• Food Science and Biotechnology
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• v.16 no.4
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• pp.520-525
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• 2007

The physicochemical properties of sun-dried and cyclic freeze-thaw dried Alaska pollack were analyzed to compare the 2 drying processes. The moisture content and water activity of sun-dried Alaska pollack were higher than cyclic freeze-thaw dried and 1 year-aged cyclic freeze-thaw dried Alaska pollack (hwangtae). The relatively low temperatures used in cyclic freeze-thaw drying retards lipid oxidation compared to sun drying based on the acid and peroxide values, and the levels of thiobarbituric acid-reactive substances (TBARS) in the dried fish. The water holding capacity of cyclic freeze-thaw dried Alaska pollack aged for 1 year (hwangtae) under ambient conditions at the drying location was higher than that of sun-dried Alaska pollack. The swelling of myofibrilar filaments during cyclic freeze-thaw drying may be responsible for the softening of the dried muscle protein. Aging the cyclic freeze-thaw dried Alaska pollack for 1 year contributed to an increased yellowish color of the hwangtae.

• Proceedings of the Korea Concrete Institute Conference
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• 2006.11a
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• pp.957-960
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• 2006

In order to predict the accumulated damages by cyclic freeze-thaw, a regression analysis by the Response Surface Method (RSM) is used. RSM has merits when the other probabilistic simulation techniques can not guarantee the convergence of probability of occurrence or when the others can not differentiate the derivative terms of limit state functions, which are composed of random design variables in the model of complex system or the system having higher reliability. For composing limit state function, the important parameters for cyclic freeze-thaw-deterioration of concrete structures, such as water to cement ratio, entrained air pores, and the number of cycles of freezing and thawing, are used as input parameters of RSM. The predicted results of relative dynamic modulus and residual strains after 300 cycles of freeze-thaw for specimens show very good agreements with the experimental results. The RSM result can be used to predict the probability of occurrence for designer specified critical values. Therefore, it is possible to evaluate the life cycle management of concrete structures considering the accumulated damages by the cyclic freeze-thaw by the use of proposed prediction method.

• Journal of the Korea Concrete Institute
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• v.17 no.5 s.89
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• pp.857-868
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• 2005

This paper deals with the accumulated damage in concrete structures due to the cyclic freeze-thaw as an environmental load. The cyclic ice body nucleation and growth processes in porous systems are affected by the thermo-physical and mass transport properties, and gradients of temperature and chemical potentials. Furthermore, the diffusivity of deicing chemicals shows significantly higher value under cyclic freeze-thaw conditions. Consequently, the disintegration of concrete structures is aggravated at marine environments, higher altitudes, and northern areas. However, the properties of cyclic freeze-thaw with crack growth and diffusion of chloride ion effects are hard to be identified in tests, and there has been no analytic model for the combined degradations. The main objective is to determine the driving force and evaluate the reduced strength and stiffness by freeze-thaw. For the development of computational model of those coupled deterioration, micro-pore structure characterization, pore pressure based on the thermodynamic equilibrium, time and temperature dependent super-cooling with or without deicing salts, nonlinear-fracture constitutive relation for the evaluation of internal damage, and the effect of entrained air pores (EA) has been modeled numerically. As a result, the amount of ice volume with temperature dependent surface tensions, freezing pressure and resulting deformations, and cycle and temperature dependent pore volume has been calculated and compared with available test results. The developed computational program can be combined with DuCOM, which can calculate the early aged strength, heat of hydration, micro-pore volume, shrinkage, transportation of free water in concrete. Therefore, the developed model can be applied to evaluate those various practical degradation cases as well.

• Journal of the Korean Society of Food Science and Nutrition
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• v.36 no.9
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• pp.1182-1187
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• 2007

Changes in composition of fatty acids and free amino acids in three differently dried Alaska pollack (sun dried, naturally cyclic freeze-thaw dried, and 1-year-aged cyclic freeze-thaw dried Alaska pollack (Hwangtae)) were investigated to correlate them with browning reactions in drying and aging Alaska pollack. Major fatty acids of the sun dried Alaska pollack were palmitic acid, oleic acid, and eicosapentaenoic acid (EPA), and those in the Hwangtae were palmitic acid, oleic acid, and gondoic acid. Hwangtae showed the lowest amount of polyunsaturated fatty acids among the three types of dried Alaska pollack. Free amino acids content of sun dried Alaska pollack was higher than that of the cyclic freeze-thaw dried Alaska pollack and Hwangtae. Lesser amount of histidine in Hwangtae (0.02%) than that in the cyclic freeze-thaw dried Alaska pollack (0.087%) may indicate the degradation of histidine due to the browning reaction in aging the cyclic freeze-thaw dried Alaska pollack. Significant changes in compositions of fatty acids and free amino acids among the dried products revealed the browning reaction resulted from carbonyl compounds produced by decomposition of lipid hydroperoxides and free amino acids. Aging the cyclic freeze-thaw dried Alaska pollack for a year contributed to the development of browning.

• Geomechanics and Engineering
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• v.25 no.1
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• pp.41-48
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• 2021

In cold regions, the integrity of the infrastructures built on weak soils can be extensively damaged by weathering actions due to the cyclic freezing and thawing. This damage can be mitigated by exploiting soil stabilization techniques. Generally, ordinary Portland cement (OPC) is the most commonly used binding material for investigating the chemo-hydromechanical behavior. However, due to the environmental issue of OPC producing a significant amount of carbon dioxide emission, calcium sulfoaluminate (CSA) cement can be used as one of the eco-sustainable alternatives. Although recently several studies have examined the strength development of CSA treated sand, no research has been concerned about CSA cement-stabilized sand affected by cyclic freeze and thaw. This study aims to conduct a comprehensive laboratory work to assess the effect of the cyclic freeze-thaw action on strength and durability of CSA cement-treated sand. For this purpose, unconfined compressive strength (UCS) and ultrasonic pulse velocity (UPV) tests were performed on the stabilized soil specimens cured for 7 and 14 days which are subjected to 0, 1, 3, 5, and 7 freeze-thaw cycles. The test results show that the strength and durability index of the samples decrease with the increase of the freeze-thaw cycles. The loss of the strength and durability considerably decreases for all soil samples subjected to the freeze-thaw cycles. Overall, the use of CSA as a stabilizer for sandy soils would be an eco-friendly option to achieve sufficient strength and durability against the freeze-thaw action in cold regions.

• Journal of the Korea Concrete Institute
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• v.20 no.1
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• pp.13-22
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• 2008

The initiation and growth processes of cyclic ice body in porous systems are affected by the thermo-physical and mass transport properties, as well as gradients of temperature and chemical potentials. Furthermore, the diffusivity of deicing chemicals shows significantly higher value under cyclic freeze-thaw conditions. Consequently, the disintegration of concrete structures is aggravated at marine environments, higher altitudes, and northern areas. However, the properties of cyclic freeze-thaw with crack growth and the deterioration by the accumulated damages are hard to identify in tests. In order to predict the accumulated damages by cyclic freeze-thaw, a regression analysis by the response surface method (RSM) is used. The important parameters for cyclic freeze-thawdeterioration of concrete structures, such as water to cement ratio, entrained air pores, and the number of cycles of freezing and thawing, are used to compose the limit state function. The regression equation fitted to the important deterioration criteria, such as accumulated plastic deformation, relative dynamic modulus, or equivalent plastic deformations, were used as the probabilistic evaluations of performance for the degraded structural resistance. The predicted results of relative dynamic modulus and residual strains after 300 cycles of freeze-thaw show very good agreements with the experimental results. The RSM result can be used to predict the probability of occurrence for designer specified critical values. Therefore, it is possible to evaluate the life cycle management of concrete structures considering the accumulated damages due to the cyclic freeze-thaw using the proposed prediction method.

• Geomechanics and Engineering
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• v.14 no.4
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• pp.307-314
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• 2018

Strength of loess that experienced cyclic freeze and thaw is of great significance for evaluating stability of slopes and foundations in loess regions. This paper takes the frequently encountered loess in the Northwestern China as the study object and carried out three kinds of laboratory tests including freeze-thaw test, direct shear test and SEM test to investigate the strength behaviors of loess after cyclic freeze and thaw, and the correlation with meso-level changes in soil structure. Results show that for loess specimens at four dry densities, the cohesion decreases with freeze-thaw cycles until a residual value is reached and thus an exponential equation is proposed. Besides, little change in the angle of internal friction was observed as freeze-thaw proceeds. This may depend on the varying of soil structure, based on which a clue can be found from the surface morphology and mesoscopic scanning of loess specimens. Clearly we observed significant changes in surface morphology of loess and it tends to aggravate at higher water contents or more cycles of freeze and thaw. Moreover, freeze-thaw cycling leads to obvious changes in the meso-structure of loess including lowering the particle aggregates and increasing both the proportion of fine particles and porosity area ratio. A damage variable dependent on the ratio of porosity area is introduced based on the continuum damage mechanics and its correlation with cohesion is discussed.

• Journal of the Korea Concrete Institute
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• v.22 no.3
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• pp.399-407
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• 2010

The flexural behaviors of two types of beam members exposed to freeze-thaw cycles were evaluated. This study aims to examine the effect of freeze-thaw cycles on the behavior characteristics of reinforced concrete (RC) beams. For the purpose, a part of the beam specimens were damaged until yielding of tension reinforcement was reached, before they were exposed to 150 and 300 cycles of freeze-thaw. Cyclic tests, as well as monotonic tests, were conducted to evaluate the stiffness degradation characteristics when same cycle is repeated. The material tests showed that relative dynamic modulus of concrete exposed to 300 cycles of freeze-thaw moderately decreased to 86.8% of normal concrete, indicating that concrete used in this study has good durability against freeze and thaw damage. The results of monotonic tests showed reduction of flexural strength, ductility and stiffness of the beam specimens exposed to freeze-thaw cycles compared with those of the control speciments. In particular, BDF13 specimens, which had been subjected to artificial cracking damage, did not showed enough flexural strength to satisfy nominal moment required by current concrete structure design code. In the monotonic tests results, BF75 specimens exposed to freeze-thaw cycles showed 10% or more cyclic stiffness degradation. Therefore, it was thought that deformation of concrete in compression have to be considered in design process of members under cyclic load, such as seismic device.

• Geomechanics and Engineering
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• v.10 no.2
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• pp.225-245
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• 2016

Settlement of foundations in permafrost regions primarily results from three physical and mechanical processes such as thaw consolidation of permafrost layer, creep of warm frozen soils and the additional deformation of seasonal active layer induced by freeze-thaw cycling. This paper firstly establishes theoretical models for the three sources of settlement including a statistical damage model for soils which experience cyclic freeze-thaw, a large strain thaw consolidation theory incorporating a modified Richards' equation and a Drucker-Prager yield criterion, as well as a simple rheological element based creep model for frozen soils. A novel numerical method was proposed for live computation of thaw consolidation, creep and freeze-thaw cycling in corresponding domains which vary with heat budget in frozen ground. It was then numerically implemented in the FISH language on the FLAC platform and verified by freeze-thaw tests on sandy clay. Results indicate that the calculated results agree well with the measured data. Finally a model test carried out on a half embankment in laboratory was modeled.

• Tunnel and Underground Space
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• v.6 no.2
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• pp.144-156
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• 1996

The deformation behaviors under uniaxial compressive cyclic loading were investigated for fresh rocks and freeze-thaw cycled samples. The Pocheon granite which is one of the most popular building stone in Korea was selected for tests. 0.5 Hz and 50% of dynamic strength were used as test conditions for frequency and fatigue span, respectively. For freezethaw procedure, sample were frozen for 3 hours under the temperature of -2$0^{\circ}C$ and then followed 3 hours thawing under the temperature of +2$0^{\circ}C$. Twenty seven samples were used as untreated and seventy three for freeze-thaw samples. No failure occurred up to 15000 cycles at the stress level of 60% of dynamic strength, indicating that the lowest strees level for fatigue failure may be around 60% of dynamic strength. Permanent strain and damping capacity curves show that there were three stages when rock behaves like under creep. Young's moduli were increased and Possion's ratios were decreased with the increase of the number of cycles. Possion's ratios varied more rapidly than Young's moduli did with the increase of the number of cycles. This may represent that most microcracks developed by fatigue stress are parallel to the axis of loading. The deformation behavior of freeze-thaw cycled samples were almost the same as that of untreated samples. However, the result of freeze-thaw cycled samples showed lower regression constant, indicating that the physical durability of rock is much lowered because of cyclic temperature variation.