• Title/Summary/Keyword: dip coating method

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Development of Alkali Metal Thermal-to-Electric Converter Unit Cells Using Mo/TiN Electrode

  • Seog, Seung-won;Choi, Hyun-Jong;Kim, Sun-Dong;Lee, Wook-Hyun;Woo, Sang-Kuk;Han, Moon-Hee
    • Journal of the Korean Ceramic Society
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    • v.54 no.3
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    • pp.200-204
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    • 2017
  • Molybdenum (Mo), an electrode material of alkali metal thermal-to-electric converters (AMTEC), facilitates grain growth behavior and forms Mo-Na-O compounds at high operating temperatures, resulting in reduced performance and shortened lifetime of the cell. Mo/TiN composite materials have been developed to provide a solution for such issues. Mo is a metal that possesses excellent electrical properties, and TiN is a ceramic compound with high-temperature durability and catalytic activity. In this study, a dip-coating process with an organic solvent-based slurry was used as an optimal coating method to achieve homogeneity and stability of the electrodes. Cell performance was evaluated under various conditions such as the number of coatings, ranging from 1 to 3 times, and heat treatment temperatures of $800-1100^{\circ}C$. The results confirmed that the cell yielded a maximum power of 9.99 W for the sample coated 3 times and heat-treated at $900^{\circ}C$.

Continuous Nanocomposite Coatings on a Phosphor for the Enhancement of the Long-term Stability

  • Kim, Jong-Woung;Song, Jung-Oh;Kim, Chang-Keun
    • Proceedings of the Polymer Society of Korea Conference
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    • 2006.10a
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    • pp.233-233
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    • 2006
  • [ $Y_{2}O_{2}S:Eu$ ], a red phosphor, coated with silica nanoparticles or nanocomposites composed of silica nanoparticles and polymeric materials such as PMMA and PVP was prepared via sol-gel process. Samples were prepared from four different methods coded P1, P2, P3, and P4. P1 includes a conventional sol-gel process and a dip-coating method while P2 has the same procedure with P1 except that nanocomposites containing both silica nanoparticles and polymer prepared by sol-gel process were used as coating materials. In P3 method, phosphors were dispersed in a solution containing silica precursor, i.e., TEOS and then polymerization was performed to coat onto the phosphors surface while P4 followed the same procedure with P3 except that a solution containing both TEOS and organic monomer were used in preparing coating materials. Among various coating methods examined in this study, uniform coating of phosphor could be achieved by using method P4, i.e., phosphor surface coating in a solution containing hydrophobic monomer and TEOS. Furthermore, $Y_{2}O_{2}S:Eu$ red phosphor coated with nanocomposite composed of PMMA matrix and silica nanoparticles exhibited enhanced PL intensity and long-term stability.

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NO and $SO_2$ Removal by Dielectric Barrier Discharge-Photocatalysts Hybrid Process (유전체 장벽 방전-광촉매 복합공정에 의한 NO와 $SO_2$ 제거)

  • Kim, Dong-Joo;Nasonova, Anna;Kim, Kyo-Seon
    • Clean Technology
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    • v.13 no.2
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    • pp.115-121
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    • 2007
  • In this study, we analyzed experimently the NO and $SO_2$ removal by the dielectric barrier discharge-photocatalysts hybrid process. The glass spheres were used as a dielectric material for dielectric barrier discharge and the $TiO_2$ photocatalysts were coated onto those spheres by the dip-coating method. The $TiO_2$ particles were coated in the sponge-shape, which has the larger surface area. As the voltage applied to the plasma reactor, the pulse frequency of applied voltage, or the residence time increases, the NO and $SO_2$ removal efficiencies increase. The increase in the supplied concentrations of NO and $SO_2$ leads to the higher energy for NO and $SO_2$ removal and the NO and $SO_2$ removal efficiencies decrease. These experimental results can be used as a basis to design the dielectric barrier discharge-photocatalysts hybrid process to remove NO and $SO_2$.

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Fabrication and Properties of Au fine Particles Doped ZrO2 Thin Films by the Sol-gel Method (졸-겔법에 의한 Au 미립자 분산 ZrO2 박막의 제조와 특성)

  • 이승민;문종수
    • Journal of the Korean Ceramic Society
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    • v.40 no.5
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    • pp.475-480
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    • 2003
  • Nanocomposite of Au doped ZrO$_2$ films was prepared, which could be used as non-linear optic materials, selective absorption and transmission films. After heat treatment of prepared thin film by dip-coating method, the characteristics were investigated by X-ray diffraction, UV-VIS Spectrometer, Atomic Force Microscopy (AFM) and Scanning Electron Microscope (SEM). Film thickness was about 150 nm, the Au particle size was 15~35 nm. The thin film had a smooth surface roughness about 1.06 nm. Nonlinearity optics was found that films showed absorption peak at 600~650 nm visible region by plasma resonance of Au metal particles.

Resistive Polymeric Humidity Sensor Fabricated with Ink-Jet Printing Technique (잉크젯 프린팅을 이용한 저항형 고분자 습도센서)

  • 공명선;금내리
    • Journal of the Microelectronics and Packaging Society
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    • v.11 no.1
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    • pp.49-57
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    • 2004
  • The modified polyionene polyelectrolyte inks were newly prepared and applied to the humidity-sensitive membrane of humidity sensor. The films were fabricated on the alumina substrate with comb-type gold electrode using a ink-jet printing technique. The copolymers of methyl methacrylate, acrylic acid, 2-hydroxyethyl methacrylate and [(2-methacryloyloxy)ethyl]trimethylammonium chloride were also prepared for the humidity-sensing material. which was fabricated by dip-coating method. Electrical measurements under various relative humidity were performed. The humidity-sensitive characteristics of sensors obtained by ink-jet printing technique were compared with that of dip-coating method. Humidity sensors showed a decrease in resistance as an increase of relative humidity and their resistance characteristics are in a close agreement each other.

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Fabrication and Characterization of Functional Gradient Ceramic Bone Substitutes

  • Kim, Min-Seong;Min, Yeong-Gi;Yang, Hun-Mo;Song, Ho-Yeon;Lee, Byeong-Taek
    • Proceedings of the Materials Research Society of Korea Conference
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    • 2010.05a
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    • pp.42.2-42.2
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    • 2010
  • Recently, highly porous bone substitutes, which have interconnected open pore structure, have been focused on improving their mechanical properties and modifying their functions. Especially, it is highly required to develop functional gradient structured bone substitute which is available for controlling their material properties such as bioresorption rate and elastic modulus. Porous $ZrO_2$ scaffold was fabricated by the sponge replica method using PU sponge. After 3 times of dip coating and the subsequent oven drying, burning out and microwave sintering were carried out. Various $ZrO_2$-BCP powder mixtures were prepared depending on the ratio and coated on the $ZrO_2$ scaffold by dip coating process. X-ray diffraction analysis was performed to characterize the phase identification of the scaffolds. Microstructures of the bone substitutes were observed using scanning electron microscopy.

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Temperature-dependent photoluminescence study on aluminum-doped nanocrystalline ZnO thin films by sol-gel dip-coating method

  • Nam, Giwoong;Park, Hyunggil;Yoon, Hyunsik;Kim, Soaram;Leem, Jae-Young
    • Proceedings of the Korean Institute of Surface Engineering Conference
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    • 2012.11a
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    • pp.131-133
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    • 2012
  • The photoluminescence (PT) properties of Al-doped ZnO thin films grown by the sol-gel dip-coating method have been investigated. At 12 K, nine distinct PL peaks were observed at 2.037, 2.592, 2.832, 3.027, 3.177, 3.216, 3.260, 3.303, and 3.354 eV. The deep-level emissions (2.037, 2.592, 2.832, and 3.027 eV) were attributed to native defects. The near-band-edge (NBE) emission peaks at 3.354, 3.303, 3.260, 3.216, and 3.177 eV were attributed to the emission of the neutral-donor-bound excitons (D0X), two-electron satellite (TES), free-to-neutral-acceptors (e,A0), donor-acceptor pairs (DAP), and second-order longitudinal optical (2LO) phonon replicas of the TES (TES-2LO), respectively. According to Haynes' empirical rule, we calculated the energy of a free exciton (FX) to be 3.374 eV. The thermal activation energy for D0X in the nanocrystalline ZnO thin film was found to be ~25 meV, corresponding to the thermal dissociation energy required for D0X transitions.

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Separation of Aqueous Ethanol Solution Using a PAA-PAN Composite Membrane Through Pervaporation (PAA-PAN 복합막을 이용한 에탄올 수용액의 투과증발 분리)

  • 원장묵;하백현;최호상
    • Membrane Journal
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    • v.6 no.3
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    • pp.182-187
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    • 1996
  • Hydrophilic poly(acrylonitrile) [PAN] membrane with good molecular weight cut-off characteristics were prepared by using the phase inversion method. Permeability and molecular weight cut-off of the membranes were measured through the ultrafiltration test. On the surface of the PAN support membranes, poly(acrylic acid) [PAA] was deposited by dip-coating. The water permeability of the PAN support membrane had $0.17~31\textrm{mm}^3/m^{2} \cdot s \cdot Pa$, the molecular weight cut-off 42, 000~150, 000. The transport characteristics of the prepared composite membranes were significantly affected by the variation of the support membrane mophology. The permeability of the composite membrane was decreased with increasing molecular weight cut-off of the support membrane, and the separation factor was slightly changed depending on the feed concentration.

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