• Journal of Korean Society for Atmospheric Environment
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• v.26 no.1
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• pp.77-84
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• 2010

The diffusion and partition coefficients of polyurethane foam (PUF) are estimated using a microbalance experiment and small chamber test. The microbalance is used to measure sorption/desorption kinetics and equilibrium data. When the diffusion condition is controlled in the chamber of the sample, interactions between volatile organic compounds (VOCs) and PUF can lead to the estimation of a relatively homogenous rate of mass transfer in the interiors and surfaces of PUF. The estimates of the material/air partition coefficient (K) and the material-phase diffusion coefficient (D) are shown to be independent of the concentrations of VOCs. This approach, if applied to a diffusion-controlled or physically-based model, can facilitate more precise prediction of their source/sink behavior. Although further research and more rigorous validation is needed, an emission model applied with the diffusion and partition coefficients from this research holds promise for the improvement of reliability in predicting the behavior of VOCs emitted from porous building materials by D and K.

• Computers and Concrete
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• v.13 no.2
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• pp.187-207
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• 2014

This paper mainly discusses the influence of the aggregate properties including grading, shape, content and distribution on the chloride diffusion coefficient, as well as the initiation time of steel corrosion from a probabilistic point of view. Towards this goal, a simulation method of random aggregate structure (RAS) based on elliptical particles and a procedure of finite element analysis (FEA) at meso-scale are firstly developed to perform the analysis. Next, the chloride diffusion coefficient ratio between concrete and cement paste $D_{app}/D_{cp}$ is chosen as the index to represent the effect of aggregates on the chloride diffusion process. Identification of the random distribution of this index demonstrates that it can be viewed as actually having a normal distribution. After that, the effect of aggregates on $D_{app}/D_{cp}$ is comprehensively studied, showing that the appropriate properties of aggregates should be decided by both of the average and the deviation of $D_{app}/D_{cp}$. Finally, a case study is conducted to demonstrate the application of this mesoscopic method in predicting the initiation time of steel corrosion in reinforced concrete (RC) structures. The mesoscopic probabilistic method developed in this paper can not only provide more reliable evidences on the proper grading and shape of aggregates, but also play an important role in the probability-based design method.

• Analytical Science and Technology
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• v.9 no.3
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• pp.292-301
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• 1996

The synthesis of poly(ether)tailed bipyridine complex as redox reaction probes has advanced attempts to interpret very slow diffusion and heterogeneous electron transfer. Diffusion coefficients as low as $1.5{\times}10^{-15}cm^2/s$ have been observed for the oxidation of neat $Co(bpy(ppgm)_2)_{3^-}(ClO_4)_2$ with $LiClO_4$ electrolyte. Heterogeneous electron transfer rate constants of materials were found to vary with diffusion coefficient. The decrease in k as the diffusion coefficient decreases was actually caused by the decreasing D. Diffusion coefficient for compound of strong ion pairing anion($ClO{_4}^-$) was much smaller than the diffusion coefficient for compound of weak ion pairing anion($CF_3COO^-$).

• Bulletin of the Korean Chemical Society
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• v.4 no.5
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• pp.223-227
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• 1983

A molecular dynamic computer experiment was performed on a system of 108 particles composed of a single polymer chain and solvent molecules. The state considered was in the immediate neighborhood of the triple point of the system. The polymer itself is an analog of a freely jointed chain. The Lennard-Jones potential was used to represent the interactions between all particles except for that between the chain elements forming a bond in the polymer chain, for which the interaction was expressed by a harmonic potential. The self-diffusion coefficient and velocity autocorrelation function (VACF) of a polymer were calculated at various chain lengths $N_p$, and various interaction strengths between solvent molecules and a polymer chain element. For self-diffusion coefficients D, the Einstein relation holds good; as chain length $N_p$ increases the D value decreases, and D also decreases as ${\varepsilon}_{cs}$ (the interaction parameter between the chain element and solvent molecules) increases. The relaxation time of velocity autocorrelation decreases as ${\varepsilon}_{cs}$ increases, and it is constant for various chain lengths. The diffusion coefficients in various conditions reveal that our systems are in a free draining limit as is well known from the behavior of low molecular weight polymers, this also agrees with the Kirkwood-Riesman theory.

• Journal of The Korean Astronomical Society
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• v.24 no.1
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• pp.95-105
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• 1991

In the presence of synchrotron losses, diffusion of an ensembel of relativistic particles in an intraculster medium is investigated. The diffusion coefficient in the medium is found to be constrained by $28.8\;{\pm}\;0.4\;{\leq}\;Log\;D\;{\leq}\;30.5\;{\pm}\;0.4\;cm^2s^{-1}$ with the energy dependency of $D_0{\varepsilon}^{\mu}$ of ${\mu}=0.4{\pm}0.2$ as the previous observations suggested. As an important implication of the result, the brightest head-tail radio source NGC 4869, whose radio tail structure is indicative for its orbit within the cluster core, is considered to be the major contributor of particles for the formation of the Coma radio halo.

• Journal of the Korean Institute of Electrical and Electronic Material Engineers
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• v.14 no.2
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• pp.169-174
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• 2001

The electron transport coefficients(the electron drift velocity, W, and the longitudinal and transverse diffusion coefficient, D$_{L}$ and D$_{T}$) in SiH$_4$-Ar mixtures containing 0.5% and 5.0% monosilane were calculated over the E/N range from 0.01 to 300 Td and over the gas pressure range 0.5, 1.0 and 1.5 Torr by the time-of-flight(TOF) method of the Boltzmann equation(BE.) and Monte-Carlo simulation(MCS). The electron energy distribution function in each SiH$_4$-Ar mixtures at E/N=10 Td and L=0.2 cm, which in equilibrium region in the mean electron enregy were compared.red.

• Journal of Biomedical Engineering Research
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• v.27 no.5
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• pp.203-209
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• 2006

The aim of this study is to investigate the feasibility of ex vivo MR diffusion tensor imaging technique in order to observe the diffusion-contrast characteristics of human gastric tissues. On normal and pathologic gastric tissues, which have been fixed in a polycarbonate plastic tube filled with 10% formalin solution, laboratory made 3D diffusion tensor Turbo FLASH pulse sequence was used to obtain high resolution MR images with voxel size of $0.5{\times}0.5{\times}0.5mm^3\;using\;64{\times}32{\times}32mm^3$ field of view in conjunction with an acquisition matrix of $128{\times}64{\times}64$. Diffusion weighted- gradient pulses were employed with b values of 0 and $600s/mm^2$ in 6 orientations. The sequence was implemented on a clinical 3.0-T MRI scanner(Siemens, Erlangen, Germany) with a home-made quadrature-typed birdcage Tx/Rx rf coil for small specimen. Diffusion tensor values in each pixel were calculated using linear algebra and singular value decomposition(SVD) algorithm. Apparent diffusion coefficient(ADC) and fractional anisotropy(FA) map were also obtained from diffusion tensor data to compare pixel intensities between normal and abnormal gastric tissues. The processing software was developed by authors using Visual C++(Microsoft, WA, U.S.A.) and mathematical/statistical library of GNUwin32(Free Software Foundation). This study shows that 3D diffusion tensor Turbo FLASH sequence is useful to resolve fine micro-structures of gastric tissue and both ADC and FA values in normal gastric tissue are higher than those in abnormal tissue. Authors expect that this study also represents another possibility of gastric carcinoma detection by visualizing diffusion characteristics of proton spins in the gastric tissues.

• Journal of the Korea institute for structural maintenance and inspection
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• v.19 no.5
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• pp.83-91
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• 2015

With varying conditions of concrete surface, induced chloride contents are changed and this is a key parameter for steel corrosion and service life in RC (Reinforced Concrete) structures. Many surface enhancement techniques using impregnation have been developed, however the evaluation techniques for chloride behavior through doubly layered media and time-dependent diffusion are rarely proposed. This paper presents an analysis technique considering double-layer concrete and time-dependent diffusion behavior, and the results are compared with those from the previous test results through reverse analysis. The chloride profiles from the surface-impregnated concrete exposed to atmospheric, tidal, submerged zone for 2 years are adopted. Furthermore surface chloride contents and diffusion coefficients are obtained, and are compared with those from Life365. Through consideration of time effect, the relative error decreases from 0.28 to 0.20 in atmospheric, 0.29 to 0.11 in tidal, and 0.54 to 0.40 in submerged zone, respectively, which shows more reasonable results. Utilizing the diffusion coefficients from Life365, relative errors increases and it needs deeper penetration depth (e) and lower diffusion coefficient ratio ($D_1/D_2$) due to higher diffusion coefficient.

• Proceedings of the Korea Concrete Institute Conference
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• 2003.05a
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• pp.681-686
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• 2003

One of the major degradation processes of reinforced concrete (RC) structure is corrosion of reinforced steel due to chloride attack. Severe environments, such as marine environment and exposure to de-icing salts, could accelerate the steel corrosion of RC structures through the chloride ion intrusion into concrete. In order to delay this degradation process, several kinds of admixtures have been used in concrete mix. In this study, effective diffusion coefficient of chloride ion ($D_{eff}$) and total passed charge of concrete with and without fly ash were measured using electrical method. It is found that fly ash concrete has much less chloride ion coefficient than ordinary concrete at later age. By analyzing the test results, $D_{eff}$ at 28 and 90 days was obtained as a function of water-binder ratio (W/B) and an equation for predicting $D_{eff}$ with age was proposed considering the decreasing rate of $D_{eff}$.

• Journal of Wetlands Research
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• v.13 no.3
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• pp.385-394
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• 2011

In this study, optimal parameters of diffusion-analogy GIUH were calculated by separating channel and hillslope from drainage structures in the basin. Parameters of the model were composed of channel and hillslope, each velocity($u_c$, $u_h$) and diffusion coefficient($D_c$, $D_h$). Tanbu subwatershed in Bocheong river basin as a target basin was classified as 4th rivers by Strahler's ordering scheme. The optimization technique was applied to the SCE-UA, the estimated optimal parameters are as follows. $u_c$ : 0.589 m/s, $u_h$ : 0.021 m/s, $D_c$ : $34.469m^2/s$, $D_h$ : $0.1333m^2/s$. As a verification for the estimated parameters, the error of average peak flow was about 11 % and the error of peaktime was 0.3 hr. By examining the variability of parameters, the channel diffusion coefficient didn't have significant effect on hydrological response function. by considering these results, the model is expected to be simplified in the future.