cu-TiB2 나노 복합재료의 제조)

  • Choi, Baek-Boo;Park, Jung-Su;Yun, Ji-Hun;Ha, Man-Young;Park, Yong-Ho;Park, Ik-Min
    • Korean Journal of Materials Research
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    • v.17 no.1
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    • pp.11-17
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    • 2007
  • Turbulent in-situ mixing process is a new material process technology to get dispersed phase in nanometer size by controlling reaction of liquid/solid, liquid/gas, flow ana solidification speed simultaneously. In this study, mixing which is the key technology to this synthesis method was studied by computational fluid dynamics. For the simulation of mixing of liquid metal, static mixers investigated. Two inlets for different liquid metal meet ana merge like 'Y' shape tube having various shapes and radios of curve. The performance of mixer was evaluated with quantitative analysis with coefficient of variance of mass fraction. Also, detailed plots of intersection were presented to understand effect of mixer shape on mixing. The simulations show that the Reynolds number (Re) is the important factor to mixing and dispersion of $TiB_2$ particles. Mixer was designed according to the simulation, and $Cu-TiB_2$ nano composites were evaluated. $TiB_2$ nano particles were uniformly dispersed when Re was 1000, and cluster formation and reduction in volume fraction of $TiB_2$ were found at higher Re.

Dielectric and Mechanical Properties of BNT-LCP Composites

  • Park, Myoung-Sung;Cho, Jeong-Ho;Kim, Byung-Ik;Chun, Myoung-Pyo;Nahm, Sahn
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.24 no.7
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    • pp.547-553
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    • 2011
  • We investigated the dielectric and mechanical properties of ceramic polymer composite xBNT - (1-x)LCP (x= 0, 10, 20, 30, 40 vol.%). The disk shaped BNT ($BaNd_2Ti_4O_{12}$) - LCP (liquid crystal polymer) composite samples were prepared by compression molding method. With increasing the BNT content in composites from 10 to 40 vol.%, the dielectric constant increased but the dielectric loss as well as bending strength of composites reduced. These composites were well described with modified Lichtenecker's model having k = 0.392 and 0.303 for the first and second ball milled BNT filled composites, which means that the BNT filler in composites are well dispersed. The dielectric constant of the composite comprised of the second milled BNT ($D_{50}$ = 1.39 um) was higher that of the composite of the first milled BNT ($D_{50}$= 2.45 um), which seems to be related with the different particle size and dispersion of BNT fillers in LCP matrix. The bending strength of the composite containing the second milled BNT was superior to that of the composite of the first milled BNT.

Optimization of Inner Nitriding Process for Cr-Mo-V Steel of Small Arms Barrel by using Taguchi Experimental Design Method (다구찌 실험계획법을 이용한 소구경화기 총열 내부용 Cr-Mo-V강의 질화공정 최적화)

  • Kwon, Hyuk-Rin;Kim, Dong-Eun;Son, Hyung-Dong;Shin, Jea-Won;Park, Jae-Ha;Kang, Myung-Chang
    • Journal of the Korean Society of Manufacturing Process Engineers
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    • v.17 no.3
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    • pp.148-154
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    • 2018
  • When shooting small arms, the inner surface temperature is heated up to about $700{\sim}1,000^{\circ}C$ by the friction of the bullet and the inner wall of the barrel and the combustion of propellant. High-temperature propellant gas and high-speed movement of the bullet cause corrosion of the inner wall, which is noticeable immediately in front of the chamber. In this study, the mechanical properties of Cr-Mo-V steel, which is the base material, were tested using Taguchi experimental design to find the best nitriding treatment conditions. For the nitriding process, the working time, salt bath temperature, and salt concentration were combined as three conditions and placed in the $L_9(3^4)$, orthogonal array table. The thicknesses of the white layer and the nitrogen diffusion layer were measured after nitriding under each condition in a salt bath furnace. Durability was evaluated by measuring the degree of dispersion through actual shooting because it was difficult to evaluate the mechanical properties of the cylinder inner structure. As a result, it was confirmed that the durability was optimal at $565^{\circ}C$, 1 hour, 0.5%. These optimal conditions were selected by the statistical analysis of the Minitab program(ver.17).

A Comparative Study on Characteristics of Nanofluids Using Carbon NanoTubes (탄소 나노튜브를 이용한 나노유체의 특성 비교 연구)

  • An, Eoung-Jin;Park, Sung-Seek;Kim, Nam-Jin
    • 한국신재생에너지학회:학술대회논문집
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    • 2011.05a
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    • pp.74.1-74.1
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    • 2011
  • 탄소나노튜브는 높은 전기 전도성과 열 전도성을 가지며, 이러한 특성 때문에 21세기를 주도해 나갈 수 있는 차세대 첨단 소재로서 각광을 받고 있다. 또한 최근에는 나노공학기술의 발달로 인하여 획기적으로 높은 열전도도를 나타내는 다중벽 탄소나노튜브(Multi-walled Carbon Nanotubes, MWCNTs)의 대량 생산이 가능하게 되면서 다중벽 탄소나노튜브의 높은 열전도도 특성을 이용하여 탄소나노튜브를 기본 유체 및 기능성 유체에 안정하게 분산 시킨 후 이를 이용하고자 하는 연구가 활발히 진행되고 있으며, 탄소나노튜브를 유체에 안정하게 분산시키기 위한 방법으로는 기계적 분산법, 물리적 흡착에 의한 분산법, 화학적 개질에 의한 분산법이 있다. 따라서 본 연구에서는 이들 분산 방법과 탄소나노튜브 입자의 물성치에 따른 나노유체의 특성을 알아보기 위하여 나노유체의 열전도도와 점도 특성을 비교 분석하였다. 모든 물성치는 같지만 탄소나노튜브의 길이만 다른 두 종류의 다중벽 탄소나노튜브에 각각 계면 활성제(Sodium Dodecyl Sulfate, SDS) 100 wt%와 고분자 화합물(Polyvinyl Pyrrolidone, PVP) 300 wt%를 첨가하여 나노유체를 제조하였으며, 산화처리 된 다중벽 탄소나노튜브(Oxidized Multi-Walled Carbon Nanotubes, OMWCNTs)를 증류수에 초음파 분산하여 산화나노유체를 제조하였다. 나노유체의 열전도도는 전기 전도성 유체의 비정상 열선법(Transient Hot-wire Method)을 이용하여 측정하였고, 나노유체의 점도는 회전형 디지털 점도계를 이용하여 측정하였다. 실험 결과, 상온에서 동일 혼합비의 나노유체를 비교했을 때, 산화나노유체가 SDS 100 wt%, PVP 300 wt%를 혼합한 다른 나노유체보다 높은 열전도도 특성을 보였으며 점도 특성 또한 가장 낮은 것으로 측정되었다. 특히 상온에서 0.1vol%의 산화 CM-100 나노유체는 증류수보다 열전도도가 8.34%가 증가하였고, $10^{\circ}C$의 저온에서는 상온에서 증류수와 비교하여 측정된 열전도도 값보다 0.36%가 감소한 7.98%가 증가함을 보였다. 본 연구를 통하여 얻어진 결과는 높은 열전도도를 필요로 하는 열교환기의 작동유체나 기타 활용 분야에 대한 기초 자료로써 유용한 정보를 제공할 것이라 판단된다.

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Sol-gel Derived Nano-glass for Silicon Solar Cell Metallization (솔-젤법에 의해 제조된 실리콘 태양전지 전극형성용 나노 글래스)

  • Kang, Seong Gu;Lee, Chang Wan;Chung, Yoon Jang;Kim, Chang-Gyoun;Kim, Seongtak;Kim, Donghwan;Lee, Young Kuk
    • Current Photovoltaic Research
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    • v.2 no.4
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    • pp.173-176
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    • 2014
  • We have investigated the seed layer formation of front side contact using the inkjet printing process. Conductive silver ink was printed on textured Si wafers with 80 nm thick $SiN_x$ anti reflection coating (ARC) layers and thickened by light induced plating (LIP). The inkjet printable sliver inks were specifically formulated for inkjet printing on these substrates. Also, a novel method to prepare nano-sized glass frits by the sol-gel process with particle sizes around 5 nm is presented. Furthermore, dispersion stability of the formulated ink was measured using a Turbiscan. By implementing these glass frits, it was found that a continuous and uniform seed layer with a line width of $40{\mu}m$ could be formed by a inkjet printing process. We also investigated the contact resistance between the front contact and emitter using the transfer length model (TLM). On an emitter with the sheet resistance of $60{\Omega}/sq$, a specific contact resistance (${\rho}_c$) below $10m{\Omega}{\cdot}cm^2$ could be achieved at a peak firing temperature around $700^{\circ}C$. In addition, the correlation between the contact resistance and interface microstructures were studied using scanning electron microscopy (SEM). We found that the added glass particles act as a very effective fire through agent, and Ag crystallites are formed along the interface glass layer.

A Study on the producing of Non-realistic 3D Character Animation with the style of 2D Animation (비사실적 3D 캐릭터 애니메이션의 효과적인 2D 애니메이션 스타일 연출 연구)

  • Kim, Sungrae
    • Proceedings of the Korea Contents Association Conference
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    • 2007.11a
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    • pp.894-898
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    • 2007
  • Now a day, lots of the animations include TV series Animations are made by the technique of 3D Animation. However, 3D Animation obstructs visual elements and deteriorates an acquaintance with the limit of unfamiliar material methods and dispersion of light. For this reason, a large of number of 3D Animations are repacked with the style of 2D Animation. Most of previous studies for the conversion of output 3D Animation to the style of 2D Animation are analysis for 2D rendering techniques. In case of Non-realistic 3D Character Animation, first and foremost it needs investigation of the basic producing method for the 2D Animation is different with the realistic expression way of the one for the 3D animation. For a case study, expression methods for the non-realistic and the non-actuality 2D Character Animation come with impossible ways in the real life. This study for the 3D Animation with the style of 2D Animation is to investigate on the keynote for effective expression methods, when we turn 3D Animation into the style of 2D Animation.

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Evaluation of mechanical properties and non-flammability of Nylon6 using melamine-based halogen-free flame retardant (Melamine계 난연제를 이용한 Nylon6의 난연성 및 물리적 특성 평가)

  • Kim Dong-Hak;Ryu Kwan-Suk;Son Young-Gon
    • Journal of the Korea Academia-Industrial cooperation Society
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    • v.7 no.4
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    • pp.743-748
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    • 2006
  • We investigated the flame retardancy and the mechanical properties of Nylon6 by using melamine-based halogen-free flame retardants(melamine cyanurate:MC-100 and melamine phosphate:MP-100). We chose the UL-94 method for flame retardancy and measured the tensile strength, flexural strength, flexural modulus by using UTM and impact strength by using Izod impact tester. We also tested the effect of nano-clay on flammability and mechanical properties. We obtained the V0 grade when the concentration of flame retardant was over 5 wt%. The tensile strength and flexural strength decreased and flexural modulus increased with the concentration of both flame retardant systems. The results showed that MC-100 system was better than MPP-100 system. Because of poor dispersion, we did not obtain the synergistic effect of nano-clay.

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Electrical Breakdown Properties of Extrusion Blended Low Density Polyethylene (사출 블렌드 저밀도 폴리에틸렌의 절연파괴 특성)

  • 조돈찬;김형주;신현택;이충호;이수원;홍진웅
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2001.07a
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    • pp.593-596
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    • 2001
  • In the previous work, the effect of blending with two kinds of low density polyethylene (LDPE) on physical and electrical properties have been investigated. From the results, blending with two kinds of LDPE was effective method on changing the morphology of LDPE and improving the high-field characteristics in high temperature region. Especially, it suggested that the F$\_$BImp/ was associated with the changes of the crystal size. In this work, the relationship between the morphology and the high-field characteristics of blended LDPE was discussed. In addition, the physical and electrical properties of blended LDPE with extrusion treatment were investigated. The two groups of specimen were prepared; Group 1 was prepared by passing 1 time through the extruder included in the film-blowing process, and Group 2 was prepared by passing 2 times through the extruder. From the relation between the crystal size which was perpendicular to the (020) plane and the F$\_$BImp/ of blended LDPE, it was confirmed that the F$\_$BImp/ was associated with the changes of crystal size due to the blending. Moreover, the F$\_$BImp/ of blended LDPE in Group 2 was higher than that of blended LDPE in Group 1. The crystal size of the (020) plane became smaller according to the extrusion treatment. These results suggest that the uniform distribution and dispersion of crystalline occurred due to the extrusion treatment and the morphological change due to the extrusion treatment influenced on the electrical properties of blended LDPE.

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Recognition of License Plates Using a Hybrid Statistical Feature Model and Neural Networks (하이브리드 통계적 특징 모델과 신경망을 이용한 자동차 번호판 인식)

  • Lew, Sheen;Jeong, Byeong-Jun;Kang, Hyun-Chul
    • Journal of KIISE:Software and Applications
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    • v.36 no.12
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    • pp.1016-1023
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    • 2009
  • A license plate recognition system consists of image processing in which characters and features are extracted, and pattern recognition in which extracted characters are classified. Feature extraction plays an important role in not only the level of data reduction but also performance of recognition. Thus, in this paper, we focused on the recognition of numeral characters especially on the feature extraction of numeral characters which has much effect in the result of plate recognition. We suggest a hybrid statistical feature model which assures the best dispersion of input data by reassignment of clustering property of input data. And we verify the effectiveness of suggested model using multi-layer perceptron and learning vector quantization neural networks. The results show that the proposed feature extraction method preserves the information of a license plate well and also is robust and effective for even noisy and external environment.