• Proceedings of the Polymer Society of Korea Conference
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• 2006.10a
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• pp.58-59
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• 2006

Less than a decade ago, most alternate membrane materials for fuel cells relied upon a post-sulfonation process to generate ionic groups capable of transporting protons from the anode to the cathode. These random post sulfonations showed some promise, but in general they produced materials that were not sufficiently stable or protonically conductive at ion exchange capacities where aqueous swelling could be restricted. Our group began to synthesize disulfonated monomers that could be used to incorporate into random copolymer proton exchange membranes. The expected limitation was that the aromatic polymers might not be stable enough to withstand fuel cell conditions. However, this was mostly based upon an accelerated test known was the Fenton's Reagent Test, which did not seem to this author as being a reliable predictor of performance. A much better approach has been to evaluate the open circuit voltage (OCV) for alternate membranes, as well as the benchmark perfluorosulfonic acid systems. When this is done, the aromatic ionomers of this study, primarily based upon disulfonated polyarylene ether sulfones, show up quite well. Real time 3000 hours DMFC results have also been generated. Obtaining conductive materials at low humidities is another major issue where alternate membranes have not been particularly successful. In order to address this problem, multiblock copolymers with relatively high water diffusion coefficients have been designed, which show promise for conductivity at lowered humidity.

• Membrane Journal
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• v.9 no.3
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• pp.141-150
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• 1999

A novel permeation apparatus was developed which could make the on-line measurements of both flux transient and permeate composition in gas permeation. The measurement by using the per¬meation apparatus was based on the continuous-flow technique. The transient measurement allowed the simultaneous determinations of permeation characteristics, such as, permeability, diffusion and solubility coefficients, and activation energies only with one experiment. The apparatus performance was illustrated by conducting the permeation of pure gases through two glassy polyimides and a rubbery poly (dimethyl¬siloxane) membranes, respectively. A comparison of the permeation characteristics determined from the flux transients was made with the literature values for verifying the confidence and accuracy of the measurement. Also, the analysis of the permeation transients obtained was carried out for the close investigation of the permeation behaviors of gases through membrane.

• The Journal of the Institute of Internet, Broadcasting and Communication
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• v.13 no.6
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• pp.79-85
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• 2013

In this paper, we discussed the traditional methods of generating digital halftoning image and DCT transform. Then we propose a new and simple halftoning algorithm that is based on DCT transformation. We do the feasibility test to verify the proposed algorithm. So we assessed several images generated by adjusting weights of DCT coefficients. As a result, we got the better result for weights of the ramp function type than for weights of the step function type through experiment. As a simple application, we can apply our algorithm to the MPEG video for generating the halftoning video.

• Journal of Korea Water Resources Association
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• v.33 no.1
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• pp.39-50
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• 2000

Generally speaking, a hydrodynamic model needs a friction coefficient (Manning coefficient or Chezy coefficient) and eddy viscosity. For numerical solution the coefficients are usually determined by recursive calculations. The eddy viscosity in numerical model plays physical diffusion in flow and also acts as numerical viscosity. Hence its value has influence on the stability of numerical solution and for these reasons a consistent evaluation procedure is needed. By using records of stage and discharge in the downstream reach of the Han river, I-D models (HEC-2 and NETWORK) and 2-D model (SMS), estimated values of Manning coefficient and an empirical equation for eddy viscosity are presented. The computed results are verified through the recorded flow elevation data.n data.

• Macromolecular Research
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• v.11 no.3
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• pp.157-162
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• 2003

6FDA-based polyimides were prepared from the thermal imidization reaction of 6FDA with diamines of BAPAF, DAP, and DABA having a polar group of hydroxyL or carboxyl. Properties of the dense polyimide membranes were characterized and their gas permeation properties for H$_2$, $CO_2$, $O_2$, $N_2$, and CH$_4$ were investigated. Permeabilities, diffusion coefficients and diffusivity selectivities of polar group-containing polyimide membranes including 6FDA-BAPAF, 6FDA-DAP, and 6FDA-DABA polymer for the gases did not change largely. The separation properties of 6FDA-TrMPD polyimide membrane used as a reference polymer were compared with those of the polyimide membranes mentioned above. It was found that the polyimides of 6FDA-BAPAF, 6FDA-DAP, and 6FDA-DABA, which were soluble in alcohol or/and 2-methoxyethanol, could be applicable to the preparation of a dense composite membrane by dip-coating method.

• Journal of Pharmaceutical Investigation
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• v.22 no.1
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• pp.63-68
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• 1992

An HPLC procedure with UV detection has been developed for the quantitation of flurbiprofen released into isopropyl myristate used as the receptor phase in an in vitro membraneless drug diffusion cell. The drug and the internal standard (oxaprozin) were extracted from isopropyl myristate with a mixture of dimethylsulfoxide:methanol:water (2:1:1) and quantitated using a reverse phase $C_{18}$ column. The chromatograms were completely free from interfering peaks, and the relative retention times of flurbiprofen and the internal standard were 4.9 and 6.8 min, respectively. Calibration plots were linear over the concentration range of $1-200\;{\mu}g/ml$ of flurbiprofen with correlation coefficients, all higher than 0.99. The mean intra-day precision and accuracy among three replicate sets of the assay in a day were 4.26 and 4.52%, respectively, whereas the mean inter-day precision and accuracy were 3.35 and 3.64%, respectively. The mean recovery of the drug was 92.5% over the calibration range. The method was simple, reliable and accurate for the quantitation of flurbiprofen in unpurified isopropyl myristate.

• Journal of Biosystems Engineering
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• v.31 no.5 s.118
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• pp.410-415
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• 2006

This study was performed to develop thin layer drying equations for green rice. Thin layer drying tests of green rice were conducted at three temperature levels of 30, 40, $50^{\circ}C$ and two relative humidity levels of 30, 50% respectively. The measured moisture ratio were fitted to the selected four drying models (Page, Thompson, Simplified diffusion and Lewis model) using stepwise multiple regression analysis. The overall drying rate increased as the drying air temperature and as relative humidity was increased, but the effect of temperature increase was dominant. Half response time (Moisture ratio=0.5) of drying was affected by both drying temperature and relative humidity Drying rate was mainly affected by relative humidity at drying temperature of $50^{\circ}C$. The results of comparing coefficients of determination and root mean square error of moisture ratio for four drying models showed the Page model was found to ft adequately to all drying test data.

• Journal of Biosystems Engineering
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• v.22 no.1
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• pp.11-20
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• 1997

Thin layer drying tests of short gain rough rice were conducted in an experimental dryer equiped with air conditioning unit. The drying tests were performed in triplicate at three air temperatures of $35^circ$, $45^circ$, $55^circ$, and three relative humidities of 40%, 55%, 70%, respectively. Previously published thin layer equations were reviewed and four different models widely used as thin layer drying equations for cereal grains were selected. The selected four models were Pages, simplified diffusion, Lewis's and Thompson's models. Experimental data were fitted to these equations using stepwise multiple regression analysis. The experimental constants involved in tow equations were represented as a function of temperature and relative humidity of drying air. The results of comparing coefficients of determination and root mean square errors of miosture ratio for low equations showed that Page's and Thompsons models were found to fit adequately to all drying test data with coefficient of determination of 0.99 or better and root mean square error of moisture ratio of 0.025.

• Journal of Biosystems Engineering
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• v.29 no.6 s.107
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• pp.495-500
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• 2004

This study was performed to develop thin layer drying equations for low temperature. Thin layer drying tests of short grain rough rice were conducted at three low temperature levels of 15, 25, $35^{\circ}C$ and two relative humidity levels of 30, $50\%$, respectively. The measured moisture ratios were fitted to the selected four drying models (Page, Thompson, Simplified diffusion and Lewis model) using stepwise multiple regression analysis. The overall drying rate increased as the drying air temperature was increased and as relative humidity was decreased, but the effect of temperature increase was dominant. Half response time (Moisture ratio=0.5) of drying was affected by both drying temperature and relative humidity at drying temperature of below $25^{\circ}C$, but at $35^{\circ}C$ was mainly affected by drying temperature. The results of comparing coefficients of determination and root mean square error of moisture ratio for low drying models showed that Page model was found to fit adequately to all drying test data.

• Bulletin of the Korean Chemical Society
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• v.24 no.3
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• pp.345-349
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• 2003

The quantity, process and kinetics of di-(2-ethylhexyl)phthalate (DEHP) migration in the 30/70 and 40/60 poly(vinylchloride) (PVC)/DEHP blends were investigated using gas chromatograph. A thin and flexible PVC sheet was soaked in surrounding medium (SM) of water/ethanol mixture and acetonitrile with constant stirring to release DEHP. By observed concentration of DEHP in the SM, it is found that acetonitrile is more intense in DEHP migration than water/ethanol mixture. In addition the amount of extracted DEHP is proportional to the leaching temperature and added ratio of DEHP. The behavior of DEHP migration from flexible PVC sheets was described by the Ficks's law with $2.72-10.1\;{times}\;10^{-10}$ cm²/s of the diffusion coefficients.