• Title/Summary/Keyword: differential thermal analysis

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Thermo-mechanical analysis of carbon nanotube-reinforced composite sandwich beams

  • Ebrahimi, Farzad;Farazamandnia, Navid
    • Coupled systems mechanics
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    • v.6 no.2
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    • pp.207-227
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    • 2017
  • In this paper Timoshenko beam theory is employed to investigate the vibration characteristics of functionally graded carbon nanotube-reinforced composite (FG-CNTRC) Beams with a stiff core in thermal environment. The material characteristic of carbon nanotubes (CNT) are supposed to change in the thickness direction in a functionally graded form. They can also be calculated through a micromechanical model where the CNT efficiency parameter is determined by matching the elastic modulus of CNTRCs calculated from the rule of mixture with those gained from the molecular dynamics simulations. The differential transform method (DTM) which is established upon the Taylor series expansion is one of the effective mathematical techniques employed to the differential governing equations of sandwich beams. Effects of carbon nanotube volume fraction, slenderness ratio, core-to-face sheet thickness ratio, different thermal environment and various boundary conditions on the free vibration characteristics of FG-CNTRC sandwich beams are studied. It is observed that vibration response of FG-CNTRC sandwich beams is prominently influenced by these parameters.

Kinetics on the Thermal Decomposition of Cellulose (셀룰로오스의 열분해 반응속도론)

  • 최승찬;박영수
    • Journal of the Korean Society of Tobacco Science
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    • v.5 no.2
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    • pp.55-62
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    • 1983
  • Four of non- isothermal methods evaluating kinetics have been studied by using differential scanning calorimetry (DSC) and thermogravimetry (TG) and applied for kinetics of the thermal decomposition of cellulose. It is concluded that the heating evolution methods with DSC and approximative methods with TC can lead to satisfactory kinetic analysis. Results calculating the reacting order and the activation energy of cellulose decomposition were 1/2 order and 42kcaB/mol, respectively.

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Improvement of the T-history Method to Measure Heat of Fusion for Phase Change Materials

  • Hong, Hi-Ki;Park, Chang-Hyun;Choi, Ju-Hwan;Peek, Jong-Hyeon
    • International Journal of Air-Conditioning and Refrigeration
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    • v.11 no.1
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    • pp.32-39
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    • 2003
  • Though conventional calorimetry methods such as differential scanning calorimetry and differential thermal analysis are used generally in measuring heat of fusion, T-history method has advantages of a simple experimental apparatus and no requirements of sampling process, which is particularly useful for measuring thermophyical properties of in-homogeneous phase change materials in sealed tubes. However, the degree of supercooling used in selecting a range of latent heat release and neglecting sensible heat during the phase change process can cause significant errors in determining the heat of fusion. In the present study, it was shown that a 40% discrepancy exists between the original T-history and the present methods when analyzing the same experimental data. As a result, a reasonable modification to the original T-history method is proposed.

Nonlinear thermal vibration of FGM beams resting on nonlinear viscoelastic foundation

  • Alimoradzadeh, M.;Akbas, S.D.
    • Steel and Composite Structures
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    • v.44 no.4
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    • pp.557-567
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    • 2022
  • Nonlinear free vibration analysis of a functionally graded beam resting on the nonlinear viscoelastic foundation is studied with uniform temperature rising. The non-linear strain-displacement relationship is considered in the finite strain theory. The governing nonlinear dynamic equation is derived based on the finite strain theory with using of Hamilton's principle. The Galerkin's decomposition technique is utilized to discretize the governing nonlinear partial differential equation to nonlinear ordinary differential equation and then is solved by using of multiple time scale method. The influences of temperature rising, material distribution parameter, nonlinear viscoelastic foundation parameters on the nonlinear free response and phase trajectory are investigated. In this paper, it is aimed that a contribution to the literature for nonlinear thermal vibration solutions of a functionally graded beam resting on the nonlinear viscoelastic foundation by using of multiple time scale method.

Study of Thermal Ageing Behavior of the Accelerated Thermally Aged Chlorosulfonated Polyethylene for Thermosetting Analysis (열경화성 분석을 위한 가속열화 된 Chlorosulfonated Polyethylene의 경년특성 연구)

  • Shin, Yong-Deok
    • The Transactions of The Korean Institute of Electrical Engineers
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    • v.66 no.5
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    • pp.800-805
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    • 2017
  • The accelerated thermal ageing of CSPE (chlorosulfonated polyethylene) was carried out for 16.82, 50.45, and 84.09 days at $110^{\circ}C$, equivalent to 20, 60, and 100 years of ageing at $50^{\circ}C$ in nuclear power plants, respectively. As the accelerated thermally aged years increase, the insulation resistance and resistivity of the CSPE decrease, and the capacitance, relative permittivity and dissipation factor of those increase at the measured frequency, respectively. As the accelerated thermally aged years and the measured frequency increase, the phase degree of response voltage vs excitation voltage of the CSPE increase but the phase degree of response current vs excitation voltage decrease, respectively. As the accelerated thermally aged years increase, the apparent density, glass transition temperature and the melting temperature of the CSPE increase but the percent elongation and % crystallinity decrease, respectively. The differential temperatures of those are $0.013-0.037^{\circ}C$ and, $0.034-0.061^{\circ}C$ after the AC and DC voltages are applied to CSPE-0y and CSPE-20y, respectively; the differential temperatures of those are $0.011-0.038^{\circ}C$ and $0.002-0.028^{\circ}C$ after the AC and DC voltages are applied to CSPE-60y and CSPE-100y, respectively. The variations in temperature for the AC voltage are higher than those for the DC voltage when an AC voltage is applied to CSPE. It is found that the dielectric loss owing to the dissipation factor($tan{\delta}$) is related to the electric dipole conduction current. It is ascertained that the ionic (electron or hole) leakage current is increased by the partial separation of the branch chain of CSPE polymer as a result of thermal stress due to accelerated thermal ageing.

A Study of Thermal Properties of LDPE-Nanoclay Composite Films

  • Bumbudsanpharoke, Nattinee;Ko, Seonghyuk
    • KOREAN JOURNAL OF PACKAGING SCIENCE & TECHNOLOGY
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    • v.21 no.3
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    • pp.107-113
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    • 2015
  • This work focused on the study of thermal properties and kinetic behavior of LDPE-nanoclay composite films. The effect of nanoclay content (0.5, 1, 3, and 5 wt%) on thermal stability and crystallization characteristics of the nanocomposites were investigated by Thermogravimetric Analysis (TGA) and Differential Scanning Calorimetry (DSC). The results from endothermic curve showed that the nanoclay played an important role in the crystallization of nanocomposites by acting as nucleating agent. From exothermic curve, there was a crystallization temperature shift which was attributed to crystallization process induced by nanoclay. The TGA results showed that the addition of nanoclay significantly increased the thermal stability of LDPE matrix, which was likely due to the characteristic of layered silicates/clays dispersed in LDPE matrix as well as the formation of multilayered carbonaceous-silicate char. A well-known Coats-Redfern method was used to evaluate the decomposition activation energy of nanocomposite. It was demonstrated that introducing of nanoclay to LDPE matrix escalated the activation energy of nanocomposite decomposition resulting in thermal stability improvement.

A Study on Electrical and Thermal Properties of Polyimide/MWNT Nanocomposites

  • Park, Soo-Jin;Chae, Sung-Won;Rhee, John-Moon;Kang, Shin-Jae
    • Bulletin of the Korean Chemical Society
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    • v.31 no.8
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    • pp.2279-2282
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    • 2010
  • In this work, the electrical and thermal properties of polyimide/multi-walled carbon nanotube (MWNT) nanocomposites were investigated. The polyimide/MWNT nanocomposites contained from 0 to 2.0 wt % of MWNT. The electrical properties of the polyimide films were characterized by a specific resistance measurement. The thermal properties were evaluated using thermogravimetric analysis (TGA) and a differential scanning calorimeter (DSC). It was found that the thermal properties of the polyimide nanocomposites increased with increasing MWNT content and specific resistance as well. This result indicated that the crosslinking of polyimide/MWNT nanocomposites was enhanced by good distribution of the MWNT in the polyimide resins, resulting in the increase of the electrical and thermal properties of the nanocomposites.

The Thermal Diffusivity of Standard Pieces for Spark Test (불꽃試驗용 標準試片 의 熱擴散 係數)

  • 차경옥;이관수;이흥주
    • Transactions of the Korean Society of Mechanical Engineers
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    • v.7 no.3
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    • pp.319-327
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    • 1983
  • The thermal diffusivity one of the series of standard pieces for spark test are determined by the flash method. The standard pieces are composed with carbon steels, structural carbon steels, alloy steels and high speed tool steels. In order to compute the thermal conductivity of the standard pieces, their specific heats are measured by a differential scanning calorimeter. The thermal conductivities are calculated from the data of specific heat, density and thermal diffusivity. To increase the accuracy of data for the thermal diffusivity by data reduction excursion method in the flash method, the governing heat diffusion equation, which is closely described experimental conditions with the finite pulse and the heat loss from the sample surfaces, is solved. In this analysis an integral transform is used.

Analysis of Thermal Distribution and Compensation of Error for Spindle of Machining Center (공작기계 스핀들 부위의 열분포 분석 및 오차 보정)

  • Ko, H.S.;Park, K.H.;Seo, H.R.;Ha, J.S.
    • Proceedings of the KSME Conference
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    • 2004.04a
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    • pp.1352-1357
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    • 2004
  • Thermal error compensation has been developed for CNC (Computer Numerical Control) machining center with moving heat sources. The thermal error in CNC machining center has an effect on machining accuracy more than the geometric error does. Thus, temperature distributions of a spindle unit have been analyzed numerically by a Finite Differential Method and experimentally by an infrared (IR) camera in this study. A multiple variable method has been derived to estimate the thermal deformation of the machine origin stably and effectively after measuring deformation and temperature data. The experimental results for a vertical machining center have shown that the thermal errors of the machine origins were reduced more than 30% by the developed method.

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Effects of Methacrylamide Treatment on Silk Fibers II. Thermal Behavior of Methacrylamide-treated Silk Fibers (견섬유에 대한 메타크릴아미드의 처리효과 II. 메타크릴아미드 처리견의 열적 거동에 관하여)

  • 신봉섭;남중희
    • Journal of Sericultural and Entomological Science
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    • v.34 no.1
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    • pp.49-56
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    • 1992
  • Treatment of vinyl monomers onto silk fiber modifies the properties of the original silk fiber considerably. This field has been the subject of investigation by many workers using chemical and radiation initiation. Many studies on the reaction conditions, polymerization mechanism, physical properties and practical performances of methacrylamide-treated silk fiber have been continued. However, the polymerization mechanism has not been clearly revealed yet and this remains ambiguously whether the grafting is formed on fiber or not. In general, it has been accepted that free radicals were formed and vinyl monomers were polymerized in silk fibroin by graft polymerization mechanism, while active sties were varied by the types of monomer and initiator as well as by the reaction conditions. On the other hand, there is another argument on polymerization mechanism, in which monomers are polymerized and impregnated in the internal side of the fiber by homopolymerization. Though a large number of analytical methods are used to examine the polymerization mechanism of methacrylamide-treated silk fiber, the results on the basis of thermal analysis are merely reported in this paper. In differential scanning calorimetry (DSC) analysis, the thermal decomposition behaviors of the methacrylamie-treated silk fibers were determined and compared to those of the controlled silk fibers. DSC curves obtained from the methacrylamide-treated silk fibers showed double peaks at around 290$^{\circ}C$ (A peak) and 320$^{\circ}C$ (B peak) which are attributed to the thermal decomposition of the methacrylamide polymer and silk fibroin fiber, respectively. The temperature of A and B peak shifted to higher value with the increase of add-on. Also, the moisture regain of the treated silk fibers increased with add-on.

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