• Title/Summary/Keyword: de-$NO_x$

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SHADOWING, EXPANSIVENESS AND STABILITY OF DIVERGENCE-FREE VECTOR FIELDS

  • Ferreira, Celia
    • Bulletin of the Korean Mathematical Society
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    • v.51 no.1
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    • pp.67-76
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    • 2014
  • Let X be a divergence-free vector field defined on a closed, connected Riemannian manifold. In this paper, we show the equivalence between the following conditions: ${\bullet}$ X is a divergence-free vector field satisfying the shadowing property. ${\bullet}$ X is a divergence-free vector field satisfying the Lipschitz shadowing property. ${\bullet}$ X is an expansive divergence-free vector field. ${\bullet}$ X has no singularities and is Anosov.

A Study on a Combined DeNOx Process of Plasma Oxidation and $NH_3$ SCR for Diesel Engine (플라즈마 산화와 암모니아 SCR 복합탈질공정의 엔진적용 연구)

  • Song, Young-Hoon;Lee, Jae-Ok;Cha, Min-Suk;Kim, Seock-Joon;Ryu, Jeong-In
    • Journal of the Korean Society of Combustion
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    • v.12 no.4
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    • pp.39-46
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    • 2007
  • The technique of $NH_3$ SCR (selective catalytic reduction) assisted by plasma oxidation has been applied to a 2,000 cc diesel engine. The present combined $deNO_x$ process consists of two steps. The first step is that about 50% of emitted NO from the engine is oxidized to $NO_2$ in a plasma oxidation process. The second step is that NO and $NO_2$ are simultaneously reduced to $N_2$ in the $NH_3$ SCR process. The engine test results showed that the $deNO_x$ rates of the present combined process are higher than those of conventional SCR process by 20%. Such a high performance of the combined process is noticeable especially, when the exhaust temperature are relatively low, i.e., $170-220^{\circ}C$. To provide a feasibility of the present technique the effects of operating conditions, such as an electrical input energy, an exhaust gas temperature, an initial NO concentration, and the amount of hydrocarbon addition, were discussed.

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An Experimental Study on the NH3-SCR of NOx over a Vanadium-based Catlayst (바나듐 계열 촉매를 통한 NOx의 NH3-SCR에 관한 실험적 연구)

  • Jeong, Hee-Chan;Sim, Sung-Min;Kim, Young-Deuk;Jeong, Soo-Jin;Kim, Woo-Seung
    • Transactions of the Korean Society of Automotive Engineers
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    • v.20 no.1
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    • pp.20-27
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    • 2012
  • The $NH_3$-SCR characteristics of $NO_X$ over a V-based catalyst are experimentally examined over a wide range of operating conditions, i.e., $170-590^{\circ}C$ and $30,000-50,000h^{-1}$, with a simulated diesel exhaust containing $NH_3$, NO, $NO_2$, $O_2$, $H_2O$, and $N_2$. The influences of the space velocity and oxygen concentration on the standard-SCR reaction are analyzed, and it is shown that the low space velocity and high oxygen concentration promote the SCR activity by ammonia. The best $deNO_X$ efficiency is obtained with a $NO_2/NO_X$ ratio of 0.5 because of an enhanced chemical activity induced by the fast-SCR reaction, while at the $NO_2/NO_X$ ratios above 0.5 the $deNO_x$ activity decreases due to the slow-SCR reaction. The oxidation of ammonia begins to take place at about $300^{\circ}C$ and the reaction products, such as $N_2$, NO, $NO_2$, $N_2O$, and $H_2O$, are produced by the undesirable oxidation reactions of ammonia, particularly at high temperatures above $450^{\circ}C$. Also, $NO_2$ decomposes to NO and $O_2$ at temperatures above $240^{\circ}C$. Therefore, $NO_2$ decomposition and ammonia oxidation reactions deteriorate significantly the SCR catalytic activity at high temperatures.

The Effect of Electrode length Variation in The $DeSO_2$$DeNO_x$ Simultaneous Plasma Reactor (플라즈마 동시처리설비에서 전극에 따른 탈황/탈질 변화)

  • 석동찬;이천우;한영욱;하상안;지평삼;엄희문;장경룡;이상권
    • Proceedings of the Korea Air Pollution Research Association Conference
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    • 1999.10a
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    • pp.258-259
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    • 1999
  • 각종 산업공정에서 발생되는 SO$_2$를 처리하기 위하여 화력발전소와 같은 대형 배출업소에서는 주로 FGD 공법이 사용되고, 중소형의 배출업소에서는 건식 또는 반건식 공법 등이 많이 사용되고 있다. 또한 NO$_{x}$의 제거는 SCR 또는 SNCR 공법을 사용하고 있다.(중략)

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Study on Wet Scrubber for SOX/NOX Treatment in Ship Flue Gas (선박 배가스내 SOX/NOX 처리용 습식 스크러버에 대한 연구)

  • Choi, Jin-Sik;Kim, Jae-Gang;Park, Byung Hyun;Lee, Ju-Yeol
    • Journal of the Korean Applied Science and Technology
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    • v.34 no.1
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    • pp.183-188
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    • 2017
  • This study deals with $de-SO_X$ and $de-NO_X$ process of a wet scrubber for small size ship engines. The experiment was conducted according to the E3 mode of the $NO_X$ technical code. In order to discharge the sulfur containing flue gas, ditertiarybutyldusulfide was added to the diesel fuel to increase the sulfur content. NO gas, which occupies most of the nitrogen oxides in the exhaust gas, was oxidized into $NO_2$ and absorbed by a wet scrubber. The developed equipment of this work achieved 100% of removal efficiency for highly soluble $SO_2$ gas in an aqueous solution.

The Endophyte Curtobacterium flaccumfaciens Reduces Symptoms Caused by Xylella fastidiosa in Catharanthus roseus

  • Lacava, Paulo Teixeira;Li, Wenbin;Araujo, Welington Luiz;Azevedo, Joao Lucio;Hartung, John Stephen
    • Journal of Microbiology
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    • v.45 no.5
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    • pp.388-393
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    • 2007
  • Citrus variegated chlorosis (CVC) is a disease of the sweet orange [Citrus sinensis (L.)], which is caused by Xylella fastidiosa subsp. pauca, a phytopathogenic bacterium that has been shown to infect all sweet orange cultivars. Sweet orange trees have been occasionally observed to be infected by Xylella fastidiosa without evidencing severe disease symptoms, whereas other trees in the same grove may exhibit severe disease symptoms. The principal endophytic bacterial species isolated from such CVC-asymptomatic citrus plants is Curtobacterium flaccumfaciens. The Madagascar periwinkle [Citrus sinensis (L.)] is a model plant which has been used to study X. fastidiosa in greenhouse environments. In order to characterize the interactions of X. fastidiosa and C. flaccumfaciens, periwinkle plants were inoculated separately with C. flaccumfaciens, X. fastidiosa, and both bacteria together. The number of flowers produced by the plants, the heights of the plants, and the exhibited disease symptoms were evaluated. PCR-primers for C. flaccumfaciens were designed in order to verify the presence of this endophytic bacterium in plant tissue, and to complement an existing assay for X. fastidiosa. These primers were capable of detecting C. flaccumfaciens in the periwinkle in the presence of X. fastidiosa. X. fastidiosa induced stunting and reduced the number of flowers produced by the periwinkle. When C. flaccumfaciens was inoculated together with X. fastidiosa, no stunting was observed. The number of flowers produced by our doubly- inoculated plants was an intermediate between the number produced by the plants inoculated with either of the bacteria separately. Our data indicate that C. flaccumfaciens interacted with X. fastidiosa in C. roseus, and reduced the severity of the disease symptoms induced by X. fastidiosa. Periwinkle is considered to be an excellent experimental system by which the interaction of C. flaccumfaciens and other endophytic bacteria with X. fastidiosa can be studied.

[ De-NOx ] Characteristics for Pt/γ-Alumina/Cordierite Foam Filter of Beads Shape (Pt/γ-Alumina/Cordierite 비드형 세라믹 폼 필터의 NOx 제거 특성)

  • Park, Jung-Wook;Park, Jay-Hyun;Park, Jai-Koo
    • Journal of Korean Society for Atmospheric Environment
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    • v.23 no.3
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    • pp.277-285
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    • 2007
  • Porous cordierite beads, of which the average pore size was $130{\mu}m$ and porosity was about 80%, were prepared by the foaming method and then their application as support of the $Pt/{\gamma}-alumina$ catalyst for $NO_x$, reduction with propene was investigated. The pressure drop of a 2 mm porous beads filter was less than that of a 1 mm porous beads filter and the difference in pressure drop between these two increased as the flow rate increased. The catalytic activity of $Pt/{\gamma}-alumina$ washcoated on the porous bead was tested with varying Pt loading $(0.005{\sim}0.1g/cm^3),\;C_3H_6/NO$ mole ratio $(0.5{\sim}8)$, space velocity $(20,000{\sim}30,000h^{-1})$ and oxygen contents (1 and 8). Pt loading of $0.04g/cm^3$ showed the highest activity for $NO_x$ conversion. The $De-NO_x$, test was operated in the temperature range of $200{\sim}400^{\circ}C$ and the best operation temperature of the catalytic filter is about $250^{\circ}C$. As the C/N ratio increased, increase of the $NO_x$, conversion might result from the increase in exhaustion of the amount of oxygen by the reduction of hydrocarbon. $NO_x$ conversion at $20,000h^{-1}$ of space velocity shows a maximum 34% higher conversion than that at $30,000h^{-1}$. On condition that $O_2$ was 5%, space velocity was $20,000h^{-1}$ and the C/N ratio was 8, the $NO_x$ conversion exhibited a maximum of 40% at $250^{\circ}C$.

A Study for SCR Catalyst Reduction in Fast SCR Using Oxidation Catalyst (산화촉매를 이용한 Fast SCR에서의 SCR 촉매 저감 연구)

  • Lee, Jae Ok;Lee, Dae Hoon;Song, Young-Hoon;Oh, Dong-Kyu;Seo, Jung-Wook
    • Applied Chemistry for Engineering
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    • v.24 no.3
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    • pp.333-336
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    • 2013
  • Experimental investigation to estimate the feasibility of fast selective catalytic reduction (SCR) or oxidation catalyst combined ammonia SCR system to abate NOx in low temperature condition ($150{\sim}250^{\circ}C$) is reported. Because the conversion of NO to $NO_2$ is pre-requisite of the fast SCR process, the effect of the amount of oxidation catalyst to NO conversion to $NO_2$ was tested. 37, 45 and 51% of conversion rates were obtained for the OCV of 563000, 375000 and 281000 h, respectively. $De-NO_x$ performance in the case of $NO_2/NO_x$ ratio of 45% showed the best result in all tested temperature conditions. Comparison of the fast SCR and standard SCR with the condition of $NO_2/NO_x$ ratio of 45%, $200{\sim}250^{\circ}C$ and space velocity of 10000~30000 h showed that the fast SCR does not show much difference according to the variance of space velocity. Also it was shown that using the fast SCR, the volume of SCR catalyst can be reduced less than half of the standard SCR condition by increasing space velocity without the loss of $De-NO_x$ performance.

Pollutants Behavior in Oxy-CFBC by Application of In-Furnace deSOx/deNOx Method (순산소 순환유동층에서 로내 탈황 및 탈질법 적용에 따른 오염물질 거동특성)

  • Choi, Gyung-Goo;Na, Geon-Soo;Shin, Ji-Hoon;Keel, Sang-In;Lee, Jung-Kyu;Heo, Pil-Woo;Yun, Jin-Han
    • Clean Technology
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    • v.24 no.3
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    • pp.212-220
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    • 2018
  • Oxy-fuel combustion is considered as a promising greenhouse gas reduction technology in power plant. In this study, the behaviors of NO and $SO_2$ were investigated under the condition that in-furnace $deNO_x$ and $deSO_x$ methods are applied in oxy-fuel circulating fluidized bed combustion condition. In addition, the generation trends of $SO_3$, $NH_3$ and $N_2O$ were observed. For the purpose, limestone and urea solution were directly injected into the circulating fluidized bed combustor. The in-furnace $deSO_x$ method using limestone could reduce the $SO_2$ concentration in exhaust gas from ~403 to ~41 ppm. At the same experimental condition, the $SO_3$ concentration in exhaust gas was also reduced from ~3.9 to ~1.4 ppm. This trend is mainly due to the reduction of $SO_2$. The $SO_2$ is the main source of the formation of $SO_3$. The negative effect of $CaCO_3$ in limestone, however, was also appeared that it promotes the NO generation. The NO concentration in exhaust gas reduced to ~26 - 34 ppm by appling selective non-catalytic reduction method using urea solution. The $NH_3$ concentration in exhaust gas was appeared up to ~1.8 ppm during injection of urea solution. At the same time, the $N_2O$ generation also increased with increase of urea solution injection. It seems that the HNCO generated from pyrolysis of urea converted into $N_2O$ in combustion atmosphere. From the results in this study, the generation of other pollutants should be checked as the in-furnace $deNO_x$ and $deSO_x$ methods are applied.