• 제목/요약/키워드: dispersion matrix

검색결과 464건 처리시간 0.029초

소수성 CNT/PVDF 복합막에서 CNT의 분산과 전도성의 관계 (Relations Between Dispersion of CNTs and Electrical Conductivity in the Hydrophobic CNT/PVDF Composite Film)

  • 이선우
    • 한국전기전자재료학회논문지
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    • 제28권7호
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    • pp.462-466
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    • 2015
  • In this paper, we investigated the relations between dispersion of CNTs (carbon nanotubes) and electrical conductivity in the CNT/PVDF (polyvinylidene fluoride) composite film. By adding hydrophobic CNTs as filler into the PVDF matrix, we fabricated hydrophobic and electrically conducting polymer coating film. Dispersion of CNTs in the CNT/PVDF composite film plays a significant role in terms of electrical conductivity and wetting property. Spray coating method was used to form the CNT/PVDF composite films by injecting the dispersed CNTs in the PVDF solution with different weight ratios from 0.7 wt% to 7 wt%. We investigated the electrical properties and contact angles of the CNT/PVDF composite films with the CNT concentration. Finally we discussed the conducting mechanism and feasibility of the CNT/PVDF composite film for the conducting polymer films.

손실 매질에 대한 Isotropic-Dispersion 유한 차분식의 2D Crank-Nicolson FDTD 기법 (2D Crank-Nicolson FDTD Method Based on Isotropic-Dispersion Finite Difference Equation for Lossy Media)

  • 김현;고일석;육종관
    • 한국전자파학회논문지
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    • 제21권7호
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    • pp.805-814
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    • 2010
  • 기존 Crank-Nicolson FDTD 기법(CN FDTD 기법)의 비등방성 분산 특성을 개선하기 위한 CN ID-FDTD 기법을 제안하였다. 제안한 CN ID-FDTD 기법은 공간 미분 연산을 위해 기존 CN FDTD 기법의 centered 유한 차분식 (Finite Difference equation: FD 연산식)이 아닌 isotropic-dispersion 유한 차분식(ID-FD 연산식)$^{[1],[2]}$을 이용한다. 본 논문에서는 손실 매질에 대한 CN ID-FDTD 기법의 분산 관계식을 유도하였고, 이 분산 관계식을 이용해 ID-FD 연산식에서 분산 오차(dispersion error)를 줄이는 가중치(weighting factor)와 보정값(scaling factor)을 제시하였다. 그리고 해석 결과의 정확성 비교를 통해 CN ID-FDTD 기법에서는 기존 CN FDTD 기법의 단점이었던 비등방성 분산 오차가 확연하게 감소하는 것을 확인하였다.

강섬유 보강 시멘트 복합체의 시공성 향상에 관한 연구 (A Study on the Improvement of Construction Performance of Steel Fiber Reinforced Cementitious Composites)

  • 고경택;박정준;김방욱;이종석;김성욱;이장화
    • 한국콘크리트학회:학술대회논문집
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    • 한국콘크리트학회 2002년도 가을 학술발표회 논문집
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    • pp.749-754
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    • 2002
  • In this study, it is investigate to influence on tile dispersion of fiber and the flowability of matrix of type and amount of superplasticizer, velocity agent, mineral admixture and steel fiber to improve for construction performance of steel fiber reinforced cementitious composites. As for the test results, it was found that the dispersion of fiber and the flowability of matrix in steel fiber reinforced cementitious composites can improve by using of properly amount and combination of superplasticizer, velocity agent, mineral admixture. Furthermore, It show that the aspect ratio of steel fiber affect the construction performance of fiber reinforced cementitious composites, and the improvement for construction performance is the more effective the smaller aspect ration of steel fiber.

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Multivariate Cumulative Sum Control Chart for Dispersion Matrix

  • 장덕준;신재경
    • Journal of the Korean Data and Information Science Society
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    • 제13권2호
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    • pp.21-29
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    • 2002
  • Several different control statistics to simultaneously monitor dispersion matrix of several quality variables are presented since different control statistics can be used to describe variability. Multivariare cumulative sum (CUSUM) control charts are proposed and the performances of the proposed CUSUM charts are evaluated in terms of average run length (ARL). Multivariate Shewhart charts are also proposed to compare the properties of the proposed CUSUM charts. The numerical results show that multivariate CUSUM charts are more efficient than multivariate Shewhart charts for small or moderate shifts. And we also found that small reference value of the CUSUM chart is more efficient for small shift.

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Rheological characterization of nanoparticle filled polymeric systems

  • Kim, Byoung-Chul;Chae, Dong-Wook
    • 한국고분자학회:학술대회논문집
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    • 한국고분자학회 2006년도 IUPAC International Symposium on Advanced Polymers for Emerging Technologies
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    • pp.219-219
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    • 2006
  • This study focuses on the effects of dispersion method of a nanoparticle in a polymer matrix such as melt mixing, solution blending, and in-situ polymerization on the physical properties of the nanocomposites. Introduction of a nanoparticle to a polymer resulted in some unusual physical properties. In some cases the nanoparticle played a role of a nucleating agent, leading to decreasing induction time to crystallization. In addition, the dispersion state of the nanoparticle in the polymer matrix also had a significant influence on the physical properties of the nanocomposites. Hence the method of introducing the nanoparticle to the polymer made contribution to the rheological properties of the nanocomposite systems.

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그래핀 옥사이드/카르복실화한 스티렌-부타디엔 고무 나노 복합체에 관한 연구 (A Study on Graphene Oxide and Carboxylated Styrene-Butadiene Rubber(XSBR) Nanocomposites)

  • 장선호;리시앙수;조을룡
    • 반도체디스플레이기술학회지
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    • 제16권1호
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    • pp.52-58
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    • 2017
  • Graphene oxide (GO)/carboxylated styrene-butadiene rubber (XSBR) nanocomposites with various contents of GO were prepared by a latex compounding method. It has been confirmed that the functional groups of GO and the hydrogen bonds between GO and XSBR are existed. It can be seen that the scorch time ($t_{s2}$), which is the measurement of incipient vulcanization of rubber, showed a delay after the addition of GO. Field emission scanning electron microscopy was employed to confirm the uniform dispersion of filler in the matrix. Indeed, with increasing fillers loading, the torque, tensile strength, thermal stability and crosslink density of obtained nanocomposites were improved. These results were correlated to the better dispersion of fillers through the rubber matrix.

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Numerical Switching Performances of Cumulative Sum Chart for Dispersion Matrix

  • Chang, Duk-Joon
    • 통합자연과학논문집
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    • 제12권3호
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    • pp.78-84
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    • 2019
  • In many cases, the quality of a product is determined by several correlated quality variables. Control charts have been used for a long time widely to control the production process and to quickly detect the assignable causes that may produce any deterioration in the quality of a product. Numerical switching performances of multivariate cumulative sum control chart for simultaneous monitoring all components in the dispersion matrix ${\Sigma}$ under multivariate normal process $N_p({\underline{\mu}},{\Sigma})$ are considered. Numerical performances were evaluated for various shifts of the values of variances and/or correlation coefficients in ${\Sigma}$. Our computational results show that if one wants to quick detect the small shifts in a process, CUSUM control chart with small reference value k is more efficient than large k in terms of average run length (ARL), average time to signal (ATS), average number of switches (ANSW).

발사르탄 고체 분산체를 함유하는 위체류 매트릭스 부유 정제의 개발 및 평가 (Development and Evaluation of Gastro Retentive Floating Matrix Tablet Containing Valsartan Solid Dispersion)

  • 조영호;이종화;이계원
    • KSBB Journal
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    • 제31권4호
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    • pp.219-227
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    • 2016
  • Valsartan, a drug for the treatment of cardiovascular disease, exhibited low bioavailability which was caused by, at least in part, limited solubility at low pH. Present investigation deals with the preparation and characterization of gastro-retentive drug delivery system (GRDDS) using valsartan solid dispersion. We prepared solid dispersion using surfactants (Poloxamer 407) and alkalizer ($Na_2CO_3$) which may to be useful for improving solubility of valsartan at low pH and evaluated by saturated solubility of valsartan in distilled water. Valsartan gastro-retentive (GR) tablets containing solid dispersion prepared and evaluated by weight variation, floating time and dissolution rate. Compression at lower pressures resulted in the tablets floating over simulated gastric fluid (pH 1.2) for more than 17 h. In vitro release of valsartan from GR tablet was dependent on the amount of poloxamer 407 and hydroxypropyl methylcellulose. On the basis of evaluation parameter, formulation E-3 was selected as a final formulation. Therefore, it can be concluded that the GR tablets containing solid dispersion may be exploited successfully for the delivery of poorly drug such as valsartan.

MSPD 전처리법과 HPLC를 이용한 Furazolidone의 계란내 잔류분석 (Matrix Solid-Phase Dispersion (MSPD) Isolation and Liquid Chromatographic Determination of Residual Furazolidone in Eggs)

  • 서계원;이재일;이채용;이정치
    • 한국식품위생안전성학회지
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    • 제18권2호
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    • pp.43-50
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    • 2003
  • A liquid chromatographic method, using matrix solid-phase dispersion (MSPD) is developed for the extraction of residual furazolidone in chicken eggs. Blank or fortified egg samples (0.5 g) were blended with Octadecylsilyl (Bulk $C_{18}$, 40${\mu}{\textrm}{m}$, 18%. load, endcapped. 2 g) derivatized silica. After homogenization, $C_{18}$/egg and Na$_2$S $O_4$matrix were transferred to a column made of 10 ml glass syringe and filter paper and compressed 4.0∼4.5 ml volume. The column was washed with 8 ml of hexane and dried under $N_2$ gas. Furazolidone was eluted with acetonitrile (8 ml) under gravity. The eluate containing furazolidone was free from interfering compounds when analyzed by HPLC with UV detection (365 nm, photodiode array). Calibration curves were linear (r = 0.99985) and inter- (1.47%) and intra-assay (5.29%) variabilities for the concentration range examined (7.8∼497 ng/g of eggs, 20 ${mu}ell$ injection volume) were indicative of an acceptable methodology for the analysis of furazolidone. Average recovery of furazolidone added to egg was 96.2%. The limit of detection for the proposed method was 1 ng/g for furazolidone. The method using MSPD is proposed as an alternative assay to the classical method which involves the use of large volumes of a harmful solvent and requires a long tedious separation and clean-up processes prior to its determination.

란타넘 산화물의 분산을 통해 향상된 파괴인성을 갖는 몰리브데넘 합금의 제조 (Fabrication of Molybdenum Alloys with Improved Fracture Toughness through the Dispersion of Lanthanum Oxide)

  • 최원준;박천웅;박정효;김영도;변종민
    • 한국분말재료학회지
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    • 제26권3호
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    • pp.208-213
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    • 2019
  • In this study, lanthanum oxide ($La_2O_3$) dispersed molybdenum ($Mo-La_2O_3$) alloys are fabricated using lanthanum nitrate solution and nanosized Mo particles produced by hydrogen reduction of molybdenum oxide. The effect of $La_2O_3$ dispersion in a Mo matrix on the fracture toughness at room temperature is demonstrated through the formation behavior of $La_2O_3$ from the precursor and three-point bending test using a single-edge notched bend specimen. The relative density of the $Mo-0.3La_2O_3$ specimen sintered by pressureless sintering is approximately 99%, and $La_2O_3$ with a size of hundreds of nanometers is uniformly distributed in the Mo matrix. It is also confirmed that the fracture toughness is $19.46MPa{\cdot}m^{1/2}$, an improvement of approximately 40% over the fracture toughness of $13.50MPa{\cdot}m^{1/2}$ on a pure-Mo specimen without $La_2O_3$, and this difference in the fracture toughness occurs because of the changes in fracture mode of the Mo matrix caused by the dispersion of $La_2O_3$.