This paper presents a systematic approach for the economical design of stormwater quality control systems. For the design of runoff quality control system (RQCS), the rainfall-runoff process requires the local rainfall data recorded continuously. In this study the rainfall probability distribution is assumed to follow an exponential decay function. Applying the exponential decay function, the normalized curves are derived to explain the non-exceedance probability distributions. The optimal curves for the determination of the RQCS size are derived based on the overflow risk. Comparison of the optimal capture volume and peak runoff rate to those computed by an urban rainfall-runoff model(ILLUDAS) demonstrates that the optimal CSOs(Combined Sewer Overflows) curves derived in this study can be utilized for the design of stormwater quality control systems in Korea avoiding an excessive computational effort based on over flow risks.
Wada, Shinichi;Kobayashi, Tsuneo;Katayama, Yoshiro;Iwami, Toshiaki;Kato, Tsuguhisa;Cameron, John R.
Proceedings of the Korean Society of Medical Physics Conference
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2002.09a
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pp.275-278
/
2002
The recognition of the natural background radiation is important not only for radiological education but also for the promotion of people's scientific view about radiation. We made a "room" on the web showing natural background radiation as part of a VRM (Virtual Radiation Museum). The "room" shows the video images of the tracks of charged particles from natural background radiation, alpha and beta ray track from known sources using a Large Scale Diffusion Cloud Chamber. The purpose of this study is to make clear the origin of a kind of track (named A-track) which is thick and easy to recognize with the length less than several cm in the cloud chamber, and to make numerical explanation of its counting rate. The study was carried out using a Large Scale Diffusion Cloud Chamber (Phywe, Germany) installed in the Niigata Science Museum. The Model RNC (Pylon Electronics, Canada) was used as Rn-222 source. Ra-226 activity in RNC was 111.6 Bq calibrated with NIST protocol. Rn-222 gas was injected into the cloud chamber. Continuous video recording with use of Digital Handycam (SONY, Japan) was carried out for 360 min. after injection of Rn-222 gas. The number of alpha-ray track (alpha track) in the video images was analyzed. The growth and decay curve of the total activity of Rn-222 and its alpha emitting progeny were calculated and compared with the count of the alpha tracks. As a result the alpha tracks formed by Rn-222 injection resemble A-Tracks. The relationship between A-track in the cloud chamber and atmospheric Rn is discussed.
A new textile material, poly(trimethylene terephthalate) polymer, has been introduced to the textile industry. The structure of PTT is similar to the PET, while the tensile deformation and subsequent recovery property is better than that of PET. In this study, the physical and mechanical properties of textile woven fabrics made of PTT, PET, and nylon 6 yarns as the filling yarn were determined using the Kawabata Evaluation System (KES), including tensile, bending, shearing, compression, and surface related parameters. On top of these measurements, the subjective ratings by evaluators were performed on the fabric samples. From the examination of the stress-strain behavior of the yarn specimens focused on the recovery mode, it was evident that the PTT specimen developed lower stress at 3% elongation. The subsequent recovery curve showed that the PTT has less stress-decay rate than the other specimens, implying that the recovery behavior of the PTT is recommendable for the end-uses including stretchable textile materials, sports wears, etc. The KES bending rigidity(B) value of the PTT sample fabric was lower than that of the PET sample fabric. Subjective evaluation of the fabric samples by the evaluators on the descriptive word pair "soft - not soft" showed similar tendency with the KES B determination of the fabric samples.
The purpose of this research is to investigate the characteristics of static and total pressure distribution in the upward free water jet system impinged on a downward flat plate. The rectangular nozzle was used and its contraction and aspect ratio was five and about seven respectively. Experimental conditions considered were jet velocity, distance between nozzle and flat plate, height of supplementary water. It was founded that pressure distribution on the flat plate had the Gaussian curve when the pressure at stagnation point and impinging half width were chosen as the scaling parameters. The maximum pressure was shown at the stagnation point. The central impingement velocity decreased with the increment of distance between nozzle and flat plate, and its slop of decay was similar to that of chracteristics decay region in the three-dimensional free jet.
Understanding charge trapping at the interface between conjugated semiconductor and polymer dielectric basically gives insight into the development of long-term stable organic field-effect transistors (OFET). Here, the charge transport properties of OFETs using polymer dielectric with various molecular weights (MWs) have been investigated. The conjugated semiconductor, pentacene exhibited morphology and crystallinity, insensitive to MWs of polymethyl methacrylate (PMMA) dielectric. Consequently, transfer curves and field-effect mobilities of as-prepared devices are independent of MWs. Under bias stress in humid environment, however, the drain current decay as well as transfer curve shift are found to increase as the MW of PMMA decreases (MW effect). The charge trapping induced by MW effect is irreversible, that is, the localized charges are difficult to be delocalized. The MW effect is caused by the variation in the density of polymer chain ends in the PMMA: the free volumes at the PMMA chain ends act as charge trap sites, corresponding to drain current decay depending on MWs of PMMA.
Kim, Gyeong Hwa;Park, Jong Gyu;Park, Hui Dong;Han, Jeong Hwa
Journal of the Korean Chemical Society
/
v.45
no.6
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pp.570-576
/
2001
The europium doped yttrium oxybromide phosphors were synthesized by solid-state reaction method. The YOBr: $Eu^{3+}$ phosphor showed a strong and narrow red emission band at 621 nm and maximum emission intensity obtained when 0.05 mol Eu ions were doped. The red emission of $Eu^{3+}$ originated from $^5D_0$${\rightarrow}$$^7F_2$electric dipole transition. In order to investigate on photoluminescence behavior, several experimental skills and numerical fittings are conducted to the YOBr: $Eu^{3+}$ phosphor. The emission spectrum was measured in the UV range and then decay curve of $^5D_0$${\rightarrow}$$^7F_j$transitions was examined. The energy interaction type of YOBr: $Eu^{3+}$ phosphor was dipole-dipole interaction. In addition to the calculating by critical concentration, the critical distance ($R_0$) was calculated by decay curve fitting parameter from Inokuti-Hirayamas equation, and spectral overlap method. The critical distance was 17.03, 10.51 and 7.18$\AA$ for those methods, respectively. As considering systematic error of measurements, these values are within the same order, so that the above fitting methods are plausible and recommendable.
Journal of the Korean Society of Groundwater Environment
/
v.6
no.2
/
pp.95-100
/
1999
Hydrocarbon compounds in vadose zone soils caused by adsorption onto the surfaces of solid particles are generally considered to show retardation effect. In this study, we investigated the retardation effect on the transport of Benzene in a sandy soil by conducting batch and column tests. The batch test was conducted by equilibrating dry soil mass with Benzene solutions of various initial concentrations. and by analyzing the concentrations of Benzene in initial and equilibrated solutions using HPLC. The column test consisted of monitoring the concentrations of effluent versus time known as a breakthrough curve (BTC). We used KCl and Benzene solutions with the concentration of 10 g/L and 0.88 g/L as a tracer, and injected them into the inlet boundary of the soil sample as a square pulse type respectively, and monitored the effluent concentrations at the exit boundary under a steady state condition using an EC-meter and HPLC. From the batch test, we obtained a distribution coefficient assuming that a linear adsorption isotherm exists and calculated the retardation factor based on the bulk density and porosity of the column sample. We also predicted the column BTC curve using the retardation factor obtained from the distribution coefficient and compared with the measured BTC of Benzene. The results of the column test showed that i) the peak concentration of Benzene was much smaller than that of KCl and ⅱ) the travel times of peak concentrations for the two tracers were more or less identical. These results indicate that adsorption of Benzene onto the sand panicles occurred during the pulse propagation but the retardation of Benzene caused by adsorption was not present in the studied soil. Comparison of the predicted with the measured BTC of Benzene resulted in a poor agreement due to the absence of the retardation phenomenon. The only way to describe the absolute decrease of Benzene concentration in the column leaching experiment was to introduce a decay or sink coefficient in the convection-dispersion equation (CDE) model to account for an irreversible sorption of Benzene in the aqueous phase.
The macrocycle L exhibited a switch on-off behavior through the fluorescent responses by aromatic imine molecule 1 (X=H) / trifluoroacetic acid (TFA). In the 'switch on' state, it was supposed that the aromatic imine molecule 1 is in the cavity of macrocycle L and a photoinduced electron transfer (PET) from the nitrogen of azacrown part to the anthryl group is inhibited by the interaction between the aromatic imine molecule 1 and the azacrown part of macrocycle L. In the 'switch off' state, it was supposed that the protonated imine molecule 1 is induced by the continuous addition of TFA and a repulsion between the protonated azacrown part and the protonated imine molecule 1 is occurred. It was considered that this process induces the intermolecular PET from the protonated imine molecule 1 to the anthryl group of macrocycle L because of a proximity effect between the anthryl group and the protonated imine molecule 1. From the investigation of the transient emission decay curve, the macrocycle L showed three components (3.45 ns (79.72%), 0.61 ns (14.53%), and 0.10 ns (5.75%). When the imine molecule 1 was added in the macrocycle L as molar ratio=1:1, the first main component showed a little longer lifetime as 3.68 ns (82.75%) although the other two components were similar as 0.64 ns (14.28%) and 0.08 ns (2.96%). On the contrary, when the imine molecule 3 (X=C1) was added in the macrocycle L as molar ratio=l:1, all the three components were decreased such as 3.27 ns (69.83%), 0.44 ns (13.24%), and 0.06 ns (16.93%). The fluorescent pH titration of macrocycle L was carried out from pH=3 to pH=9. The macrocycle L and C $U^{2+}$- macrocycle L complex were intersected at about pH=5, while the E $u^{3+}$ -macrocycle L complex was intersected at about pH=5.5. In addtion, we investigated the fluorescence change of macrocycle L as a function of the substituent constant ($\sigma$$_{p}$$^{o}$) showing in the para-substituent with electron withdrawing groups (X=F, Cl) and electron donating groups (X=C $H_3$, OC $H_3$, N(C $H_3$)$_2$), respectively, as well as non-substituent (X=H).).ctively, as well as non-substituent (X=H).
Proceedings of the Korean Society of Soil and Groundwater Environment Conference
/
1998.06a
/
pp.43-49
/
1998
Retardation effect of heavy metals in soils caused by adsorption onto the surfaces of solids particles is well known phenomena. The adsorption of metal ions has been recognized more strong in clay mineral and organic matter contents rather than sands and gravels. In this study, we investigated the retardation effect in two sandy soils by conducting batch and column tests. The column tests were conducted to obtain the relationship between concentration and time known as breakthrough curve (BTC). We applied pulse type injection of ZnCl$_2$solution on the inlet boundary and monitored the effluent concentration at the exit boundary under steady state condition using EC-meter and ICP-AES. Batch test consisted of an equilibrium procedure for fine fractions collected from two sandy soils for various initial ZnCl$_2$concentrations, and analysis of Zn ions in equilibrated solution using ICP-AES. The results of column test showed that i) the peak concentration of Zn analyzed by ICP was far less than that detected by EC-meter for both soils and ii) travel times for peak concentration were more less identical for two different monitoring techniques. The first result can be explained by ion exchange between Zn and other cations initially present in the soil particles since ICP analysis showed a significant amount of Ca, Mg ions in the effluent. From the second result, we found that retardation effect was not present in these soils due to strong cation exchange capacity of Zn ion over other cations since we did not apply a solution containing more adsorptive cations such as Al. The result of batch test also showed high distribution coefficients (K$_{d}$) for two soils supporting the dominant ion exchange phenomena. Based on the retardation factor obtained from the Kd, we predicted the BTC using CDE model and compared with the BTC of Zn concentration obtained from ICP The predicted BTC, however, disagreed with the monitored in terms of travel time and magnitude of the peak concentrations. The only way to describe the prominent decrease of Zn ion was to introduce decay or sink coefficient in the CDE model to account for irreversible decrease of Zn ions in liquid phase.e.
Journal of Korean Association for Spatial Structures
/
v.7
no.5
/
pp.75-82
/
2007
The present work measured and analyzed changes in the acoustics of a sound field which has a retractable ceiling. An 1/20 scale model of an openable space was built and measurement was carried out by varying the opened area of a ceiling. The most widely used room acoustic and design parameters, RT, EDT, and D50 were investigated. The results suggest that the use of RT as an acoustic design parameter may not be proper in an openable space and further it is likely to mislead the initial acoustic design of such spaces. It is mainly due to the characteristics of RT in which non-exponential decay processes are linearly fitted. Early decay times were found to be decreased in proportion to increaing the ratio of opened area. D50, an index of speech intelligibility, was effectively shows the influence of openings on the acoustics. It is also found that EDT and D50 at the seats, not directly exposed to the opened part of a ceiling, were almost linearly decreased in proportion to the ratio of opened area, while little influence was found for the opening ratio larger than 40% at the directly exposed seats to the opened part of a ceiling.
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