• 접착 및 계면
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• 제10권3호
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• pp.134-140
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• 2009

분자설계를 통하여 측쇄를 변화시킨 아크릴공중합체를 합성하여 아크릴공중합체 점착제와 초박형웨이퍼와의 젖음성 및 점착물성을 조사하였다. 선형 아크릴공중합체를 에폭시계 Tetra-DX 가교제와 반응시켜 3차원 망상구조를 형성하고 가교의 영향을 조사하였다. 계면상호작용보다는 아크릴공중합체의 측쇄변화가 젖음성에 더 큰 영향을 미쳤다. 가교도가 증가할수록 probe tack, peel strength가 감소하는 경향을 나타냈다. 가교에 의해 SAFT 내열성이 증가하였지만 가교제의 함량이 증가하면 오히려 SAFT 내열성이 감소하였다.

• 폴리머
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• 제24권3호
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• pp.418-430
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• 2000

알칼리키토산과 프로필렌옥사이드를 반응시킴에 의해 유방성 및 열방성 액정상을 형성하는 새로운 히드록시프로필키토산(HPCTO)을 합성함과 동시에 HPCTO/메탄올의 유방성 액정용액에 glyoxal첨가하여 주형시킴에 의해 HPCTO의 가교필름들을 제조하였다. 가교필름들의 열 및 팽윤 특성을 검토하였다. 필름들은 cholesteric 액정상의 특징적인 지문조직을 나타내었으며 이들의 pitch는 온도 및 가교제의 농도가 증가할수록 증가하였다. 가교시료들은 물과 메탄을 중에서 이방성 팽윤을 나타내었으며, 이러한 사실은 HPCTO분자들간에 2차원적인 가교가 우선적으로 일어남을 시사한다. 이방성 팽윤의 정도는 용매의 종류에 크게 의존하나 검토된 가교제의 농도에는 의존하지 않았다.

• 한국재료학회지
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• 제22권5호
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• pp.227-236
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• 2012

Ionomer is a thermoplastic that is composed of covalent bonds and ionic bonds. It is possible to use this material in processes such as injection molding or extrusion molding due to the material's high oil resistance, weatherproof characteristics, and shock resistance. In this study, a new ionomer having a multifunctional group was prepared by a stepwise neutralization system with the addition of acidic and salt additives. In step I, to increase the contents of the multifunctional group and the acid degree in ethylene acrylic acid (EAA), MGA was added to the ionomer resin (EAA). A new ionomer was prepared via the traditional preparation method of the ionic cross-linking process. In step II, metal salt was added to the mixture of EAA and MGA. The extrusion process was performed using a twin extruder (L/D = 40, size : ${\varphi}30$). Ionomer film was prepared for evaluation of gas permeability by using the compression molding process. The degree of neutralized and ionic cross-linked new ionomer was confirmed by FT-IR and XRD analysis. In order to estimate the neutralization of the new ionomer film, various properties such as gas permeation and mechanical properties were measured. The physical strength and anti-scratch property of the new ionomer were improved with increase of the neutralization degree. The gas barrier property of the new ionomer was improved through the introduction of an ionic site. Also, the ionic degree of cross-linking and gas barrier property of the ionomer membrane prepared by stepwise neutralization were increased.

• 한국막학회:학술대회논문집
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• 한국막학회 2004년도 추계 총회 및 학술발표회
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• pp.64-67
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• 2004

• 한국식품과학회지
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• 제27권5호
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• pp.753-756
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• 1995

아스파탐 전구체의 보다 효율적인 효소적 합성 방법을 개발하기 위하여 thermolysin의 고정화 방법을 확립하고자 고정화 담체로서 다공성 수지인 Amberlite XAD-7을, 가교화제로서 glutaraldehyde를 사용하여 최적 고정화 조건을 조사하고자 하였다. Thermolysin이 Amberlite XAD-7에 흡착되는 속도는 초기에 빠른 것으로 나타났으며, $5^{\circ}C$에서 24시간후는 96%가 흡착되었다. Thermolysin에 대한 Amberlite XAD-7의 최대흡착량은 수지 l당 340g 이상이었으며, 투입한 thermolysin 양이 300g일 때까지는 흡착된 양의 증가하는 관계는 직선관계를 보여주었다. thermolysin의 가교화를 위한 효과적인 pH와 glutaraldehyde의 농도, 가교화시간은 각각 $pH\;6.0{\sim}7.0,\;6{\sim}12.5%$ 및 $3{\sim}7$시간이었다. 특히 glutaraldehyde 6%에서는 7시간, 12.5%에서 3시간의 가교화가 효소의 잔존역가와 가교화 정도를 현저히 높였다. 이때의 잔존역가는 30% 이상인 것으로 나타났다.

• 대한의용생체공학회:의공학회지
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• 제35권6호
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• pp.192-196
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• 2014

Collagen scaffolds were synthesized by cross linking into a solution mixture of 1-ethyl-3-[3-dimethylaminopropyl] carbodiimide hydrochlorid(EDC) in ethanol, followed by pressing, cleaning and lyophilization process after the type I atelo-collagen solutions in D.I water(pH3). The experimental conditions are collagen concentration of 1.0 wt%, 3.0 wt%, 5.0 wt% and differential concentration of cross-linker. Then, parametric studies were performed by varying the parameters to investigate the morphology, the porosity, the swelling ratio and the thickness and genotoxicity of the scaffolds. The scaffolds thickness pattern was regular to concentration of the degree of cross-linker and collagen. It was observed that the swelling ratio, the degree of crosslink, and the pore size(thickness of scaffold) can be controlled by adjusting the collagen, crosslinker. Among the parameters investigated, the smallest thickness can be achieved by collagen, crosslinker concentrate condition. The collagen scaffold is induced no genotoxicity. The lowest swelling ratio, as an indication of the highest degree of crosslink, can be obtained by adding crosslink agent.

• 한국의류산업학회지
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• 제14권4호
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• pp.677-683
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• 2012

1-octanethiol and vinyl acetate telomers ($R_8S$-nVAc) were synthesized and hydrolyzed with sodium hydroxide subsequently, 1.2-epoxyhexane was then introduced to the telomers. In addition, we prepared cotelomers of multi-alkylated nonionic surfactants with a molecular structure of xRnMA-yVA (x; hydrophobic group, y; hydrophilic group, MA; methacrylic ester, VA; vinyl alcohol, R; and alkyl group) and cross-linked with sodium tetraborate decahydrate. Their active surface properties were investigated by several techniques such as surface tension, foaming property, and emulsification power measurements. The surface tension of $R_8S$-8.8VA decreased without the introduction of 1.2-Epoxy hexane, and the degree of emulsification and foaming abilities of $R_8S$-8.8VA increased without the introduction of 1.2-Epoxy hexane. However, the differences were insignificant. The epoxy groups were attached to a $R_8S$-8.8VA cotelomer with a limited variation of the active surface properties. The surface tension of $1.1R_6MA$-8.8VA decreased after cross-linking subsequently, the degree of emulsification and foaming abilities of $1.1R_6MA$-8.8VA increased after cross-linking. However, there was no clear difference between them. The B-O bonds were attached to a $1.1R_6MA$-8.8VA cotelomer with a limited variation of the active surface properties.

• Journal of Microbiology and Biotechnology
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• 제27권3호
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• pp.552-560
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• 2017

Quorum quenching (QQ) bacteria entrapped in a polymeric composite hydrogel (QQ medium) have been successfully applied in membrane bioreactors (MBRs) for effective biofouling control. However, in order to bring QQ technology closer to practice, the physical strength and lifetime of QQ media should be improved. In this study, enforcement of physical strength, as well as an extension of the lifetime of a previously reported QQ bacteria entrapping hollow cylinder (QQ-HC), was sought by adding a dehydration procedure following the cross-linking of the polymeric hydrogel by inorganic compounds like $Ca^{2+}$ and boric acid. Such prepared medium demonstrated enhanced physical strength possibly through an increased degree of physical cross-linking. As a result, a longer lifetime of QQ-HCs was confirmed, which led to improved biofouling mitigation performance of QQ-HC in an MBR. Furthermore, QQ-HCs stored under dehydrated condition showed higher QQ activity when the storage time lasted more than 90 days owing to enhanced cell viability. In addition, the dormant QQ activity after the dehydration step could be easily restored through reactivation with real wastewater, and the reduced weight of the dehydrated media is expected to make handling and transportation of QQ media highly convenient and economical in practice.

• 보존과학회지
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• 제34권3호
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• pp.157-166
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• 2018

본 연구에서는 아교의 접착 특성 향상을 위해 가교제(Cross-linking Agent)를 첨가하는 방법으로 젤라틴 결합력을 증대하였다. 제니핀 첨가 아교는 물성 측정, 구조 분석, 색잔류도, 용출도, 파단강도를 측정하였으며, 수분과 자외선에 대한 내수성과 내광성을 비교하였다. 연구 결과 겔강도와 점도는 제니핀 첨가량에 따라 증가하였다. 구조분석 결과, 젤라틴에서는 구조적으로 안정된 콜라겐의 3중 구조의 흡수 피크가 관찰되었다. 색잔류도 결과, 명도가 낮아지기 때문에 피막이 관찰되는 것으로 판단된다. 용출량은 $50^{\circ}C$ 증류수에서 제니핀 첨가량이 증가할수록 용출된 아교 양이 증가하였고 파단강도는 제니핀 첨가량에 따라 증가하였다. 내수성과 내광성은 제니핀 첨가에 따른 열화 전 후 양상이 나타나지 않았다. 본 연구 결과를 바탕으로 제니핀 첨가 아교의 접착 특성을 확인할 수 있었으며 아교에 적용 가능한 실험 방법을 고찰하였다. 제니핀을 첨가한 후에도 아교 고유의 특성인 유연성, 재용해성, 접착력, 경화속도가 사라지지 않고 향상되기 때문에 균질한 아교가 확보된다면 문화재 보존 및 아교 제작에 적용이 가능할 것으로 기대한다.

• Elastomers and Composites
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• 제54권4호
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• pp.271-278
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• 2019

Polyurethane elastomers (PUEs) were synthesized using trans-1,4-bis(isocyanatomethyl) cyclohexane (1,4-H₆XDI), poly(oxytetramethylene) glycol, 1,4-butanediol (BD), and 1,1,1-trimethylol propane (TMP). To control the molecular aggregation state and mechanical properties of these PUEs, hard segment contents of 20 and 30 wt% and BD/TMP ratios of 10/0 and 8/2 were chosen. Differential scanning calorimetry and small-angle X-ray scattering measurements revealed that the degree of microphase separation increased with an increase in both hard segment content and BD ratio. The Young's modulus and strain at break of the 1,4-H₆XDI-based PUE were 6-20 MPa and 5-15, respectively. Incorporation of 20% TMP as a cross-linking agent into BD increased the melting temperature of the hard segment chains, that is, heat resistance, and decreased the Young's modulus. This could be due to the low density of the physical cross-linking network and the dispersion of hard segment chains in the soft segment matrix in the PUE in the presence of 20% TMP.