• Title/Summary/Keyword: diffuse light

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Effects of transition metal-doping on the properties of ZnO nanoparticles and the photocatalytic degradation of methylene blue (전이금속 도핑이 ZnO 나노분말의 특성 및 메틸렌블루 광촉매 분해 특성에 미치는 영향)

  • Chang, Han Kwon;Oh, Kyung Jun;Jang, Hee Dong;Cho, Kuk;Kim, Dong-Jin;Choi, Jin Hoon
    • Particle and aerosol research
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    • v.6 no.1
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    • pp.29-35
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    • 2010
  • Transition metals such as V, Fe, and Ni were used to synthesize doped zinc oxide nanoparticles from mixed liquid precursors by using the flame spray pyrolysis (FSP). The effects of dopants on the powder properties such as morphology, specific surface area, crystal structure, and light adsorption were analyzed by TEM, BET, XRD, and UV-Vis diffuse reflection spectrum (DRS), respectively. The results showed that hexagonal wurtzite structured ZnO:M (M = V, Fe, Ni) nanoparticles were successfully synthesized by the FSP. The transition metal-doping resulted in the decrease in its particle size and crystallite size. The UV-vis absorption spectra of ZnO:M nanoparticles were also red-shifted. ZnO:V showed the highest MB degradation of 99.4% under the UV irradiation after 3 hrs.

Hair dyeing and the consequential change in luster (모발 염색에 따른 광택도의 변화)

  • Park, Jae-Jung;Moon, Hyo-Seung;Kim, Jong-Hyub;Kim, Wang-Gi;Han, Sang-Hun
    • Proceedings of the Korean Society of Dyers and Finishers Conference
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    • 2011.11a
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    • pp.13-13
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    • 2011
  • Hair luster is a key objective for consumers in the hair care market. Recently, as consumers using hair coloring or bleaching product increase, measurement and quantification of hair luster become more important. A hair visual appearance measurement system called SAMBA can quantitate the luster and effectively separate specular and diffuse light. SAMBA usually has been employed to measure, mainly with the change of shine value, effects of cosmetic treatments on hair shine and surface smothness. We conducted a study on the effect of dyeing and bleaching on the luster, as a result, a strong bleaching caused large decline of the luster. But the large decline of luster was caused by increasing intensity of diffusion and width of chroma peak, not the shine value. The system of dye toning for higher luster can be developed on reference to the peak type of chroma and diffusion depends on kinds and combination of dye.

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p-type Zn Diffusion using by Solid State Method of $GaAs_{0.60}P_{0.40}$ and the Properties of Electroluminescence (고상 확산 법에 의한 P-type Zn 확산과 $GaAs_{0.60}P_{0.40}$의 전계발광 특성)

  • Pyo, Jin-Goo;Lim, Keun-Young;So, Byung-Moon;Park, Choon-Bae
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2003.11a
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    • pp.481-485
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    • 2003
  • To diffuse Zn at solid-state, the $SiO_2/ZnO/SiO_2$ wafers was made by PECVD and RF Spotter. Thicknesses of bottom $SiO_2$ and cap $SiO_2$ was about $500{\AA}$ and about $3500{\AA}$. First test was Diffusion temperatures were $760^{\circ}C$, $780^{\circ}C$, and $800^{\circ}C$, and diffusion times were 1, 2, 3, 4, 5, and 6 hr and 2nd test was Diffusion temperatures were $760^{\circ}C$, $720^{\circ}C$, and $680^{\circ}C$, and diffusion times were 1, 2, 3, 4, 5, and 6 hr. LED chips were fabricated by the diffused wafers at Fab. The peak wavelength of all chips showed about $625{\sim}650\;nm$ and red color Main reason for Iv change was by diffusion temperature not diffusion time. The lower temperature was the higher Iv. We thick that these properties is because of the very high diffusion temperature.

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New mathematical approach to determine solar radiation for the southwestern coastline of Pakistan

  • Atteeq Razzak;Zaheer Uddin;M. Jawed Iqbal
    • Advances in Energy Research
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    • v.8 no.2
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    • pp.111-123
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    • 2022
  • Solar Energy is the energy of solar radiation carried by them in the form of heat and light. It can be converted into electricity. Solar potential depends on the site's atmosphere; the solar energy distribution depends on many factors, e.g., turbidity, cloud types, pollution levels, solar altitude, etc. We estimated solar radiation with the help of the Ashrae clear-sky model for three locations in Pakistan, namely Pasni, Gwadar, and Jiwani. As these locations are close to each other as compared to the distance between the sun and earth, therefore a slight change of latitude and longitude does not make any difference in the calculation of direct beam solar radiation (BSR), diffuse solar radiation (DSR), and global solar radiation (GSR). A modified formula for declination angle is also developed and presented. We also created two different models for Ashrae constants. The values of these constants are compared with the standard Ashrae Model. A good agreement is observed when we used these constants to calculate BSR, DSR, GSR, the Root mean square error (RMSE), Mean Absolute error (MABE), Mean Absolute percent error (MAPE), and chisquare (χ2) values are in acceptance range, indicating the validity of the models.

Synthesis and Infrared Light Reflecting Characteristics of TiO2/Mica Hybrid Composites (이산화 티타늄/마이카 복합 재료의 적외선 광반사 특성)

  • Kil, Hyun Suk;Rhee, Seog Woo
    • Applied Chemistry for Engineering
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    • v.27 no.1
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    • pp.16-20
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    • 2016
  • In this work, we describe the synthesis and infrared light reflecting characteristics of $TiO_2$/mica hybrid composites. $TiO_2$/mica composite materials were obtained by the hydrolysis and condensation reaction of titanium isopropoxide in an aqueous solution of acetic acid in the presence of mica particles. Amorphous phase of $TiO_2$ on the surface of mica was converted to the crystalline rutile phase via anatase phase by heat treatment ($600-1000^{\circ}C$, 1-3 h) of $TiO_2$/mica composite materials, and the size of crystals was controlled by heat treatment conditions. Physicochemical properties of mica and $TiO_2$/mica composites were investigated using FE-SEM, ED-XRF, and PXRD. The solar reflectance of $TiO_2$/mica composites in the near IR region (780~2,500 nm) measured using a diffuse reflectance NIR spectrophotometer was 88.6%, which is rather higher than that of calcined pure mica (86.6%). Therefore, $TiO_2$/mica composites can be used as NIR light reflective pigments.

Fabrication of Microwire Arrays for Enhanced Light Trapping Efficiency Using Deep Reactive Ion Etching

  • Hwang, In-Chan;Seo, Gwan-Yong
    • Proceedings of the Korean Vacuum Society Conference
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    • 2014.02a
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    • pp.454-454
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    • 2014
  • Silicon microwire array is one of the promising platforms as a means for developing highly efficient solar cells thanks to the enhanced light trapping efficiency. Among the various fabrication methods of microstructures, deep reactive ion etching (DRIE) process has been extensively used in fabrication of high aspect ratio microwire arrays. In this presentation, we show precisely controlled Si microwire arrays by tuning the DRIE process conditions. A periodic microdisk arrays were patterned on 4-inch Si wafer (p-type, $1{\sim}10{\Omega}cm$) using photolithography. After developing the pattern, 150-nm-thick Al was deposited and lifted-off to leave Al microdisk arrays on the starting Si wafer. Periodic Al microdisk arrays (diameter of $2{\mu}m$ and periodic distance of $2{\mu}m$) were used as an etch mask. A DRIE process (Tegal 200) is used for anisotropic deep silicon etching at room temperature. During the process, $SF_6$ and $C_4F_8$ gases were used for the etching and surface passivation, respectively. The length and shape of microwire arrays were controlled by etching time and $SF_6/C_4F_8$ ratio. By adjusting $SF_6/C_4F_8$ gas ratio, the shape of Si microwire can be controlled, resulting in the formation of tapered or vertical microwires. After DRIE process, the residual polymer and etching damage on the surface of the microwires were removed using piranha solution ($H_2SO_4:H_2O_2=4:1$) followed by thermal oxidation ($900^{\circ}C$, 40 min). The oxide layer formed through the thermal oxidation was etched by diluted hydrofluoric acid (1 wt% HF). The surface morphology of a Si microwire arrays was characterized by field-emission scanning electron microscopy (FE-SEM, Hitachi S-4800). Optical reflection measurements were performed over 300~1100 nm wavelengths using a UV-Vis/NIR spectrophotometer (Cary 5000, Agilent) in which a 60 mm integrating sphere (Labsphere) is equipped to account for total light (diffuse and specular) reflected from the samples. The total reflection by the microwire arrays sample was reduced from 20 % to 10 % of the incident light over the visible region when the length of the microwire was increased from $10{\mu}m$ to $30{\mu}m$.

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The Clinical Accuracy of Endoscopic Ultrasonography and White Light Imaging in Gastric Endoscopic Submucosal Dissection

  • Park, Soon-Hong;Sung, Sang-Hun;Lee, Seung-Jun;Jung, Min-Kyu;Kim, Sung-Kook;Jeon, Seong-Woo
    • Journal of Gastric Cancer
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    • v.12 no.2
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    • pp.99-107
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    • 2012
  • Purpose: Gastric mucosal neoplastic lesions should have characteristic endoscopic features for successful endoscopic submucosal dissection. Materials and Methods: Out of the 1,010 endoscopic submucosal dissection, we enrolled 62 patients that had the procedure cancelled. Retrospectively, whether the reasons for cancelling the endoscopic submucosal dissection were consistent with the indications for an endoscopic submucosal dissection were assessed by analyzing the clinical outcomes of the patients that had the surgery. Results: The cases were divided into two groups; the under-diagnosed group (30 cases; unable to perform an endoscopic submucosal dissection) and the over-diagnosed group (32 cases; unnecessary to perform an endoscopic submucosal dissection), according to the second endoscopic findings, compared with the index conventional white light image. There were six cases in the under-diagnosed group with advanced gastric cancer on the second conventional white light image endoscopy, 17 cases with submucosal invasion on endoscopic ultrasonography findings, 5 cases with a size greater than 3 cm and ulcer, 1 case with diffuse infiltrative endoscopic features, and 1 case with lymph node involvement on computed tomography. A total of 25 patients underwent a gastrectomy to remove a gastric adenocarcinoma. The overall accuracy of the decision to cancel the endoscopic submucosal dissection was 40% (10/25) in the subgroup that had the surgery. Conclusions: The accuracy of the decision to cancel the endoscopic submucosal dissection, after conventional white light image and endoscopic ultrasonography, was low in this study. Other diagnostic options are needed to arrive at an accurate decision on whether to perform a gastric endoscopic submucosal dissection.

A Case of Primary Diffuse Nodular Pulmonary Amyloidosis Localized in the Lung (원발성 결절성 폐실질형 유전분증 1예)

  • Jung, Sung-Kwoen;Oh, Joon;Roh, Yang-Won;Kong, Hee-Sang;Park, Kae-Young;Park, Jeong-Woong;Park, Jae-Kyung;Nam, Gui-Hyun;Ha, Seong-Hwen;Lee, Han-Kyung;Jeong, Seong-Hwan
    • Tuberculosis and Respiratory Diseases
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    • v.49 no.3
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    • pp.365-371
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    • 2000
  • Nodular pulmonary amyloidosis is one of the rare manifestation of amyloid disease. It is known to be caused by amyloid L fibrils in the majority of cases. We experienced an unusual case of a forty-one year-old woman who was presented with multiple nodular lesion on the chest X-ray. CT-guided core needle biopsy, performed on the lesion, showed apple green birefringes, when stained Congo red and examined under polarized light, Ultrastructurally, there are randomly oriented, forming densed networks, and consists of fine, 7.5 to 10nm diameter, rigid, non-branching filaments of various lengths in electron-microscopic finding. We report a case of primary diffuse nodular pulmonary amyloidosis only localized in the lung, which was confirmed by CT guided core needle biopsy.

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Calcium Aluminate Phosphor Supported $TiO_2$ Nanoparticles (산화(酸化)티탄 나노입자(粒子)가 담지(擔持)된 칼슘 알루미늄 형광체(螢光體))

  • Thube, Dilip R.;Kim, Jin-Hwan;Kang, Suk-Min;Ryu, Ho-Jin
    • Resources Recycling
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    • v.18 no.4
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    • pp.24-30
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    • 2009
  • Rare earth based calcium aluminate phosphor ($CaAl_2O_4:Eu^{2+}$, $Nd^{3+}$) supported $TiO_2$ nanoparticles are synthesized by using sol-gel method, which are further characterized using powder X-ray diffraction (XRD), fourier transform infrared (FT-IR), diffuse reflectance UV-Visible spectroscopy (DRS UV-Vis) and transmission electron microscopy (TEM). The XRD pattern of as-prepared and sintered phosphor supported $TiO_2$ does not show the tendency to change the crystal structure from anatase to rutile phase up to $600^{\circ}C$. This indicates that the phosphor support might inhibit the densification and crystallite growth by providing dissimilar boundaries. The diffuse reflectance spectral (DRS) measurements showed shift towards longer wavelength indicating reduction in the band-gap energy as compared to free $TiO_2$. The FT-IR spectra of phosphor supported $TiO_2$ nanoparticles show shift in the peak positions to lower wavelengths. This indicates that the $TiO_2$ nanoparticles are not free, but covalently bonded to the phosphor support. TEM micrographs show presence of crystalline and spherical $TiO_2$ nanoparticles (8 - 15 nm diameter) dispersed uniformly on the surface of phosphor.

Color Restoration Method Using the Dichromatic Reflection Model for Low-light-level Environments (저조도 환경에 적합한 이색도 반사 모델을 이용한 색 복원 기법)

  • Lee, Woo-Ram;Jun, WooKyoung;Jun, Byoung-Min
    • Journal of the Korea Academia-Industrial cooperation Society
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    • v.15 no.12
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    • pp.7324-7330
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    • 2014
  • Color distortion of the dark images acquired under a low-light-level environment with a weak light source can be cause of the performance decreation of various vision systems. Therefore, recovering the original color of the images is an important process for enhancing the performance of the system. For this, this study proposes a color restoration method using a dichromatic reflection model. This paper assumes that the dark images can be classified into two parts affected by specular or diffuse reflection. Two different color constancy methods were then applied to the images to remove the effects of each reflection and two images were created as a result. The resulting images produced a one color-corrected image by combining with different weights according to the position in the images. For the performance evaluation, this paper used a synthesized image, and considered the Euclidean distance and angular error as an evaluation factor. In addition, a performance comparison was performed with the existing various color constancy method to achieve the objectivity of evaluation. The experimental results showed that the proposed method can be a more suitable solution for color restoration than the existing method.