• Korean Chemical Engineering Research
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• v.40 no.6
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• pp.715-718
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• 2002

The supercritical dyeing process has been gaining the increasing importance because of environment reason. For further development of this process, it is needed to measure the solubility in supercritical fluids in the extensive ranges of temperature and pressure. In this study, using the semi-flow type apparatus consisted of supercritical fluid equilibrium cell, the solubility of disperse dye(C.I. disperse red 60) in supercritical HFC-134a has been measured at the temperatures of 383.2 K and 413.2 K, and in the pressure range of 50 bar to 160 bar. The solubility data are, with good agreement, correlated by an expanded liquid model which considers the supercritical fluid as compressed liquid.

• Clean Technology
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• v.27 no.2
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• pp.182-189
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• 2021

The adsorption of disperse yellow 3 (DY 3) on granular activated carbon (GAC) was investigated for isothermal adsorption and kinetic and thermodynamic parameters by experimenting with initial concentration, contact time, temperature, and pH of the dye as adsorption parameters. In the pH change experiment, the adsorption percent of DY 3 on activated carbon was highest in the acidic region, pH 3 due to electrostatic attraction between the surface of the activated carbon with positive charge and the anion (OH^-) of DY 3. The adsorption equilibrium data of DY 3 fit the Langmuir isothermal adsorption equation best, and it was found that activated carbon can effectively remove DY 3 from the calculated separation factor (R_L). The heat of adsorption-related constant (B) from the Temkin equation did not exceed 20 J mol^-1, indicating that it is a physical adsorption process. The pseudo second order kinetic model fits well within 10.72% of the error percent in the kinetic experiments. The plots for Weber and Morris intraparticle diffusion model were divided into two straight lines. The intraparticle diffusion rate was slow because the slope of the stage 2 (intraparticle diffusion) was smaller than that of stage 1 (boundary layer diffusion). Therefore, it was confirmed that the intraparticle diffusion was rate controlling step. The free energy change of the DY 3 adsorption by activated carbon showed negative values at 298 ~ 318 K. As the temperature increased, the spontaneity increased. The enthalpy change of the adsorption reaction of DY 3 by activated carbon was 0.65 kJ mol^-1, which was an endothermic reaction, and the entropy change was 2.14 J mol^-1 K^-1.

• Nuclear Engineering and Technology
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• v.55 no.3
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• pp.1152-1166
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• 2023

The bubbly flow of air or steam in subcooled water are investigated here in several test cases, characterized by different pipe sizes, bubble dimensions and flow rates, by means of CFD using a Eulerian-Eulerian approach. The performance of models that differ for the turbulence closure in the continuous phase, as well as for the description of the lift force on the dispersed phase, are compared in detail. When air is considered, the space of the experimental parameters leading to a reasonable performance for the selected models are identified and discussed, while the issues left in the modelling of the concurrent condensation are highlighted for the cases where steam is used.

• Journal of the Korea Academia-Industrial cooperation Society
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• v.20 no.9
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• pp.532-540
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• 2019

PET microfibers with various diameters (0.5, 0.2, 0.06, and 0.01 dpf) were dyed with a dispersed dye (C.I. Disperse Blue 56) at various temperatures. The dyeing process was conducted under infinite dyebath conditions at constant temperatures. The effects of the dyeing temperature and diameter on the partition coefficient, affinity, and diffusion coefficient of disperse dyes were studied. The curve of isotherms was fitted well to Nernst-type model in a large range of initial dye concentrations. At the same temperature, the partition coefficient and affinity decreased with increasing sample diameter due to the increase in surface area. At all deniers, the partition coefficient and affinity decreased with increasing temperature because the dyeing process is an exothermic reaction. In addition, the decrease in radius of the sample gives rise to a decrease in the heat of dyeing. The fine diameter of the sample resulted in an increased surface area but decreased space between the microfibers. Consequently, decreasing the diameter of the microfibers leads to a decrease in the diffusion coefficient. At the same diameter, the diffusion coefficient increased with increasing temperature because of rapid dye movement and the large free volume of the sample inside. In addition, thermal dependence of the diffusion coefficient increased when the diameter of the sample increased.

• Korean Journal of Environment and Ecology
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• v.34 no.5
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• pp.466-482
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• 2020

This study used 3D computational fluid dynamics (CFD) in the ENVI-met program to investigate how particulate matters (PM) generated on roads disperse through adjacent urban neighborhoods according to the urban development pattern. An urban area centered on a six-lane road in the vicinity of Miryang City Hall in Gyeongnam Province was selected to simulate the effect of the green space and building height on the PM concentration. The ENVI-met model considered the presence of green space and different building heights (high/low) on both sides of the road to examine the dispersion of PM. The result showed that the area of high-rise buildings and green space had the lowest PM concentration dispersed to the adjacent area, followed by the area of high-rise buildings and no green space. In contrast, the PM concentration remained relatively high for low-rise buildings, regardless of the green space. The reason for the low PM concentration in the area with high-rise buildings was a strong building wind, which caused PM to disperse to the outside, lowering the PM concentration quickly. These results indicate that the PM can disperse faster, and the PM concentration remains low in the urban neighborhood. On the other hand, green space had no significant effect on reducing PM in the urban neighborhood. In particular, when there are low-rise buildings on both sides of the road, the green space has no effect on the PM concentration in the urban neighborhood. Since this study considered only the case of PM emitted from the road, future studies should investigate other factors to figure out the dispersion model of PM and conduct on-site experiments.

• Toxicological Research
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• v.28 no.4
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• pp.209-216
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• 2012

The biological activity of particles is largely dependent on their size in biological systems. Dispersion in the aqueous phase has been both a critical impediment to and a prerequisite for particle studies. Carbon black has been used as a surrogate to investigate the biological effects of carbonaceous particles. Here, biocompatible methods were established to disperse carbon black into ultrafine and fine particles which are generally distinguished by the small size of 100 nm. Carbon black with a distinct particle size, N330 and N990 were suspended in blood plasma, cell culture media, Krebs-Ringer's solution (KR), or physiological salt solution (PSS). Large clumps were observed in all dispersion preparations; however, sonication improved dispersion - averaged particle sizes for N330 and N990 were $85.0{\pm}42.9$ and $112.4{\pm}67.9$ nm, respectively, in plasma; the corresponding sizes in culture media were $84.8{\pm}38.4$ and $164.1{\pm}77.8$ nm. However, sonication was not enough to disperse N330 less than 100 nm in either KR or PSS. Application of Tween 80 along with sonication reduced the size of N330 to less than 100 nm, and dispersed N990 larger than 100 nm ($73.6{\pm}28.8$ and $80.1{\pm}30.0$ nm for N330 and $349.5{\pm}161.8$ and $399.8{\pm}181.1$ nm for N990 in KR and PSS, respectively). In contrast, 1,2-dipalmitoyl-sn-glycero-3-phosphocholine (DPPC) exhibited little effect. Electron microscopy confirmed the typical aciniform structure of the carbon arrays; however, zeta potential measurement failed to explain the dispersibility of carbon black. The methods established in this study could disperse carbon black into ultrafine and fine particles, and may serve as a useful model for the study of particle toxicity, particularly size-related effects.

• Textile Coloration and Finishing
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• v.11 no.6
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• pp.1-6
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• 1999

The porosities of PET fibers were investigated using a nitrogen porosimeter according to oxygen plasma treatment and dyeing with a disperse dye, and they were discussed in terms of the change of internal micro-structure of the PET fiber. The total pore volume, surface area and average pore size of the plasma treated PET fibers increased expectably compared with the untreated sample. The PET fibers treated with oxygen plasma and then dyed with a disperse dye were increased significantly in the surface area and the total pore volume comparing with those of plasma treated only, but decreased in the average pore size. The increase of the surface area, after dyeing, of the plasma treated PET fibers was due to addition of the surface area of the dye itself to that of the PET fiber. The increase of the total pore volume of the plasma treated PET fibers by dyeing, which is the opposite result to the general idea that the pore volume of fibers would be reduced by occupation of dye molecules in the pores, could be explained by the free-volume model. This is that the amorphous region in the fiber expanded by occupation of dye molecules, and the marginal space surrounding dyes was generated as many smaller pores, and the decrease of the average pore size of the dyed sample also could be explained The decrease of the average pore size was caused by the splitting of a larger pore into smaller pores.

• Fibers and Polymers
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• v.7 no.2
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• pp.191-194
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• 2006

This paper adopts nonlinear vibration method to analyze the fluctuation process of fiber movement. Based on Hamilton Principle, this paper establishes differential equation of fiber axial direction movement. Using variable-separating method, this paper separates time variable from space variable. By using the disperse movement equation of Galerkin method, this paper also discusses stable region of transition curve and points out those influencing factor and variation trend of fiber vibration.

• Journal of Ocean Engineering and Technology
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• v.27 no.1
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• pp.16-23
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• 2013

By carrying out numerical analyses and model experiments, this paper presents the attenuation characterization of an L(0,2) guided ultrasonic wave propagating in a buried steel pipe. From this investigation, we first find that the L(0,2) mode has a better attenuation property. Second, it is shown from the numerical analyses that the attenuation increases with increases in the soil embedment length (0, 500, 1000, and 1500 mm) and degrees of saturation (0, 50, 99, and 100%). Third, it is also shown from the model experiment that the attenuation increases as the embedment lengths and soil moisture quantities (0, 10, 20, and 30 kg) increase. Finally, we find that an exponential extrapolation gives a better attenuation prediction because the extrapolation gives similar attenuation patterns between the numerical and experimental results.

• Journal of Technologic Dentistry
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• v.38 no.3
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• pp.151-156
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• 2016

Purpose: The dental implant should be enough to endure chewing load and it's required to have efficient design and use of implant to disperse the stress into bones properly. This study was to evaluate the stress distribution on a supporting bone by lengths and diameters of the implant fixture. Methods: The modeling and analysis of stress distribution was used for the simple molar porcelain crown model by Solidworks as FEM program. It was designed on applying with tightening torque of 20 Ncm of a abutment screw between a cement retained crown abutment and a fixture. The fixtures of experimental model used 10, 13mm by length and 4, 5mm by diameter. A external vertical loading on the two buccal cusps of crown and performed finite element analysis by 100 N. Results: The maximum von Mises stress(VMS) of all supporting bone models by fixture length and diameter were concentrated on the upper side of supporting compact bone. The maximum stress of each model under vertical load were 164.9 MPa of M410 model, and 141.2 MPa of M413 model, 54.3 MPa of M510 model, 53.6 MPa of M513 model. Conclusion: The stress reduction was increase of fixture's diameter than it's length. So it's effective to use the wider fixture as possible to the conditions of supporting bone.