• Title/Summary/Keyword: diffuse film

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Determination of the pH of Iso-Selectivity of the Interfacial Diffusion Layer of Fe

  • Ha, Heon Young;Kwon, Hyuk Sang
    • Corrosion Science and Technology
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    • v.7 no.1
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    • pp.40-44
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    • 2008
  • Passive metal forms an interfacial diffuse layer on the surface of passive film by its reaction with $H^+$ or $OH^-$ ions in solution depending on solution pH. There is a critical pH, called pH point of iso-selectivity ($pH_{pis}$) at which the nature of the diffuse layer is changed from the anion-permeable at pH<$pH_{pis}$ to the cation-permeable at pH>$pH_{pis}$. The $pH_{pis}$ for a passivated Fe was determined by examining the effects of pH on the thickness of passive film and on the dissolution reaction occurring on the passive film under a gavanostatic reduction in borate-phosphate buffer solutions at various pH of 7~11. The steady-state thickness of passive film formed on Fe showed the maximum at pH 8.5~9, and further the nature of film dissolution reaction was changed from a reaction producing $Fe^{3+}$ ion at $pH\leq8.5$ to that producing $FeO_2{^-}$ at $pH\geq9$, suggesting that the $pH_{pis}$ of Fe is about pH 8.5~9. In addition, the passive film formed at pH 8.5~9, $pH_{pis}$, was found to be the most protective with the lowest defect density as confirmed by the Mott-Schottky analysis. Pitting potential was decreased with increasing $Cl^-$ concentration at $pH\leq8.5$ due probably to the formation of anion permeable diffuse layer, but it was almost constant at $pH\geq9$ irrespective of $Cl^-$ concentration due primarily to the formation of cation permeable diffuse layer on the film, confirming again that $pH_{pis}$ of Fe is 8.5~9.

Diffuse Reflectance Enhancement through Wrinkling of Nanoscale Thin Films (나노스케일 박막의 표면주름 형성을 통한 산란반사도 향상)

  • Kim, Yun Young
    • Transactions of the Korean Society of Mechanical Engineers A
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    • v.39 no.12
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    • pp.1245-1249
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    • 2015
  • This study investigated the reflection spectra of wrinkled metal/polymer multilayers. A wavy surface was self-assembled by annealing an aluminum-coated poly(methyl metacrylate) layer on a silicon substrate. The total and diffuse reflectance characteristics of the sample with additional metal coatings(aluminum or silver) were evaluated in the visible wavelength(400~800 nm) using a spectrophotometer. The results showed that the wrinkled surface enhanced the diffuse reflectance up to 40~50% in the lower-wavelength range, demonstrating its potential for applications to optical thin-film devices.

Improvement of on-axis luminance by optimization of edge-lit backlight optic (LCD 에지형 백라이트 광학계의 휘도집광 효율 향상에 관한 연구)

  • Joo, Byung-Yun;Hong, Joo-Pyo
    • Proceedings of the Korean Society for Technology of Plasticity Conference
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    • 2009.10a
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    • pp.95-98
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    • 2009
  • This paper dealt with the design guide of the conventional edge-lit backlight optic with which the on-axis luminance could be increased by trying to improve the light condensing efficiency of a bright enhancement film (BEF). First, the general design guide concerned with the backlight optic was proposed, and then its validness was experimentally proved by conducting design examples with haze controls of both diffuse film and microdot material printed on the backside of the light guide plate. Experimental results showed that the variation range of the on-axis luminance by the present approach was about $5{\sim}9%$, which would be by no means negligible in the practical application.

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Eyestrain-free Bi-Focal 3D Projection Display System

  • Seo, Jong-Wook;Kim, Tae-Ho
    • 한국정보디스플레이학회:학술대회논문집
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    • 2007.08b
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    • pp.1739-1741
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    • 2007
  • A 3D projection display using stacked screens to display the near and far images, respectively, is developed. The front screen is made of a scattering polarizer film, and the far image on the rear screen is clearly visible through it. The image is perceived as three-dimensional, and no eyestrain is suffered.

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Ni-assisted growth of transparent and single crystalline indium-tin-oxide nanowires

  • Kim, Hyeon-Gi;Kim, Jun-Dong;Park, Hyeong-Ho
    • Proceedings of the Korean Vacuum Society Conference
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    • 2015.08a
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    • pp.259-259
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    • 2015
  • Single crystalline indium-tin-oxide (ITO) nanowires (NWs) were grown by sputtering method. A thin Ni film of 5 nm was deposited before ITO sputtering. Thermal treatment forms Ni nanoparticles, which act as templates to diffuse Ni into the sputtered ITO layer to grow single crystalline ITO NWs. This Ni diffusion through an ITO NW was investigated by transmission electron microscope to observe the Ni-tip sitting on a single crystalline ITO NW. Meanwhile, a single crystalline ITO structure was found at bottom and body part of a single ITO NW without remaining of Ni atoms. This indicates the Ni atoms diffuse through the oxygen vacancies of ITO structure. Rapid thermal process (RTP) applied to generate an initial stage of a formation of Ni nanoparticles with variation in time periods to demonstrate the existence of an optimum condition to initiate ITO NW growth. Modulation in ITO sputtering condition was applied to verify the ITO NW growth or the ITO film growth. The Ni-assisted grown ITO layer has an improved electrical conductivity while maintaining a similar transmittance value to that of a single ITO layer. Electrically conductive and optically transparent nanowire-coated surface morphology would provide a great opportunity for various photoelectric devices.

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Double-Layer 3D Rear Projection Display System using Scattering Polarizer Film (후면투사 방식의 이중스크린 3D 프로젝션 디스플레이)

  • Kim, Tae-Ho;Seo, Jong-Wook
    • Korean Journal of Optics and Photonics
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    • v.18 no.6
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    • pp.421-425
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    • 2007
  • A new 3D rear projection display system using double-layer polarization-selective screen systems, one stacked in front of the other, has been developed. The front and rear screens are made of scattering polarizer films, and they either diffuse-scatter or transmit the incident light depending on the polarization state of the light. The near and for images are projected onto the front and rear screens, respectively, using light waves with mutually orthogonal polarization states. The new display system produces clear high-resolution images, which are visible over a wide range of viewing angle. It was found that the impression of depth is pronounced and eyestrain is only comparable to that by 2D display systems.

Bone Scintigraphic Findings in Leukemic Patients (백혈병 환자의 골스캔 소견)

  • Choi, Hyo-Sun;Park, Jeong-Mi;Sohn, Hyeong-Seon;Chung, Soo-Kyo;Kim, Choon-Yul;Bahk, Yong-Whee;Shinn, Byung-Sub
    • The Korean Journal of Nuclear Medicine
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    • v.26 no.1
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    • pp.101-105
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    • 1992
  • The leukemias represent diffuse lesions of the bone marrow and significant bony abnormalities are associated with the more aggressive varieties of leukemias and with the younger age groups. On plain film, several roentgenographic findings are observed such as diffuse osteopenia, radiolucent metaphyseal bands, osteolytic lesions and periostitis. We evaluated bone scintigraphic findings using $^{99m}Tc-methylene$ diphosphonate $(^{99m}Tc-MDP)$ in ten patients with proven leukemia. The scan is abnormal in 90%. We classified abnormal scintigraphic findings to 3 types and these are increased diffuse juxta-articular uptake, focal increase of uptake and combined type. The common sites of focal uptake were femur, humerus, tibia, spine, ribs, calvarium, scapula and mandible. We concluded that $(^{99m}Tc-MDP)$ bone scintigraphy is sensitive imaging modality in leukemic patients with bone pain.

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Characteristics of thin film solar cell with patterns for diffuse light (광확산 패턴이 삽입된 박막형 실리콘 태양전지의 특성 변화)

  • Han, Kang-Soo;Jang, Ji-Hoon;Kim, Yang-Doo;Lee, Jeong-Chul;Lee, Heon
    • 한국신재생에너지학회:학술대회논문집
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    • 2011.05a
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    • pp.126.1-126.1
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    • 2011
  • 박막형 태양전지의 효율 향상을 위하여 광확산 패턴이 형성된 기판을 제작하고 이를 이용하여 비정질 실리콘 박막 태양전지를 제작하였다. 나노 임프린트 방법을 사용하여 제작된 광확산 패턴은 불규칙한 마이크로-나노 크기의 미세구조를 가지고 있어 빛의 확산투과 비율을 향상시켜주는 역할을 하였다. 제작된 광확산 기판위에 TCO물질을 증착하고, PECVD법을 사용하여 비정질 실리콘 p-i-n 접합 구조를 형성하였다. 제작된 태양전지 소자를 1.5 AM의 조건에서 I-V 특성을 분석하였으며, 비교군으로 사용된 일본 Asahi 사의 U-type glass에 비해 높은 Jsc 값을 나타내었다. 또한 외부양자효율을 측정함으로써 광확산 패턴에 의한 양자효율 변화를 확인 할 수 있었다.

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The study of Design Surface Treatment Obtained Metal Color in Magnesium Alloy

  • Lee, Jung Soon;Lee, Hee Myoung
    • Applied Science and Convergence Technology
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    • v.26 no.2
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    • pp.21-25
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    • 2017
  • The shape of the reflection spectrum is complex and appears to overlap with several signals, because the surface state is uneven due to the natural oxide film, so that the spectrum becomes a complicated signal shape divided into regions 1 and 2 due to diffuse reflection. On the other hand, it is seen that the reflection spectrum after PEO surface treatment is overlapped with several signals. In addition, the reflectance of the energy band varies from 1.32 to 1.46 eV. Usually, the MgO-type oxide film was observed at an energy band of ~4.2 eV. The thickness of the oxide film was increased as the DC voltage was increased by the thin film thickness meter (QuaNix; 7500M) after Plasma Electrolytic Oxidation (; PEO) surface treatment. This is because the higher the DC voltage, the easier the binding of the $OH^-$ ions in the solution solution and the $Mg^+$ ions of the magnesium alloy. An important part of the bonding of ordinary ions is the energy source (plasma) which can promote bonding. However, when a certain threshold voltage or more is applied, the material is adversely affected. The oxide film of the surface may be destroyed without increasing the thickness of the oxide film, that is, whitening of the material may occur.

A Study of Cu-doped CdS thin film by E-beam (E-beam 제작된 Cu-doped CdS 박막에 관한 연구)

  • Kim, Seong-Ku;Park, Gye-Choon;Jo, Jae-Cheol;Jung, Woon-Jo;Rye, Yong-Tek
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 1992.11a
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    • pp.67-72
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    • 1992
  • In this paper, We prepared the thin film Cu-doped CdS Photovoltaic Cell, varying deposition condition by E-beam process and investigated its properties. After the Cu/CdS films were deposited on transparent ITO glass. We heat-treated to diffuse Cu atoms to CdS fi1m at 350[$^{\circ}C$]. With deposited Cu-doped CdS film. We investigated the electrical. optical. X-ray diffraction and junction property. We studied how to prepare the High conversion efficiency Solar cell window layer.

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