• Title/Summary/Keyword: degradation process

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Storage lifetime estimation of detonator in Fuse MTSQ KM577A1 (기계식 시한 신관 KM577A1용 기폭관 저장수명 예측)

  • Chang, Il-Ho;Park, Byung-Chan;Hwang, Taek-Sung;Hong, Suk-Whan;Back, Seung-Jun;Son, Young-Kap
    • Journal of Korean Society for Quality Management
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    • v.38 no.4
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    • pp.504-511
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    • 2010
  • A fuze detonator comprising star shells is an important device so that its failure usually leads to failure of the shells. In this paper, accelerated degradation tests of RD1333 (lead azide) using temperature stress were performed, and then degradation data of explosive power for the detonator were analyzed to predict the storage lifetime of detonator. Degradation data analysis to estimate the storage lifetime is based on a distribution-based degradation process. Statistical distribution parameters of explosive power degradation measures at each time were estimated for each temperature level, and then reliability of the detonator for each accelerated temperature level was estimated using both time-varying distribution parameters and critical level of explosive power. Arrhenius model was applied to estimate storage lifetime of the detonator under the field temperature condition. Accelerated distribution-based degradation analysis to estimate storage lifetime is explained in detail, and estimation results are compared to field data of storage lifetime in this paper.

Experimental Analysis of GDL Degradation in PEM Fuel Cell (고분자전해질형 연료전지 가스확산층의 내구 성능 저하에 관한 실험적 분석)

  • Ha, Tae-Hun;Park, Jae-Man;Cho, Jun-Hyun;Min, Kyoung-Doug;Lee, Eun-Suk;Jung, Ji-Young;Kim, Do-Hun;Jin, Yong-Won;Lee, Dae-Han
    • 한국신재생에너지학회:학술대회논문집
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    • 2009.11a
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    • pp.132-132
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    • 2009
  • To achieve the commercialization of PEM fuel cell, the durability problem must be solved. Recently, many researchers have focused on this durability problem and degradation studies about membrane and electrode have been reported. But durability characteristics of gas diffusion layer is not much reported yet. Durability of GDL is very important to maintain the performance of PEM fuel cell because the main function of GDL is a path of fuel and water and the GDL degradation causes the loss of the GDL function. In this study, the degradation of GDL, especially, the mechanical degradation process was investigated with the leaching test. The effect of water dissolution was observed through the test and the amount of GDL degradation was measured with various measurement methods such as weight measurement, static contact angle measurement, scanning electron microscope. After 2,000 hours test, the GDL showed structural damage and loss of hydrophobicity.

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Enhance degradation of insecticide chlorpyrifos by iron salts and potassium persulfate during zerovalent iron treatment in aqueous solution

  • Rahman, M. Mokhlesur;Hwang, Jung-In;Kwak, Se-Yeon;Kim, Jang-Eok
    • Journal of Applied Biological Chemistry
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    • v.61 no.4
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    • pp.383-389
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    • 2018
  • Degradation of the insecticide O,O-diethyl O-3,5,6-trichloro-2-pyridyl phosphorothioate (chlorpyrifos) in aqueous solution was investigated using iron salts and potassium persulfate during ZVI treatment through a series of batch experiments. The degradation rate of chlorpyrifos increased with increases in the concentrations of iron salts and potassium persulfate in the aqueous system. Ferric chloride was found to be the most effective iron salt for the ZVI-mediated degradation of chlorpyrifos in aqueous solution. Further, the iron salts tested could be arranged in the following order in terms of their effectiveness: $FeCl_3$> $Fe_2(SO_4)_3$> $Fe(NO_3)_3$. The persulfate-ZVI system could significantly degrade chlorpyrifos present in the aqueous medium. This revealed that chlorpyrifos degradation by treatment with $Fe^0$ was promoted on adding ferric chloride and potassium persulfate. The kinetics of the degradation of chlorpyrifos by persulfate-amended $Fe^0$ was higher than that for iron-salt-amended $Fe^0$. This suggests that using a sequential $Fe^0$ reduction-ferric chloride or $Fe^0$ reduction-persulfate process may be an effective strategy to enhance the removal of chlorpyrifos in contaminated water.

Degradation analysis of horizontal steam generator tube bundles through crack growth due to two-phase flow induced vibration

  • Amir Hossein Kamalinia;Ataollah Rabiee
    • Nuclear Engineering and Technology
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    • v.55 no.12
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    • pp.4561-4569
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    • 2023
  • A correct understanding of vibration-based degradation is crucial from the standpoint of maintenance for Steam Generators (SG) as crucial mechanical equipment in nuclear power plants. This study has established a novel approach to developing a model for investigating tube bundle degradation according to crack growth caused by two-phase Flow-Induced Vibration (FIV). An important step in the approach is to calculate the two-phase flow field parameters between the SG tube bundles in various zones using the porous media model to determine the velocity and vapor volume fraction. Afterward, to determine the vibration properties of the tube bundles, the Fluid-Solid Interaction (FSI) analysis is performed in eighteen thermal-hydraulic zones. Tube bundle degradation based on crack growth using the sixteen most probable initial cracks and within each SG thermal-hydraulic zone is performed to calculate useful lifetime. Large Eddy Simulation (LES) model, Paris law, and Wiener process model are considered to model the turbulent crossflow around the tube bundles, simulation of elliptical crack growth due to the vibration characteristics, and estimation of SG tube bundles degradation, respectively. The analysis shows that the tube deforms most noticeably in the zone with the highest velocity. As a result, cracks propagate more quickly in the tube with a higher height. In all simulations based on different initial crack sizes, it was observed that zone 16 experiences the greatest deformation and, subsequently, the fastest degradation, with a velocity and vapor volume fraction of 0.5 m/s and 0.4, respectively.

Degradation Measurement from Electrical Tree Image Using Foreground Object Extracting Skill (전경 물체 추출 기법을 이용한 전기트리 영상에서 열화 측정)

  • 김형균;정기봉;고석만;오무송;김태성
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2001.11a
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    • pp.270-273
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    • 2001
  • Electrical tree is studied widely by manufacture state of insulating material fare and blazing fire diagnosis system of use in phenomenon of part discharge that happen for main cause of dielectric breakdown of equipment for electric power. Use process that draw tree pattern here measuring above zero to study special quality of this electricity tree, real-time processing by image processing is proposed because reproduction of tree blazing fire process drops and pattern of tree is difficult correct quantification of tree growth by existent visual observation by involution. This research presents general process that need in image processing of tree blazing fire, and that remove various noises that happen in above zero by measuring electrical tree dividing background and complete view in measured above zero taking advantage of specially proposed complete view object abstraction techniques effectively and quantification of tree becomes easy naturally, can apply to dielectric breakdown estimate because can chase growth process of tree.

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Effect of Disinfection Process Combination on E. coli Deactivation and Oxidants Generation (E. coli 불활성화와 산화제 생성에 미치는 소독 공정 결합의 영향)

  • Kim, Dong-Seog;Park, Young-Seek
    • Journal of Environmental Science International
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    • v.20 no.7
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    • pp.891-898
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    • 2011
  • The aim of this research was to evaluate the effect of combination of disinfection process (electrolysis, UV process) on Escherichia coli (E. coli) disinfection and oxidants (OH radical, $ClO_2$, HOCl, $H_2O_2$ and $O_3$) generation. The effect of electrolyte type (NaCl, KCl and $Na_2SO_4$) on the E. coli disinfection and oxidants generation were evaluated. The experimental results showed that performance of E. coli disinfection of electrolysis and UV single process was similar. Combination of electrolysis and UV process enhanced the E. coli disinfection and 4-carboxybenzaldehyde (4-CBA, indicator of the generation of OH radical) degradation. It is clearly showed synergy effect on disinfection and OH radical formation. However chlorine ($ClO_2$, HOCl) and oxygen type ($H_2O_2$, $O_3$) oxidants were decreased with the combination of two process. In electrolysis + UV complex process, electro-generated $H_2O_2$ and $O_3$ were reacted with UV light of UV-C lamp and increased 4-CBA degradation(increase OH radical). Disinfection of electrolyte of chlorine type was higher than that of the sulfate type electrolyte due to the higher generation of OH radical and oxidants.

Degradation of Humic Acid in Ozone/GAC Process (오존/GAC 공정에서의 부식산 분해 특성)

  • Rhee, Dong Seok
    • Journal of Industrial Technology
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    • v.28 no.B
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    • pp.47-52
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    • 2008
  • In this study, GAC adsorption, ozonation and $O_3/GAC$ hybrid processes were investigated for treatment of humic acid. The degradation characteristics and efficiencies of humic acid in each process were evaluated through pH variation, $UV_{254}$ decrease, DOC removal, change of molecular size distribution and by-products formation. DOC removal rate in $O_3/GAC$ hybrid process (80%) was higher than arithmetic sum of ozonation (38%) and GAC adsorption process (19%) by synergism. $UV_{254}$ decrease rate of humic acid was also the highest than any other processes when treated in $O_3/GAC$ hybrid process. Molecular size distribution was not significantly changed in the GAC adsorption process. Main distribution of molecular size of humic acid was converted from 3 k~30 kDa into 0.5 k~3 kDa in ozonation. But the most of large molecular sizes of humic acid converted into small molecules(smaller than 0.5 kDa) in $O_3/GAC$ hybrid process. Quantities of formaldehyde and glyoxal formed in $O_3/GAC$ hybrid process were less than the ones in ozonation.

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Degradation-Based Remaining Useful Life Analysis for Predictive Maintenance in a Steel Galvanizing Kettle (철강 도금로의 예지보전을 위한 열화 기반 잔존수명 분석)

  • Shin, Joon Ho;Kim, Chang Ouk
    • Journal of the Korea Convergence Society
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    • v.10 no.12
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    • pp.271-280
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    • 2019
  • Smart factory, a critical part of digital transformation, enables data-driven decision making using monitoring, analysis and prediction. Predictive maintenance is a key element of smart factory and the need is increasing. The purpose of this study is to analyze the degradation characteristics of a galvanizing kettle for the steel plating process and to predict the remaining useful life(RUL) for predictive maintenance. Correlation analysis, multiple regression, principal component regression were used for analyzing factors of the process. To identify the trend of degradation, a proposed rolling window was used. It was observed the degradation trend was dependent on environmental temperature as well as production factors. It is expected that the proposed method in this study will be an example to identify the trend of degradation of the facility and enable more consistent predictive maintenance.

Effects of Operating Parameters on Electrochemical Degradation of Rhodamine B and Formation of OH Radical Using BDD Electrode (BDD 전극을 이용한 OH 라디칼 생성과 염료 분해에 미치는 운전인자의 영향)

  • Park, Young-Seek;Kim, Dong-Seog
    • Journal of Environmental Science International
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    • v.19 no.9
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    • pp.1143-1152
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    • 2010
  • The purpose of this study is to degradation of Rhodamine B (RhB, dye) and N, N-Dimethyl-4-nitrosoaniline (RNO, indicator of the electro-generation of OH radical) in solution using boron doped diamond (BDD) electrode. The effects of applied current (0.2~1.0 A), electrolyte type (NaCl, KCl, and $Na_2SO_4$) and electrolyte concentration (0.5~3.0 g/L), solution pH (3~11) and air flow rate (0~4 L/min) were evaluated. Experimental results showed that RhB and RNO removal tendencies appeared with the almost similar thing, except of current. Optimum current for RhB degradation was 0.6 A, however, RNO degradations was increased with increase of applied current. The RhB and RNO degradation of Cl type electrolyte were higher than that of the sulfate type. The RhB and RNO degradation were increased with increase of NaCl concentration and optimum NaCl dosage was 2.5 g/L. The RhB and RNO concentrations were not influenced by pH under pH 7. Optimum air flow rate for the oxidants generation and RhB and RNO degradation were 2 L/min. Initial removal rate of electrolysis process was expressed Langmuir - Hinshelwood equation, which is used to express the initial removal rate of UV/$TiO_$2 process.

Application of a Thermophilic Aerobic Digestion Process to Industrial Waste Activated Sludge Treatment

  • Kim, Young-Kee;Eom, Yong-Suk;Oh, Byung-Keun;Lee, Won-Hong;Choi, Jeong-Woo
    • Journal of Microbiology and Biotechnology
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    • v.11 no.4
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    • pp.570-576
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    • 2001
  • Thermophilic aerobic bacteria were applied in the degradation of industrial waste activated sludge (WAS) on a laboratory scale expreiment. The performance of digestion was estimated by measuring the reduction of total suspended solids (TSS), dissolved organic carbon (DOC), and total organic carbon (TOC). Among three strains of Bacillus stearothermophilus and three strains of Thermus species, B. stearothemophilus ATCC 31197 showed the best overall efficiency level for the degradation of industrial WAS, which was collected from a wastewater treatment plant in an oil refinery factory. Industrial WAS coul be successfully detraded in a batch digestion with ATCC 31197. The stability of the digestion process with ATCC 31197 was successfully verified by semi-continuous (fill-and-draw) digestion experiment. From the results of this study, it was shown that the thermophilic aerobic digestion process with ATCC 31197 could efficiently be applied to the degradation of industrial WAS.

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