• 한국지하수토양환경학회:학술대회논문집
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• 한국지하수토양환경학회 1997년도 총회 및 춘계 학술발표회 논문집
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• pp.79-82
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• 1997

토양내에서 오염유기물질이 불포화토양내에 유입될 때의 dispersion coefficient를 adsorption과 desorption과정에 대해 알아보았다. apparent dispersion coefficient를 측정하기 위해 일상적인 상대습도(46%)조건에서 parametric analysis를 행하였다. 실험에 사용된 토양은 fine sand와 silt-clay혼합시료였고, 흐름방향은 상향과 하향으로 하였다. 그리고, Freon gas를adsorbing solute로 사용하였다. 오염물질로는 DCM, TCE, DCB를 사용하였다. 분석을 위해서 linear와 probability scale의 breakthrough curve를 사용하였다. 공기에서의 diffusion coefficient의 예측을 위하여 Graham's law를 계산에 사용하였고, DCM diffusion coefficient는 0.098$\textrm{cm}^2$/s로 계산되었다. 연구결과, adsorption과 desorption의 속도는 차이가 있는 것으로 나타났으며, diffusion이 flow regime을 좌우하는 것으로 나타났다. 그리고, desorption에서의 D$^{a}$ D$^{o}$ 는 1보다 클수도 있다. 또한, dispersion은 silt-clay혼합시료에서의 속도와 함께 증가한다. dispersion은 Freon의 sorption방향에 크게 의존한다.

• 한국건축시공학회:학술대회논문집
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• 한국건축시공학회 2010년도 춘계 학술논문 발표대회 1부
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• pp.87-88
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• 2010

A permeability of concrete is a very important factors evaluating durability. So, we are carrying out a lot of relational data bases and experiment regarding a permeability. In order to evaluate a permeability of concrete, we are proceeding study on the water penetration and diffusion in concrete by water pressure. Because a way to evaluate a permeability of concrete has a limit. We will present a good method of evaluating durability of concrete using the water penetration depth of concrete by water pressure. To carry this out, we executed experiment with penetration depth of concrete by water pressure and verified it though FEM analysis.

• 한국콘크리트학회:학술대회논문집
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• 한국콘크리트학회 2010년도 춘계 학술대회 제22권1호
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• pp.217-218
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• 2010

본 연구에서는 탄산화에 의해 열화를 받은 콘크리트 부재의 보수 후 재열화과정을 Fick's 확산(diffusion) 제1법칙을 이용하여 모델링하였다. 여러 콘크리트 보수재 중 단면복구재에 의해 보수된 콘크리트 부재에 대한 이산화탄소에 재탄산화를 고려한 합리적인 예측식을 제시하였다. 연구결과는 보수재의 이산화탄소 확산 프로파일과 기존 구체콘크리트의 탄산화된 부분의 이산화탄소 확산 프로파일을 효과적으로 모델링할 수 있음을 보여줬다.

• 열처리공학회지
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• 제14권5호
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• pp.282-285
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• 2001

Based on the mass balance of anion and cation fluxes, the parabolic rate constant ($K_p$) of oxide grown during the high-temperature oxidation of metal is theoretically calculated. It is assumed that the diffusion of oxygen anion and metal cation through oxide scale obeys the Fick's 1st law, the growth of oxide is controlled by the diffusion of ions, electrical potential gradient as driving force for diffusion of ions is ignored, and oxidation occurs within an existing oxide layer. Then, the parabolic rate constant can be expressed by $K_p=[2{\rho}_{MmOn}{M^2}_{MmOn}(mD_oC_o{^e}+nD_MC_M{^e})/nm]$.

• 한국막학회:학술대회논문집
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• 한국막학회 1995년도 추계 총회 및 학술발표회
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• pp.43-44
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• 1995

The diffusion behavior of liquid into polymer has been described by Fick's law, but the departure from Fickian diffusion is frequently found. In this study, 'noble' expressions for the rates of relaxation and sorption are introduced to eliminate these limitations. The ralaxation-sorption coupled mechanism model are based on the possibility of contacting liquid molecule and the active site which has the numerical concept of free volume. The concept has an analogy of reaction rate expressed by the possibility of collision with molecules and used in adsorption and reactive extraction etc. The new model simulated by Rungc-Kutta method for initial-value problem and Fickian diffusion is caompared with experimental data. The results show that the ralaxation-sorption coupled mechanism is able to account well for Fickian and non-Fickian sorption behavior including sigmoid and two-stage. In addition, this model has a chance of expansion to multi-component sorption with ease.

• Bulletin of the Korean Chemical Society
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• 제12권5호
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• pp.468-473
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• 1991

Viscoelastic properties of PET filament fibers on stress relaxation were investigated in the solvents of $H_2$O, 0.05% NaOH and 50% DMF using an Instron (UTM4-100 Tensilon) with solvent chamber. The theoretical stress relaxation equation derived by applying the Ree-Eyring's hyperbolic sine law to dashpot of three element non-Newtonian model was applied to the experimental stress relaxation curves, and the model parameters $G_1,G_2$, ${\alpha}$ and ${\beta}$ were obtained. By analyzing temperature dependency of the relaxation time, the values of activation entropy, activation enthalpy and activation free energy for flow in PET filament fiber were evaluated, the activation free energy being about 25.7 kcal/mol. The self diffusion coefficient and hole distance were obtained from parameters ${\alpha}$, ${\beta}$ and crystallite size in order to study the self diffusion and the orientation of crystallites in amorphous region and the effect of solvent.

• 무역상무연구
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• 제31권
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• pp.59-78
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• 2006

The purpose of this research is to discuss the excepted perils of carriers, to expose moot points arising from the applications of the excepted perils of the carriers, and then to suggests improvements them. The methodology of this research depended largely upon a combination of the related precedents, international treaties related to the excepted perils of carriers. The excepted perils of carriers in marine carriage begin with extremely limited perils based on the receptum liabilities and the absolute liability principle in English common law. Proceed via the intemperate expansion of the excepted perils by the widespread diffusion of the principle of free contract. but via the American Harter Act, The Hague Rules, The Hague Visby Rules, and The Hamburg Rules Came contracted. This study conducted an analysis of the excepted perils for the carriers and suggests improvements in them but it remains regrettable that we are not in a position to sustain them since we are lacking is precedents connected with The Hamburg rules.

• 한국안전학회지
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• 제20권2호
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• pp.113-118
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• 2005

Recently, the corrosion of reinforced concrete structures has received great attention related with the deterioration of sea-side structures, such as new airport, bridges, and nuclear power plants. In this regards, many studies have been done on the chloride attack in concrete structures. The purpose of the present study is to explore the influences of chloride attack parameters to service life of reinforced concrete structures and to propose the rational program for the guarantee of service life. for this purpose, several codes for durability design have been examined and the diffusion analysis based on Fick's second law has been performed with various parameter value. The present study indicates that durability design code of Japan Society of Civil Engineers is more rational than other codes but the application of durability design code of JSCE to domestic durability design needs more studies to the various parameter values related with chloride penetration.

• Journal of the Korean Wood Science and Technology
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• 제22권2호
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• pp.61-70
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• 1994

This study was executed to find the applicability of press drying of tree disk by investigating the shrinkage and drying defect and to form appropriate model by comparing the actual moisture content(MC) and internal temperature in respect of drying time with calculated values based computer simulation to which was applied finite difference method. In press drying disk, heating period, constant drying rate period maintained plateau temperature at 100$^{\circ}C$ and falling drying rate period were significantly distinguished. Actual MC and internal temperature were analogous to those calculated at comparing points. Heat transfer model formed by Fourier's law using specific heat of moist wood and conduction coefficient considering fractional volume of each element of wood cell wall, bound water, free water and air showed applicability as basic data to developing heat expansion, shrinkage and drying stress during press drying. Also mass transfer model formed by Fick's diffusion law using water vapor diffusion coefficient showed applicability. Longitudinal shrinkage was developed by pressure of hot press and tangential shrinkage was restrained by hygrothermal recovery. The heart check, surface check and ring failure were occurred differently in species, but V-shaped crack didn't develop.

• Advances in concrete construction
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• 제7권1호
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• pp.11-22
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• 2019

A comprehensive assessing approach for durability of reinforced concrete structures dealing with the corrosion process of rebar subjected to the attack of aggressive agent from environment was proposed in this paper. Corrosion of rebar was suggested in the form of combination of global corrosion and pitting. Firstly, for the purposed of considering the influence of rebar's radius, a type of Plane Corrosion Model (PCM) based on uniform corrosion of rebar was introduced. By means of FE simulation approach, global corrosion process of rebar regarding PCM and LCM (Linear Corrosion Model) was regressed and compared according to the data from Laboratoire $Mat{\acute{e}}riaux$ et $Durabilit{\acute{e}}$ des Constructions (LMDC). Secondly, pitting factor model of rebar in general descend law with corrosion degree was introduced in terms of existing experimental data. Finally, with the comprehensive numerical simulation, the durability of an existing arch bridge was studied in depth in deterministic way, including diffusion process and sectional strength of typical cross section of arch, crossbeam and deck slab. Evolution of structural capacity considering life-cycle rehabilitation strategy indicated the degradation law of durability of reinforced arch bridges.