• Title/Summary/Keyword: dispersion degree

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Electromagnetic interference shielding materials using carbon nanotubes (탄소나노튜브를 이용한 전자파 차폐재)

  • 윤호규
    • Proceedings of the Korean Society For Composite Materials Conference
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    • 2003.10a
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    • pp.33-36
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    • 2003
  • AC and DC conductivity of the MWNT(Multi walled nanotubes)/polyurethane composites were investigated with respect to the various oxidative conditions, where these means acid concentration, treatment temperature, and treatment time. We suppose that the conditions of oxidation of the MWNTS have a certain influence on the degree of functionalization, damages, and dispersion of the MWNT themselves. Futhermore, the electrical properties of the resulting composites strongly depend on the oxidative conditions of MWNTS. The conductivity of the composites produced by using the optimal condition was measured as a function of frequency with volume content of MWNTS. These experimental results were analyzed using percolation theory Electromagnetic interference shielding effectiveness (SE) of the mixtures of polyurethane (PU), optimized MWNTs, and silver (Ag) is measured in the frequency range from 10 MHz to 6 ㎓ by using ASTM D4935-89. The measured SEs of the mixtures could be controlled from about 55 dB to 85 dB with the compositions of Ag/MWNT and compounding methods(C1, C2).

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Characterization of Polyolefin Bumper Recycled by Chemical Removal Method using Electronic Speckle Pattern Interferometry (화학적 박리방법과 ESPI에 의한 재생된 폴리올레핀 범퍼수지의 물성평가)

  • 김현경;강기수;김경석;홍진후
    • Proceedings of the Korean Society of Precision Engineering Conference
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    • 1997.10a
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    • pp.295-298
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    • 1997
  • Recycl ing of PP/EPR based bumper coated with polyester urethane paint has been per formed by chemical decoating method. Electronic Speckle Pattern Interferometry (ESP11 has been applied to characterize the deformation of polyolef in based bumper. In additon, physical properties and processability of recycled materials have been investigated by dynamic mechanical thermal analysis, impact test and melt flower index measurement. The results show that the deformation ratio of recycled material is higher than that of virgin one. The morphological change of EPR, degree of distribution and dispersion during the recycling process seem to be the most important factor for the deformation and the mechanical properties of recycled materials. The experimental results obtained show that ESPI is very powerful technique to study the thermal mechanical property of polyolefin bumper system.

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Domain Structure of Liguid Water According to the Theory of Intermolecular Forces

  • Mu Shik Jhon;Ung In Cho
    • Journal of the Korean Chemical Society
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    • v.16 no.3
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    • pp.135-141
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    • 1972
  • In the past years, a number of theories have been published to elucidate the structure of liquid water. common to most of these theories is that water mainly consist of several different kinds of clusters and also hydrogen bonds in water may be bent to some degree. Recentrly, in a series of paper, Jhon and Eyring successfully explained thermodynamic, dielectric, surface and transport properites of water, assuming that it contains small domains of about 46 molecules. According to the theory, the cluster size does not change with temperature, but the cluster concentration changes. In this paper, the potential function for the hydrogen bond, the dispersion energy and dipole-dipole interaction terms. The calculated results show that the domain of nearly 46 molecules is energetically most probable, and its size is independent of temperature. And also, we evaluated the effect of angel variation of the bent hydrogen bond. In addition, the relaxation energy different for ice and water is also explained by this method.

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Electrical Conductivity of Polymeric Composites with respect to Damage of Carbon Nanotube (탄소나노튜브의 손상에 따른 전기전도도 변화)

  • Kim Yun Jin;Jeong Yeon Chun;Yun Ho Gyu
    • Proceedings of the International Microelectronics And Packaging Society Conference
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    • 2003.11a
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    • pp.22-26
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    • 2003
  • Electrical conductivity of the oxidized MWNT(Multi walled nanotubes)/polymer composites were investigated with respect to various oxidative conditions of acid concentration, treatment temperature, and treatment time. To remove the impurities existing in MWNT-deposites, liquid-phase oxidation was performed using the $HNO_3/HSO_4$ mixtures. Secondary effects occurred by the oxidation of MWNTs such as the damages of MWNTs and the introduction of functionalities were analyzed through measuring FT-IR, TEM, and zeta potential, All the oxidized NWNTs were functionalized with carboxylic groups and the conditions of oxidation of the MWNTs could have a certain influence on the degree of functionalization, damages, and dispersion of the MWNT. The electrical properties of MWNT composites strongly depend on the oxidative conditions of MWNTs. The conductivity of the composites filled with the proper oxidized MWNT showed the highest percolation threshold.

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Evaluation of Physical Properties of Polyurethane Resin for Wound Covering according to PTMG, DMBA Application (PTMG, DMBA 적용에 따른 창상피복 폴리우레탄 수지의 물리적 특성 평가)

  • Lee, Joo-Youb
    • Journal of the Korean Applied Science and Technology
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    • v.37 no.5
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    • pp.1248-1256
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    • 2020
  • In this study, the polyurethane resin was synthesized by applying PTMG and DMBA of different composition ratios for the synthesis of water-dispersible polyurethane used in wound coating resin. The varying properties of the synthesized water-dispersible polyurethane were measured through tensile strength, elongation, and abrasion resistance analysis. As for the tensile strength measurement result according to the PTMG content, the sample with the highest reaction molar ratio was measured as 1.08 kgf/mm2 and the elongation was measured as 520%. As for the tensile strength result according to the DMBA content, the sample with the highest reaction molar ratio was measured as 0.51 kgf/mm2, and the elongation was measured as 435%. The degree of surface destruction by the abrasion resistance measurement was visually confirmed through SEM.

Pill Counting and Packaging Automation Using Non-contact Photo Sensor and Recognition of Characterized Feature (비접촉식 광학센서와 특징량 인식에 의한 알약 계수 및 포장 자동화)

  • 원민규;윤상천;이순걸
    • 제어로봇시스템학회:학술대회논문집
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    • 2000.10a
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    • pp.9-9
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    • 2000
  • Accurate counting and packaging pills is one of the most fundamental works of the pharmaceutical industry. But it is so labor consuming and very hard to be automated. As the pharmaceutical industry is growing bigger, the need of counting and packaging automation is increasing to obtain effective mass production. Precise and quick sensing is required in the counting and processing of quickly dropping pills to improve the productivity. There are many trials for this automation and automatic machine. But the performance of the existing counting machine varies with the size, shape and the dispersion degree of pills In this research, authors design the counting and packing machine of medicinal pills that is more accurate and highly trustworthy After getting analog signal from optical sensor, pill passage is discriminated from chosen characteristic feature using microprocessor.

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Physicochemical Properties of Octenylsuccinated Corn Starch (옥테닐호박산나트륨 전분의 이화학적 특성)

  • 정만곤;임번삼
    • Journal of Food Hygiene and Safety
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    • v.14 no.1
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    • pp.84-89
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    • 1999
  • Octenylscuccinated corn starches prepared by reaction of corn starch with 1-octenylsuccinic anhydride(OSAn) and their degree of substitution (DS), reaction efficiency(RE), residual octenylsuccinic acid (OSA), and physicochemical properties were compared with those of the native corn starch. DS increased with increase of OSAn and RE was much nearly the same regardless of increased of OSAn. The content of residual of residual OSA was significantly lower than that of regulation of food additives. And as washing frequency of dispersion of the reactant was increased, the content of residual OSA of octenylsuccinated starch was decreased. Raid Visco-Analyzer initial pasting temperature and setback of octenylsuccinated starches decreased whereas peak viscosity and breakdown increased. When DS of octenylsuccinated starches increased, temperature of initial gelatinization of octenylscuccinated starches drastically decreased. The octenylsuccinated starches also formed clearer pastes. The solubility was much nearly the same regardless of increase of DS at 7$0^{\circ}C$ but the swelling power increased 1.2~1.7 times higher than that of native corn starch at 7$0^{\circ}C$. The water binding capacity of octenylsuccinated starches also decreased.

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Effect of Matrix Viscosity on Clay Dispersion in Preparation of Polymer/Organoclay Nanocomposites

  • Ko, Moon-Bae;Jho, Jae-Young;Jo, Won-Ho;Lee, Moo-Sung
    • Fibers and Polymers
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    • v.3 no.3
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    • pp.103-108
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    • 2002
  • The viscosity effect of matrix polymer on melt exfoliation behavior of an organoclay in poly($\varepsilon$-caprolactone) (PCL) was investigated. The viscosity of matrix polymer was controlled by changing the molecular weight of poly($\varepsilon$-eaprolactone), the processing temperature, and the rotor speed of a mini-molder. Applied shear stress facilitates the diffusion of polymer chains into the gallery of silicate layers by breaking silicate agglomerates down into smaller primary particles. When the viscosity of PCL is lower, silicate agglomerates are not perfectly broken into smaller primary particles. At higher viscosity, all of silicate agglomerates are broken down into primary particles, and finally into smaller nano-scale building blocks. It was also found that the degree of exfoliation of silicate layers is dependent upon not only the viscosity of matrix but thermodynamic variables.

Thermal Aging Embrittlement of High Chromium Oxide Dispersion Strengthened Steels

  • Lee, J.S.;Kim, I.S.;Jang, C.H.;Kimura, A.;Kim, B.G.;Choo, K.N.;Choo, Y.S.;Kang, Y.H.
    • Proceedings of the Korean Nuclear Society Conference
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    • 2005.05a
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    • pp.471-472
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    • 2005
  • After thermal aging treatment at 693 K for 322 hours, any discernable precipitation could not be found in the $13{\sim}22$ Cr ODS steels, but showing an increase in SP-DBTT and reduction in upper shelf energy. The degree of aging embrittlement increases with Cr content such that the increases in SP-DBTT are 10, 50 and 73 K in 13, 16 and 19 Cr ODS steel, respectively. Amount of hardening also increased linearly as a function of Cr content. Based on the TEM observation, the origin of hardening must be related to the invisibly fine size of Cr-rich ${\acute{\alpha}}-phase$ (<1 nm).

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Analysis of Partial Discharge Pattern in XLPE/EDPM Interface Defect using the Cluster (군집화에 의한 XLPE/EPDM 계면결함 부분방전 패턴 분석)

  • Cho, Kyung-Soon;Lee, Kang-Won;Shin, Jong-Yeol;Hong, Jin-Woong
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2007.11a
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    • pp.203-204
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    • 2007
  • This paper investigated the influence on partial discharge distribution of various defects at the model power cable joints interface using K-means clustering. As the result of analyzing discharge number distribution of ${\Phi}-n$ cluster, clusters shifted to $0^{\circ}\;and\;180^{\circ}$ with increasing applying voltage. It was confirmed that discharge quantity and euclidean distance between centroids were increased with applying voltage from the analyzing centroid distribution of ${\Phi}-q$ cluster. The degree of dispersion was increased with calculating standard deviation of ${\Phi}-q$ cluster centroid. The tendency both number of discharge and mean value of ${\Phi}-q$ cluster centroid were some different with defect types.

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