• Title/Summary/Keyword: dehumidification membrane

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Developing Trend of Gas Separation Membrane for Dehumidification (제습용 기체분리막 개발동향)

  • Koh, Hyungchul;Lee, Choongsup;Ha, Seong Yong;Choi, Whee Moon;Rhim, Jiwon;Nam, Sangyong
    • Prospectives of Industrial Chemistry
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    • v.14 no.3
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    • pp.25-36
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    • 2011
  • 압축공기 중의 수분은 공압설비의 모든 요소에 중대한 해를 입히며 밸브의 고착, 계기의 막힘 또는 공압기기의 오작동을 일으키며 생산하는 제품의 질에 있어서도 많은 해를 입혀서 제품의 질을 떨어뜨리는 역할을 하게 된다. 따라서 수분을 제거하는 방법이 필요하며 기존의 냉동식 및 흡착식을 대신하여 분리막 법이 적용될 수 있다. 현재 제습용 기체분리막 모듈은 적용이 시작된 단계에 있다. 제습용 기체분리막은 의료기기, 분석기기, Instrument air 장비에 응용이 진행되고 있다. 최근 들어 선진각국 뿐만 아니라 국내에서도 막소재 개발, 복합막 개발, 모듈 개발, 시스템 설계 및 제작 기술 개발이 진행되고 있다. 현재로서는 제습막공정에 적합한 막소재의 개발이 시급하지만 이후 적용확대를 위해서는 제습용 기체분리막의 신뢰성 향상을 위한 다각도의 노력이 필요하다.

A Study on the Optimization of Water Balance Control in the Intermittent PEM Fuel Cell

  • Choi, Kwang-Hwan;Yoon, Jung-In;Son, Chang-Hyo;Hong, Boo-Pyo;Bakhtiar, Agung
    • Journal of Power System Engineering
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    • v.17 no.5
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    • pp.64-68
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    • 2013
  • One of the water management goals in PEM fuel cell is to avoid flooding and drying in the membrane, therefore the air humidification process is required. In order to increase water removal out of the membrane, the water management system may require the dehumidification process and it also requires a large space for application, moreover the process time is slow. In conformity with this fact, this present study proposes an advanced dynamic fuel cell water management which can be an intermittent optimization control using air flow rate instead of the air humidity as an variable in the optimization process. The results of this study have shown that the membrane flooding and drying can be avoided after being assisted by air velocity controlling method.

[ $CO_2$ ] Recovery from LNG-fired Flue Gas Using a Multi-staged Pilot-scale Membrane Plant (파일럿규모의 다단계 막분리 공정을 통한 LNG 연소 배가스로부터 이산화탄소의 회수연구)

  • Kim, Jeong-Hoon;Choi, Seung-Hak;Kim, Beom-Sik;Lee, Soo-Bok;Lee, Yong-Taek
    • Membrane Journal
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    • v.17 no.3
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    • pp.197-209
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    • 2007
  • In this study, a multi-staged pilot-scale membrane plant was constructed and operated for the separation of $CO_2$ from LNG-fired boiler flue gas of 1,000 $Nm^3/day$. The target purity and recovery ratio of $CO_2$ required for the pilot plant were 99% and 90%, respectively. For this purpose, we previously developed the asymmetric polyethersulfone hollow fibers and evaluated the effects of operating pressure and feed concentration of $CO_2$ on separation performance[1,2]. The permeation data obtained were also analyzed in relation with the numerical simulation data using counter-current flow model[3,4]. Based on these results, we designed and prepared the demonstration plant consisting of dehumidification process and four-staged membrane process. The operation results using this plant were compared with the numerical simulation results on multi-staged membrane process. The experimental results matched well with the numerical simulation data. The concentration and the recovery ratio of $CO_2$ in the final stage permeate stream were ranged from $95{\sim}99%$ and $70{\sim}95%$, respectively, depending on the operating conditions. This study demonstrated the applicability of the membrane-based pilot plant for $CO_2$ recovery from flue gas.

Study on Performance of Water Vapor-Permeation Through Hydrophilic Polymer Membranes (친수성 고분자 막을 이용한 수증기 투과 성능에 관한 연구)

  • Rhim Ji-Won;Yun Tae-Il;Seo Moo-Young;Cho Hyun-Il;Ha Seong-Yong
    • Membrane Journal
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    • v.16 no.2
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    • pp.115-122
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    • 2006
  • In this study the membrane preparation and water vapor permeation of the hydrophilic polymer materials, polyaminosiloxane and polyhydroxylsiloxane, used as the coating materials for the preparation of asymmetric flat and hollow fiber membranes were investigated. And the water vapor permeation towards air permeation and their permselectivity were intensively studied for the resulting Resin A/Resin C (coupling agent) and Resin B/Resin C membranes. The water vapor permeability for 3 wt% Resin C introduced into Resin A (Resin A/Resin C) membrane was higher than for 1 and 5 wt% membranes and also water vapor permeability increased with increasing operating temperatures. In addition, at this content of 3 wt% Resin C, the absorption capability became maximum through dynamic equilibrium absorption experiment. Water vapor permeability, 43578 Barrer (1 Barrer = $10^{-10}cm^3(STP){\cdot}cm/cm^2{\cdot}s{\cdot}cmHg$) and 53000 Barrer, and the selectivity of $P(H_2O)P(Air)$, 101.3 and 102.6 were shown at 25 and $35^{\circ}C$, respectively.

Membrane Process Using Polysulfone Hollow Fiber Membranes for Vehicle Fuel Production from Bio-Methane Mixture (폴리설폰 중공사막 모듈을 이용한 자동차 연료용 고순도 바이오메탄 분리공정 연구)

  • Kim, Jee Sang;Kong, Chang In;Park, Bo Ryoung;Kim, Jeong-Hoon
    • Membrane Journal
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    • v.24 no.3
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    • pp.213-222
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    • 2014
  • In this study, 2-stage recirculation membrane process was developed for purification of high purity bio-methane for the vehicle fuel application. Pure gas permeation and mixture gas permeation test were done as a function of methane content and pressure in the feed using polysulfone membrane modules. 2-stage membrane plant was designed, constructed in a food waste treatment cite. Dehumidification, dry desulfurization, and desiloxane plants are installed for the removal of $H_2O$, $H_2S$ and siloxane in the biogas. Permeation test were done with the pre-treated methane mixture in terms of methane purity and recovery by adjusting the ratio of membrane area (1:1, 1:3, 2:2) in the first and second membrane modules in the plant. When membrane area of 2 stage increased to $3m^2$ from $1m^2$ at 1-stage membrane area of $1m^2$, the feed rate and $CH_4$ recovery at 95% methane purity were increased from 47.1% to 92.5% respectively. When the membrane area increased two-fold (1:1 to 2:2), $CH_4$ recovery increased from 47.1% to 88.3%. When the feed flow rate was increased, in 1:3 ratio, final purity of the methane is reduced, the methane recovery is increased. When operating pressure was increased, the feed rate was increased and recovery was slightly decreased. From this result, membrane area, feed pressure and feed rate could be the important factor to the performance of the membrane process.

A Study on Establishment of Technical Guideline of the Installation and Operation for the Biogas Utilization of Transportation and City Gas: Design and Operation Guideline (고품질화 바이오가스 이용 기술지침 마련을 위한 연구(III): 도시가스 및 수송용 - 기술지침(안) 중심으로)

  • Moon, HeeSung;Kwon, Junhwa;Park, Hoyeon;Jeon, Taewan;Shin, Sunkyung;Lee, Dongjin
    • Journal of the Korea Organic Resources Recycling Association
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    • v.27 no.2
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    • pp.67-73
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    • 2019
  • In this study, to optimize the production and utilization of biogas for organic waste resources, the precision monitoring of on-site facilities and the energy balance by facility were analyzed, and the solutions for field problems were investigated, and the design and operation guidelines for pretreatment facilities and generators were presented. Gas pre-treatment is required to solve frequent failures and efficiency degradation in operation of high quality refining facilities, and processing processes such as desulfurization, dehumidification, deoxidization, dust treatment, volatile organic compounds, etc. Since these processes are substances that are also eliminated from the high-quality process, quantitative guidelines are not presented in the gas pretreatment process, but are suggested to operate during the processing process as a qualitative guideline. In particular, dust, siloxane, and volatile organic compounds are the main cause of frequent failure of high-quality processes if they are not removed from the gas pretreatment process. Design of the biogas high-quality process. The operation guidelines provide quality standards [Methane content (including propane) of 95% or more] with 90% or more utilization of the total gas generation, two systems, and a margin of 10% or more. It also proposed installing gas equalization tank, installing thermal automatic control system for controlling equalization of auxiliary fuel, installing dehumidification device at the back of high quality for removing moisture generated in the process of gas compression, installing heat-resisting facilities to prevent freezing of facilities in winter and reducing efficiency, and installing membrane facilities in particular.

Recent Progress in Air-Conditioning and Refrigeration Research : A Review of Papers Published in the Korean Journal of Air-Conditioning and Refrigeration Engineering in 2016 (설비공학 분야의 최근 연구 동향 : 2016년 학회지 논문에 대한 종합적 고찰)

  • Lee, Dae-Young;Kim, Sa Ryang;Kim, Hyun-Jung;Kim, Dong-Seon;Park, Jun-Seok;Ihm, Pyeong Chan
    • Korean Journal of Air-Conditioning and Refrigeration Engineering
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    • v.29 no.6
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    • pp.327-340
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    • 2017
  • This article reviews the papers published in the Korean Journal of Air-Conditioning and Refrigeration Engineering during 2016. It is intended to understand the status of current research in the areas of heating, cooling, ventilation, sanitation, and indoor environments of buildings and plant facilities. Conclusions are as follows. (1) The research works on the thermal and fluid engineering have been reviewed as groups of flow, heat and mass transfer, the reduction of pollutant exhaust gas, cooling and heating, the renewable energy system and the flow around buildings. CFD schemes were used more for all research areas. (2) Research works on heat transfer area have been reviewed in the categories of heat transfer characteristics, pool boiling and condensing heat transfer and industrial heat exchangers. Researches on heat transfer characteristics included the results of the long-term performance variation of the plate-type enthalpy exchange element made of paper, design optimization of an extruded-type cooling structure for reducing the weight of LED street lights, and hot plate welding of thermoplastic elastomer packing. In the area of pool boiling and condensing, the heat transfer characteristics of a finned-tube heat exchanger in a PCM (phase change material) thermal energy storage system, influence of flow boiling heat transfer on fouling phenomenon in nanofluids, and PCM at the simultaneous charging and discharging condition were studied. In the area of industrial heat exchangers, one-dimensional flow network model and porous-media model, and R245fa in a plate-shell heat exchanger were studied. (3) Various studies were published in the categories of refrigeration cycle, alternative refrigeration/energy system, system control. In the refrigeration cycle category, subjects include mobile cold storage heat exchanger, compressor reliability, indirect refrigeration system with $CO_2$ as secondary fluid, heat pump for fuel-cell vehicle, heat recovery from hybrid drier and heat exchangers with two-port and flat tubes. In the alternative refrigeration/energy system category, subjects include membrane module for dehumidification refrigeration, desiccant-assisted low-temperature drying, regenerative evaporative cooler and ejector-assisted multi-stage evaporation. In the system control category, subjects include multi-refrigeration system control, emergency cooling of data center and variable-speed compressor control. (4) In building mechanical system research fields, fifteenth studies were reported for achieving effective design of the mechanical systems, and also for maximizing the energy efficiency of buildings. The topics of the studies included energy performance, HVAC system, ventilation, renewable energies, etc. Proposed designs, performance tests using numerical methods and experiments provide useful information and key data which could be help for improving the energy efficiency of the buildings. (5) The field of architectural environment was mostly focused on indoor environment and building energy. The main researches of indoor environment were related to the analyses of indoor thermal environments controlled by portable cooler, the effects of outdoor wind pressure in airflow at high-rise buildings, window air tightness related to the filling piece shapes, stack effect in core type's office building and the development of a movable drawer-type light shelf with adjustable depth of the reflector. The subjects of building energy were worked on the energy consumption analysis in office building, the prediction of exit air temperature of horizontal geothermal heat exchanger, LS-SVM based modeling of hot water supply load for district heating system, the energy saving effect of ERV system using night purge control method and the effect of strengthened insulation level to the building heating and cooling load.