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Geochemical Study on the Genesis of Chuncheon Nephrite Deposit (춘천 연옥의 기원에 관한 지구화학적 연구)

  • 박계현;노진환
    • The Journal of the Petrological Society of Korea
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    • v.9 no.2
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    • pp.53-69
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    • 2000
  • To reveal the origin of the Chuncheon nephrite deposit, radiogenic isotopes of Sr and Pb, stable isotopes of 0 and H, and rare earth elements concentrations were analyzed. Such geochemical data were integrated to track the stepwise changes during the various ore formation stages. All the samples from the nephrite deposit have significantly low 0 isotopic ratios compared with the marble from which they had been formed, which reflects the very important role of the crustal circulating water with low 6180 and 6D in every stage of ore formation. There were progressive decrease of 6180 and 6D during the genesis of Chuncheon nephrite deposit. Newly formed minerals during the ore formation reveal disequilibrium with existing minerals in the respect of 0 isotope, which suggests that the ore-forming fluid of circulating water origin was involved with significant water-rock ratios in every step of ore formation process. The ore samples have Sr and Pb isotopic ratios similar to the values of Kyeonggi gneiss complex within which the deposit is located, which also suggests the important role of crustal circulating water in the genesis of the deposit. In conclusion, all the geochemical data support that major portion of the ore-forming fluid of Chuncheon nephrite deposit was derived ultimately from the surface water of meteoric origin. The meteoric water supplied Sr and Pb through leaching the rocks surrounding the ore deposits.

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Genesis of the acidic metavolcanic rocks distributed around the Chungju iron deposit in the Gyemyeongsan Formation (계명산층 내의 충주 철광상 주변에 분포하는 산성 변성화산암의 성인)

  • Park Maeng-Eon;Kim Gun-Soo;Park Kye-Hun
    • The Journal of the Petrological Society of Korea
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    • v.14 no.3 s.41
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    • pp.169-179
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    • 2005
  • Acidic metavolcanic rocks distributed around the Chungju iron deposit show significantly high abundances of rare earth elements and high field strength elements. Relatively high ${\epsilon}_{Nd}$(0) values and lack of negative Nb anomaly suggest that assimilation of crustal material is not involved in their generation. They are plotted within the within-plate environment according the tectonic discrimination diagrams. Such geochemical characteristics are very similar to the acidic metavolcanic rocks of Munjuri Formation. They also show geochemical characteristics of Al-type magma of Eby (1992). All such diagnostic characters indicate differentiation of mantle-derived magma produced from the rift environment, related to the breakup of continent. In contrast to the alkali granites and the rare metal deposit both having age of c. 330 Ma, Sm-Nd isotopic data of the acidic metavolcanic rocks do not form well defined isochron. However, the alkali granites reveal low ${\epsilon}_{Nd}$(0) values, while the acidic metavolcanic rocks and the rare metal deposit both have significantly higher ${\epsilon}_{Nd}$(0) values. Considering such differences, we propose following generation hypothesis: The acidic metavolcanic rocks around Chungju iron deposit was erupted at 750 Ma as rest of the acidic metavolcanic rocks of Gyemyeongsan and Munjuri Formations. About 330 Ma ago, partial melting of existing Al-type igneous materials and some old crustal materials produced alkali granite. The rare metal deposit was also produced by redistribution of related materials within the acidic volcanics due to hydrothermal activities occurred at the same time. Sm-Nd isotopic systematics of the acidic metavolcanic rocks were disturbed during the regional metamorphic event at ca. 280 Ma.

Hydrothermal Gold Mineralization of the Sambo Deposit in the Muan Area, Korea (무안 지역, 삼보 광상의 금광화작용)

  • Pak, Sang-Joon;Choi, Seon-Gyu
    • Economic and Environmental Geology
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    • v.41 no.3
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    • pp.275-286
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    • 2008
  • The Sambo gold deposit located nearby the Cretaceous Hampyeong basin is composed of gold quartz fine vein(the Jija vein) within Cretaceous rhyolite showing $N10{\sim}20W$ trends as well as $N5{\sim}10E$ trending quartz veins(the Pungja, Gwangsan and Pungjaji veins) in Precambrian gneiss. The gold vein typically displays the intermittent and irregular fine veins within rhyolite. Electrum is disseminated in wallrock along the fine cracks as well as coexists with hematite replacing pyrite. Ore-forming fluids from the mineralized vein($H_2O/-NaCl$ system, Th; $340{\sim}200^{\circ}C$, Salinity <2.7 eq. wt.% NaCl) and NE-trending veins($H_2O-NaCl/-CO_2$ system, Th; $400{\sim}190^{\circ}C$, salinity <7.9 eq. wt.% NaCl) are featured by dissimilar physicochemical conditions but their fluid evolution trends(boiling and mixing) are similar with each other. Gold veins of the Sambo deposit filled along NNW-trending tension crack are related to pull-apart basin evolution. Selective gold mineralization of the deposit reflect to dissimilarity between two ore-forming fluid sources. Consequently, gold veining of the Sambo deposit formed at shallow-crustal level and could be categorized into epithermal-type gold deposit related to tensional fractures filling triggered by Cretaceous geodynamics.

Evaluation of Discharge Capacity of Upper Sand Deposit at the Nakdong River Estuary (낙동강 하구 상부퇴적사질토의 통수능 평가)

  • Jeong, Jin-Yeong;Kim, Tae-Hyung;Im, Eun-Sang;Hwang, Woong-Ki;Kim, Gyu-Jong
    • Journal of the Korean Geosynthetics Society
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    • v.16 no.2
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    • pp.109-119
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    • 2017
  • In this research, it was investigated that whether the upper sand deposited in Nakdong River Estuary Delta region has the role of horizontal drains like sand mat. The results from tests for particle size distribution and permeability of the upper sand deposit did not meet completely the criteria for the horizontal drain material. Thus, numerical analysis has been conducted additionally. Numerical analyses of consolidation of soft soils with upper layer of sand deposit are conducted in both the sand mat with a thickness of 1m and the upper sand deposit with 1, 2, 3, and 4 m of thickness and their results are compared. As the results of numerical analysis, the upper sand deposit with a thickness of 2m or more may play the role of horizontal drains similar to a sand mat. If a PVD is installed, the ability of upper sand deposit as horizontal drains is increased. Form this study, it was concluded that the upper sand deposited in Nakdong River Estuary Delta has the role of horizontal drain.

The Characteristic Analysis of Calcareous Deposit Films Formed on Steel Plate by Cathodic Current Process in Marine Environment (해양환경 중 음극전류 프로세스에 의해 강판에 형성된 석회질 피막의 특성 분석)

  • Park, Jun-Mu;Kang, Jae Wook;Choi, In-Hye;Lee, Seung-Hyo;Moon, Kyung-Man;Lee, Myeong-Hoon
    • Journal of the Korean institute of surface engineering
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    • v.49 no.2
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    • pp.166-171
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    • 2016
  • Cathodic protection is widely recognized as the most cost effective and technically appropriate corrosion prevention methodology for the port, offshore structures, ships. When applying the cathodic protection method to metal facilities in seawater, on the surface of the metal facilities a compound of calcium carbonate($CaCO_3$) or magnesium hydroxide($Mg(OH)_2$) films are formed by $Ca^{2+}$ and $Mg^{2+}$ ions among the many ionic components dissolving in the seawater. And calcareous deposit films such as $CaCO_3$ and $Mg(OH)_2$ etc. are formed by the surface of the steel product. These calcareous deposit film functions as a barrier against the corrosive environment, leading to a decrease in current demand. On the other hand, the general calcareous deposit film is a compound like ceramics. Therefore, there may be some problems such as weaker adhesive power and the longer time of film formation uniting with the base metal. In this study, we tried to determine and control the optimal condition through applying the principle of cathodic current process to form calcareous deposit film of uniform and compact on steel plate. The quantity of precipitates was analyzed, and both the morphology, component and crystal structure were analyzed as well through SEM, EDS and XRD. And based on the previous analysis, it was elucidated mechanism of calcareous deposit film formed in the sacrificial anode type (Al, Zn) and current density (1, 3, $5A/m^2$) conditions. In addition, the taping test was performed to evaluate the adhesion.

The Effect of Nitrogen Supply on Tomato Plants by NH4-Beaker-Deposits (토마토에 대한 NH4-Beaker Deposit 비료의 질소공급 효과)

  • Chang, Kyong-Ran;Somrner, Karl
    • Korean Journal of Soil Science and Fertilizer
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    • v.33 no.1
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    • pp.8-14
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    • 2000
  • Long term cultivation crops like tomato, capsicum, melon etc. demand much amount of continuous supplying of nutrition during the whole growing periods. It is not easy to cover satisfactorily the nutritional demands for them by splitted top dressings, slow release fertilizer applications and fertigation systems. To overcome these problems, the "CULTAN" (Controlled Uptake Long Term Ammonium Nutrition) Beaker Deposit techniques have been developed and it was put into PVC beaker with the combined nitrogen fertilizer type mixed with the ratio of one-third of ammonium sulfate-N and two-thirds of urea-N, in which nitrogen was loaded on the demanding amount of a tomato plant during the growing period. Gypsum was mixed as a binder, and loamy soil and compost were used as a diffusion regulator. It was placed upside down into root zone of tomato at the transplanting. Tomato roots were spreaded into the Deposit beaker by ammonium ions which attract root growth. The tomato fruit yield and nitrogen uptake by plant were increased by application of $NH_4$-Beaker deposit fertilizer rather than those of common fertilizer treatment. In conclusion, it was able to improve economic and ecological benefits through CULTAN system compared with common fertilization systems. CULTAN system was estimated as a prospective alternative to enhance productivity and minimize nutrient lose. In addition, it shows further developing possibility of CULTAN system by the supplement of micro-nutrients and pesticides in the macro-nutrient beaker deposits.

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Spatio-Temporal Variation of Polymetallic Mineralization in the Wooseok Deposit (우석광상 다금속 광화작용의 시공간적 특성변화)

  • Im, Heonkyung;Shin, Dongbok;Jeong, Junyeong;Lee, Moontaek
    • Economic and Environmental Geology
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    • v.51 no.6
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    • pp.493-507
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    • 2018
  • The Wooseok deposit in Jecheon belongs to the Hwanggangri Mineralized Distict of the northeastern Ogcheon Metamorphic Belt. Its geology consists mostly of limestone of the Choseon Supergroup and the Cretaceous Muamsa granite intruded at the eastern area of the deposit. The deposit shows vertical occurrence of skarn and hydrothermal vein ores with W-Mo-Fe and Cu-Pb-Zn mineralization and skarn is developed only at lower levels of the deposit. Skarn minerals are replaced or cut by ore minerals in paragenetic sequence of magnetite-hematite, molybdenite-scheelite-wollframite, and higher abundances of pyrrhotite-chalcopyrite-pyrite-sphalerite-galena. Garnet has chemical compositions of $Ad_{65.9-97.8}Gr_{0.3-32.0}Pyr_{0.9-3.0}$, corresponding to andradite series, and pyroxene compositions are $Hd_{4.5-49.7}Di_{42.3-93.9}Jo_{0.5-7.9}$, prevailing in diopside compositions, both of which suggest oxidized conditions of skarnization. On the FeS-MnS-CdS ternary diagram, FeS contents of sphalerite in vein ores decrease with increasing MnS contents from bottom to top levels, possibly relating to W mineralization in deep and Pb-Zn mineralization in shallow level. Sulfur isotope values of sulfide minerals range from 5.1 to 6.8‰, reflecting magmatic sulfur affected by host rocks. W-Mo skarn and Pb-Zn vein mineralization in the Wooseok deposit were established by spatio-temporal variation of decreasing temperature and oxygen fugacity with increasing sulfur fugacity from bottom to top levels.

The Holocene tidal sedimentary changes in Mosan Bay Estuary, Korea (홀로세 충남 모산만 하구역내 간석지의 퇴적과정)

  • Shin, Young Ho
    • Journal of The Geomorphological Association of Korea
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    • v.18 no.3
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    • pp.37-51
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    • 2011
  • Geomorphic changes and sedimentary changes are investigated by sediment analysis from estuarine tidal flat, Mosan Bay Estuary, which is a tide-dominated and rias estuary. Sediments separatedly deposited during the early Holocene and the late Holocene. There are unconformities between the early Holocene sediment unit and the late Holocene sediment unit. Developments of these unconformities were related with fluctuated sea level change during the mid Holocene. Three deposit zones are spatially classified, which are named "intermittent tide channel deposit zone"(A1, B1, D3), "flood-dominated deposit zone"(A3, B3, C1, C3), and "fluvial sediment deposit zone"(A2, B2). This classification is explained by three main effects; laterally restricted migration of a tidal channel, diffract flood effect and settling lag effect, and fluvial induced reworking. These effects are deserved as main factors which have formed estuarine geomorphology in tidedominated and rias estuary. This study suggests research directions in reconstructing estuarine geomorphic and sedimentary change in west coast of Korea. Furthermore, it gives useful data for making a "land-ocean interaction" model for west coast of Korea.

A New Test Method to Evaluate Potential White Pitch Deposit - Influence of pH and calcium hardness - (백색 점착성 이물질을 측정하기 위한 새로운 시험법 - pH와 칼슘경도의 영향 -)

  • Shin, Eun-Ju;Choi, Tae-Ho;Song, Bong-Keun;Cho, Byoung-Uk;Ryu, Jeong-Yong
    • Journal of Korea Technical Association of The Pulp and Paper Industry
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    • v.41 no.2
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    • pp.26-33
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    • 2009
  • A new testing method to evaluate the deposition potential of white pitch was developed. The new method involves depositing the potential white pitch particles on the air bubble covered plastic film in the pitch deposit tester (PDT) developed by KRICT and analysing the deposited area of white pitch using an image analyzer. In addition, the effect of two important factors (pH and calcium hardness) on white pitch deposition potential was elucidated. When pH of the coated broke stock was increased from neutral to alkali or the calcium hardness of the stock was decreased, the pitch deposit area was decreased, implying that these two factors have to be controlled during the evaluation of pitch deposition potential. It was found that hydrophobicity of the surface of latex binding films repulped is a key factor influencing white pitch deposition.

A Study on a Compression Index for Settlement Analysis of SCP Treated Ground Using Back Analysis (역해석을 이용한 모래다짐말뚝(SCP)으로 개량된 연약점토지반의 압축지수 결정에 관한 연구)

  • Hwang, Sungpil;Im, Jongchul;Kwon, Jeonggeun;Kang, Yeounike;Joo, Ingon
    • Journal of the Korean GEO-environmental Society
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    • v.11 no.7
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    • pp.5-14
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    • 2010
  • The paper processed settlement analysis using Finite Elements Method(FEM). Because Stress Distribution Ratio has to be decreased, for settlement analysis of soft clay deposit improved by sand compaction piles(SCP). Back analysis was processed comparing the measured settlements of laboratory model tests and finite element analysis where the SCP treated area was assumed as mixed ground with clay deposit rather than being a composite ground. The paper proposes a methodology which employs a compression index($C_c$) for settlement analysis of soft clay deposit improved by sand compaction piles from the back analysis. This approach is applied to a field measurement case(A revetment founded on the SCP improved clay deposit with the replacement ratio of 45%).