• Title/Summary/Keyword: diphosphoric acid

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Synthesis of Phosphoric Polymer Coating Solution with Antimicrobial Activity and Flame Retardant Efficiency (항균성과 난연성을 함유하고 있는 인계고분자 코팅용액의 합성)

  • Kim, Sang-Kyum;Lee, In-Soo;Seo, Sang-Hee;Choi, Seong-Ho
    • Polymer(Korea)
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    • v.35 no.5
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    • pp.431-437
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    • 2011
  • A polymeric coating solution based on poly(acryloyl diphosphoric acid)(poly(ADP)) was prepared via a radical polymerization of acryloyl diphosphoric acid using ammonium persulfate (APS) as an initiator in water at 70 $^{\circ}C$. The prepared polymeric coating solution exhibited significant antibacterial activity against salmonella typhimurium, pseudomonas aeruginosa, escherichia coli, and staphylococcus aureus. It also exhibited good antifungal activity against Asperigillus niger and good antiviral activity against the influenza (H1N1) virus. Additionally, it exhibited good flame retardant efficiency after applying it as a coating to a cotton fabric.

Flame Retardancy of Novel Phosphorus Flame Retardant for Polyurethane Foam (새로운 인계 난연제가 연질폴리우레탄 폼의 난연성에 미치는 영향)

  • Kim, Chang Bum;Seo, Won Jin;Kwon, Oh Deok;Kim, Sang-Bum
    • Applied Chemistry for Engineering
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    • v.22 no.5
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    • pp.540-544
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    • 2011
  • Novel phosphrous flame retardant tetramethylene bis(orthophosphorylurea) (TBPU) was synthesized by the reaction of diphosphoric acid with 1,4-butanediol and urea, and charaterized by Fourier transform infrared spectroscopy (FT-IR). As the amount of TBPU added in polyurethane foam (PUF) was increased, the flame retardancy of PUF was increased and the mechanical properties were not decreased. Also, in the flame resistance test after the reduced pressure storage, the flame retardancy of TBPU added PUF was retained. We could find out that the thermal resistance of TBPU added PUF increased compared to that of pure PUF.