• 제목/요약/키워드: density evolution

검색결과 488건 처리시간 0.028초

아연-공기 전지용 음극재의 자가방전 억제 효과 (Effect of Zinc Based Anodes on Self-Discharge Behavior for Zinc-Air Batteries)

  • 정민서;조용남
    • 한국재료학회지
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    • 제30권12호
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    • pp.709-714
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    • 2020
  • For zinc-air batteries, there are several limitations associated with zinc anodes. The self-discharge behavior of zinc-air batteries is a critical issue that is induced by corrosion reaction and hydrogen evolution reaction (HER) of zinc anodes. Aluminum and indium are effective additives for controlling the hydrogen evolution reaction as well as the corrosion reaction. To enhance the electrochemical performances of zinc-air batteries, mechanically alloyed Zn-Al and Zn-In materials with different compositions are successfully fabricated at 500rpm and 5h milling time. Investigated materials are characterized by X-ray diffractometer (XRD), field emission scanning electron microscope (FE-SEM), and energy dispersive spectrometer (EDS). Alloys are investigated for the application as novel anodes in zinc-air batteries. Especially, the material with 3 wt% of indium (ZI3) delivers 445.37 mAh/g and 408.52 mAh/g of specific discharge capacity with 1 h and 6 h storage, respectively. Also, it shows 91.72 % capacity retention and has the lowest value of corrosion current density among attempted materials.

탄소나노튜브/흑연펠트 전극의 산소작용기를 활용한 바나듐 레독스 흐름 전지의 수소발생 억제 효과 (Suppressing Effect of Hydrogen Evolution by Oxygen Functional Groups on CNT/ Graphite Felt Electrode for Vanadium Redox Flow Battery)

  • 김민성;고민성
    • 한국표면공학회지
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    • 제54권4호
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    • pp.164-170
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    • 2021
  • Vanadium redox flow batteries (VRFB) have emerged as large-scale energy storage systems (ESS) due to their advantages such as low cross-contamination, long life, and flexible design. However, Hydrogen evolution reaction (HER) in the negative half-cell causes a harmful influence on the performance of the VRFB by consuming current. Moreover, HER hinders V2+/V3+ redox reaction between electrode and electrolyte by forming a bubble. To address the HER problem, carbon nanotube/graphite felt electrode (CNT/GF) with oxygen functional groups was synthesized through the hydrothermal method in the H2SO4 + HNO3 (3:1) mixed acid solution. These oxygen functional groups on the CNT/GF succeed in suppressing the HER and improving charge transfer for V2+/V3+ redox reaction. As a result, the oxygen functional group applied electrode exhibited a low overpotential of 0.395 V for V2+/V3+ redox reaction. Hence, this work could offer a new strategy to design and synthesize effective electrodes for HER suppression and improving the energy density of VRFB.

Phase-field simulation of radiation-induced bubble evolution in recrystallized U-Mo alloy

  • Jiang, Yanbo;Xin, Yong;Liu, Wenbo;Sun, Zhipeng;Chen, Ping;Sun, Dan;Zhou, Mingyang;Liu, Xiao;Yun, Di
    • Nuclear Engineering and Technology
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    • 제54권1호
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    • pp.226-233
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    • 2022
  • In the present work, a phase-field model was developed to investigate the influence of recrystallization on bubble evolution during irradiation. Considering the interaction between bubbles and grain boundary (GB), a set of modified Cahn-Hilliard and Allen-Cahn equations, with field variables and order parameters evolving in space and time, was used in this model. Both the kinetics of recrystallization characterized in experiments and point defects generated during cascade were incorporated in the model. The bubble evolution in recrystallized polycrystalline of U-Mo alloy was also investigated. The simulation results showed that GB with a large area fraction generated by recrystallization accelerates the formation and growth of bubbles. With the formation of new grains, gas atoms are swept and collected by GBs. The simulation results of bubble size and distribution are consistent with the experimental results.

Statistical Analysis of Interacting Dark Matter Halos: On two physically distinct interaction types

  • An, Sung-Ho;Kim, Juhan;Moon, Jun-Sung;Yoon, Suk-Jin
    • 천문학회보
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    • 제46권1호
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    • pp.28.1-28.1
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    • 2021
  • We present a statistical analysis of dark matter halos with interacting neighbors using a set of cosmological simulations. We classify the neighbors into two groups based on the total energy (E12) of the target-neighbor system; flybying neighbors (E12 ≥ 0) and merging ones (E12 < 0). First, we find a different trend between the flyby and merger fractions in terms of the halo mass and large-scale density. The flyby fraction highly depends on the halo mass and environment, while the merger fraction show little dependence. Second, we measure the spin-orbit alignment, which is the angular alignment between the spin of a target halo (${\vec{S}}$ ) and the orbital angular momentum of its neighbor (${\vec{L}}$). In the spin-orbit angle distribution, the flybying neighbors show a weaker prograde alignment with their target halos than the merging neighbors do. With respect to the nearest filament, the flybying neighbor has a behavior different from that of the merging neighbor. Finally, we discuss the physical origin of two interaction types.

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Enhancing Irregular Repetition Slotted ALOHA with Polarization Diversity in LEO Satellite Networks

  • Su, Jingrui;Ren, Guangliang;Zhao, Bo;Ding, Jian
    • KSII Transactions on Internet and Information Systems (TIIS)
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    • 제14권9호
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    • pp.3907-3923
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    • 2020
  • An enhanced irregular repetition slotted ALOHA (IRSA) protocol is proposed by using polarization characteristic of satellite link and MIMO detection in low earth orbit (LEO) satellite networks, which is dubbed polarized MIMO IRSA (PM-IRSA). In the proposed scheme, one or two packets in one slot can be decoded by employing polarized MIMO detection, and more than two collided packets in multiple slots which can construct the virtual MIMO model can be decoded by the MIMO detection algorithm. The performance of the proposed scheme is analyzed with the density evolution (DE) approach and the degree distribution is optimized to maximize the system throughput by using a differential evolution. Numerical results certify our analysis and show that the normalized throughput of the proposed PM-IRSA can achieve 1.89 bits/symbol.

The Key role of the Bulge Compactness in Star-forming Activity in Late-type Galaxies

  • Jee, Woong-bae;Yoon, Suk-Jin
    • 천문학회보
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    • 제40권2호
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    • pp.32.2-32.2
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    • 2015
  • Which mechanism governs star-formation activity in galaxies is still one of the most important, open questions in galactic astronomy. To address this issue, we investigate the specific star formation rate (sSFR) of late-type galaxies as functions of various structural parameters including the morphology, mass, radius, and mass compactness (MC). We use a sample of ~200,000 late-type galaxies with z = 0.02 ~ 0.2 from SDSS DR7 and a catalog of bulge-disk decomposition (Simard et al. 2011; Mendel et al. 2013). We find a remarkably strong correlation between bulge's MC and galaxy's sSFR, in the sense that galaxies with more compact bulge tend to be of lower sSFR. This seems counter-intuitive given that galactic sSFR is driven predominantly by disks rather than bulges and suggests that the central mass density plays a key role in recent star-forming activity. We discuss the physical cause of the new findings in terms of the bulge growth history and AGN activities.

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Unstructured Moving-Mesh Hydrodynamic Simulation

  • Yun, Kiyun;Kim, Juhan;Yoon, Suk-Jin
    • 천문학회보
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    • 제39권2호
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    • pp.65.2-65.2
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    • 2014
  • We present a new hydrodynamic simulation code based on the Voronoi tessellation for estimating the density precisely. The code employs both of Lagrangian and Eulerian description by adopting the movable mesh scheme, which is superior to the conventional SPH (smoothed particle hydrodynamics) and AMR (adaptive mesh refinement) schemes. The code first generates unstructured meshes by the Voronoi tessellation at every time step, and then solves the Riemann problem for all surfaces of each Voronoi cell so as to update the hydrodynamic states as well as to move current meshes. Besides, the IEM (incremental expanding method) is devised to compute the Voronoi tessellation to desired degree of speed, thereby the CPU time is turned out to be just proportional to the number of particles, i.e., O(N). We discuss the applications of our code in the context of cosmological simulations as well as numerical experiments for galaxy formation.

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An Ultraviolet Study of Star-Forming Regions in M33

  • Kang, Yongbeom;Rey, Soo-Chang;Bianchi, Luciana
    • 천문학회보
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    • 제41권2호
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    • pp.62.3-63
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    • 2016
  • We studied the young stellar populations of star-forming (SF) regions in M33 based on the Galaxy Evolution Explorer (GALEX) ultraviolet (UV) imaging data. The SF regions are defined from far-UV data with various thresholds. We examined the reddening and spatial distribution of hot massive stars within SF regions from Hubble Space Telescope multi-band survey and Local Group Galaxy Survey (LGGS) data. The H-alpha sources from the LGGS are used for comparing with the spatial distribution of SF regions. The GALEX UV flux measurements of SF regions are used to derive their ages and masses. We also estimated the size and density of SF regions. The younger and compact SF regions are often arranged within older and sparser SF complexes. The results allow us to understand the hierarchical star formation and recent evolution of M33.

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액체 필름 끝단에서의 유동특성에 관한 수치연구 (Blob and Wave Formation at the Free Edge of an Initially Stationary fluid Sheet)

  • 송무석;안자일
    • 대한기계학회:학술대회논문집
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    • 대한기계학회 2002년도 학술대회지
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    • pp.307-310
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    • 2002
  • A two-dimensional numerical method for inviscid two-fluid flows with evolution of density interface is developed, and an initially stationary two-dimensional fluid sheet surrounded by another fluid is studied. The Interface between two fluids is modeled as a vertex sheet, and the flow field u÷th the evolution of interface is solved by using vortex-in-cell/front-tracking method. The edge of the sheet Is pulled back into the sheet due to surface tension and a blob is formed at the edge. This blob and fluid sheet are connected by a thin neck. In the inviscid limit, such process of the blob and neck formation is examined in detail and their kinematic characteristics are summarized with dimensionless parameters. The edge recedes at $V=1.06({\sigma}/{\rho}h)^{0.5}$ and the capillary wave Propagating into the fluid sheet must be considered for bettor understanding of the edge receding.

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Simulation of the SDSS Survey Region of the Universe

  • Park, Chang-Bom;Van De Weygaert, Rien;Wojceich, Hellwing;Kim, Ju-Han
    • 천문학회보
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    • 제35권2호
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    • pp.43.2-43.2
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    • 2010
  • We reconstruct the large-scale initial density field from the distribution of galaxies observed by the Sloan Digital Sky Survey (SDSS). After adding the small-scale fluctuations to match the power spectrum to that of the standard LCDM model, we make a cosmological N-body simulation of formation of structures from the initial conditions. Properties of the objects formed in the simulation can be statistically compared with those of the observed SDSS galaxies. The simulation makes it possible to know the past history of evolution of objects located in different environments, and also gives us information on the environmental parameters that cannot be directly obtained observationally. It is hoped that this comparative study leads us to better understanding of formation and evolution of galaxies in conjunction with large-scale structures in the universe.

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