• 제목/요약/키워드: dispersed phase

검색결과 506건 처리시간 0.025초

에멀젼 변환과 에멀젼 전이 (Emulsion Inversion and Emulsion Transition)

  • 임경희
    • 한국응용과학기술학회지
    • /
    • 제21권4호
    • /
    • pp.267-273
    • /
    • 2004
  • 에멀젼 구조가 변하는 에멀젼 변환은 이미 40년 전에 알려졌다. 에멀젼 변환에서는 O/W 에멀젼이 W/O 에멀젼으로, 또는 이와 반대로 구조가 변하므로 연석상과 분산상이 서로 바뀌게 된다. 그러나 3상 에멀젼에서는 이와 같은 에멀젼 변환뿐만 아니라 어떤 특정한 온도에서 연속상은 변하지 않고 분산상의 구조가 바뀌는 현상이 관찰되었다. 이 현상을 에멀젼이라고 불렀으며 에멀젼 전이가 일어나는 온도를 에멀젼 전이 온도라고 하였다. 에멀젼 전이는 이론적인 고찰의 결과이었으며 양친매성 분자/기름/물의 두 3성분계에 대해서 실험적으로 관찰하였다. 이는 이제까지 보고되지 않았던 새로운 현상이다. 본 논문에서는 에멀젼 전이와 에멀젼 전이를 비교 분석하였다.

Fabrication of Nano-sized Metal Dispersed Magnesia Based Composites and Related Mechanical and Magnetic Properties

  • Choa, Yong-Ho;Tadachika Nakayama;Tohru Sekino;Koichi Niihara
    • The Korean Journal of Ceramics
    • /
    • 제5권4호
    • /
    • pp.395-399
    • /
    • 1999
  • MgO/metal nanocomposite powder mixtures were prepared by solution chemical processes to obtain suitable structure for ceramic/metal nanocomposites. Nickel or cobalt nitrate, as a source of metal dispersion, was dissolved into alcohol and mixed with magnesia powder. After calcined in air, these powders were reduced by hydrogen. Densified nanocomposites were successively obtained by Pulse Electric Current Sintering (PECS) process. The dispersed metal partical size depended on temperature and time in calcination and reduction processes. The phase analyses in the synthesized powders as a functioni of temperature were tracked using a dynamic high temperature X-ray diffractioni (HTXRD) system. Phase and crystallite size analyses were done using X-ray diffractioni and TEM. The MgO/metal nanocomposites were successfully fabricated, and ferromagnetic responses with enhanced coercive force were also investigated for these composites.

  • PDF

폴리머 분산 액정의 전기 광학적 스위칭 특성에 대한 액정방울 크기의 효과 (Effect of droplet size on electro-optical switching properties of polymer dispersed liquid crystals)

  • 김인태;유연석
    • 한국광학회지
    • /
    • 제17권1호
    • /
    • pp.23-30
    • /
    • 2006
  • 폴리머 분산 액정의 전기광학 스위칭 특성에 대한 액정 방울 크기의 효과를 실험적으로 연구하였다. 액정 방울의 크기는 상 분리를 위해 조사하는 레이저 광원의 세기와 LC/oligomer의 혼합 비율에 따라 변화되었다. 전기 광학적 스위칭 전압은 LC/oligomer의 혼합비율과 액정의 방울 크기에 크게 의존하였다. 실험 결과를 보면 상 분리용 조사 레이저광의 세기가 클 때 액정방울의 크기는 작아졌고 포화투과도 전압은 상승했지만 rise time은 짧아 졌다.

휘스커상을 함유한 수산화아파타이트시멘트 경화체의 미구조-강도 특성 (Microstructure and Mechanical Strength of Hardened Paste of Hydroxyapatite Cement Containing Whisker Phase)

  • 손영도;송태웅
    • 한국세라믹학회지
    • /
    • 제36권12호
    • /
    • pp.1342-1349
    • /
    • 1999
  • In order to improve the density and the mechanical strength without change in chemical composition the hardened pastes of hydroxyapatite cement were reinforced with powders and/or whiskers of hydroxyapatite. The powders behaved as a seed of hydroxyapatite formation rather than a filler while the whiskers were mrerly dispersed in matrix and capillary pores of the hardened bodies leading to increase in mechanical strength. But the increase in strength But the increase in strength was nnt enough owing to the lack of homogeneous dispersion of the fibers. The highest diametral tensile strength of 18.5 MPa was measured at the hardened hydroxyapatite body in which well-dispersed whisker phase formed uniformly during hydro-thermal curing of power-added and dry-formed hydroxyapatite cement.

  • PDF

Removal of Pollutants and Recovery of Toxic Heavy Metals from Wastewater Using Microporous Hollow Fiber Modules

  • Yun, Chang-Han
    • 한국막학회:학술대회논문집
    • /
    • 한국막학회 1993년도 춘계 총회 및 학술발표회
    • /
    • pp.25-27
    • /
    • 1993
  • Multiphase equilibrium-based processes for separation and purification generally utilize dispersed systems in which one phase is dispersed in the other as bubbles or drops or thin films. Using microporous membranes, novel techniques have been developed such that multiphase processes can now be carried out in a nondispersive fashion for gas-liquid (Sirkar, 1992) and liquid-liquid (Prasad and Sirkar, 1992) contacting processes. Among such processes, only nondispersive solvent extraction of pollutants using microporous membranes will be of concern here. These processes employ immobilized immiscible phase interfaces at the pore mouths in a microporous membrane. Through such interfaces, solutes are extracted into the solvent as two immiscible phases flow on two sides of a microporous membrane. Many advantages of such a technique over conventional dispersion-based extractors have been summarized (Prasad and Sirkar, 1992).

  • PDF

입자와 주위유체와의 상호작용에 관한 연구 (A Study on the Interaction between Particles and Surrounding Fluid)

  • 최해만
    • 설비공학논문집
    • /
    • 제14권2호
    • /
    • pp.108-115
    • /
    • 2002
  • The fundamental mechanism of a dispersed two-phase flow was investigated. Experiments were carried out to understand how the particles behaves under the influence of the particle size, shape, metamorphoses (bubble) and buoyancy of a single particle which is ascending from the standstill water. Two CCD cameras were employed for image processing of the behavior of the particles and the surrounding flow, which was interpreted with the technique of correlation PIV (Particle Image Velocimetry) and PTV (Particle Tracking Veloci- metry), respectively The experimental results showed that the large density difference bet- ween a particle and water caused high relative velocity and induced zigzag motion of the particle. Furthermore, the turbulence intensity of a bubble was about twice the case of the spherical solid particle of similar diameter.

Electrorheological Effect of the Suspension Composed of Bismark Brown Chitosan Succinate as the Dispersed Phase

  • Choi, Ung-Su
    • KSTLE International Journal
    • /
    • 제8권2호
    • /
    • pp.21-25
    • /
    • 2007
  • The electrorheological effect of the suspension composed of Bismark Brown chitosan succinate as the dispersed phase in silicone oil was investigated. Bismark Brown chitosan succinate suspension showed a typical ER response (Bingham flow behavior) upon application of an electric field. The shear stress for the suspension exhibited the dependence with a factor equals to 1.84 power on the electric field. The experimental results for the suspension correlated with the polarization model and Bismark Brown chitosan succinate suspension behaved as an anhydrous ER fluid. On the basis of the results, Bismark Brown chitosan succinate suspension showed the ER flow behavior upon application of the electric field due to the polarizability of the branched amide and amine polar groups of the Bismark brown chitosan succinate particles.

인산처리 셀룰로오스를 첨가한 비수계 ER 유체의 전기유변학적 특성 (Electrorheological Properties of Anhydrous ER Suspensions Based on Phosphated Cellulose)

  • 안병길;최웅수;권오관;문탁진
    • Tribology and Lubricants
    • /
    • 제14권2호
    • /
    • pp.1-9
    • /
    • 1998
  • The electrorheological (ER) behavior of suspensions in silicone oil of phosphated cellulose particles (average particle size 17.77 ${\mu}{\textrm}{m}$) was investigated at room temperature with electric fields up to 2.5 KV/mm. In this paper, for development of anhydrous ER suspensions using at wide temperature range, we would like to know fundamental understandings on the ER activity. As a first step, the anhydrous ER suspensions dispersed the phosphated cellulose particles were measured, and not only the electrical characteristics such as dielectric constant, current density and electrical conductivity but also the rheological properties on strength of electric field and quantity of dispersed phase were studied. From the experimental results, the anhydrous ER suspensions dispersed phosphated cellulose particles showed a stable current density and very high performance of ER effect $(\tau/\tau_0=1030)$ on the 2.5 KV/mm and the dynamic yield stress $(\tau_y)$ was in exponential proportion to the strength of electric fields.

분무 증발을 이용한 칩 냉각 향상에 대한 수치적 연구 (NUMERICAL STUDY OF CHIP COOLING ENHANCEMENT WITH EVAPORATING MIST FLOW)

  • 노상은;김동철;손기헌
    • 한국전산유체공학회지
    • /
    • 제18권2호
    • /
    • pp.9-16
    • /
    • 2013
  • The heat transfer enhancement of heat sink with mist flow is studied numerically by solving the conservation equations for mass, momentum and energy in the continuous and dispersed phases. A Lagrangian method is used for tracing dispersed water droplets in the heat sink and an Eulerian species transport model for air and steam mixture. The continuous and dispersed phases are interacted with the drag and evaporation source terms. The computed results show that addition of evaporating mist droplets enhances the cooling performance of heat sink significantly.

AFM을 이용한 폴리술폰막의 표면구조와 상분리현상에 관한 연구 (Surface structure and phase separation mechanism of polysulfone membranes by AFM)

  • 김제영;이환광;김성철
    • 한국막학회:학술대회논문집
    • /
    • 한국막학회 1998년도 추계 총회 및 학술발표회
    • /
    • pp.103-105
    • /
    • 1998
  • Asymmetric polymeric membranes prepared by the phase transition technique usually have either a top layer consisting of closely packed nodules or pores dispersed throughout the membrane surfaces. In this study, we present AFM image of a polysulfone membrane which show a clear evidence for the nodular structure and porous structure resulted from different phase separation mechanisms; spinodal decomposition and nucleation and growth. The surface morphology obtained by SEM and AFM was also compared.

  • PDF