• Corrosion Science and Technology
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• v.5 no.4
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• pp.117-122
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• 2006

Hydrogen permeation measurements have been carried out on API X65 grade linepipe steel. In order to study the effect of steel microstructure on hydrogen diffusion behavior in linepipe steel, the accelerated cooling condition was applied and then three different kinds of microstructures were obtained. Hydrogen permeation measurement has been performed in reference to modified ISO17081 (2004) and ZIS Z3113 method. Hydrogen trapping parameters in these steels were evaluated in terms of the effective diffusivity ($D_{eff}$), permeability ($J_{ss}L$) and the amount of diffusible hydrogen. In this study, microstructures which affect both hydrogen trapping and diffusion were degenerated pearlite (DP), acicular ferrite (AF), bainite and martensite/austenite constituents (MA). The low $D_{eff}$ and $J_{ss}L$ mean that more hydrogen can be trapped reversibly or irreversibly and the corresponding steel microstructure is dominant hydrogen trapping site. The large amount of diffusible hydrogen means that corresponding steel microstructure is predominantly reversible. The results of this study suggest that the hydrogen trapping efficiency increases in the order of DP, bainite and AF, while AF is the most efficient reversible trap.

• Special Issue of the Society of Naval Architects of Korea
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• 2007.09a
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• pp.118-127
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• 2007

SAW(Submerged Arc Welding) process is generally applied to a wide range of welding area in the fabrication of steel structure. This process has a good characteristic properties such as the high quality of welds and the high deposition rates, but in case of welding on a thick steel plate, it also has higher cold crack susceptibility than that of a thin steel plate. The purpose of this research is to find the main factor of crack generation and clarify the countermeasure for crack prevention, and then establish the optimum welding condition in a heavy thick steel plate. The results of this study are as follows, 1. The cause of crack generation is found the diffusible hydrogen penetrated into weld metal by decomposition of the remained moisture in SAW flux during welding. 2. For the removal of diffusible hydrogen, the raw materials of SAW flux are to be dehydrated at the high temperature in the initial manufacturing stage. 3. Mechanical properties of weld metal welded with the dehydrated SAW flux were evaluated very excellent, furthermore the weld metal has been proved to have low diffusible hydrogen content with 3.1ml /100g. 4. The weldability and quality welded with thick steel plates were improved by establishing the new optimum welding condition.

• Journal of Welding and Joining
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• v.2 no.2
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• pp.62-69
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• 1984

In this study, cold crack susceptibility of high strength steel (ABS EH32 Steel) welded zone with shielded metal are welding was investigated by tensile restraint cracking test method. Effects of diffusible hydrogen content on root cracking, lower critical stress, crack initiation and fracture mode, hardness value distribution of welded zone and fractograph were mainly investigated. Following conclusions are made: 1. In the view of the lower critical stress level, wet electrode, containing much diffusible hydrogen content shows lower value than dried electrode. 2. Hardness value(Hv 5kg) in Heat Affected Zone of wet electrode is higher than that of dried electrode caused by hydrogen embrittlement. 3. In the case of wet electrode, root crack is initiated and propagated in Heat Affected Zone and then propagated to weld metal, but using of dried electrode, root crack is initiated in Heat Affected Zone and propagated to weld metal without propagating in HAZ. 4. For wet electrode, quasi-cleavage fracture mode is majorly observed on the fracture surface of HAZ and partially of weld metal due to hydrogen embrittlement.

• Journal of Welding and Joining
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• v.28 no.2
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• pp.54-59
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• 2010

The effects of welding parameters such as contact tip-to-work distance (CTWD), voltage, and current on the weld metal diffusible hydrogen contents (HD) were investigated and rationalized by the calculation of heating time and amount of heat generated in the extension length of flux cored wire. As CTWD increased from 15 to 25mm, HD decreased from 8.46 to 5.45mL/100g deposited metal. Calculations showed that, with an increase of CTWD, the amount of heat generated increased from 46 to 92J in addition to an increase of heating time. Increase of current from 250 to 320A, however, gave little variation of HD. It showed that no significant change in the amount of heat generated was found, and heating time was decreased with an increase of current. It also showed that CTWD is more influential than voltage in relatively lower heat input ranges, while voltage is more in higher input ranges

• Journal of Welding and Joining
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• v.23 no.2
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• pp.6-9
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• 2005

• Proceedings of the KWS Conference
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• 2005.06a
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• pp.141-143
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• 2005

Yttrium has been investigated as hydrogen trapping site in pure iron and HSLA steel welds. Assessment of hydrogen trapping parameters for yttrium oxide has also shown the high potential of yttrium addition to improve hydrogen management in high strength steel welding. The purpose of this study was to reduce and control the diffusible hydrogen content in the weld deposit.

• Journal of Ocean Engineering and Technology
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• v.28 no.6
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• pp.540-545
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• 2014

Multipass self-shielded flux cored arc welding with different heat inputs (1.3–2.0 kJ/mm) was conducted to determine the effects of the heat input on the proportion of the reheated region, impact toughness, and diffusible hydrogen content in the weld metal. The reheated region showed twice the impact toughness of the as-deposited region because of its fine grained ferritic-pearlitic microstructure. With decreasing heat input, the proportion of the reheated region in the weld metal became higher, even if the depth of the region became shallower. Accordingly, the greatest impact toughness, 69 J at −40℃, was obtained for the lowest heat input welding, 1.3 kJ/mm. Irrespective of the heat input, little difference was observed in the hardness and diffusible hydrogen content in the weld metal. This result implies that low heat input welding with 1.3 kJ/mm can be performed to obtain a higher proportion of reheated region and thus greater impact toughness for the weld metal without the concern of hydrogen cracking.

• Journal of Welding and Joining
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• v.13 no.4
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• pp.46-54
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• 1995

The cold cracking susceptibility of a variety of weld metals deposited by GMAW with several kinds of commercial solid wires for high strength-toughness steel was investigated. G-BOP test and LB-TRC test were carried out to study the effects of preheat, chemical composition and hydrogen level on the weld metal cold cracking. The results obtained are as follows. 1) 10% CPT obtained by G-BOP test was the most valuable criteria for evaluating the cold cracking susceptibility of weld metals compared with percentage of cracking at room temperature and crack free temperature, and it had good correlation with the results of LB-TRC test. 2) Cold cracking susceptibility of weld metals was high in the row of MG100A, MG100C, MG100D and MG100B. Welds deposited with MG130 and MG80 showed similar icidents of cracking with MG100C and MG100B respectively, even though their strength levels were different. 3) Diffusible hydrogen level in weld metals which has good relation with hydrogen content in wire itself was the most critical factor for controlling the cold cracking susceptibility of weld metal.

• Journal of Welding and Joining
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• v.7 no.2
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• pp.49-59
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• 1989

The effect of non-metallic inclusions on the HAZ hydrogen induced cracking was investigated. Quench and temper high tensile strength steels containing various sulphur contents were employed. The sulphur contents range between 0.007% and 0.040%. Non-metallic inclusions were mainly MnS type sylphide and Mn-Al-Si type. The sensitivity of HAZ delayed cracking was evaluated by implant testing. Diffusible hydrogen content was varied by controlling the moisture absorbing condition of manual arc welding electrodes. The one was asreceived condition, the other was dipping the electrodes in the water for ten minutes. The main results obtained were as follows; 1) The results of implant test showed that critical stress increased with increasing S content up to 0.013%. But steel containing 0.040%S showed lower critical stress than that of 0.013% S. These result suggest that there will be optimum S content to prevent HAZ delayed cracking of high strength steels. 2) Under the lower D.H.C. level, critical stress was increased with rolling reduction, but higher D.H.C. level, effect of rolling reduction was not recognized.

• Journal of Ocean Engineering and Technology
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• v.17 no.2
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• pp.14-20
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• 2003

In this paper, a practical design criteria for judgement of crack occurrence in weldments is presented as a function of typical welding parameters, such as diffusible hydrogen, restraint intensity, and preheating temperature. The elastic analyses using the finite element techniques are employed in order to quantify the restraint intensities, numerically. Systematic experiments are also conducted in order to investigate the propensity of crack to typical welding parameters. The results of numerical estimation using the proposed method for the experimental specimens show the usefulness as a practical tool in welding induced crack problems with extensive uncertainties. Systematic experiments are also conducted in order to investigate the propensity of crack to typical welding parameters. The results of numerical estimation using the proposed method for the experimental specimens show the usefulness as a practical tool in welding induced crack problems with extensive uncertainties.