• The Journal of Korean Academy of Prosthodontics
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• v.41 no.1
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• pp.61-70
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• 2003

The purpose of this study was to investigate the contact angles and wettability of conventional dental stones and improved dental stones and newly developed dental stones on several impression materials. Materials included in this study were several dental stones and newly developed dental stone ; 2 type III stones (Snow Rock, New Diastone), 6 type IV stones(Crystal Rock, Vel Mix, Fuji Rock, Tuff Rock, Resin Rock and newly developed dental stone) and 1 type V stone (Die Keen). Contact angles on the impression materials were measured with contact angle measuring device. Ten specimens for each material, total 180 specimens were made on void entrapment model. The two impression materials (Handae, GC) were used to produce 9 groups of die stone casts form void entrapment model. Voids in the stone casts were counted under a stereoscopic microscope. The grad for the reproduction ability of each materials on the void entrapment model was calculated from the casts by one examiner. From the experiment, the following results were obtained : 1. The newly developed stones showed smallest contact angle. Type III dental stone had larger contact angles than type IV and V stones. Contact angle was much affected by the impression materials. 2. Resin containing die materials such as Tuff Rock and Resin Rock had smallest void number than any other groups. 3. In comparing reproduction parameters, Tuff Rock and Resin Rock presented superior results, while Vel Mix showed lowest reproduction ability.

• Economic and Environmental Geology
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• v.15 no.2
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• pp.89-102
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• 1982

Several mines in Jeonnam produce the ores of having high SK number of refractoriness. Among those for 5 mines, this paper deals with the relationahip between SK number and mineral composition of the ore, and with the genesis of the deposits. 1. Byok-Song and Chon-Un Mine: Mineral compositions of the ores are chiastolite, chloritoid(monoclinic), kaolinite, sericite, diaspore, corundum, and quartz. The ores having SK number of 36 or 37, consist chiefly of chiastolite and diaspore and a little amount of kaolinite, sericite, corundum, chloritoid, and quartz. The ores having SK number of 33 or 34 consist of chloritoid, sericite, kaolinite, chiastolite, and diaspore. With increasing the amount of chloritoid and sericite, and decreasing the amount of diaspore and chiastolite, the SK number of the ores decreases. The deposit, originally high alumina-bearing shale of Chon-Un San formation, seems to be formed by contact metamorphism(forming of chiastolite), regional metamorphism(forming of monoclinic chloritoid), and hydrothermal replacement(forming of large crystal of diaspore veinlets). 2. Song-Sauk Mine: Mineral compositions of the ores are chiefly pyrophyllite and quartz and a little amount of kaolinite, dickite, diaspore, and pyrite. Many spherical inclusions containing in pyrophyllite deposits, consist chiefly of diaspore and kaolinite, The inclusions have the high SK number of 38. Amount of spherical inclusions is about 5 % to the whole pyrophyllite ores. The SK number of other pyrophyllite ore is less than 32. Quartz and pyrite are chief minerals lowering the SK number of the ore. The deposits have been formed by hydrothermal processes by replacing the siliceous tuff of Mesozoic age. Spherical inclusions consisting of diaspore and kaolinite, show the selective replacement of hydrothermal solutions to the materials of feldspar in tuff. 3. Seung-San Mine: Mineral compositions of the ores are chiefly kaolinite, dickite, diaspore, and quartz. But some part of the mine consists of alunite deposits. The ores having SK number of 35 or higher consist chiefly of kaolinite and diaspore and a little amount of quartz. With increasing the amount of quartz and decresing the amount of diaspore, the SK number of the ore decreases. The deposits have been formed by hydrothermal processes by replacing the siliceous tuff and quartz porphyry. 4. Wan-Do Mine: Mineral compositions of the ores are chiefly pyrophyllite and quartz. But some ore contains a little amount of diaspore, kaolinite, pyrite, and chloritoid. The ores having high SK number of 36 consist chiefly of diaspore and pyrophyllite. Pyrophyllite ore has a SK number of 32 or lower. Amount of quartz and pyrite decreases the SK number of ores in this mine. Rhyolite was replaced by the action of hydrothermal solutions forming the pyrophyllite deposits.

• Journal of the Geological Society of Korea
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• v.54 no.5
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• pp.513-527
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• 2018

We have carried out granulometry and component analysis on pyroclastic deposits of the Maljandeung Tuff, Ulleung Island, to interpret the eruption types and prime dynamic mechanisms. It is divided into three members in the extracaldera area, each of which comprises the lithofacies of coarse tuffs and lapillistones in the lower part, and pumice deposits in upper one. The lithofacies present quantitative evidences in the granularity and component distribution patterns. As compared to the pumice deposits, the coarse tuffs and lapillistones exhibit a relative increase in both the lithic/juvenile and the crystal/juvenile ratios, and a preferential fragmentation of the juvenile fraction. The abundance of lithics and crystals in the tuffs and lapillistones can be attributed to preferential fragmentation of the aquifer-hosting rocks due to explosive evaporation of ground water, and indirect enrichment in lithics and crystals due to removal of juvenile fines from eruptive cloud. The above data exhibit that early phreatopmagmatic phase was followed by purely magmatic fragmentation phases. The coarse tuffs and lapillistones suggest phreatoplinian eruption derived from explosive interaction of magma with ground water near the conduit, while pumice deposits indicate magmatic eruption by magmatic explosion from juvenile gas pressure. In early stage, phreatoplinian eruption occurred from explosive magma/water interaction in connecting confining water with drawdown of the magma column in the conduit; Later it shifted to plinian eruption by explosive expansion of only magmatic volatiles in intercepting water influx due to higher magmatic gas pressure than confining water pressure with rising of the magma column in the conduit.

• The Journal of the Petrological Society of Korea
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• v.25 no.1
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• pp.1-12
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• 2016

This study reports the results about the petrography of volcanic rocks in Namoo island and Namhyeongje island, off the southern coast of Busan City. The rocks in the Namhyeongje island composed of dacitic crystal-vitric welded tuff, showing phenocrysts of plagioclase, rock fragment with flow structure of elongated and flattened pumice fragments. In thin section it shows pyroclastic texture. The volcanic rocks in Namoo island are mainly dark grey-bluish dacite with phenocrysts of plagioclase and gradually changed to pink-greyish rhyodacite with auto-brecciated. In the northeastern part of the island, the volcanic rocks occurred as aggromerate with a poorly sorted mixture of blocks, lappili and ash and felsic feeder dike intrude the aggromerate. Major element composition of the volcanic rocks in Namhyeongje island and Namoo island are $SiO_2$ 73.6~74.4 wt.% and 65.5~68.3 wt.%, respectively. The volcanic rocks in these island are felsic volcanic rocks.

• Economic and Environmental Geology
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• v.18 no.4
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• pp.399-410
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• 1985

Bentonites from the Janggi Group of the Lower Miocene age from the Geumgwangdong area, Korea, have been studied for mineralogical and genetic characterization. The Janggi Group is subdivided, in ascending order, into the Janggi Conglomerate, the Nuldaeri Tuff, the Geumgwangdong Shale, the Lower Coal-bearing Formation, the Basaltic Tuff, and the Upper Coalbearing Formation. Bentonites occur as thin or thick beds in all sedimentary units of the Janggi Group, except for the Janggi Conglomerate. Significant bentonite deposits are found in the Nuldaeri Tuff, the Lower Coal-bearing Formation and the Basaltic Tuff. Bentonites consist mainly of smectite (mainly montmorillonite), with minor quartz, cristobalite, opal-CT and feldspar. Occasionally, kaolinite, clinoptilolite or gypsum is associated with bentonites. Bentonites were studied by the methods of petrographic microscopy, X-ray diffraction, thermal analysis (DT A and TG), infrared absorption spectroscopic analysis, SEM, intercalation reaction, and chemical analysis. Smectites commonly occur as irregular boxwork-like masses with characteristic curled thin edges, but occasionally as smoothly curved to nearly flat thin flakes. Most of smectites have layer charge of 0.25-0.42, indicating typical montmorillonite. Crystal-chemical relations suggest that Fe is the dominant substituent for Al in the octahedral layer and there are generally no significant substituents for Si in the tetrahedral layer. Ca is the dominant interlayer cation in montmorillonite. Therefore, montmorillonite from the study area is dioctahedral Ca-montmorillonite. Occurrence and fabrics of bentonites suggest that smectites as well as cristobalite, opal-CT and zeolites have been formed diagenetically from tuffaceous materials. The precursor of smectites is trachytic or basaltic tuff. Smectites derived from the former contain relatively more $Al_2O$ a and less $Fe_2O_3$ than those from the latter.

• The Journal of the Petrological Society of Korea
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• v.6 no.3
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• pp.166-184
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• 1997

The Wondong caldea is a deeply eroded structure that offers spectacular exposures through the core and margins of a resurgent caldera. The Wondong Tuff and the postcollapse intrusions range from medium-silica rhyolite to rhyodacite in composition and the postcollapse lava and tuff, preresurgent and resurgent intrusions also range from medium-silica rhyolite to an-desite, which jump to gap dacite composition. The continuous compositional zonations generally define a large stratified magma system in the postcollapse and resurgent magma chamber. Isotopic and trace element evidence suggest that the compositional zonations might have resulted from the differentiations from crystal fractionations of a parental andesitic magma, accompanying a little contamination from the crustal assimilations near the chamber roof and wall. But chemically and isotopically distinct late intusions might have resulted from emplacement of any different magma batch.

• The Journal of the Petrological Society of Korea
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• v.7 no.1
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• pp.27-36
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• 1998

The volcanic piles in the northern Yucheon Minor Basin area are the Hagbong basaltic rocks, the Chaeyaksan basaltic rocks, the Jusasan andesitic rocks, the Unmunsa rhyolitic rocks, and the Tertiary voicanics. Stratigraphically, from the lowermost, (1) the Hagbong basaltic rocks are composed mainly of basaltic tuff with two olivine basalt flows intercalated, (2) the Chaeyagsan basaltic rocks are predominantly in tuffs and agglomerate with 3 basaltic flow interlayers, (3) the Jusasan andesitic rocks consist of thick piles of alternated sequences of 4 andesite flows and 5 andesitic tuffs and tuffaceous sediments and (4) the Unmunsa rhyolitic rocks which embed some rhyolite and obsidian are dominant in tuffs such as ash flow and crystal welded tuff. These volcanics reveal distinguishable characteristics in petrochemistry. In discriminating by major elements, the Hagbong and the Chaeyagsan basaltic rocks are alkaline, whereas the latter is also spilitic. In comparison, the volcanic rocks of the Jusasan andesitic rocks and the Tertiary sequences are characteristically calc-alkaline although their distribution is spatially separated. On the other hand, the variations in immobile trace elements indicate that the Hagbong basaltic rocks range from alkaline to calc-alkaline and from WPB/VAB transition to VAB, whereas the Chaeyagsan basaltic rocks are calc-alkaline WPB/VAB transition type and the two others calc-alkaline VAB. In order to show such a variety in their rock series of the volcanic rocks, the environment during their magma generation, magma rising, and post-eruption alteration could be positively considered.

• The Journal of the Petrological Society of Korea
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• v.28 no.2
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• pp.111-128
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• 2019

Ulleung Island is the top of an intraplate alkalic volcano rising 3200 m from sea floor in the East Sea (or Sea of Japan). The emergent 984.6 m consist of eruptive products of basaltic, trachytic and phonolitic magmas, which are divided into Dodong Basaltic Rocks, and Ulleung, Seonginbong and Nari groups. The Maljandeung Tuff in the Nari Group consists of thick pyroclastic sequences which are subdivided into 4 members (N-5, U-4, 3, 2), generating from explosive eruptions during past 18.8~5.6 ka B.P. From chemical data, the Member N-5, phonolitic in composition, is considerably enriched in incompatible elements and REE patterns with significant negative Eu anomalies. The members 4, 3 and 2 are phonolitic to tephriphonolitic in composition, and their REE patterns do not have significant Eu anomalies. In variation trend diagrams, many elements show abrupt compositional gaps between members, and gradual upward-mafic variations from phonolite to tephriphonolite within each member. It suggests a downward-mafic zonation that were evolved into phonolitic zone in the lower part to tephriphonolitic zone in upper part of magma chamber. It is supposed that the chemical stratification generated from multiple mechanisms of thermal gravidiffusion, crystal fractionation, and gradual melting and sequential emplacement. The stratified magmas were explosively erupted to generate a small caldera during short period (11 ka B.P.). Especially both members (U-3, 2) were accumulated by gradually erupting from the upper phonoltic zone to the lower tephriphonoltic zone of the stratified chamber in 8.4 ka B.P. and 5.6 ka B.P. time, respectively.

• Geophysics and Geophysical Exploration
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• v.11 no.3
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• pp.204-213
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• 2008

This paper presents the analysis about the stability of the Pohang deep geothermal borehole drilled in 2006. Severe wellhole instability problems such as collapse and tight hole occurred in weak rocks while drilling. Optimal mud pressure (mud window) required to prevent instability problems during drilling is obtained from analysis on in-situ stress and rock strength. The window is bounded by vertical stress in its upper limit and by either collapse pressure or pore pressure in its lower limit. Mud window varies with different types of rocks. In the top-most semi-consolidated mudstone formation, no mud window can secure borehole stability. In some weak rock types (basic dyke and crystal tuff), the borehole pressure needs to be higher by $50{\sim}60%$ than hydrostatic pressure. That means a mud density of 1.5 g/$cm^3$ or higher should be applied during drilling in order to prevent excessive collapse around the borehole.

• Journal of the Mineralogical Society of Korea
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• v.23 no.4
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• pp.377-393
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• 2010

Pumiceous tuffs occurring in the Beomgockri Group are examined applied-mineralogical characteristics and their controling factors to evaluate their potentials as the adsorption-functional mineral resources. The pumiceous tuffs are diagenetically altered to low-grade zeolitcs and bentonites in the Janggi area. Compositional specialty due to the presence of pumice fragments induces the altered tuffs to exhibit the characteristic adsorption property combined with cation exchange capacity, specific surface area, and acidic pH. Unusual lower pH in the adsorption-functional mineral substances is turned out to be originated from the presence of H-smectite having $H^+$ in the interlayer site of the sheet structure. On account of disordered crystallinity resulting from the exchanged $H^+$ in the interlayer site, the smectite commonly forms crenulated edges in the planar crystal form and exhibits characteristic X-ray diffraction patterns showing comparatively lower intensities of basal spacings including (001) peak than conventional Ca-smectite. Based on the interpretation of paragenetic relations and precursor of the H-smectite, a genetic model of the peculiar clay mineral was proposed. The smectite formation may be facilitated resulting from the precipitation of opal-CT at decreasing pH condition caused by the release of H+ during diagenetic alteration of pumice fragments. Because of the acidic smectite, the low-grade mineral resources from the Beomgockri Group may be applicable to the adsorption industry as the raw materials of acid clays and bed-soil.