• International Journal of Highway Engineering
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• v.12 no.2
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• pp.107-113
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• 2010

In this study, the relative effects of low-chloride deicier(LCD) and two other deicing agents on the scaling of concrete were conducted in a series of tests at laboratory accordance with the ASTM C 672. The solutions concentration of deicers tested included 1, 4, 10%. Tap water was used as control. The amount of scaling was evaluated gravimetrically. As test result of deicer solution types, when applied to 4% solutions, surface scaling of concrete after 56 freeze-thaw cycles was produced significantly as about 9 times on LCD solution, as about 18 times on $CaCl_2$ solution, and as about 33 times on NaCl solution comparing with tap water. As test result of deicer solution concentrations, relatively low concentrations (of the 4% by weight) of deicer were produced more surface scaling than higher concentrations (of the 10% by weight) or lower concentrations (of the 1% by weight) of deicer. It show that the damaging concentration is of the order of 3~4% for previous research result. It appears that the mechanism of surface scaling is primarily physical rather than chemical. Also, the effect of chloride deicier types, freeze-thaw cycling, and air contents on the performance of concrete was experimentally investigated. The results show that the concrete specimens subjected to freeze-thaw cycling scaled more severely in exposure to deicing salt than those in non-exposure to deicing salt, weight losses of the specimens tested in exposure to deicing salt were twice as much as those tested in non-exposure to deicing salt. Relative dynamic modulus of elasticity of concrete specimens decreased more quickly in exposure to deicing salt than in non-exposure to deicing salt. Also, relative dynamic modulus of elasticity of concrete specimens in exposure to sodium chloride deicing salt was decreased more quickly comparing with exposure to LCD salt. It is also shown that the chloride contents according to concrete specimen depths was more largely in exposure to LCD salt. When concrete specimen is exposed to chloride deicing salts and freeze-thaw cycling, performance degradation in the entrained air concrete(AE concrete) retarded more considerably comparing with non-entrained air concrete(Non-AE concrete).

• International Journal of Highway Engineering
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• v.19 no.4
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• pp.9-18
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• 2017

PURPOSES : This study evaluates the reasonableness of the recommended amount of deicing chemicals based on historical data for snow removal. The result can be used to aid decision-making for the reservation of cost-effective de-icing chemicals. METHODS : First, the recommended amount of de-icing chemical to use and historical usage data were evaluated to identify specific usage characteristics for each region. Road maintenance length and snow-removal working days were analyzed over the past five winter seasons. Next, differences in the recommended amount of chemical to use and actual use were compared using the Kolmogorov-Smirnov test. Last, the two types of data were analyzed using a chi-square test to verify if the two distributions of variation pattern are statistically significant. We found that there are significant differences between the data from each region during the past five winter seasons. RESULTS : The results showed that the equation for calculating the amount of de-icing chemical to use appears to be revised. CONCLUSIONS : The results imply that the equation for calculating the amount of de-icing chemical to apply as a national standard is very important when the public agency makes decisions related to snow-removal.

• Journal of the Korea institute for structural maintenance and inspection
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• v.19 no.2
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• pp.68-75
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• 2015

This study established key factors causing deck slab deterioration based on GPR database of 747 highway bridges, and predicted deck slab damage rates with respect to bridge service life. To minimize the influence of bridge service life on deck slab deterioration, the deck slab damage rate database was corrected based on a linear regression model of bridge service life vs. deck slab damage rate. The corrected deck slab damage rates were analyzed to determine correlation considering the number of snowy days, the amount of snowfalls, the number of freeze-thaw days, average winter temperature, altitude, the amount of deicing chemicals and equivalent traffic volume, and then both the number of freeze-thaw days and the amount of deicing chemicals were determined to be key factors causing deck slab deterioration. The complex deterioration considering both key factors was represented deck slab damage rate charts, and the average deck slab life was derived. The results of this study will be used as a guideline for highway bridge maintenance to identify the progress of deck slab deterioration for a given bridge and predict the time required deck slab rehabilitation.

• Proceedings of the Korea Concrete Institute Conference
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• 2008.04a
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• pp.529-532
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• 2008

Domestic area of most be happened chloride deicer damage. Because daily mean temperature is below 0$^{\circ}C$ from the area of domestic most. Use of deicing chemicals has been and will continue to be a major part of highway snow and ice control methods. Chloride-containing chemicals such as calcium chloride or rock salt are main deicers for the road. Extensive use of chloride deicers is, however, not only the source of substantial cost penalties due to their corrosive action and ability to deterioration roadway surface materials but also the source of environmental damages. Particularly, it has been recognized that chlorides present in deicing agents can significantly increase concrete surface scaling. In severe cases, scaling can result in dislodgement of coarse aggregate. This research estimates that pH and test of specific pollutants, dynamic modulus of elasticity for freeze-thaw test of concrete were higher than those NaCl, $CaCl_2$, and NaCl+$CaCl_2$(7:3, w/w), also weight losses for scaling test of concrete were much lower than those of NaCl, $CaCl_2$, and NaCl+$CaCl_2$(7:3, w/w).

• Proceedings of the Korea Concrete Institute Conference
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• 2008.04a
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• pp.561-564
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• 2008

Concrete scaling is the progressive surface deterioration of susceptible subjected to freeze-thaw cycling in the presence of moisture. Particularly, it has been recognized that chlorides present in deicing agents can significantly increase concrete surface scaling. Domestic area of most be happened chloride deicer damage. Because daily mean temperature is below 0$^{\circ}C$ from the area of domestic most. Use of deicing chemicals has been and will continue to be a major part of highway snow and ice control methods. Chloride-containing chemicals such as calcium chloride or rock salt are main deicers for the road. Extensive use of chloride deicers is, however, not only the source of substantial cost penalties due to their corrosive action and ability to deterioration roadway surface materials but also the source of environmental damages. In this study, Use of (40, 27, 21MPa) pavement concrete analyze freeze-thaw test and scaling on the chlorides present.

• Journal of the Korea Concrete Institute
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• v.17 no.5 s.89
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• pp.857-868
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• 2005

This paper deals with the accumulated damage in concrete structures due to the cyclic freeze-thaw as an environmental load. The cyclic ice body nucleation and growth processes in porous systems are affected by the thermo-physical and mass transport properties, and gradients of temperature and chemical potentials. Furthermore, the diffusivity of deicing chemicals shows significantly higher value under cyclic freeze-thaw conditions. Consequently, the disintegration of concrete structures is aggravated at marine environments, higher altitudes, and northern areas. However, the properties of cyclic freeze-thaw with crack growth and diffusion of chloride ion effects are hard to be identified in tests, and there has been no analytic model for the combined degradations. The main objective is to determine the driving force and evaluate the reduced strength and stiffness by freeze-thaw. For the development of computational model of those coupled deterioration, micro-pore structure characterization, pore pressure based on the thermodynamic equilibrium, time and temperature dependent super-cooling with or without deicing salts, nonlinear-fracture constitutive relation for the evaluation of internal damage, and the effect of entrained air pores (EA) has been modeled numerically. As a result, the amount of ice volume with temperature dependent surface tensions, freezing pressure and resulting deformations, and cycle and temperature dependent pore volume has been calculated and compared with available test results. The developed computational program can be combined with DuCOM, which can calculate the early aged strength, heat of hydration, micro-pore volume, shrinkage, transportation of free water in concrete. Therefore, the developed model can be applied to evaluate those various practical degradation cases as well.

• Computers and Concrete
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• v.11 no.3
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• pp.201-222
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• 2013

A comprehensive simulation model for the transport process of fully coupled moisture and multi-species in non-saturated concrete structures is proposed. The governing equations of moisture and ion diffusion are formulated based on Fick's law and the Nernst-Planck equation, respectively. The governing equations are modified by explicitly including the coupling terms corresponding to the coupled mechanisms. The ionic interaction-induced electrostatic potential is described by electroneutrality condition. The model takes into account the two-way coupled effect of moisture diffusion and ion transport in concrete. The coupling parameters are evaluated based on the available experimental data and incorporated in the governing equations. Differing from previous researches, the material parameters related to moisture diffusion and ion transport in concrete are considered not to be constant numbers and characterized by the material models that account for the concrete mix design parameters and age of concrete. Then, the material models are included in the numerical analysis and the governing equations are solved by using finite element method. The numerical results obtained from the present model agree very well with available test data. Thus, the model can predict satisfactorily the ingress of deicing salts into non-saturated concrete.

• International Journal of Highway Engineering
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• v.17 no.1
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• pp.35-41
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• 2015

PURPOSES : The purpose of this study is to analyze the service life of expressway pavement based on both traffic volumes and use of deicing chemicals. METHODS : A database was built using expressway rehabilitation history information from over the last decade. In order to estimate the service life of expressway pavement, various analysis methods were considered, and a decision was made to perform analysis using a method based on an accumulated rehabilitation ratio. The service life of expressway pavement was then analyzed by classifying the scale of traffic volume and extent of de-icing chemicals used. RESULTS : The service life of PMA and SMA ranged from 7.8 to 10.6 years and from 9.9 to 12.0 years, respectively. The service life of JCP ranged from 16.0 to 22.2 years, and the service life of CRCP was 33.5 years on average. Results of assessing service life according to traffic volumes and de-icing chemicals showed that the lower the traffic volumes were, the greater the service life of PMA and JCP, and the less that de-icing chemicals were applied, the greater the service life of JCP. CONCLUSIONS : The dependence of expressway pavement service life on traffic volumes and de-icing chemicals makes it possible to apply LCCA for regional maintenance plans and cost-effective selection of expressway pavement type.

• Journal of the Korean GEO-environmental Society
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• v.13 no.2
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• pp.5-17
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• 2012

The amount of snow due to global warming and climate change has recently increased. The effective management of snow removal materials will be required. First, on the basis of domestic winter temperature, it is not necessary to get a baseline to less than the freezing point of $-52^{\circ}C$ for the calcium chloride($CaCl_2$) of 30%.. In terms of cost comparison between calcium chloride($CaCl_2$) and sodium chloride($NaCl$), the calcium chloride($CaCl_2$) is 2 to 3 times more expensive, and the supply of the calcium chloride($CaCl_2$) is not produced in domestic country and is in the conditions that have to imports all needed. Accordingly, the effective use scheme of snow removal materials should be considered to multifaceted ways. Thus, the objective of this study is to develop effective method and to replace from calcium choride($CaCl_2$) to sodium chloride($NaCl$) solution in the current snow removal operating system that uses a pre-wetted salt spreading method. The effective method that equals to the quality of the existing snow removal materials was developed in this study through performance tests for deicing chemicals, corrosion test of steel and freezing and thawing tests of concrete.

• Proceedings of the Korea Concrete Institute Conference
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• 2008.04a
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• pp.565-568
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• 2008

Domestic area of most be happened chloride deicer damage. Because daily mean temperature is below 0$^{\circ}C$ from the area of domestic most. Concrete durability influence Air Content. Presently, We used to AE(air-entraining agent) for increase freeze-thaw durability. So, on concrete Air Spacing ratio used $200{\mu}m{\sim}230{\mu}m$ in Canada and under $250{\mu}m$ in Japan institution. Use of Air content has been and will continue to be a major part of concrete durability and scaling. Chloride-containing chemicals such as calcium chloride or rock salt are main deicers for the road. The prepared optimum mix concrete in this study show that freeze-thaw and scaling resistance of Non-AE(air content 1.5%) and AE (air content 4.5%, 7.2%). Solution concentrations of deicing agent were good result, and the pore system and change of hydration products is not difference comparing before freeze-thaw test.