• Title/Summary/Keyword: diborides

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Effect of Boron on Electrical and Thermal Conductivities of Aluminum (알루미늄의 전기 및 열전도도에 미치는 Boron의 영향)

  • Park, Min-Kyung;Cho, Jae-Ik;Lee, Seong-Hee;Kim, Cheol-Woo
    • Journal of Korea Foundry Society
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    • v.36 no.5
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    • pp.147-152
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    • 2016
  • Aluminum has been used as an alternative material for copper, due to its good electrical and thermal conductivities. However, small quantities of transition elements such as Ti and V affect the conductivities of aluminum. Therefore, in this study, the influence of B addition to reduce the effects of Ti and V on the conductivities of aluminum was investigated. Both the electrical and thermal conductivities of aluminum were improved with addition of B up to 0.05 wt%, while the conductivities were gradually reduced with an excess amount of B. SEM-EDS and XRD results exhibited that B reacted with Ti and V element to form diborides, such as $TiB_2$ and $VB_2$ phase, and those diborides tended to settle down to the bottom of the crucible because their densities were higher than that of aluminum melt. As a result, B reduced the deleterious effects of Ti and V, and the electrical and thermal conductivities of aluminum were improved.