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The Reactivity of Thiopyrylium Compound. Reduction of Thiopyrylium Cation by Alkali Metals-Evidence of Thiabenzene Radical

  • Joo, Wan-Chul;Kim, Chung-Kyun
    • Bulletin of the Korean Chemical Society
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    • v.1 no.3
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    • pp.98-101
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    • 1980
  • For the first time we have synthesized thiabenzene radical by the reaction of thiopyrylium cation with alkali metals. As might be expected for a free radical, ESR-spectrum of 2,4,6-triphenylthiabenzene radical shows the single signal with g-value of 2.0045. The proton signal of 2,4,6-triphenylthiabenzene radical in nmr spectrum shifts to the higher field than that of 2,4,6-triphenylthiopyrylium cation by ca. 0.5 ppm. From the UV-spectrum of thiabenzene radical the presence of 6${\pi}$ non-benzenoid aromatic system was observed as in the case of thiopyrylium cation. The reactivity of alkali metals with thiopyrylium cation increases in the order of decreasing ionization energy, Li

An Analysis of Railroad Modal Shift in Japan - for example H Company - (일본의 철도 모달시프트 사례분석 - H사의 사례를 중심으로 -)

  • Chung, Byung-Hyun;Moon, Dae-Seop;Kim, Hyun-Woong
    • Proceedings of the KSR Conference
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    • 2008.11b
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    • pp.1853-1859
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    • 2008
  • A lot of efforts are inclined by concluding the Kyoto Protocol in Japan for the exhaust decreasing of the $CO_2$ gas in 1997. The Japan Ministry of Land, Infrastructure, Transport and Tourism is promoting various policies through various policies such as `new synthesis logistics policy', 'green logistic partnership meeting', establishment of 'logistics efficiency law' etc. The modal shift case that the individual logistic company in Japan was promoting under such a policy was analyzed in this research, and a modal shift on the distribution site was very promoted, and applicability in our country was examined through the instruction point to this in the future.

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SURFACE ROUGHNESS EFFECTS ON THE COERCIVITY OF THIN FILM HEADS

  • Kim, Hyunkyu;Horvath, M. Pardavi
    • Journal of the Korean Magnetics Society
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    • v.5 no.5
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    • pp.663-666
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    • 1995
  • The domain wall motion coercivity, $H_{c}$, of magnetic materials arises from the dependence of the wall energy on localized changes in material parameters (magnetization, anisotropy, exchange energy densities). However, in an otherwise perfectly homogeneous material, the domain wall energy might change due to the change in the volume of the wall versus the wall position. Thus, any surface roughness contributes to the coercivity. Assuming different two-dimensional surface profiles, characterized by average wavelengths ${\lambda}_{x}$ and ${\lambda}_{y}$, and relative thickness variations dh/h, the coercivity due to the surface roughness has been calculated. Compared to the one dimensional case, the 2D coercivity is reduced. Depending on the ratio of ${\lambda}$ to the domain wall width, $H_{c}$ has a maximum around 2, and increasing with dh/h. With the decreasing thickness of the thin film and GMR heads, it might be the domain factor in determining the coercivity.

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A Demand Paging for Reducing The Memory Usage of OS-Less Embedded Systems (운영체제 없는 시스템의 메모리 절감을 위한 요구 페이징 기법)

  • Lew, Kyeung Seek;Jeon, Hyun Jae;Kim, Yong Deak
    • IEMEK Journal of Embedded Systems and Applications
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    • v.6 no.1
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    • pp.32-40
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    • 2011
  • For a NAND booting based embedded system, an application program on the NAND flash memory is downloaded to the RAM when the system is booted. In this case, the application program exists in both the RAM and the NAND flash so the RAM usage is increased. In this paper, we suggested the demand paging technique for the decreasing of the RAM usage for OS-less NAND booting based embedded systems. As a result of a benchmark test, 40~80% of the code memory usage was reduced with below 5% of execution time delay.

Classical and Bayesian studies for a new lifetime model in presence of type-II censoring

  • Goyal, Teena;Rai, Piyush K;Maury, Sandeep K
    • Communications for Statistical Applications and Methods
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    • v.26 no.4
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    • pp.385-410
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    • 2019
  • This paper proposes a new class of distribution using the concept of exponentiated of distribution function that provides a more flexible model to the baseline model. It also proposes a new lifetime distribution with different types of hazard rates such as decreasing, increasing and bathtub. After studying some basic statistical properties and parameter estimation procedure in case of complete sample observation, we have studied point and interval estimation procedures in presence of type-II censored samples under a classical as well as Bayesian paradigm. In the Bayesian paradigm, we considered a Gibbs sampler under Metropolis-Hasting for estimation under two different loss functions. After simulation studies, three different real datasets having various nature are considered for showing the suitability of the proposed model.

Design of Air-Lifted Seawater Propulsion System (ALSP) for Ecoships' Auxiliary Propulsion 1

  • Lee, Jae-hyuk
    • International journal of advanced smart convergence
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    • v.10 no.2
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    • pp.15-20
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    • 2021
  • We constructed an air-lifted seawater propulsion system for decreasing fuel consumption of the ships. The system has a form of pipes which can be easily installed on the sides of the ship. Seawater mixed with air, will rise along within the pipe, and will be discharged downward. If the directions of inlet / outlet of the pipe are designed properly, a propulsive energy can be obtained. We tested the system with a model ship in Jangsa port at Sokcho-city with a water depth of 2.5 meters. The system was supplied regulated air at 6 bars during the 3 tests. The model ship was moving forward at a rate of 0.18 meters per second. In case of large ships equipped zfrom clean energy.

EARLY WARNING FORECASTS FOR COVID-19 IN KOREA USING BAYESIAN ESTIMATION OF THE TRANSMISSION RATE

  • Byul Nim Kim
    • East Asian mathematical journal
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    • v.39 no.5
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    • pp.493-503
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    • 2023
  • Tendency prediction of daily confirmed cases is an important issue for public health authorities. To protect the tendency, we estimate the transmission rate of stochastic SEIR model for COVID-19 in Korea using particle Markov chain Monte Carlo method. The results show that the increasing and decreasing tendency of estimated transmission rate appear one or two days in advance compared to daily incidence cases, and as time evolves the standard deviation of the estimates of transmission rate reduces. Since ten months have passed since the first incident case of COVID-19 in Korea, we expect to forecast the tendency of daily confirmed cases for the next one or two days more accurately using our method.

current profiles in a coated conductor with transport current (외부 전류가 흐를 때 초전도 선재에서의 전류 분포)

  • Yoo, Jae-Un;Lee, Sang-Moo;Jung, Ye-Hyun;Lee, Jae-Young;Youm, Do-Jun
    • Progress in Superconductivity and Cryogenics
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    • v.9 no.3
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    • pp.1-4
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    • 2007
  • The current profiles in a coated conductor with transport current were calculated using an iterative inversion method from the data of the magnetic flux density profiles measured. The applied current was increased from 0 to 60 A by 10A step and decreased down to -60A by 20A step. The magnetic flux profiles were measured at a distance of 400 mm above the surface of the coated conductor using a scanning hall probe method. The current profiles calculated were very different from the Bean model: current density profile is not a constant in the critical region. However the aspect of the change of the current and magnetic flux density profiles in the case of decreasing applied current are similar to the theoretical calculations in Brandt's paper.

A Study on the Taper Plunger Type Proportional Electromagnet for ISC Valve (ISC 밸브용 테이퍼 플런저형 비례전자석에 관한 연구)

  • Song, Chang-Seop;Lee, Tae-Hyeong;Yun, Jang-Sang
    • Journal of the Korean Society for Precision Engineering
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    • v.10 no.3
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    • pp.125-132
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    • 1993
  • On this study, magnetic force versus input currents is analyzed by modeling taper plunger type proportional electromagnet of ISC valve using the permernce method. And, the reliabiliy of simulation is verified by comparing the experimental values with the calaulate magnetic force. From the result of this study, it is found that the taper angles at plunger and core, the length of air gap between plunger and yoke are the prumary factors in designing taper plunget type proportional electromagnet. Magnetic force is decreased as a whole according to increasing the air gap between pluger and yoke, and vise versa. But, the magnetic force is not proportional to current, when the air gap is very small. In case of decreasing the taper angle of pluger, the stroke range of plunger where magnetic force is proportional to current becomes farther from core.

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Study on the floating coupling for high precision feeding with ballscrew (고정밀 이송을 위한 볼스크류용 체결기구에 관한 연구)

  • PARK, C.H.;KIM, I.C.;CHUNG, Y.K.;LEE, H.S.
    • Journal of the Korean Society for Precision Engineering
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    • v.14 no.5
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    • pp.157-163
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    • 1997
  • In the case of direct connecting the nut of ballscrew to guide table, machining error and misalignment of ballscrew largely affect to the motional accuracy of guideway. For decreasing these influences, two type of floating couplings: leaf spring type and hybrid type which releases the table from nut of ballscrew except feed and rotational direction is proposed in this study. In order to verify practical availability of the proposed floating couplings, motional accuracy, dynamic characteristics and micro step response of hydrostatic guideway, mounted with each type of couplings are tested. The conventional fixed type coupling is also tested as the reference in characteristics. From the results of experiments, it is proved that the hybrid type coupling is superior to other couplings and is available to high precision feeding system with ballscrew.

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