• Title/Summary/Keyword: crystal base

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A Fast Response Smectic LCD using Induced Polarization

  • Mochizuki, Akihiro
    • Journal of Information Display
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    • v.6 no.3
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    • pp.6-11
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    • 2005
  • In this paper, a general performance of the PSS-LCD or Polarization Shielded Smectic Liquid Crystal Display is discussed. This smectic base LCD does not use any spontaneous polarization, but uses induced polarization just sa me with current nematic base LCDs. Specific initial molecular alignment as well as specific cell design realizes ext remely fast optical response speed with native wide viewing angle. Moreover, this performance is provided by full compatible electronics for current conventional LCDs. A general performance of the PSS-LCD is introduced herein.

A General Performance of PSS-LCDs

  • Mochizuki, Akihiro
    • 한국정보디스플레이학회:학술대회논문집
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    • 2005.07a
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    • pp.91-96
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    • 2005
  • In this paper, a general performance of the PSS-LCD or Polarization Shielded Smectic Liquid Crystal Display is discussed. This smectic base LCD does not use any spontaneous polarization, but uses induced polarization just same with current nematic base LCDs. Specific initial molecular alignment as well as specific cell design realizes extremely fast optical response speed with native wide viewing angle. Moreover, this performance is provided by full compatible electronics for current conventional LCDs. A general performance of the PSS-LCD is introduced here.

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The formation of $\beta$-quartz solid silution in lithiu alumino silicate glasses (Lithium Alumino Silicate계 유리에서 알카리 토류 첨가에 따른 $\beta$-quartz고용체의 형성에 관한 연구)

  • Kim, Byeong-Il;Gang, Won-Ho
    • Korean Journal of Materials Research
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    • v.4 no.6
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    • pp.611-619
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    • 1994
  • The formation of , $\beta$-quartz solid solution in the $LiO_2-Al_2O_3-SiO_2$glasses containing $TiO_{2}$ and $ZrO_{2}$ as nucleating agents was investigated for various temperatures and times. Linear thermal expansion coefficients of base glasses and crystallized glasses were $45\sim 55 \times 10^{-7} \textrm{cm}/^{\circ}C$ and $ -8\sim +8 \times 10^{-7}\textrm{cm}/^{\circ}C$ ($25^{\circ}C \sim 525^{\circ}C$), respectively. The crystal phase formed by heat-treatment below $900^{\circ}C$was , $\beta$--quartz solid solution, and the crystal sizes were less than 0.21m. On the other hand, the crystal size of the base glasses containing 3.5 wt% MgO is relatively uniform and is independent with temperature. The specimen containing 3.5 wt% ZnO shows a minimum crystal size(O.l8$\mu \textrm{m}$), and it strongly depends on temperature of heat-treatment.

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Synthesis of nanosize $SiO_2$particles by a reverse micelle and sol-gel processing

  • Bae, Dong-Sik;Han, Kyong-Sop;James H. Adair
    • Journal of the Korean Crystal Growth and Crystal Technology
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    • v.11 no.2
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    • pp.67-70
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    • 2001
  • Nanosize $SiO_2$composite particles have been synthesized within reverse micelle via metal alkoxide hydrolysis and condensation. The size of the particles can be controlled by manipulating the relative rates of the hydrolysis and condensation reactions of tetraethoxysilane (TEOS) within the microemulsion. The average size of synthesized particles was about in the size range 14~30nm. The effects of synthesis parameters, such as the molar ratio of water to TEOS, the molar ratio of water to surfactant, and the amount of base catalyst, are discussed.

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The Study on Solid-State Reaction Between MgO Single Crystal and $Fe_2O_3$ Powder (단결정 MgO와 분말 $Fe_2O_3$간의 고상 반응 연구)

  • 김성재;박재우
    • Journal of the Korean Ceramic Society
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    • v.32 no.2
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    • pp.234-238
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    • 1995
  • MgFe2O4 formation, grain growth in Fe2O3, Fe solid-solution limit in MgO for MgO-Fe2O3 mixture were studied by means of investigating the distribution of phases and compositions in reaction area between MgO and Fe2O3. The reaction area at equlibrium was composed with MgO-FexO matrix and MgFe2O4 precipitation, MgFe2O4 was formed by precipitating from MgO-FexO matrix dependent on oxygen partial pressure. Fe contents was exponentially decreased with diffusion distance in MgO single crystal, and thus Fe solid-solution limitation in MgO was about 4mol%. The grain growth rate in Fe2O3 base was increased with Mg contents diffused from MgO single crystal.

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Development of Mechanical Properties of Ni-based Superalloy for Land-based Gas Turbine (산업용 가스터빈 블레이드용 초내열합금의 기계적 특성 향상에 관한 연구)

  • Chun, C.H.;Kim, G.M.;KIM, D.S;Jang, J.C;Kim, J.C.
    • Journal of Power System Engineering
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    • v.7 no.3
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    • pp.18-22
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    • 2003
  • A Study has been made to investigate the effects of hot isostatic press(HIP) and post-HIP heat treatment on microstructures and mechanical properties of Ni-based single crystal superalloy CMSX-4. HIP process was found to heal and close micropores significantly, but did not affect the morphologies of. The elimination of as-cast micropores obtained by HIP process resulted in improved stress-rupture lives of Ni-base single crystal superalloy by 185%.

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Fabrication of Large-Area Photovoltaic Crystal with Modified Surface Using Trimethoxysilyl Propyl Methacrylate (TMSPM) for Solar Cell Protection

  • Kang, Kwang-Sun
    • Current Photovoltaic Research
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    • v.2 no.3
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    • pp.84-87
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    • 2014
  • Protection of solar cell surface is important to prevent from dust, pollen, sand, etc. Therefore, development of large area antifouling film is urgent for high performance of solar cells. The surface of silica spheres was modified to fabricate large area antifouling film. The surface of monodisperse silica spheres has been modified with 3-(trimethoxysilyl) propylmethacrylate (TMSPM) to fabricate large area photonic crystal. Although the surface modification of silica spheres with TMSPM has been failed for the base catalyst, the second trial using acid catalyst showed the following results. The FTIR absorption peak at $1721cm^{-1}$ representing C=O stretching vibration indicates that the TMSPM was attached on the surface of silica spheres. The methanol solution comprised of the surface modified silica spheres (average diameter of 380 nm) and a photoinitiator was poured in the patterned silicon wafer with the dimension of 10 cm x 10 cm and irradiated UV-light during the self-assembly process. The result showed large area crack and defect free nanostructures.

The Structure and Ab Initio Studies of Thiourea Dioxide

  • 송진수;김은희;강성권;윤석성;서일환;최성산;이삼근;William P. Jensen
    • Bulletin of the Korean Chemical Society
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    • v.17 no.2
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    • pp.201-205
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    • 1996
  • The crystal and molecular structure of thiourea dioxide, (NH2)2CSO2, was determined by x-ray single crystal diffraction techniques. Lattice constants are a=10.669(2), b=10.119(2), and c=3.9151(5) Å with the space group Pnma and Z=4. The thiourea portion of the molecule has a planar conformation. When the two oxygen atoms are included, the sulfur atom is at the apex of a trigonal pyramid formed with the two oxygen atoms and the carbon atom as the base. The crystal structure is stabilized by strong intermolecular hydrogen bonds. Ab initio calculations were performed to investigate the bonding features and reactivity of thiourea dioxide. The calculated bond order of S-C is only 0.481. The hydrogen bond energy was computed to be 22.3 kcal/mol for dimer. MEP analysis reveals that the sites on nucleophilic reactions are S and C atoms.

Structures and Magnetic Properties of Monomeric Copper(II) Bromide Complexes with a Pyridine-Containing Tridentate Schiff Base

  • Kang, Sung Kwon;Yong, Soon Jung;Song, Young-Kwang;Kim, Young-Inn
    • Bulletin of the Korean Chemical Society
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    • v.34 no.12
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    • pp.3615-3620
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    • 2013
  • Two novel copper(II) bromide complexes with pyridine containing Schiff base ligands, $Cu(pmed)Br_2$ and $Cu(pmed)Br_2$ where pmed = N'-((pyridin-2-yl)methylene)ethane-1,2-diamine (pmed) and dpmed = N,N-diethyl-N'-((pyridin-2-yl)methylene)ethane-1,2-diamine (dpmed) were synthesized and characterized using X-ray single crystal structure analysis, optical and magnetic susceptibility measurements. Crystal structural analysis of $Cu(pmed)Br_2$ showed that the copper(II) ion has a distorted square-pyramidal geometry with the trigonality index of ${\tau}=0.35$ and two intermolecular hydrogen bonds, which result in the formation of two dimensional networks in the ab plane. On the other hand, $Cu(pmed)Br_2$ displayed a near square-pyramidal geometry with the value of ${\tau}=0.06$. In both compounds, the NNN Schiff base and one Br atom occupy the basal plane, whereas the fifth apical position is occupied by the other Br atom at a greater Cu-Br apical distance. The reported complexes show $g_{\mid}$ > $g_{\perp}$ > 2.0023 with a $d_{x2-y2}$ ground state and a penta-coordinated square pyramidal geometry. Variable temperature magnetic susceptibility measurements showed that the developed copper(II) complexes follow the Curie-Weiss law, that is there are no magnetic interactions between the copper(II) ions since the Cu--Cu distance is too far for magnetic contact.