• Title/Summary/Keyword: delayed absorption

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Thermal Energy Storage and Release Characteristics of the Soil in the Greenhouse Equipped with Heat Pump and Latent Heat Storage System (열펌프-잠열축열 시스템 온실에서 토양의 열저장 및 방열 특성)

  • 노정근;송현갑
    • Journal of Biosystems Engineering
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    • v.27 no.1
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    • pp.39-44
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    • 2002
  • In order to obtain the information of bio-environment control, the thermal characteristics of soil in the greenhouse heated by the heat pump and latent heat storage system were experimentally analyzed. The experimental systems were composed of the greenhouse with a heat pump and a latent heat storage system (system I), the greenhouse with a heat pump (system II), the greenhouse with a latent heat storage system (system III), and the greenhouse without auxiliary heating system (system IV). The thermal characteristics experimentally analyzed in each system were temperature of soil layers, soil heat storage and release, soil heat capacity and soil heat storage ratio. The results could be summarized as follows. 1. Time to reach the highest temperature at 20cm deep in soil layers of the crop routs in case of system I was shown to be delayed by 6 hours in comparison to the time of the highest temperature at the soil surface. 2. In the clear winter days, the stored heat capacity values fur the system I and the system II were shown to be 22.3% and 11.0% higher than the released heat capacity respectively, and the stored heat capacity values for the system III and the system IV were shown to be 6.2% and 29.6% lower than the released heat capacity respectively This confirms that the system I provided the best heat storage effect. j. The heat quantity values stored or released were shown to be highest at 5 cm depth of soil layers. And it was reduced with increasing of depth of soil layers until 20 cm and was not changed under the soil layer of 20 cm depth. 4. The heat absorption rates of soil, the ratio between supplied and stored heat energy, fur both the system I and system II were lower than 23%.

Analysis of Binodal Structures of Final State Distributions in Vibrational Predissociations of Triatomic van der Waals Molecules

  • 이천우
    • Bulletin of the Korean Chemical Society
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    • v.16 no.12
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    • pp.1193-1203
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    • 1995
  • In this work, we focused on the setup of the tools for the analysis of the final rotational state distribution of photofragments in vibrational predissociations of triatomic van der Waals molecules A-B2. We found that reflection principle used for the direct photodissociation processes can also be applied to find out the final rotational state distributions for indirect photodissociation processes. The quantity which represents the strength of rovibrational coupling between the quasi-bound state and the final state is reflected into the mirror of the classical angular momentum function, instead of the initial state before light absorption used in the reflection principle of direct processes. The sign change in the first derivative of the interaction potential with respect to the bond distance of B2 is found to be the source of the binodal structures in the final rotational distributions of photofragments in the model system studied in this work. In MQDT analysis, short range eigenchannel basis functions were found to be localized in angle, in the previous work [Lee, C.W. Bull. Korean Chem. Soc. 1995, 16, 957.] and may be called angle functions. Angle functions enjoy simple geometrical structures which have simple functional relations with the final state distributions of photofragments. Two processes take place along the angle functions which resemble the quasi-bound state and dominate over other processes. Two such angle functions are found to be not only localized angularly but also localized either one of ends of B2 in motions along the bond of B2. These dominating photodissociation processes, however, cancel each other. This cancellation causes photodissociation to depend sensitively on the interaction potential at other angles than the dominant one. Part of potential surface where much larger torque exists can now play an important role in photodissociation. MQDT also enables us to see which processes play important roles after cancellation. This is done by examining the amounts of time delayed by asymptotic eigenchannels.

Theoretical Study for Thermally Activated Delayed Fluorescence (TADF) Property in Organic Light-Emitting Diode (OLED) Candidates (유기발광소재(OLED) 후보물질의 지연형광(TADF) 성질에 대한 이론적 연구)

  • Seo, Hyun-il;Jeong, Hyeon Jin;Yoon, Byung Jin;Kim, Seung-Joon
    • Journal of the Korean Chemical Society
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    • v.63 no.3
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    • pp.151-159
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    • 2019
  • The TADF properties for carbazol-dicyanobenzene, carbazol-diphenyl sulfone, carbazol-benzonitrile derivatives as OLED candidate materials are theoretically investigated using density functional theory (DFT) with $6-31G^{**}$, cc-pVDZ, and cc-pVTZ basis sets. The optimized geometries, harmonic vibrational frequencies, and HOMO-LUMO energy separations are predicted at the B3LYP/$6-31G^{**}$ level of theory. The harmonic vibrational frequencies of the molecules considered in this study show all real numbers implying true minima. The time dependent density functional theory (TD-DFT) calculations have been also applied to investigate the absorption and emission wavelength (${\lambda}_{max}$), energy differences (${\Delta}E_{ST}$) between excited singlet ($S_1$) and triplet ($T_1$) states of candidate materials.

Explore the possible advantages of using thorium-based fuel in a pressurized water reactor (PWR) Part 1: Neutronic analysis

  • Galahom, A. Abdelghafar;Mohsen, Mohamed Y.M.;Amrani, Naima
    • Nuclear Engineering and Technology
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    • v.54 no.1
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    • pp.1-10
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    • 2022
  • This study discusses the effect of using 232Th instead of 238U on the neutronic characteristics and the main operating parameters of the pressurized water reactor (PWR). MCNPX version 2.7 was used to compare the neutronic characteristics of UO2 with (Th, 235U)O2 and (Th, 233U) O2. Firstly, the infinity multiplication factor (Kinf), thermal neutron flux, and power distribution have been studied for the investigated fuel types. Secondly, the effect of Gd2O3 and Er2O3 on the Kinf and on the radial thermal neutron flux and thermal power has been investigated to distinguish which of them is more suitable than the other in reactivity management. Thirdly, to illustrate the effectiveness of 232Th in decreasing the inventory of both the actinides and non-actinides, the concentration of plutonium (Pu) isotopes and minor actinides (MAs) has been simulated with the fuel burnup. Besides, due to their large thermal neutron absorption cross-section, the concentrations of 135Xe, 149Sm, and 151Sm with the fuel burnup have been investigated. Finally, the main safety parameters such as the reactivity worth of the control rods (ρCR), the effective delayed neutron fraction βeff, and the Doppler reactivity coefficient (DRC) were calculated to determine to which extent these fuel types achieve the acceptable limits.

A Basic Study to Use Recycled Limestone Powder as a Mixture for Secondary Concrete Products (재활용 석회석 분말을 콘크리트 2차제품 혼합재로 이용하기 위한 기초적 연구)

  • Jung, Jae-Ho
    • Journal of the Korean Recycled Construction Resources Institute
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    • v.9 no.4
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    • pp.413-418
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    • 2021
  • In this study, as a basic study to use recycled limestone powder as a secondary product mixture for concrete, it was found that the compressive and flexural strengths were equal to or slightly improved compared to Plain up to 10% and 20% of the RLP mixing ratio, but the strength was rather decreased at 30% mixing. As a result of the heat of hydration experiment, as the RLP mixing rate increased, the heat of hydration decreased, and the elapsed time of the maximum heat was also delayed. As a result of the drying shrinkage test, as the fine powder RLP filled the internal pores of the cement mortar, the drying shrinkage decreased as the mixing rate increased. The compressive strength, water absorption rate, and compressive strength after freezing and thawing of the concrete block mixed with RLP 20% all satisfied the group standard criteria of the Korea Concrete Industry Cooperative Federation, confirming the possibility of use as a mixed material.

Pharmacokinetics of thalidomide in dogs: can feeding affect it? A preliminary study

  • Pierini, Alessio;Sartini, Irene;Giorgi, Mario;Lebkowska-Wieruszewska, Beata;Lisowski, Andrzej;Poapolathep, Amnart;Marchetti, Veronica
    • Journal of Veterinary Science
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    • v.21 no.5
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    • pp.60.1-60.11
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    • 2020
  • Background: Tumor-associated neoangiogenesis is a crucial target for antitumor therapies. Thalidomide (TAL) is a promising anti-neoangiogenetic drug that has recently been used in the treatment of several malignancies in dogs. Objectives: The aim of the study was to assess the pharmacokinetics of TAL after single oral administration in dogs. Additionally, the influence of feeding on the pharmacokinetic profile of TAL in dogs has been preliminarily investigated. Methods: Six healthy adult female Labradors were enrolled according to a randomized single-dose, 2-treatment, 2-phase, paired 2 × 2 cross-over study design. The dogs were administered a single 400 mg capsule of TAL in fasted and fed conditions. Blood was collected from 15 min to 48 h after dosing, and TAL quantified in plasma by a validated high-performance liquid chromatography method. The pharmacokinetics of TAL were analyzed using a non-compartmental approach. Results: TAL concentration was quantifiable up to 10 h and 24 h after fasted and fed conditions, respectively. Cmax (fasted, 1.34 ± 0.12 ㎍/mL; fed, 2.47 ± 0.19 ㎍/mL) and Tmax (fasted, 3 h; fed, 10 h) differed substantially between the 2 groups. AUC and t1/2λz were significantly higher in fed (42.46 ± 6.64 mg × h/L; 17.14 ± 4.68 h) compared to fasted (12.38 ± 1.13 mg × h/L; 6.55 ± 1.25 h) dogs. The relative oral bioavailability of TAL for the fasted group was low (36.92% ± 3.28%). Conclusions: Feeding affects the pharmacokinetics of oral TAL in dogs, showing a delayed, but higher absorption with different rate of elimination. These findings are of importance in clinical veterinary settings, and represent a starting point for further related studies.

Reviewing the fireproofing of lightweight aerataed concrete for fire door interior cores (방화문 내부 심재용 경량기포콘크리트의 방화성 검토)

  • Hong, Sang-Hun;Kim, Bong-Joo;Jung, Ui-In;Kim, Hae-Nah;Park, Jun-Seo
    • Proceedings of the Korean Institute of Building Construction Conference
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    • 2023.11a
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    • pp.43-44
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    • 2023
  • Fire doors installed to prevent the spread of fire in buildings are made of paper honeycomb, glass wool, and other materials. Due to their high water absorption rate, they absorb ambient moisture and degrade, and their increased weight causes them to sag internally, creating voids that can warp in the event of a fire and allow flames to pass through. To overcome these issues, research is being conducted on the physical performance of lightweight aerated concrete. However, there is a lack of research on how to ensure fire resistance. Therefore, in this study, the backside temperature of lightweight aerated concrete formulations was measured and compared and analyzied with the physical performance. Since it is difficult to achieve low density by saturation alone, aerated concrete with EPS was produced, which resulted in a density reduction of 24'26%, but the strength increase per unit cement increase was 5'25%, which tended to be lower than the formulation without EPS. The results showed that the lightweight aerated concrete with EPS was 130~140℃ lower than the lightweight aerated concrete with EPS, which is believed to be due to the melting point of EPS delayed the heat diffusion. In the future, wo plan to conduct research to identify the optimal formulation for fire door core materials by varying the amount of EPS added and using industrial by-products to increase long-term strength.

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Studies on the Environmental Factors Affecting Growth and Tuber Formation of Eleocharis kuroguwai Ohwi (올방개(Eleocharis kuroguwai Ohwi)의 생장(生長)과 괴경형성(塊莖形成)에 미치는 환경요인(環境要因))

  • Ku, Y.C.;Choung, S.G.
    • Korean Journal of Weed Science
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    • v.13 no.1
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    • pp.44-54
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    • 1993
  • This experiment was conducted to understand the environmental factors affecting growth and tuber formation such as temperature, day length, tight intensity, water condition and cutting time of Eleocharis kuroguwai Ohwi. Plant height, shoot number and dry weight of E. kuroguwai were higher at high temperature, 25/$25^{\circ}C$ (day/night), while nitrogen content was higher at low temperature, 20/$15^{\circ}C$. Plant height was more affected by water temperature, while shoot number and dry weight were more affected by air temperature. Contents and absorption of nitrogen, phosphorus, and potassium in top parts of E. kuroguwai were higher under greater difference between air and water temperatures, i.e., 18/$28^{\circ}C$ and 28/$18^{\circ}C$. The number and weight of tubers were increased under greater difference between air and water temperatures, i.e, 18/$28^{\circ}C$ and 28/$18^{\circ}C$, while they were inhibited at low or high air/water temperatures (18/$18^{\circ}C$ or 28/$28^{\circ}C$). Tubers of E. kuroguwai were formed at 8-or 12-hour day length, however, no tuber was formed at l6-hour day length. Photoinductive period for tuber initiation of E. kuroguwai was between 30 and 45 days after emergence, and the induction period of short-day treatment was less than 10 days. Tuber number and weight were reduced by shading due to inhibition of the growth of top and underground parts. Number of days from planting to tuber initiation was shortned as planting time was delayed and plant height, dry weight, and tuber number were also reduced by delayed planting. Tuber number at l0 to 15cm water depth was decreased 63 to 75% as compared with 1 to 5cm water depth. Tuber number and dry weight were not affected by the size of tubers at planting. Due to the reduced growth of top and underground parts, tuber number and dry weight of E. kuroguwai were decreased by delayed shoot cutting. The critical cutting time to inhibit the growth of E. kuroguwai was about 70 days after emergence.

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Development of Alginate-Coated Rice and Its Quality (알긴산을 이용한 코팅쌀의 개발 및 품질 특성)

  • Park In-Bae;Lee Tae-Hoon;Lee Soo-Young;Chung Dong-Ok;Park Yang-Kyun;Kim Jeong-Mok;Jung Soon-Teck;Kang Seong-Gook
    • Food Science and Preservation
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    • v.12 no.6
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    • pp.546-551
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    • 2005
  • The new developed production process and the coating equipment were used to prepare the alginate coated rice having functional property. Then, the quality characteristics such as proximate analysis, moisture sorption properties, influence on the retrogradation, sensory evaluation were investigated. The moisture content of the alginate coated rice was $16.5-18\%$ which is $1.5\%$ higher than the normal rice. About $0.3\%$ alginate was coated on the rice by the measurement of carbohydrate content after coating with $2\%$ alginate. The rice coated with higher alginate concentration showed the higher moisture absorption. The rice coated with $2\%$ alginate solution stored $30^{\circ}C$ and $85\%$ RH conditions for 6 weeks and it increased $1.8\%$ of the moisture content The alginate coated rice has delayed the retrogradation more than 6 hrs as well as got the higher scores for the appearance, stickiness, and taste. The alginate coated rice is a good source of the fiber in the nutritional aspect and it improves the quality and functionality of the rice.

Experimental Study on Engineering Properties of Concrete Using Fluosilicates Based Composite (규불화염계 복합 조성물을 혼입한 콘크리트의 공학적 특성에 관한 실험적 연구)

  • Yang Il-Seung;Yun Hyun-Do;Kim Do-Su;Khil Bae-Su;Han Seung-Gu
    • Journal of the Korea Concrete Institute
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    • v.17 no.5 s.89
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    • pp.769-774
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    • 2005
  • Fluosilicic acid(H2SiF6) is recovered as an aqueous solution which absorbs $SiF_4$ produced from the manufacturing of industrial-graded H3PO4 or HF. Generally, fluosilicates are the salts produced by the reaction of H2SiF6 and metal salts. Addition of fluosilicates to cement endows odd properties through unique chemical reaction with the fresh and hardened cement. This study was performed to know mechanical properties and watertightness using fluosilicates based composite made from fluosilicates and other compounds. Mix proportions for experiments were modulated at 0.45 of water to cement ratio and $0.0-2.0\%$ of adding ratio of fluosilicates based composite. Evaluation for mechanical properties of concrete was conducted to know fresh state of concrete, hardening state of concrete, and watertightness. Evaluation for watertightness of concrete was carried out permeability, absorption test and porosity analysis. In addition. Scanning Electron Microscopy(SEM) and Energy Dispersive X-Ray(EDX) used for investigating micro-structure and atomic component distributed in hardened concrete. It is ascertained that characteristics of mechanical properties and watertightness was more improved than non-added because of packing role of fluosilicates based composite and pozzolanic reaction of soluble $SiO_2$. Also, concrete added fluosilicates based composite had a tendency to delay setting time and only $0.5\%$ addition of fluosilicates based composite delayed 150 minutes compared with non-added.