• Title/Summary/Keyword: decay properties

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Variation of Material Properties of Fire-killed Timber - Impact of Time on Degradation of Mechanical Properties - (산불 피해목의 재질변화에 관한 연구(II) - 산불 피해 소나무의 경시적 재질변화 -)

  • Park, Jung-Hwan;Park, Byung-Soo;Kim, Kwang-Mo;Lee, Do-Sik
    • Journal of the Korean Wood Science and Technology
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    • v.36 no.1
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    • pp.30-35
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    • 2008
  • Degradation of mechanical properties of fire-killed Korean red pine has been investigated after death in 5 years period. Impact bending absorbed energy was the most sensitive property by elapsed time after forest fire. It is an indication of incipient decay of the wood and can be useful indicator to monitor any change of mechanical property of fire-killed tree after death. Degradation of mechanical properties was more pronounced in sapwood than heartwood. Impact bending absorbed energy was more reduced than any other properties in both sapwood and heartwood, while compressive strength was least impacted by elapsed time after forest fire. It is recommended that the fire-killed Korean red pine can be harvested in one year after the fire for industrial uses by considering decay and consequent changes of mechanical properties.

Surface static properties in polymer hybrid material after plasma treatment (플라즈마 처리한 고분자 복합재료의 표면특성변화)

  • Park, Jong-Kwan
    • 전자공학회논문지 IE
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    • v.44 no.3
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    • pp.6-11
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    • 2007
  • In this study, which was performed to identify a degradation mechanism in macromolecular insulating material, the contact angle, surface potential decay, surface resistance rate and XPS analysis were compared after exposure of fibre-glass-reinforced polymer laminate to plasma discharge. In the case of chemical changes arising from plasma treatment, carboxyl radicals were generated mainly in the plasma-treated surface, which was rapidly changed to a hydrophilic surface. In the corona potential decay study to determine the electrical changes, leading to a negative surface for the untreated specimen. However, in the case of the hydrophilic surface, a lot of carboxy radicals(-COO) acting as positive polarity were generated, resulting in a positive surface. Owing to such a positive surface, the charges of applied negative polarity were decreased rapidly.

EXCITED-STATE TWISTED INTRAMOLECLILAR CHARGE TRANSFER OF p-N,N-DIMETHYLAMINOBENZOIC ACID IN AQUEOUS CYCLODEXTRIN SOLUTIONS: TIME-RESOLVED FLUORESCENCE STUDY

  • Kim, Yong-Hee;Cho, Dae-Won;Yoon, Min-Joong
    • Journal of Photoscience
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    • v.3 no.3
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    • pp.153-158
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    • 1996
  • The effects of $\alpha$- and $\beta$-cyclodextrins (CD) on the twisted intramolecular charge transfer (TICT) behavior of p-N,N'-dimethylaminobenzoic acid (DMABA) in buffered aqueous solution have been investigated by examining formation and decay behaviors of the TICT-typical dual fluorescence. The ratio of the TICT emission to the normal emission (I$_a$/I$_b$) increases linearly $\alpha$-CD concentration increases, while in the presence of $\beta$-CD it shows nonlinear dependences on the CD concentration. The analysis of the CD-dependent changes of the I$_a$/I$_b$ and absorption spectra demonstrates formation of 1:1 inclusion complexes between DMABA and CDs. The decay time of the normal emission (ca. 700 ps) is little affected by the formation of $\alpha$-CD inclusion complex, whereas it increases upto ca. 1.6 ns upon formation of $\beta$-CD inclusion complex. The TICT emission for the $\beta$-CD inclusion complex exhibits two decay components while it shows a single component for the $\alpha$-CD inclusion complex, indicating formation of one or two types of inclusion complex in the presence of $\alpha$-CD or $\beta$-CD, respectively. These results are attributed to the CD cavity size dependence on patterns of complexation between CDs and DMABA. The CD size dependences of the TICT fluorescence properties with the orientation of the guest molecule demonstrate that the specific hydrogen bonding between the carboxylic acid group and water plays an important role in the excited-state TICT.

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Inhibitory Effects of Natural Antimicrobial Agenton Postharvest Decay in Fruits and Vegetables under Natural Low Temperature (천연 항균제처리를 병용한 과채류의 자연 저온저장기술 개발에 관한 연구)

  • 조성환;정진환;류충호
    • Journal of the Korean Society of Food Science and Nutrition
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    • v.23 no.2
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    • pp.315-321
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    • 1994
  • In order to prevent the postharvest decay and to promote the freshness retention of fruits and vegetables grapefruit seed extract(GFSE), natural microorganism control agent, was applied to the preservation of fresh fruits and vegetables. Freshfruits and vegetables treated with GFSE and stored in polyethylene film (0.1mm) at 1$0^{\circ}C$-15$^{\circ}C$ of natural low temperature low kept better qualities in color and texture than the GFSE -not- treated control. The treatment using GFSE ina 250ppm to 500ppm concentration seemed to be an effective one for the control of Botrytis cinerea isolated in red wine grapes. After 4 weeks of storage the firmness rate of cucumbers treated with the dilute GFSE was four times higher than that of non-treated ones. GFSE showed effective inhibitory action towards plant pathological bacteria and fungi which were involved in the decay of fruits and vegetables. Minimum inhibitory concentrations of GFSE towards them were in the range of 250ppm to 500ppm .Direct visualization of microbial cells and spores using electron microscopy showed microbial cells and fungal spores the function of which was destroyed by treating with the dilute solutions of GFSE. It was observed that GFSE would reduced disease damages and have bactericide & fungicide properties during the storage of such fruits and vegetables as egg plant, wild edible greens , kumquat, and kiwi fruit.

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A Research Trend on Space Charge Analysis in Polymer Irradiated by Electron Beam (온도 상승시에 전자빔 조사된 폴리머내의 전하 분포의 축퇴 현상 연구 동향)

  • Ko, Sung-Min;Kim, Nam-Yong;Kim, Dae-Yeol;Choi, Yong-Sung;Moon, Jong-Dae;Lee, Kyung-Sup
    • Proceedings of the KIEE Conference
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    • 2007.07a
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    • pp.1992-1993
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    • 2007
  • Decay processes of accumulated charge in e-beam irradiated polymers during elevating temperature are observed using pulsed electro-acoustic measurement system. Since the polymeric materials have many superior properties such as light-weight, good mechanical strength, high flexibility and low cost, they are inevitable materials for spacecrafts. In space environment, however, the polymers sometimes have serious damage by irradiation of high energy charged particles. When the polymers of the spacecraft are irradiated by high energy charged particles, some of injected charges accumulate and remain for long time in the bulk of the polymers. Since the bulk charges sometimes cause the degradation or breakdown of the materials, the investigation of the charging and the decay processes in polymeric materials under change of temperature is important to decide an adequate material for the spacecrafts. By measuring the charge behavior in e-beam irradiated polymer, such as polyimide or polystyrene, it is found that the various accumulation and decay patterns are observed in each material. The results seem to be useful and be helpful to progress in the reliability of the polymers for the spacecraft.

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Prediction of Axial Solid Holdups in a CFB Riser

  • Park, Sang-Soon;Chae, Ho-Jeong;Kim, Tae-Wan;Jeong, Kwang-Eun;Kim, Chul-Ung;Jeong, Soon-Yong;Lim, JongHun;Park, Young-Kwon;Lee, Dong Hyun
    • Korean Chemical Engineering Research
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    • v.56 no.6
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    • pp.878-883
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    • 2018
  • A circulating fluidized bed (CFB) has been used in various chemical industries because of good heat and mass transfer. In addition, the methanol to olefins (MTO) process requiring the CFB reactor has attracted a great deal of interest due to steep increase of oil price. To design a CFB reactor for MTO pilot process, therefore, we has examined the hydrodynamic properties of spherical catalysts with different particle size and developed a correlation equation to predict catalyst holdup in a riser of CFB reactor. The hydrodynamics of micro-spherical catalysts with average particle size of 53, 90 and 140 mm was evaluated in a $0.025m-ID{\times}4m-high$ CFB riser. We also developed a model described by a decay coefficient to predict solid hold-up distribution in the riser. The decay coefficient developed in this study could be expressed as a function of Froude number and dimensionless velocity ratio. This model could predict well the experimental data obtained from this work.

Evaluation of Physico-Mechanical Properties and Durability of Larix kaempferi Wood Heat-Treated by Hot Air (고온 열기 처리에 의한 낙엽송재의 물리·역학적 성능 및 내부후성능 변화 고찰)

  • Park, Yonggun;Han, Yeonjung;Park, Jun-Ho;Chang, Yoon-Seong;Yang, Sang-Yun;Chung, Hyunwoo;Kim, Kyungjung;Yeo, Hwanmyeong
    • Journal of the Korean Wood Science and Technology
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    • v.43 no.3
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    • pp.334-343
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    • 2015
  • This study was carried out to evaluate quantitatively some properties (density, equilibrium moisture content, shrinkage, water vapor adsorption, water absorptivity, compressive strength, bending strength, hardness and decay resistance) of Larix kaempferi lumber which was heat-treated by hot air and has been used commercially in Korea. Equilibrium moisture content of the heat-treated wood was decreased with increase of hydrophobicity. Dimensional stability of the wood was improved with decrease of shrinkage, water vapor adsorption and free water absorptivity. Also, with the thermo-chemical changes of wood component and lower equilibrium moisture content, decay resistance and compressive strength of heat-treated wood were increased. But, bending strength and hardness of wood were decreased.

Luminescence properties of asymmetric double quantum well composed of $Al_xGa_{l-x}As/AlAs/GaAs$ system ($Al_xGa_{l-x}As/AlAs/GaAs$계로 이루어진 비대칭 이중 양자우물 구조에서의 광 luminescsnce 특성 연구)

  • 정태형;강태종;이종태;한선규;유병수;이해권;이정희;이민영;김동호
    • Korean Journal of Optics and Photonics
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    • v.3 no.3
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    • pp.183-190
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    • 1992
  • Luminescence properties of asymmetric double quantum well structure composed of $Al_x/Ga_{1-x}$ /As AIAs/GaAs have been studied by steady state and time-resolved photoluminescence and phtoluminescence excitation spectroscopy at low temperature. Two quantum well samples with different barrier thickness (15$\AA$ and 150$\AA$) were prepared to investigate the dependence of tunneling characteristics on barrier thickness. The abscence of excitonic recombination peak from $Al_x/Ga_{1-x}$As well for the 15$\AA$ barrier sample indicates a very fast electron tunneling to GaAs well. Meanwhile, T-X transition between well and barrier is supposed to be a major route for the fast decay of luminescence from $Al_x/Ga_{1-x}$As well in the 150$\AA$ barrier sample. Time-resolved photduminescence from GaAs well of 15$\AA$ sample shows the exsitence of the rise with 100 ps which is attributed to the hole tunneling.

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Scintillation properties of BaCl2 crystal (BaCl2 결정의 섬광특성)

  • Doh, Sih-Hong;Kim, Jung-In;Kim, Hong-Joo;Kang, He-Dong;Kim, Sung-Hwan;Oh, Moon-Young
    • Journal of Sensor Science and Technology
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    • v.17 no.3
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    • pp.217-222
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    • 2008
  • $BaCl_2$ crystals were grown by using the Czochralski method, and their scintillation properties were measured. The emission spectrum was located in the range of $370{\sim}450$ nm, peaking at about 400 nm. The fluorescence decay time was approximately 75.9 ns for 662 keV ${\gamma}$-rays excitation. The energy resolution was about 24.4 % for $^{137}Cs$ 662 keV ${\gamma}$-rays, and the ${\alpha}/{\beta}$ ratio to $\alpha$ particles from a $^{210}Po$ 5.4 MeV was about 0.25.

Optical Properties of InP/InGaP Quantum Structures Grown by a Migration Enhanced Epitaxy with Different Growth Cycles

  • Oh, Jae Won;Cho, Il-Wook;Ryu, Mee-Yi;Song, Jin Dong
    • Applied Science and Convergence Technology
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    • v.24 no.3
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    • pp.67-71
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    • 2015
  • InP/InGaP quantum structures (QSs) were grown on GaAs (001) substrates by a migration-enhanced molecular beam epitaxy method. Temperature-dependent photoluminescence (PL) and emission wavelength-dependent time-resolved PL (TRPL) were performed to investigate the optical properties of InP/InGaP QSs as a function of migration enhanced epitaxy (MEE) growth cycles from 2 to 8. One cycle for the growth of InP QS consists of 2-s In and 2-s P supply with an interruption time of 10 s after each source supply. As the MEE growth cycle increases from 2 to 8, the PL peak is redshifted and exhibited different (larger, comparable, or smaller) bandgap shrinkages with increasing temperature compared to that of bulk InP. The PL decay becomes faster with increasing MEE cycles while the PL decay time increases with increasing emission wavelength. These PL and TRPL results are attributed to the different QS density and size/shape caused by the MEE repetition cycles. Therefore, the size and density of InP QSs can be controlled by changing the MEE growth cycles.